Manejo de datos:

1 Parte.

Ti H2O f = 19 C.
Teq= 42.5 C.
Ti H2O c = 77C.

Q ced+ Qabs =0.

Q H2O c + Q H2O f+ QK=0.

Q H2O c = m H2O * c esp * d T H2O c.

= (100g H2O c)(1cal/g)(42.5 C - 77 C)= -3450 cal c.

Q H2O f = m H2O * c esp * d T H2O f.

=(100g H2O c)(1 cal/g)(42.5C - 19C)= 2350 calc.

Qk =- (Q H2O c +Q H2O f).

= -(-3450 cal + 2350 cal)= 1100 calc.

QK= mk*c esp*dTk.

k= (QK)/ D Tk.
=1100 cal / (42.5 C - 19C)= 46.80 cal / C.
k= 46.80 cal/ C

2 Parte
T amb= 20.8 C.
T 6 += 26.8 C.
Agua ambiente.

Tiempo (seg)
0.5
1
1.5
2
2.5
3
3.5
4
4.5
5
5.5
6
6.5
7

Temperatura
(C)
26.3
26.1
26
26
26
26
25.9
25.9
25.9
25.9
25.5
25.5
25.5
25.5

Tinicial=25.5
Datos de la mezcla:
masa del hielo: 23.54 g

Tiempo (seg)
0.15
0.30
0.45
1
1.15
1.30
1.45
2
2.15
2.30
2.45
3
3.15
3.30

Temperatura (
C)
20.3
23
17.9
16.9
15.9
15.7
15.2
15
14.8
14.8
14.7
14.7
14.6
14.6

Q ced + Q abs = 0.

Tiempo (seg)
3.45
4
4.5
5
5.30
6
6.30
7
7.30
8
8.30
9
9.30
10

Temperatura
(C)
14.6
14.6
14.6
14.6
14.6
14.7
14.7
14.7
14.7
14.8
14.8
14.8
14.9
14.9

H2O 6+

+Qk +Q hielo + Q H2O hel =0.

Q hielo = -(Q k + Q H2O hel + Q H2O 6+).

Q H2O 6+= m H2O 6+ * c esp H2O * D T H2O 6+.

= (175 g)(1 cal/ g)(16.2 - 26.8 C)= - 1855 cal.

Q H2O hel = m H2O hel * c esp H2O * D T H2O hel.

= (23.54 g)( 1 cal/g)(16.2 - 0C)= 381.34 cal

Qk= k* D T0k

=(46.80 cal/C)(16.2 C - 25.5 C)= -435.24 cal

Q hielo = -(Q k + Q H2O hel + Q H2O 6+).

= - (-1855cal-435.24cal+381.34cal ) = 1908.9cal

L= Q hielo / m hielo
= 1908.9cal/23.54g = 81.091 cal/ g
% error
(valor teorico - valor experimental) / valor teorico x 100
=(80 cal/ g - 81.09 cal / g) / 80 cal / g x 100 = 1%