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afer rea era ah EY ar Gam Hel bare yee esa era | 2 Wea BI els (CODE) FH YS } al ay aT ofan tod yes (ge tem 44) we wT cs 3 adorn é fay ard os ok are wT & Fee ahh Senet 6 meth cere hk oh cafe arrenttalt ya Shar corde Vea Grr, St orem Bf OTE, TNT ‘aA oer aftr are Pera & Per oy A ae Sear aE | ON ys welts iter settee RTT ‘efte (97. SIR.0e, ORS) &, ot Frere ener are Sot are 1 Pea ga he ae or ra Fret / INSTRUCTIONS ‘A. General: This booklet is your Question Paper. Do not break the seals of this booklet before being instructed to do so| bythe invigilators. ‘The question paper CODE is printed on the right hand top comer of this sheet and on the back page (Page No, 44) of this booklet. Blank spaces and blank pages ere provided in the| ion paper for your rough work. No adaitonal sheets| will be provided for rough work. Blank papers, clipboards, log tables, slide rules, calculators, cameras, cellular ptiones, pagers and electronic gadgets are NOT allowed inside the examination hall. ‘Write your name and roll number in the space provided ‘on the back cover of this booklet. ‘Answers to the questions and personal details are to be filled on a two-part carbon-less paper, which is| provided separately. These parts should only be| separated at the end of the examination when| instructed by the invigilator. The upper sheet is a| machine-gradable Objective Response Sheet (ORS)| ‘hich will be retained by the invigilator. You will be allowed to take away the bottom sheet at the end of the examination el 7 we eee (BUBBLES) ®t Bret tet AIRE WHTH BATS | AM Ga Stel fH Pras Gakic es wy ar aT TE | INSTRUCTED TO DO SO BY THE INVIGILATOR | Using a black ball point pen darken the bubbles | ‘on the upper original sheet. Apply sufficient pressure so that the impression is created on the| bottom duplicate sheet. 8 saree (ORS) ar ee yftarer a Bebe / PBA T 1 8 geyser oh yet ast oearq gem aia a Re arias Te aah en er ah re eR OSE Sw 8 ue oT wed e | Get oe A RA fret at are 3 ae | B. SOIR, (ORS) Bare aT a TAT 10, ofr. & are athe arg ara Hoh ats wa gee | 11. fad f ahorene, Gl gel w wu ale gy Raa ay i ats a wars OE ay Pats aA SF BTR aS TE Gig BET THR Be | DO NOT TAMPER WITHIMUTILATE THE ORS OR ‘THE BOOKLET. ‘On breaking the seals of the booklet check that it contains 44 pages and all the 60 questions and| corresponding answer choices are legible. Read| carefully the instruction printed at the beginning of each| section. He B. Filling the right part of the ORS ‘The ORS also has a CODE printed onits et andright parts. Check that the CODE printed on the ORS (on both! sheets) is the same as that on this booklet and put ‘your signature affirming that you have verified this. srqtvil D0 NOT BREAK THE BEG WITHOUT BEING SRIF | IF THE CODES DO NOT MATCH, ASK FOR A CHANGE OF THE BOOKLET. 12. a ahs Rr € at ge Geran at aay aA aR | coe CER Ce Ce Dal ¢ of this booklet for rest of the instructions Subject Section Page No. ww O ate we Reet TE One or More Options Correct Type | 3-9 -—_— ee 8 arth | siferes Reser 2 ye TER Part Physics Paragraph Type | 10 +13 3 Wier Gi we | Matching List Type 14-17 We a afte wel eer TER One or More Options Correct Type _| 18 - 22 eT | caret Rese : age wa Part | Chemistry Paragraph Type 23 - 27 3 wer wl ver LL Matching List Type 28-31 we a afte wet foc ve One or More Options Correct Type | 32 - 34 PT A after 7 TTBS HR a Part iti | Mathematics Paragraph Type 35 - 38 3 War Ei wR L Matching List Type 39 - 42 vW—oeoCoC—_—Co_—_—_—_—_—See eee ‘wed Bre & for WIT / Space for Rough Work nN | | i | gana a Os) cy SECTION - 4 : (One or more options correct Type) BS - 1: (WHT atte we flser TER) This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which ONE or MORE are correct. wa Gus 4 8 aghtmer wet & | yee wer 4 ur fever (A), (8), (C) ak (0) &, far Uwe a ate waz | 1. The figure below shows the variation of specific heat capacity (C) of a solid as a function of temperature (7). The temperature is increased continuously from 0 to 500 K at a constant rate. Ignoring any volume change, the following statement(s) is (are) correct to a reasonable approximation. (A) the rate at which heat is absorbed in the range 0-100 K varies linearly with ¢ temperature 7. (B) heat absorbed in increasing the temperature from 0-100 K is less