Here listed 3 ways to remove Windows XP saved network password for your reference:

Method 1
Disconnect all connected network disk from NAS.

Method 2
Open a DOS prompt, using net use to list all account for windows keeping, using net use
\\IP\folder /delete or net use DriverLetter /delete to delete.

Method 3:
Delete the Manage my network passwords from User Accounts or open a DOS prompt
and using rundll32.exe keymgr.dll, KRShowKeyMgr to delete current users password.
3-1 From User Accounts:
Start -> Control Panel -> User Accounts

3-2 Open a DOS prompt and using rundll32.exe keymgr.dll, KRShowKeyMgr to delete
current users password: