5102 5102

2 : ..
: (2)
22 : 2215

2

1

( 13)
.... ....

7( : 1)

-I

Np

239
93

. AZ Pu

.1

Np

.2

.3

Np

.4

Mev Np
Ln m 0 m .t : : m 0 t 0

.5

A Z . Pu

239
93

(1)

(2.5)
239
. 93

(2.75)
239
. 93

(2.75)

m t .

.6

Ln m 0 m

(2.5)

.1-6 .
.2-6 t 1 .

(2.25)
(2.25)

.3-6 t 1 2 Np
.7

239
. 93

0,1

(1.25)

0,25

) . m (m 0

t 1 )100

-II .
12
) 6 C ( 12 ) C ( 14 .
14
6

)1
)2

C :
C

14
6

12
6

)t (jours
14
6

(1)

(2.75)

1 u 931,5 Mev.c 2 :

) (u

Np

239
93

239,07668

Pu

A
Z

239,00063

5,5.10 4

12
6

12

14,0032

6( :2)

C = 10 F R
K . t = 0
1 ) U(t 1.5( .)

2 + B :

U(t) = A

B A k.
2.1 B A k ) U(t .
2.2 ) i(t )q(t .

(1)
(1.5)

3 ) U(t .
3.1 . RC

(1)

.R

(1)

14
6

1
1

1,00727

1
0

1,00866

7( :)
: ( ) .

.30 cm
( ) .HCOOH
.
:
M(O)=16g/mol ; M(H)=1g/mol ; M(C)=12g/mol : - ( 25C ):

H3O 35,0.103 S.m.mol 1 HCOO 5,46.10 S.m.mol 1

-1 V0=100mL m
. S0 . C0=0,01mo.L-1
-1-1 . m

)(0.5pt

-2-1 .

)(0.5pt

-3-1 C0 V0 xeq xeq .

)(0.75pt

-4-1 H3O+ . C0

)(0,5pt

-5-1 . Qr, eq
2
[H 3O ]q

-2

Co [H 3O ]q

:
q
HCO

-3

Q r ,eq

S0

H 3 O

)(0.75pt

0, 051 S.m . 25C

-1-3
(0.75pt) .
-2-3 K (0,5pt) .
-4

)(0.75pt

S1 =C1
.0,10mo.L-1 .

So

S1

)Ci(mol/L

0,010

0,10

(S.m-1)q

0,051

0,17

..........

:
-

4,2.10

(0,25pt) .

- (0,25pt) .
- pH (0.75pt) S0
-5

-3

K
K

pH

10

(%)

..........

4,2

Qr,q

..........

1,8.10-4

. (0.75) .