than the heat g required for increasing the temperature from 400-500 K. ) there is no change in the rate of heat absorption in the range 400-500 K. {D) the rate of heat absorption increases in the range 200-300 K. 100 200 300 400 500 T®) Ra 4 fort dha a fre wen ear (C) aT aA (7D Wx fear BY cuat wan & | array 0 8500 K aH MH aS tas fe ek & a aE reer HF oRa alee 8, et weet Bar a) Thema BEAT Hel ER? (4) 0-100K% 4a, aavhfte Gen Bh ax aT UR tea onfhrra Reet | (8) 0-100 K ae AGA @ as Ww araehfia Gen, 400-500 K aA & da aM HGS FH germ i HAs | (C) sazifta Get SH ee 400-500 K aM & ata aaRaffa & | (0)_ Sen sazher Ft ex 200-300 K aH & Aa ag wet | ‘Space for Rough Work / @et os web 9 3 UAT PHYSICS The radius of the orbit of an electron in a Hydrogen-like atom is 4.5 ag, where ay is the 3h Bohr radius. Its orbital angular momentum is mn It is given that 4 is Planck constant and R is Rydberg constant. The possible wavelength(s), when the atom de-excites, is (are) Wem BIg aay Wea cag He BT TT 4.S ay B HET ay SE Fre F | we wees ot ate aioha war ES | fea & fra cote Pracier aR Roa racer & | eA] a para ea oe seatles fae ae aerted at eave ” oR Om © = + Using the expression 2d sin 6 = A, one calculates the values of d by measuring the corresponding angles @ in the range 0 to 90°. The wavelength 4 is exactly known oa error in @ is constant for all values of @. As @ increases from 0°, ) 4 (8) the absolute error in d increases. the absolute error in d remains constant. { (C)_ the fractional error in d remains constant. {{0) the fractional error in d decreases. BAH 2d sin O= ABI STAT BCI BY SA HW AMY FLA HT AM GPT Aled E | oe HO F90° & da FS | aT kel oT SF Wye: ae FTO am 4 afe, 0 & wl ary fae wars & 1 TS owl ar o° S ager 2 Ta (A) dH Prter gfe fee vec & | (8) d¥ Freda gfe ah & | (Cc) a4 fietere afe Rex wed & | (0) a4 free gfe edt e | ‘Space for Rough Work / area fret Ferg ear et = 4S Bboy ed) aves ay? 4 eh fee er Wiad ae 7 Vas; K es i's n, “0 > % —TIMMMTNINT P i . ‘Two non-conducting spheres of radii R, irrying uniform volume charge denshies +p and —p, sn ne they partially overlap, as i shown in the figure. At all points in the overlapping region, i * the electrostatic field is zero. | BY he electrostatic potential is constant. (C)/ the electrostatic field is constant in magnitude. } (J) the electrostatic field has same direction. % | 3 oraTer R, TEM Ry PROT aT ae BY wR +p Tp VETATT aT ater | wel 8 anata foo mr & ir tal a Ria a ealy agar ga gen vhs oe ea eT E APA oT we A RT 1 nr Ba By eter fig | A) fer te as gre / (8) fie tga fava are & i | (©) fer daa da ar oa sae 8 | (0) fer aga aa HF fen wear 8 | ‘Space for Rovah Ste =e | 3 | MOVs 3h. she RoZ® la eS : Feuy 2 Ke. 2 aan i SON we 5. A steady current / flows along an infinitely long hollow cylindrical conductor of radius R. This cylinder is placed coaxially inside an infinite solenoid of radius 2R, The solenoid has n turns per unit length and carries a steady current J. Consider a point P ata distance r from the common axis. The correct statement{s) is (are) (A) Jnthe region 0 <7 < R, the magnetic field is non-zero. In the region R 2R, the magnetic field is non-zero ye R Bren & oria ora Whael arate ders wl otary 4 yer fer aRt/ae we | se der @) 2R Ben a aria offre & oraR WH Ka TT Ee | eT oferterar 4 n ote off got ward He a uw Rew ore | ww gps fey ah re & rath oe @, GH a @) WRT HAs (A) O2R4, Gaeta as yer vets | [toed word & fry eat Space for Rough Wo “0 ‘ (AOA 6. Two vehicles, each moving with speed w on the same horizontal straight road, are appriaching each other. Wind blows along the road with velocity w, One of these vehicles blows a whistle of frequency f|. An observer in the other vehicle hears the frequency of the whistle to bef. The speed of sound in still air is 7. The correct statement(s) is (are) i | | i PHYSICS (A) Ifthe wind blows from the observer to the source, f:> fi. Wythe wind blows from the source to the observer, f,> fi. (GF Ifthe wind blows from observer to the source, fs H I (©) ate ary tay O vla a Ren A ae 8, Ke fl (D) aft arg ola 8 Bary a fen aed 8 A M’. The masses of some neutral atoms are given in the table below: We Pe 9 1 SOM (4-2) Wert ea Zoe} genre & aS om eee | sant a aii & wager Got ot der Gul wed € | ve sa Mar UM ae my Sm OTA 2 eT weds aaPewt HF Rafer ey ware BW (my + my) < ML TT ms Ti my SET OS gery aaa Wh eR aR, WR Ser BT UN) after aA Wad FHS (ms +m) >M' | HS TANS! & ger Ad gaa A Ra we: 1H [1.00782Su [tx [20141020 [i [3016050" [Fe [40026050 | SLi [6.015123 u [Tri [7.016004 u | zy | 69.928325 u PRE | 81916709 w ta Gd | 151.919803u | 2%pb | 205.974455 w | 2p; | 208.980388 w | 2°p9 | 209.982876 u (1 w= 932 MeV/c?) 15, The ebrrect statement is V2 The nucleus §Zi can emit an alpha particle. 