TM TT LUN VN THC S

Tn ti: Nghin cu ch to mng chng thm trn c s hn hp cht kt dnh

bt polymer ti phn tn v xi mng PCB
Tc gi lun vn: Nguyn Tin Dng

Kha: 2013B

Ngi hng dn khoa hc: 1. PGS.TS. Bch Trng Phc

2. TS. Trnh Minh t
Tm tt ni dung lun vn
a) L do chn ti
Hin nay, cc loi vt liu chng thm truyn thng gc bitum nh sn v tm tri
chng thm ngy cng cho thy s bt cp nh: gy nhim mi trng v rt c
hi; qu trnh thi cng phc tp, tiu tn nhiu thi gian, nhn cng, c th nh hng
n tin cng trnh v i khi gy ra chy n. Trong khi , vt liu chng thm
gc xi mng - polyme c rt nhiu u im ni tri nh: kh nng chng thm nc v
kh nng khng li thi tit rt tt, khng c hi, khng gy chy n, c th d dng thi
cng c trn cc loi b mt vi hnh dng phc tp. Hn na, vt liu chng thm gc
xi mng - polyme c th c thi cng ngay c trn b mt nn m t, do rt ngn
c thi gian thi cng, gim chi ph xy dng.
Trc nhu cu s dng v yu cu ngy cng cao ca th trng i vi h thng
vt liu chng thm th vic nghin cu v ch to thnh cng Mng chng thm
trn c s hn hp cht kt dnh bt polymer ti phn tn v xi mng PCB thn
thin vi mi trng, gp phn nng cao cht lng v tng kh nng qun l cht
lng cng trnh, lm ch c cng ngh, c gi thnh ph hp l rt cn thit.
b) Mc ch nghin cu ca lun vn, i tng, phm vi nghin cu
* Mc ch nghin cu ca lun vn
Nghin cu v ch to thnh cng mng chng thm mt thnh phn trn c s hn
hp cht kt dnh bt polyme ti phn tn v xi mng poc lng hn hp PCB t
c mc ch tiu cht lng di y:

TT

Ch tiu cht lng

Cng bm dnh:
- iu kin tiu chun
- Sau khi ngm trong nc
1
- Sau khi lo ho nhit
- Sau chu k bng gi
- Sau khi tip xc vi nc vi
- Sau khi tip xc vi nc clo
Kh nng to cu vt nt:
2
iu kin tiu chun
nhit - 50 C
3
chng thm nc
* i tng v phm vi nghin cu:

n v

N/mm2

mm
-

Mc cht
lng cn t
0,5
0,5
0,5
0,5
0,5
0,5

Phng php
th

BS EN 14891 2007

0,75
0,75
Khng thm

Nghin cu v ch to thnh cng mng chng thm mt thnh phn trn c s

bt polyme ti phn tn v xi mng poc lng hn hp PCB thn thin mi trng.
c) Tm tt cc ni dung chnh ca lun vn
- Nghin cu la chn loi v hm lng cht kt dnh s dng;
- Nghin cu la chn loi v hm lng cc ph gia cng ngh: ph gia silicafume;
ph gia gim nc; ph gia ph bt; Nghin cu cu trc vt liu;
- Thit lp quy trnh cng ngh sn xut mng chng thm quy m pilot.
d) Phng php nghin cu
Phng php tiu chun: Xc nh cng bm dnh; kh nng to cu vt nt v
chng thm nc ca mng di p lc thy tnh 150 kPa theo tiu chun BS EN
14891:2007.
Phng php phi tiu chun: S dng cc k thut phn tch: ph hng ngoi IR;
phng php phn tch nhit (TG/DTA) v cu trc ca vt liu bng phng php
knh hin vi in t qut (SEM).
e) Kt lun:
* ti nghin cu la chn c cp phi thch hp ch to mng chng thm
t cc ngun nguyn liu c sn trong nc v mt s ph gia khc ca nc ngoi
vi t l sau:
+ Xi mng PCB40 Nghi Sn: 42,00 %KL;

+ Ct trng Qung Bnh (c dmax = 0,315mm): 42,00 %KL;

+ Bt polyme ti phn tn Vinapas 7055N: 13,40 %KL; SF Grade 940U: 2,50 %KL;
+ Ph gia siu do polycarboxylat Melflux 2641F: 0,06 %KL;
+ Ph gia kh bt Vinapor DF 9010F: 0,04 %KL.
* Cht lng sn phm mng chng thm ca ti t v vt mc yu cu t ra.
* Cc ng cong TG thu c cho thy hng c trng trong bin tnh va xi mng
thng thng bng polyme. S c mt ca terpolyme trong thnh phn ca hn hp
va lm gim lng nhit thy ha ca xi mng PCB.
* S c mt Terpolyme ca vinyl axetat, vinyl este v etylene gy ra nhng s
thay i nht nh trong ph hng ngoi IR ca va xi mng bin tnh, ngoi tng tc
c th c gia nhm anion axetat hnh thnh khi terpolyme b thy phn trong mi
trng kim v ion Ca2+ to ra t s hyrat ha cc khong C2S v C3S trong xi mng
poc lng hn hp PCB th vic b sung terpolyme lm gim mnh s hnh thnh
khong portlandite, t lm cu trc vt liu c chc hn.
* Cc hnh nh ca vi cu trc thu c bng knh hin vi in t qut SEM cho
thy s hnh thnh ca hai mng li khc nhau, hu c v v c. iu ny cho php
chng ta gi nh rng trong qu trnh hyrat ha, phn a nc ca polyme hng ti
pha nc trong khi phn k nc hng ti pha kh (l rng v cc mao mch khng
ly nc). Sau khi kh, nc c ly i, cc ht k nc kt hp li vi nhau v hnh
thnh mt mng li vng chc.
* Vt liu mng chng thm c th s dng trong cc mi trng xm thc nh
nc clo v nc vi nng cho php.
H Ni, ngy

thng

nm 2014

Ngi nhn xt
Hng dn 1

PGS. TS. Bch Trng Phc

3

Hng dn 2

TS. Trnh Minh t