p(kPa)

x1
19.953
39.223
42.984
48.852
52.784
56.652
60.614
63.998
67.924
70.229
72.832
84.562

y1
0
0.1686
0.2167
0.3039
0.3681
0.4461
0.5282
0.6044
0.6804
0.7255
0.7776
1

ln 1
0
0.5714
0.6268
0.6943
0.7345
0.7742
0.8085
0.8383
0.8733
0.8922
0.9141
1

0.452339
0.385457
0.277516
0.219558
0.150729
0.092747
0.048507
0.030503
0.021106
0.012398
0

x2

y2
1
0.8314
0.7833
0.6961
0.6319
0.5539
0.4718
0.3956
0.3196
0.2745
0.2224
0

ln 2
1
0.4286
0.3732
0.3057
0.2655
0.2258
0.1915
0.1617
0.1267
0.1078
0.0859
0

0
0.013297
0.026047
0.072527
0.105712
0.146213
0.209479
0.270811
0.299762
0.323708
0.343482

GE/RT
0
0.087319
0.103931
0.134823
0.147619
0.148228
0.147821
0.13645
0.116558
0.10417 90
0.086031 80
0 70
60
50
P/kPa

40
30
20
10
0
0

0.1

GE/x1x2RT
0.622935
0.612292
0.637325
0.634641
0.599883
0.593171
0.570682
0.536007
90
0.523074
80
0.497468
70

P-x1

60
50
P/kPa

40

x1

P-y1

30

y1

20
10
0
0

0.1

0.2

0.3

0.4

0.5
x1,y1

0.6

0.7

0.8

0.9

T=
p1sat=
p2sat=

333.13K
84.562kPa
19.953kPa

experimental data
p(kPa)
x1
x2
19.953
0
39.223
0.1686
42.984
0.2167
48.852
0.3039
52.784
0.3681
56.652
0.4461
60.614
0.5282
63.998
0.6044
67.924
0.6804
70.229
0.7255
72.832
0.7776
84.562
1

calculated (wilson)
ln 1
1
ln 2
2
y1
Pcalc
y1calc
y2calc
1
0 0.865136 2.375328
0
1
19.953
0
1
0.8314
0.5714 0.473797 1.606081 0.033479 1.034045 40.05184 0.571713 0.428287
0.7833
0.6268 0.396879 1.487175 0.043091 1.044033 43.56925 0.625484 0.374516
0.6961
0.6943 0.284246 1.328759 0.060584 1.062457 48.90375 0.698249 0.301751
0.6319
0.7345
0.2191 1.244956 0.073519 1.076289 52.32226 0.740642 0.259358
0.5539
0.7742 0.15601 1.168838 0.089296 1.093404 56.17645 0.784887 0.215113
0.4718
0.8085 0.105013 1.110725 0.105974 1.111793 60.07749 0.825788 0.174212
0.3956
0.8383 0.069151 1.071598 0.121518 1.12921 63.6819 0.860034 0.139966
0.3196
0.8733 0.042425 1.043338 0.137083 1.146923 67.34339 0.891394 0.108606
0.2745
0.8922 0.030212 1.030673 0.146348 1.157599 69.57181 0.908867 0.091133
0.2224
0.9141 0.019064 1.019247 0.157078 1.170086 72.21332 0.928098 0.071902
0
1
0
1 0.203188 1.225302
84.562
1
0

p-x-y diagram

90
80
70
60

p-y1 exp

50
p(kPa)
40

x1
p-y1 wilson

30
20
10
0
0

0.1

0.2

0.3

0.4

0.5
x1,y1

0.6

0.7

0.8

0.9

20
10
0
0

T=
p1sat=
p2sat=
b12=
b21=
=

0.1

0.2

0.3

0.4

0.5
x1,y1

0.6

0.7

0.8

0.9

333.13K
84.562kPa
19.953kPa
-253.88
845.21
0.2994

experimental data
p(kPa)
x1
x2
19.953
0
39.223
0.1686
42.984
0.2167
48.852
0.3039
52.784
0.3681
56.652
0.4461
60.614
0.5282
63.998
0.6044
67.924
0.6804
70.229
0.7255
72.832
0.7776
84.562
1