20m oe 2 (B) The nucleus 3/°Po can emit a proton. us00% (C) Deuteron and alpha particle can undergo complete fusion." 6 1 (D) The nuclei 3}2n and $2Se can undergo complete fusion, 4 7° 62,3 2 wel WRT eS a PHYSICS (A) Pre SLi ye Yor wr seals we WoT E | Slee) 2 (B) =I 2°Po Ua whet acafina wx wate | ae (©) BARR ae Yor wor woh wwet we WHS E | G! (0) Ure {2m Ua at se gol eR aK WHT e | 16. The kinetic energy (in keV) of the alpha particle, when the nucleus 2!°Po at rest undergoes alpha decay, is we fermen § aire 2°Po Qoorea axel 8 ae tent ao at at oot (kev Hae & \ (A)_5319 (B)_ $422 5707 (OD) 5818 33 ‘Space for Rough feet ark fie ear by Bhs ; 08. a9. Pay B 3 ~— TAMER 9 2006 SECTION -3: aot List Type) ; WSs - 3: Pert Yet WHR) This section contains 4 multiple choice questions. Each question has matching lists. The codes for the lists have choices (A), (B), (C) and (D) out of which ONLY ONE is correct. BH Gs 4 4 aghiocd were | ger a Wort Ete | afaat & fey ais & feerer (A), (8). (C) aie (0) & rv a dat ye aS | 17. One mole of a monatomic ideal gas is taken along two cyclic processes E-F—4G-—E and E--F-+H-—E as shown in the PV diagram. The processes involved are purely isochoric, isobaric, isothermal or adiabatic. We ToD oneal ty & ww ae a, fra 4 eal pv ate & ape et aM yaAE EP>GE g EF HE 4 @ GT ore & | Satara wT YET waar, wer, WATT ar vale T | P 32Py Vo v Match the paths in List I with the magnitudes of the work done in List II and select the correct answer using the codes given below the lists. ena fea a cell ot aA fed wa orl & aha & wer Bsa sy aik gpl & Ae fa wd ats aR wed ae eK Ag | List 1/1 List / etn P. GE 1. 160 PyVo In2 Q GoH 2. 36 PoVo R. Fou 3. 24PoVo S. FoG 4. 31 PoVo Codps : PQRs 432 1 @®) 4 3 1 2 ©) 3 1 2 4 (0) 1 3 2 4 ae 14 - st II containing parent nucleus and one 1 18. Match List I of the nuclear Processes with Lis i Of the end products of each process and i P QR A424 3 1 3 then select the. correct answer using the codes given below the lists : iy LA ye carey vBeet Aa E (St St ofbarit & oe ate a ca : We aif “Praha de fey mg & 1 ape a oe ea ae ate wr set aes z | Wel war gay: i List 1/ tt List 1/31 i P. Alpha decay VY L Fos! ve.. | done Q B*decay 2 us B ms... rea | eee 3. 5 Bio Moye apie i S. Proton emission 4 ee has welt serch Codes : q | } we Rea 2 4 ae ‘Space for Rough Work / aed ret fare eat i j | 9 1s HRA PHYSICS 49. A right, angled prism of refractive index jz, is placed in a rectangular block of refractive index 1), which is surrounded by a medium of refractive index 5, as shown in the figure. A ray of light ‘e’ enters the rectangular block at normal incidence. Depending upon the relationships between 4;, 44, and 44, it takes one of the four possible paths ‘ef’, ‘eg’, ‘eh’ or ‘ei Ue po, TICS MOT HH BY p, oeraRiaien B on wa a Kear TA | wel caer y, arrertain > near @ fora aay orpene PNT gee | weber ot reo eA wt TR iftreiaera arate Net BL ay, sy HR yy, W APT WE Prfe ale gs wort FH fee ae Gea well ‘ef”, ‘eg’, eh’ ei ATH ART | Match the paths in List I with conditions of refractive indices in List II and select the correct answer using the codes given below the lists: Hea a wat BY GALI A steers Bl eal & Pra rg sie ae AR fa wa ats wr vay axe Tel Ta OA : List 1/ IT List 11 / 4 1 P. eof QIN non 1 Q emg NY 2. fy> wy and/Ga py > wy R, eshk 3. mah 8S. esi CAN ty < tty < V2 by andi poy > bs Codes : : P QR s a2 3 1 4 @) 1 2 4 3 ) eer s 23 4 1 ‘Space for Rough Work / aed wre & fery eat a0: 16 20. Match List I with List II and select the correct answer using the codes given below thellists : List I List If P. Boltzmann constant 1 (MPT) s) Q. Coefficient of viscosity 2. [Mery K = Qae R. Planck constant 3. [MLTOK") ie Reise S. Thermal conductivity 4. (MPTAK"} ist wel iol yale yafers sifiy ote Yeat & Ae ed wa ats ora ay wel TAR AP: ahi ein Pp. deca Pracie 1 (MPT) Q Bre Pie 2.0 (ME TY R. wie Paate 3. [MLT?K"] S. Be Wea 4. [MP TOK Codes : P QRS a3 1 2 4 @®),3 2 1 4 42 1g (4 1273 “0 n UIA NO eds AU SECTION — 1: (One or more options correct Type) BUS — 1: (UH a after Tal Amer TET) This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which ONE or MORE are correct. Ba Ges 4 8 agftwor wes S| ede ued AF aR famed (A), (8), (C) SIX (0) &, fry OH a afte el FI 21. The carbon-based reduction method is NOT used for the extraction of (A) Ain from Sn0, (Biron from Fe,0, ih nie from 1,0, a magnesium from MgCO, - CaCO, orga & Freeda 4 ards onenfta area fateh ar yal fer areal 4 set eta 2? (A) Sn0, & fe (8) Fe,0, 8 arRT (C) Al,0, & tafe (0) MgCo,CaCo,% AAR 22. The thermal dissociation equilibrium of CaCO,(s) is studied under different conditions. CaCOs(s) == CaO(s)+ COAg) For his equilibrium, the correct statement(s) is(are) AH is dependent on T Kis independent of the initial amount of CaCO, Kis dependent on the pressure of CO, at a given T (D) AHis independent of the catalyst, if any cacoer) & erie fees ot ara or Terr fa ares F fear 7TH | CaC 0x3) = Ca0(s)+ COAg) Fe aremen & fed, wel weer FH) f (A) an ara ox Prt ear 8 | i (B) arraaen REFS (K) CaCO, 3 RPS ufo ue Pk TET arca & t (C) K Fraa aH WR CO, ® Ta PAR aR St a (0) aN Bee BPR eB) & wa w FAR sei wea F | yO | Bi. ; oy “0 8 au ) £-0 bond lengths are equal. (5Y Thermal decomposition of O, is endothermic. (C) 2; is diamagnetic in nature. ie a ~@) 0; has a bent structure. ou fo 0; & Get Hae aaa & (A) 0-Oandet a cia arax & | 8) 0, aha ats Goreh & | (C) 0, wfereaerta & | (0) 0, Ht Geer af ahs | 24, In the nuclear transmutation {Be +X ——> iBe+y 23. Thgcorrect statement(s) about O, is(are) 0 \ 7 a CHEMISTRY (X, ¥e(are) {yt n) fs (p, D) (C) (a, D) (0) (ep) SBe +X ——> ‘Be+y Ax yee (A) (a) (B) (p,D) (C) (n, D) (D) (wp) ‘Space for Rough Work / area ard & fee aT oo ; 2 } —_ ao *0 19 NAO 25. The major product(s) of the following reaction ig(qre) OH aqueous Br2 (3.0 aquecus Bra (8.0 equivalents) | 5S oD SO3H hy oe G Ye Js “e SO3H (A) P ® @ (C) Rk Prefers aifiira wm) yer sere Be) ‘OH eT _Br2(3.0 FAM) : SO3H OH OH OH OH Br Br Br Br Br Br Br ‘Br Br Br SO3H Br Br SOgH P Q Rg Ss (A) P (B) @ (C) R bs (0) s Space for Rough Work / aed rd & fay a i | i | | 26. After completion of the reactions (I and II), the organic compound(s) in the reaction mixtures is(are) Tae afizast (sik I) eR eM & ae wears Feo 4} aie afte ifr at sere | | | | Br (1.0 mol) Reaction I: to? Son, aififipat 1; (1.0 mol) @qveous/ aca NaOH 9 ; Br. (1.0 mol) i Reaction II: ne dct, > I: (.0mo) - CHsCOOH | fo ee ; HyC7 CH,Br HC ~CBr3 BC“ CBry anise Scryer eons CHBry 1 P Q R s T u Reaction I: P and Reaction If: P Reaction I : U, acetone and Reaction II: Q, acetone (C) Reaction I: T, U, acetone and Reaction II: P (D) Reaction I: R, acetone and Reaction II : S, acetone (A) oer TP otk afiBear ML: P (8) affireni: 0 Wier ak aftitear 0: g, wer (C) afta 1: 7, U, Wee site affine Mt: P (0)_aftirar 1: Rk, wes ate aftiira mr: s, whic Space for Rough Work / ea ard & fee Sa SB 27, The K,, of. Ag,Cr0, Is 1.1 * 10°? at 298 K. The solubility (in mol) of 4gzCrO, in a 0.1 M AgNO, solution is (A) 1.1% 10-1! DS 11x10 = (C) 11x10 (D) 1x 10% K, (Ag,Cr0,) 1 APL 298 KR Lx 10 8 10.1 MAgNO, & fe FY Ag,CrO, wi facaer Ataefiex 4S (A) 1.1 10°! (B) 11x10 = () Lx 10? =D) 1.1 «10° 28, In the following reaction, the product(s) formed is(are) Prafettaa afiftea & verrerscrel oY gary OH CHCl; 1 Yyb OH ' CHs C 4 % oH are a HyC CHCl, HsC CHCl, CHs Ss (A) P (major) a Q (minor) (C) R (minor) {D) S$ (major) Pe) actin R at Se) ‘Space for Rough Work / wed ard a fee ATT kp of CsOy 4 ig Pat aH ty Bag iCv04] 7 a, io ac [-4 7 lel . et - ee 0 | | CHEMISTRY SECTION - 2 : (Paragraph Type) Ws - 2: ( War) This section contains 4 paragraphs each describing theory, experiment, data etc, Eight uestions relate to four paragraphs with two questions on each paragraph. Each question of a paragraph has only one correct answer among the four choices (A), (B), () and (D). east RF EG, FART GME ost ae at SINT 4 os ae oe daft ane wer &, fore A ex ayes Ww wyes A eT yet & an Rewer (A), (8), (C) aie (0) e HD dae Uw sha eI Paragraph for Questions 29 and 30 Wea 29 Ud 30 & ford apes An aqueous solution of a mixture of two inorganic salts, when treated with dilute HCI, gave a precipitate (P) and a filtrate (Q). The precipitate P was found to dissolve in hot