UBND TNH TIN GIANG

S GIO DC V O TO
chnh thc
M 208

CNG HA X HI CH NGHA VIT NAM

c lp T do Hnh phc

K THI TUYN SINH LP 10

Kha ngy 01 thng 7 nm 2010

Mn thi: HA HC CHUYN
Thi gian: 120 pht (Khng k thi gian giao )

Cho bit: H = 1, C = 12, N = 14, O = 16, Mg = 24, S = 32, Fe = 56, Cu = 64, Br = 80,
Ba = 137, Al=27, Na=23, P=31,Ca=40, Zn=65, Ag=108, Cl = 35,5.
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I. PHN T LUN (6 im ):
Bi 1: (1,5 im)
1. Vit phng trnh ha hc ca cc phn ng xy khi cho NaHSO4 tc dng vi cc dung dch:
NaHCO3, BaCl2, Na2S.
2. Ha tan hon ton 6,66 gam tinh th Al2(SO4)3.nH2O vo nc thnh dung dch A. Ly

1
10

dung dch A cho tc dng dung dch BaCl2 d th thu c 0,699 gam kt ta. Xc nh cng thc
ca tinh th mui nhm.
Bi 2: (1,5 im)
1. T than , vi, H2O, NaCl (cc cht xc tc thch hp) vit cc phng trnh phn ng
iu ch nha polivinylclorua (PVC).
2. Nu hin tng v vit phng trnh ha hc ca cc phn ng xy ra khi cho:
a. Na vo C2H5OH.
b. Dung dch CH3COOH vo dung dch Na2CO3.
Bi 3: (1,5 im) Ha tan m gam hn hp A gm Al v kim loi R (ha tr II v ng trc hidro
trong dy hot ng ha hc ca kim loi) bng 2 lt dung dch HCl 0,5M thy thot ra 10,08 lt kh
H2 (ktc) v dung dch B.
1. Vit phng trnh ha hc ca cc phn ng xy ra v chng minh hn hp A tan hon ton.
2. Trung ha dung dch B bng dung dch NaOH c dung dch D. C cn dung dch D th
c 46,8 g mui khan. Tnh m v xc nh tn kim loi R, bit trong hn hp A s mol ca R bng
75% s mol Al.
Bi 4: (1,5 im) t chy hon ton m gam hirocacbon X thu c 17,92 lt CO2 ( ktc) v
14,4 gam H2O. Mt khc, m gam hirocacbon X c th lm mt mu va dung dch cha 0,4
mol Br2. Hirat ho hirocacbon X trong iu kin thch hp thu c mt cht hu c Y.
1. Vit phng trnh ha hc ca cc phn ng xy ra v xc nh cng thc phn t ca Y.
2. T Y c th tng hp c polime T theo s : Y Z T (vi Z l mt hirocacbon kh
iu kin thng, cha 88,89% cacbon v khi lng). Vit phng trnh ha hc ca cc phn ng
xy ra theo s trn (ghi r iu kin nu c).

II. PHN TRC NGHIM (4 im):

Cu 1: Trung ha hon ton 3,6g mt axit n chc cn dng 25g dung dch NaOH 8%. Cng thc
ca Axit l
A. CH3-COOH
B. CH2=CH-COOH
C. C3H7-COOH
D. HCOOH
Cu 2: Cho cc phn ng sau:
a) Lng nh Na vo dung dch CuSO4
b) Cho Fe vo dung dch CuSO4
c) Cho Fe vo dung dch ZnSO4
d) Cho Cu vo dung dch FeSO4
C bao nhiu trng hp khng c kim loi sinh ra?
A. 3
B. 1
C. 2
D. 4
Cu 3: t chy hon ton hn hp gm C2H6 v C2H2 thu c CO2 v nc, c t l s mol 1:1.
Thnh phn % theo th tch ca mi kh trong hn hp ban u l
A. 50% v 50%
B. 25% v 75%
C. 30% v 70%
D. 40 v 60%