12=
21=

-0.383522
1.276812

G12=
G21=

1.121679
0.682306

NRTL calculation
ln1
1
y1
ln2
2
pcalc
y1calc
y2calc
1
0 0.846626 2.331765
0
1
19.953
0
1
0.8314
0.5714 0.019461 1.019652 0.032562 1.033097 31.67531 0.458948 0.541052
0.7833
0.6268 0.030294 1.030758 0.050996 1.052318 35.33509 0.534545 0.465455
0.6961
0.6943 0.05355 1.05501 0.091192 1.095479 42.32748 0.640531 0.359469
0.6319
0.7345 0.072683 1.07539 0.124892 1.133026 47.75948 0.700886 0.299114
0.5539
0.7742 0.097186 1.102065 0.168928 1.184034 54.65923 0.760591 0.239409
0.4718
0.8085 0.12351 1.131462 0.217463 1.24292 62.2381 0.812002 0.187998
0.3956
0.8383 0.147695 1.15916 0.263362 1.301298 69.51548 0.852239 0.147761
0.3196
0.8733 0.171026 1.186521 0.309081 1.362172 76.95422 0.887121 0.112879
0.2745
0.8922 0.184321 1.202402
0.3359 1.399199 81.43056 0.905889 0.094111
0.2224
0.9141 0.199052 1.220246 0.366401 1.442534 86.63906 0.926115 0.073885
0
1 0.252493 1.28723 0.487656 1.628495 108.8508
1
0

p-x-y diagram

90
80
70
60

p-y1 exp

50

x1

p(kPa)40

p-y1 NRTL

30
20
10
0
0

0.2

0.4

x1,y1

0.6

0.8

p-x-y diagram
90
80
70
60

p-x1 exp

50

p-y1 exp

p(kPa) 40

p-y1 wilson

30

p-y1 NRTL

20
10
0
0

0.1

0.2

0.3

0.4

0.5
x1,y1

0.6

0.7

0.8

0.9

20
10
0
0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

x1,y1

p
experiment
wilson
NRTL
p-NRTL
x1
p(kPa
pcalc
p-wilson pcalc
0
19.953
19.953
0
19.953
0
0.1686
39.223 40.05184 0.82884 31.67531 -7.54769
0.2167
42.984 43.56925 0.58525 35.33509 -7.64891
0.3039
48.852 48.90375 0.05175 42.32748 -6.52452
0.3681
52.784 52.32226 -0.46174 47.75948 -5.02452
0.4461
56.652 56.17645 -0.47555 54.65923 -1.99277
0.5282
60.614 60.07749 -0.53651 62.2381
1.6241
0.6044
63.998 63.6819
-0.3161 69.51548 5.51748
0.6804
67.924 67.34339 -0.58061 76.95422 9.03022
0.7255
70.229 69.57181 -0.65719 81.43056 11.20156
0.7776
72.832 72.21332 -0.61868 86.63906 13.80706
1
84.562
84.562
0 108.8508 24.2888
y
experiment
x1
y1
0
0.1686
0.2167
0.3039
0.3681
0.4461
0.5282
0.6044
0.6804
0.7255

30
25
20
15
p(kpa)
10

p-wilso

p-NRT

5
0
-5

0.2

0.4

0.6

0.8

1.2

1.2

-10
x1

wilson
y1calc
0
0.5714
0.6268
0.6943
0.7345
0.7742
0.8085
0.8383
0.8733
0.8922

NRTL
y-wilson y1calc
y-NRTL
0
0
0
0
0.571713 0.000313 0.458048 -0.113352
0.625484 -0.001316 0.534545 -0.092255
0.698249 0.003949 0.640531 -0.053769
0.740642 0.006142 0.700886 -0.033614
0.784887 0.010687 0.760591 -0.013609
0.825788 0.017288 0.812002 0.003502
0.860034 0.021734 0.852239 0.013939
0.891394 0.018094 0.887121 0.013821
0.908867 0.016667 0.905889 0.013689

p(kPa) vs. x1

y vs. x1
0.04
0.02
0
-0.02 0
y

0.2

0.4

0.6

-0.04

y-wilso

-0.06

y-NRTL

-0.08
-0.1
-0.12
-0.14

0.8

x1

-0.08
-0.1
-0.12

0.7776
1

0.9141 0.928098 0.013998 0.926115 0.012015

1
1
0
1
0

-0.14

x1

. x1

p-wilson
p-NRTL

1.2

1.2
y-wilson
y-NRTL

1.585827