water. The filtrate (Q) remained unchanged, when treated with HS in a dilute mineral acid medium. However, it gave a precipitate (R) with HS in an ammoniacal medium. The precipitate R gave a coloured solution (S), when treated with H,0, in an fet Se aqueous NaOH medium. a aerdhra aa & ye Rew ot aes ea Ty HC! AA ANI ORR aE vp wade (P) sik ve fege (Q) tae | oraea Pw va A yori F | fieege (Q) aq ahs orefe seam A H,8 art faa ox omfatia wea 8, fey wiiPiret area A A, & wer saey (R) Sa S| aa Rw a welts NaOH WE RM 1,0, FF atten GA free ($) StF | 29. The precipitate P contains (A) Pb (8) He? (C) Agt (0) Hg waey pH sukers & (A) Pb (8) Hgy* (C) Ag* (0) Hg 30. The coloured solution S contains (A) Fe,(SO4), (B) CuSO, (C) ZnSO, (D) Na,CrO, SAM reer SA softera & (A) Fe,(SOq), (8) CuSO, (C) ZnSO, (D) Na,CrO, Space for Rough Work / aed ard & fre GIT oa 2 UMNO Paragraphs for Questions 31 and 32 vy wer 31 Wed 32 & fed args P and Q are isomers of dicarboxylic acid C,H,0,. Both decolorize Br, /H,0. On heating, P forms the cyclic anhydride. Upon treatment with dilute alkaline KMnO,, P as well as Q could produce one or more than one from S, T and U. Pa ove sigardifeate ara CH,0, & a waar & | a Br,/H,0 #1 od aed € rl ow Pam Weggs TM z | Wy aN Kind, a PSR O aera aif He ye eran ya Y after alte $, Tarrant U aT rs S | COOH COOH OOH H—-OK H—-OH = HO--H H-f-OH = HO-F-H H--OH COOH ‘COOH COOH Ss T U 31. Compounds formed from P and @ are, respectively Optically active S and optically active pair (7, U) (8) Optically inactive § and optically inactive pair (7, U) (C) Optically active pair (7, U) and optically active S (D) Optically inactive pair (7, U) and optically inactive S PSR OER HF Ate wre. F (A) gam yoier syd qaer yvta BH (7, U) (8) yam Ffsea sud ganr fsa aH (7, U) (C) yam ele gH (7, L) Wd gor wie s (0) gam Fatwa ara (7, Uva gar Patter ‘Space for Rough Work / aed tra & fey ea Oo ui oO esa ow (-C=C-=0 a “0 x VMN | | | | 32._ In the following reaction sequences V and Ware, respectively ( Prafeifid often orgral a, vate warner Hails A AICI, (anhydrous) 4. Zn-HgHCl oO set AEE ae 2. HPO, ie 9 La) CG and/aty CO “vo wo co @) andshe CO oe Q CHEMISTRY ‘Space for Rough Work / aed ard & fae ea ie #eQ) a UTA Paragraph for Questions 33 and 34 4 WR 33 We 34 & fer A fixed mass ‘m’ of a gas is subjected to transformation of states from K to |. to M to N and back to K as shown in the figure we te & Pad ser ‘mS eT ORT KY LAMAN ae ae KA fra ant fear 1g & Pressure aa Volume Stee 33. The succeeding operations that enable this transformation of states are (A) , Heating, cooling, heating, cooing (8) Cooling, heating, cooling, heating of Heating, cooling, cooling, heating (D) Cooling, heating, heating, cooling uate at SF see Faery €, (A) 14, dor, 74, oor OA 8) 3, 7H, ws, HAR (c) 74, os, der, A oe (0) 331, 7, 7H, der oT 34. The pair of isochoric processes among the a LOM of states is (A) KtoLandLtoM Lto Mand NtoK (C) LtoM and M toN (D) MtoNandNtoK oaen oRadat a Rafedi 4 wana rH HS (A) KULaRLaM (3) LAM@RNGK (Cc) L@Mak MAN (0) MYNak NAIK ‘= Space for Rough Work / aed wre a fA ; MTG i / 0 ey ni) yin “0 2s AE 36. . 36. Paragraph for Questions 35 and 36 WRT 35 Ua 36 & The reactions of Cl, gas with cold-dilute and hot-concentrated NaOH in water give sodium salts of two (different) oxoacids of chlorine, P and Q, respectively. The Cl, gas reacts with SO, gas, in presence of charcoal, to give a product . K reacts with white phosphorus to give a compound S. On hydrolysis, S gives an oxoacid of phosphorus, 7. Cl, Te ag otk tis NaOn & wrehte fae ERT HAE: SS atk wh oe a aftinar ox a (Pie) with & sieeve & eifsar cam, Pal g tae | Ch, (g) aRarea SH waftafs F so, (g) 8 aftiirar ox sae R sae | RAT DRORG ERI aftr ox Ure s taf | SS Tea Hea TRENT ST we aneearat 7 et S| 4 CHEMISTRY ind Q, respectively, are the sodium salts of hypochlorus and chioric acids (8) hypochlorus and chlorus acids (C)_chloric and perchloric acids (D) chlotic and hypochlorus acids Pak Q was: ste wsar aay & (A) aigdiasiea atk acter art (8) sedaeiee aie eile oer (C) Fie ak aRacitey ara (0) atte sie ergttaetiea are oe $0,Cly, PCl, and HyPO, (0) SOCI,, PCl, and H,PO, R, Sand T, respectively, are (A) SO,Cl,, PCI, and HPO, (C) SOCI, PCI, and HPO, RSA THAR: & (A) S0,Cl,, PCI, a H,PO, (B) S0,Cl,, PCI, 3X H,PO, (C) SOCI, PCI, 3k HyPO, (0) SOCI,, PCI, 