Trang 1/2 - M thi 208

Cu 4: Khi cho dung dch Ba(OH)2 d vo dung dch cha FeCl2, CuSO4, AlCl3 thu c kt ta.
Nung kt ta trong khng kh n khi lng khng i thu c cht rn X. Cht rn X gm
A. FeO, CuO, Al2O3
B. Fe2O3, CuO, Al2O3, BaSO4
C. Fe3O4, CuO, BaSO4
D. Fe2O3, CuO, BaSO4
Cu 5: Hn hp X gm hidrocacbon B vi H 2 , c dX/H2 = 4,8. Cho X i qua Ni nung nng n phn ng
hon ton c hn hp Y c dY/H2 = 8 . Cng thc phn t ca hidrocacbon B l
A. C3H6
B. C2H2
C. C3H4
D. C4H8
Cu 6: Cho cc cht sau : CaCO3, (NH4)2SO4, NaH2PO4, FeCO3, Ca(HCO3)2. C bao nhiu cht tc
dng c vi dung dch NaOH ?
A. 3 cht
B. 4 cht
C. 2 cht
D. 5 cht
Cu 7: Cho 4 gam hn hp X gm Mg, Al, Zn, Fe tc dng vi dung dch HCl d gii phng 2,24
lt kh (ktc). Mt khc, cho 2 gam X tc dng ht vi kh clo d thu c 5,763 gam hn hp
mui. Thnh phn phn trm khi lng Fe trong X l
A. 14%
B. 19,2%
C. 16,8%
D. 22,4%
Cu 8: Cho m gam hn hp gm Na v Al vo nc d, sau khi phn ng kt thc thu c 8,96 lit
kh H2 (ktc) v 5,4 gam cht rn. Gi tr ca m l
A. 10,8g
B. 15,4g
C. 10,0g
D. 12,7g
Cu 9: Trong cng nghip, phn ln supephotphat kp c sn xut theo s sau:
Ca3(PO4)2
H3PO4
Ca(H2PO4)2
Khi lng dung dch H2SO4 70% dng iu ch c 234 kg Ca(H 2PO4)2 theo s bin
ho trn l bao nhiu? Bit hiu sut ca c qu trnh l 80%.
A. 396 kg
B. 350 kg
C. 300 kg
D. 260 kg
Cu 10: Hn hp X gm a mol C2H2 v 0,4 mol H2. Nung nng hn hp X vi xc tc Ni thu c
hn hp Y. Dn Y vo bnh ng dung dch AgNO 3 d trong NH3 thu c 0,05 mol C2Ag2. Hn
hp kh Z bay ra c dn vo dung dch Br 2 d, thy c 0,2 mol Br 2 phn ng. Kh thot ra khi
bnh ch cha mt cht hu c duy nht. Gi tr ca a l
A. 0,35 mol
B. 0,4 mol
C. 0,45 mol
D. 0,5 mol
Cu 11: t chy hon ton cc ankan trong cng dy ng ng thu c CO 2 v H2O, vi t l
VCO2
th tch
= T (trong cng iu kin) khong bin thin ca T c th l
VH 2O
A. 0,5 T < 1
B. 0,5 T 1
C. 0 < T < 1
D. 1 < T < 2
Cu 12: Crackinh C4H10 thu c hn hp ch gm 5 hirocacbon c t khi hi so vi H2 l
16,325. Hiu sut phn ng crackinh l
A. 17,76%
B. 38,82%
C. 16,325%
D. 77,64%
Cu 13: Cho s chuyn ha sau: Tinh bt X Y axit axetic. X, Y ln lt l
A. Saccaroz, glucoz
B. Glucoz, etylaxetat
C. Etylen, ru etylic
D. Glucoz, ru etylic
Cu 14: Chia hn hp X gm C2H6, C2H4, C2H2 thnh hai phn bng nhau. t chy phn (I), dn
sn phm chy vo dung dch nc vi trong d, thu c 10 gam kt ta trng. Hiro ha phn (II)
ri t chy, dn sn phm chy qua bnh ng H2SO4 c. Cc phn ng u xy ra hon ton.
Khi lng bnh ng H2SO4 c tng ln l
A. 1,8 gam
B. 3,6 gam
C. 2,7 gam
D. 5,4 gam
Cu 15: Thi V lt CO2 (ktc) vo 300 ml dung dch Ca(OH)2 0,02M th thu c 0,2 gam kt ta.
Gi tr ca V l
A. 44,8 ml hoc 224 ml
B. 224 ml
C. 44,8 ml
D. 44,8 ml hoc 89,6 ml
Cu 16: Mt loi than dng cho mt nh my nhit in c cha 2% lu hunh. Nu mi ngy
nh my t ht 100 tn than th trong mt nm (365 ngy) khi lng kh SO2 x vo kh quyn l
A. 1420 tn
B. 1250 tn
C. 1460 tn
D. 1530 tn
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