5.13 As indicated in the problem statement the basic differential equations are: dW ~dQy—dQc=0 a) Qu __ Tn -= (By dQc~ Te where Qc and Qy refer to the reservoirs. 63 (@) With 4Qy =CydTy and dc {ATe, Eq. (B) becomes: Cite Te Me Gate 7 T: % Whence dine = Vala hers Integration from Ty, and Te, t0 Ty and Te yields Te T™\* or q TH)" tla ent (i (0) With dQu = CydTx and dQc = CedTe. Eq. (A) becomes: dW = Cydty + Chae Integration yields W = C4 (Tu ~ Ti) + CHTe~Tes) Eliminate 7 by the boxed equation of Part (a) and rearrange slighy: (c) For infinite time, Ty, = Te = Tand the boxed equation of Part (a) becomes: ryt Tm)" rera(z,) =t%(#) ‘From which: e Tea(Tm)* T= TaOPT)? and Feamomeranenes Because W/W 4 1)— 1 = =1/8 41), hem L-(®) m (Z)-(®) Tn Tay, The, Ty [Because Ty = substitution ofthese quantities in the boxed equation of Part (b) yields van EranRroblem 2 The process involves three heat reservoirs: the house, a heat sink; the furnace, a heat source; and the surroundings, a heat source. Notation is as follows: 10] Heat transfer to the house at temperature T 1Qr| Heat transfer from the furnace at Tr 1Q.| Heat transfer from the surroundings at 7, ‘The first and second laws provide the two equations: Ql 1Qrl _ 120! 101 =1rl+1Qo1 and Th t Combine these equations to eliminate |Qal, and solve for |r|: T-T, \ Tr \or\=19(Z=2) = With T =295K Tr = 810K T, =265K and |Q| = 1000 ks The result is: 1Orl akI ‘Shown to the right is a scheme designed to ac- a complish this result. A Camot heat engine op- FURNACE @ 7) | erates with the furace as heat source and the hhouse as heat sink. The work produced by the en- gine drives a Camot refrigerator (reverse Camot engine) which extracts heat from the surround- ings and discharges heat to the house. Thus the heat rejected by the Carnot engine (|Q,|) and by the Camot refrigerator (| Q2|) together provide the heat [QI for the house. The energy balances for the engine and refrigerator are: (Wleagine = |Or1—1O11 [Wheetie = 1921 —1Qa1 Equation (5.7) may be applied to both the en; aera een ma oe aaaeemee |1Qr| _ Tr 1Qol _ To lol” 10.1 T Combine the nwo pairs of equations: : tr , T, aim = 1011 (F = UW lesis = 1a (\-#)=121 ‘Since these two quantities are equal, Ty -T T-T Tr —T 1ou lo: or 1021 = 10 Because the total heat transferred to the house is |Q| = |Qi| + |Qzl. h-T Tr-T Tr -To l9l= lol + lou toui(+ =) TT. Tr T (lr -To Bur [O11 = |r whence lal= lorta ( Tas ) Solution for |Or| yields the same equation obtained more easily by direct application of the two laws of thermodynamics to the overall result of the process.Homework 3 10 kmol/ne ave Hvattled From 25°C 10 bar —> 1.2 bar dead op Ce YR 4) downstream T more nfo om thnttte Horie 1S well invited + @ resi pos > p.Bo PE, KE changes ont nepal, no Phd work, Steady state energy balance, (eqn 2.320) at BE ath ope? ah=0 cunettle meand igunttalpie (aH=d) . for an weal gen, ate( Gar s0 > -T:0 T, so =T, Ts 25 +243 =|248 KHomewo(R 3 b) AS (a) Ewimpy hunge op am tal gas ce eho 5 cy Slt 8 R Ale 2 - 1.5, als Cod aS= ERE - ROE Wey ate be aS = - (60H 2) 2n( mol K C) Be vate A ewhropy guration — (%e) endropy, balance ee a S (Sm) po + ft _ = §, 20 j sey well srsviabd Hwesttte. prouss mAS 2S, | 10 kmel tne tn a+g Knol fa = 10 kmol Line LM = 9.00794 Enel Constant hr @min GOS s m= 2.48 mol/s (2.48 wal(inere a) 28, KHomework 3 A) Lest work if Sureurdines ok 20% “r= 204143 2293 K for sige warandings T, Wye = TS, Mag (293 K)(48.4 004 w)snana Wore Wose prom eqn 88 prett-unsadd Whose = TAS. -f! Whost = (293 KFWB 4) Wise 2 e165 x10 wo