3 H,PO, ‘Space for Rough Work / ed Grd & fag ear : C475 ane ——>H oo Ngu-C), © (old) fr \j SECTION - 3 : (Matching List Type) 4 Ws 3: Eo Yel WET) This section contains 4 multiple choice questions. Each question nas matching lists. The codes for the lists have choices (A), (B), (C) and (D) out of which ONLY ONE is correct. aa Gs 4 4 ght rere | yer 8 ater at & | afral & fay ais & feper (A), (B), (C) si (0) = Kaa SB Sar vw wel & | 37. An aqueous solution of X is added slowly to an aqueous solution of Y as shown in List I. The variation in conductivity of these reactions is given in List IT. Match List I with List II and select the correct answer using the code given below the lists: List List 11 P.(C)H,),N +CH,COOH 1. Conductivity decreases and then - ee increases Q KIM) + AgNO; (0.01M) 2. Conductivity decreases and then os 7 does not change much R. CH}COOH + KOH 3. Conductivity increases and. then x hy does not change much snBaet 4. Conductivity does not change much eee and then increases X& siete fee A are: y ar crete Pree ARM ste ret 8, SY YL A Rearn ar s |e attra oI area FH PT ety Aas EAGLE 8 Biers ane cer gee a fea ars ser eh TR : wii wn P.(C)H3);N + CH,COOH 4, Teea vet & ate Tava get F | x Y Q.KI(O.IM) +AgNO;(0.01IM) 2 WereaT wec @ she aera sift x Y uftafar at eke | R. CHyCOOH + KOH 3. Weem ded} & atk aaa after x Y uftateia vet eh | S.NaOH + HI 4. areal itis oRafia ad alt sie xX oY errand del F Codes : P R Ss Bice (A) 3 a 201 ao K+ Ss 6 @A 3 2 1 ef? 3 tee I (D) teats co. “9 * TT | 1 | | 1 38, The standard reduction potential data at 25 °C is given below. arlorrarray fra 25°C Wy Prafefaa & | E° (Re, Fe) =+0.77V; E° (Fe, Fe) =- 0.440 —3 re —i¢(79)4a4 £° (Cu, Cu) = + 0.34 V; E°(Cut, Cu) = +052 V fz BSe FF E°[O,f@) + 4H* + de” 2H,O] = +1.23 V; E°[0,(g)+2H,0+ 4c" > 40H] = + 0.40 V a E°(Cr, Cr) =- O14 V: > E°(CP*, Cr) == 0.91 2 Match E£° of the redox pair in List I with the values given in List II and select the correct answer using the code given below the lists : at 14 fet terem Te wt GH A fet TY oma fre a BAR wiry cen yfrat & AM a 7a ats a ya ad wel Se WPA - CHEMISTRY List 1 ARH a List 11 Aga P. E°(Fe™, Fe) 1 0.187 Q E°(GH,O == 4H + 40H) 2. 044 R. B°(Cw + Cu 9 2Cu) 3. 0.047 S. E°(CA*, CP) 4 0.837 Codes : P QRsS a4 1 2 3 ® 23 4 1 203 4 4 12 oe 3 ‘Space for Rough Work / aed ard & feng eat —1FE = s3elai)-.siP(2) Cm wee — oPIKS b8Z2- a) 29 CINE 39. The unbalanced chemical reactions given in List I show missing reagent or condition (?) which are provided in List IT. Match List I with List II and select the correct answer using the code given below the lists : a1 4 Skee srightd aftiiarst + amefirer aiftretwrorneny etn A et ae 2G 1a Gt 1a Gea Af an Yual & sia fey wa ols wT ord wel way afr : List Aga 1 List 1 ART I 2 P. PbO, + H,S0, —> PbSO, + 0, + other product ary Terre |. NO 2 NayS,0, + H,0 > NalHS0, + other product ae Wari E Ny, > Ny, + other productarra were 3. Ss. ek, Xe + other producti See 4. Ch Codes : P QRS a) 42 3 1 @) 3 2 4 AN © 1 4 f2\3 304 24a “Space for Rough Work / ed wd a fA aT “0 x TAIRA } i | 40. Match the chemical conversions in List I with the appropriate reagents in List II and | seleththe correct answer using the code given below the lists : | | I Bae PY a Tara wala aT GAA Ma Rey Ta ouyeR atrantet we Yea wifey car Eft & aes fey aa ss a way ad we) Ge GPA: List LAA List 1 ght OT co) be 1. Hg(Odc),; (i) NaBH, » Q ons — 0 2. NaOEt R. oe a 3. EeBr = oO Os z eye 4. @) BH; (i) H,0,/NaoH FF le ‘OH — ba Codes : o QRS a3. 4 (2) 32 «1 4 (C) 2 4.1 (D3 2 4 1 ‘Space for Rough Work / ed werd & fay ea | i | | | a aH TAC Nae eee War nek) ‘4 SECTION - 1 : (One or more options correct Type) BS — 1: (Th a afte wal fred WER) This section contains 8 multiple choice questions. Each question has four choices (A), (8), (C) and (D) out of which ONE or MORE are correct. Ba avs 8 aghtmod wet | yeta wea A are fear (A), (B), (C) BR (0) @, fer ew orate vel | 41. Let abe a complex cube root of unity with @# 1 and P = [p,] be a n x n matrix with y= 07. Then P? #0, when n= (A) 57 (8) 55 (C) 58 (0) 56 Toy wwe att Tye o cfd, TE oe 1 WM P= [p,| WH nxn HAT AA, Get p= ot THE, P40, ( a (A) 57 Cos (eps | 8) 56 eu eer \! 42. The function f(x) =P Tx] + |x+2|-| |x+2]—2 |x|] has a local minimum or a local imum at x= 2 2 (a) 2 @) > cy? ©) 5 Gert fle) =2|x|+]x+2|—| [x £2 |- 275 || HUH ware a aT YH eT atteas fort x & aM WE, aes 2 e > (2 © 3 Serene nen ent 5 ye ym 2Se4¢ = & \\e =: wd . 2 TM MATHEMATICS 43. Let we wisi 4 > *and P= (W's n= 1,2,3, ...) Furr Hy = [2 c:Rez> and Bee Hy= fe ec: Rer<5}} , where Cis the set of all complex numbers. ifz, ¢ PAH, 2) € PO Hy and O represents the origin, then Zz, 02, = z x 2n Sx A) > (8) & ) > ) = art fry Bear P= fu sn, 2,3, 0 }. ee afaer i= fzec:Ree>d] aan A, hecsres<], wet Cuttin eeansit ar | wart @ tafe ze PAM, 2, € POH, FH O Fees wafer wear 8, aa £2, 02> x z 2n Sn i A) > ®) & © > (2) = i | 44, 1f3°= 45", thenx= / ; 2 log, 2 2 1 2log, 3 | OY Tog, 2-1 OY T7h0g, 3 9 T=1og,3 ©) Tog, 3-1 i fe = 4 aa x= / a 2 log, 2 2 é 1 2ioe,3 A ) Fog,2-1 ©) 3rh0,3 ©) Ttog,3 =) Ting, 3-7 PF ES z 45. Two lines L, :x=5, a =p and Ly:x=0, Fey gere coplanar. Then a can [id take value(s) = (A) 1 (B) 2 (Cc) 3 (D) 4 a tat 2,125,575 = oem 1, reap = 52S enidta 8 a4 a a a arae (A) 1 (B) 2 (c) 3 (D) 4 y gSpaée for Rough Work / ert ar & fear at OL hey iP MATHEMATICS: 1 46. In a friangle POR, P isthe largest angle and cos P = . Further the incre ofthe triangle touches the sides PQ, QR and RP at N, L and M respectively, such that the lengths of PN, QL and RM are consecutive even integers. Then possible length(s) of the side(s) of the triangle is (are) (Aj) 16 (B) 18 (C) 24 (0) 22 Bras POR, # P gecrt am F aT cos P= 4 {eae afakar Bry a aia-ga aos PO, OR TM RP FH A: N, LAT MR ge aE eal aa @ fy PN, OL Ra RM @) aga war wa DRM e 1 va By a sn cath) w wend aay (erage) & (A) 16 (8) 18 (C) 24 (0) 22 47. For ae R (the set of all real numbers), a +~1, lim 12+ 274... +n4) at n> +i" [na +1) + (a2) +o .+(nat+ ny} 60 Then a= -15 “7 (A) 5 (B) 7 ) > (0) > ae ROR arate Renal or PE, ae — 1, fey lim 1422+. +4 ee n> GD" [at b+ att. +(nat+n)| 60 Was 5) oS alt fA) 5 (8) 7 (°C) > O) =z 48. Circle(s) touching x — axis at a distance 3 from the origin and having an intercept of length 2\/7 on y - axis is (are) (A) x2 +y?-6x+ 8y+9=0 (B) xe +y-6x+7y+9=0 (C) P+y-6x-8y+9=0 (D) P+y-6x-Ty+9=0 x~ 9H #1 Peleg 3 BO ae wel Gey are (Te) TM y— oR WR 2/7 isis FM Teac) Fae (B) (A) x2 +y?-6x + 8y+9=0 (B) 2 +y?-6r+7y+9=0 (C) 2+y?-6r-By+9=0 (D) 2 +y'-6x-Ty+9=0 Space for Rough Work ea aed fae ea NN a POAT | j { MATHEMATICS. SECTION - 2 : (Paragraph Type) WS ~ 2: (WW WHR) This section contains 4 paragraphs each describing theory, experiment, data ete, Eight questions relate to four paragraphs with two questions on each paragraph. Each question ofa paragraph has only one correct answer aongt the four choices A, (B), (C) and (0). ge avs 4 Rate, sari six sitet anfe oy cett atet 4 aqese F | ORT ary @ vals ore wer 8, He S ae ope we el oer S| fee A orp A ae A 2 ae Ae (A), G), (C) sy (0) € fort S dear yw A ae | Paragraph for Questions 49 and 50 Wer 49 Ud 50 & feet aq Let f: (0, 1] > R (the set of all real numbers) be a function. Suppose the function fis twice differentiable, f (0) = f (1) = 0 and satisfies f"(x) ~ 2f'(x) + f(x) > ex € [0, 1]. art f f:[0, JR MT acta tensit or Wye) ve wert F | wert fal aR samerhs & £0) =f(1) = 0 aM f"(x) — 26) +f) 2 e', x € (0, 1 # age oat | 49. Which of the following is true for 0fe, o 0. FT f& PO wae y? = dar Bt YH aie shar & | gsi P wen OUR URE wt wrt Part ue fey we fread & af Yar y=2r+a,a>0 WF fed & | 51. Length of chord PO is har po at wang @ (A) Ta (8) Sa (C) 2a (0) 3a 52. If chord PQ subtends an angle @at the vertex of )* = 4ax, then tan 0= afe Sitar PO, y? = 4ax & ht we eer o siaRa wet & aa tan o= 2 2 ot a 3 @ si © RS 0) 345 ‘Space for Rough Work / Sed Hrd & fee MIT ue 6 FAA ' MATHEMATICS | Paragraph for Questions 53 and 54 : Wer 63 Wa 64 & Rd aS Let S=S,9S,0S,, where Steels |z}<4}, > eec inl A a. of na Bi = {ee C:Rez>0}. art fF S=5, 08,08, et r ; $,= (eC: |z|<4}, S,=jzec in| 2=LANSE|, | ger 1 C:|z|<4}, Sy sn S\= {ze C:Rez>0} . Area of S= So aapa = 10, 20; 16. 32. “a ® ew © min, |1-3i-2|= 2-y3 2+y3 3-\3 3+y3 w 28 oe ot otf ‘Space for Rough Work / edt ard & fey ea Gal Ua er) n | MATHEMATICS ! Paragraph for Questions 55 and 56 y wer 55 Wi 56 & Rd ar A box B, contains 1 white ball, 3 red balls and 2 black balls. Another box B, contains 2 white balls, 3 red balls and 4 black balls. A third box B, contains 3 white balls, 4 red balls and 5 black balls. ye de) BH 1 ube Hz, 3 cet He cen 2 ore He TF | vH Tae WB, F 2 we He, 3 cet FE car 4 wre es | ya Ae Vg, 43 abe He, 4 Te HS aT 5 ore He & | 55. If 1 ballis drawn from each of the boxes B,, B, and B,, the probability that all 3 drawn balls are of the same colour is afe feat 2, B, ven B, Ho aeke 8 1 Ae front ond & aa Port aE wht 3 fal & ya A or & a Bi waft F : 82. 90 558 566 O Ge ey Ge ©) te ©) ae 56. If 2 balls are drawn (without replacement) from a randomly selected box and one of the balls is white aad.the other ball is red, the probability that these 2 balls are drawn from box B; is eer af 27 ve agen gata dt @ fear wf & Pere ont & aa ve ig ube o gal te ore Ped & aa ga 2 tel a 0 2, 8 Peat a wife & : a) He e@ 2é A & o 3 ‘Space for Rough Work / ed ard & fare eat ~y —») 2Ww / bis a \) BR aM | \) U 6 ; - yR [42% 4 : — | 7 oe Pa ie 8S) — ! SECTION — 3 : (Matching list Type) WS - 3:6 a WER) This section contains 4 multiple choice questions. Each question has matching lists. The codes for the lists have choices (A), (B), (C) and (D) out of which ONLY ONE is correct. wi ws F 4 aghtmed were | wer yrert Yet & | yaa & fawes (A), (B), (C) Stk (D) & TAT haat Yeo HAF | as 57. Match Ljst —I with List -Il and select the correct answer using the code given below the lists : List -1 P. Volume of parallelepiped determined by vectors @, B and 2 is 2. Then the volume of the parallelepiped determined by vectors 2(a x b), 3 (B x @) and (2 x @)is e Q. Volume of parallelepiped determined by vectors @, B and ¢ is 5 Then the volume of the parallelepiped determined by vectors 3(@ + 5), (6 + 2) and 2 + ais R. Area of a triangle with adjacent sides determined by vectors @ and B is 20. Then the area of the triangle with adjacent sides determined by vectors (2@ + 35) and (@ ~ 5)is S. Area of a parallelogram with adjacent sides determined by vectors @ and 6 is 30. Then the area of the parallelogram with adjacent sides determined by vectors (@ + 6) and @ is List — 11 1. 100 2. 30 3, 24 4. 60 ei iat gh — 1d atte oiftiy wen yfeal & Ae fey ay ats a BH TE TA : i putat 2, 8 ar ? ant Pulte waar yewor aT oR 2 @ 1 aa ate 22 x B), (8 x @) wen (2 x @) ert Pratt WAR vor 1 ara & Quftel a, 2 ven 2 ere Paifta water yew oT art 5 ze | ) afte 3 @ +B), G+ 2) wT e+ a) ant Peaia waist FEL ews mom f Pap or dara, Rr ders yond wieei @ en B art 1) 4 A faites & 20 8 | aa afte (ae + 38) cen (@ - 8) ere Afr att art Bry or dap & é We Trike aa or Aart Preval Gory aoe afte F ear -| | 6 eri Pula & 30 | ca weet @ +B) ae 2 aT X—— faite Gert yonall aret wate aE wT draws & Y |G cowee: aay win BA 1 100 = hk = Ww 2. 30 E = a 3. 24 4. 60 MATHEMATICS =1 +3 =4 yt3_ zt 58. Consider the lines L, :*3~="7=47=, 1, : tS and the planes P, Tht y $2283, Py: 3x + Sy - 62 = 4, Let ax + by + cz = d be the equation of the plane passing through the point of intersection of lines Z, and Z,, and perpendicular to planes P, and P,. : Match List —I with List — II and select the correct answer using the code given below the lists : tart 1, :* tiv 243 , SALES ey arntel Pst ty t22=3, Py xt Sy—62=4 SAY | HTT AH ax + by + cz=d, Vani L, TL, H wT fry BORA Tea TEN AI P, TP, & aa, WHT HT MTHS | ea - 1 eh - 18 Bera Sify ven Efeal & Ae fee ay ats wT aT Rh UE TAR BP List At 1 List IL RR a= 1B b= 2 3 c= 31 . d= 4, -2 Codes,: npon 3 (B) 1 (c) 3 (D) 2 RNENO R 4 4 1 1 warnon | i | MATHEMATICS 59. Match, List I with List IT and select the correct answer using the code given below the lists: List-I List -11 / 2 1 6 J (cos (tan™y) + sin (tare 2). ‘ Loa\f3 P. (fee (sin) + tan (sin) )*2") takes value If cos x + cos y + cos z= 0 = sinx + sin y+ sinz then 2. y2 fe possible value of cos => is nie x : : : R Wt eos) oar 2+ sin sin 2 sec x= cos sn Du seo x+ 3. 3 i! cos f + :] cos 2x then possible value of sec x is 8. tf cot (sin! -f1— 3) = sin (tan! (x6), x # 0, ee then possible value of x is ge BS Pfs sy cen eee} A fey ay ats a eh aS Wel Tae BP: wir whut ; 12 1 fs 1 (cos (tan™ly) + y sin (tan’ “a Lois 2.5 (costae () + tan oirtyy 7H) PUR Q. AR cos + cosy + cos7 =O sin x+ siny + sinz 74 2. 2 Pn e) cos Sor weft a & z ey 1 RR cog{ Zs) cos De + sin x sin 2x s€0 x= cos x Sn 2x see 3.9 rf aa E coo +2] cos 2x TA sec x tor BAe AS FS S. AE cot (sin . sin (tan (xJ6)), #0, 4 a xO] Waa AT Codes : QRs wMA Fv 1 2 Bye 3 2 1 SP 4,21 3 4\1 2 Space for Rough Work / area ara & fery SAT Q- fe 22 O 5 ty UREA MATHEMATICS 60. Aline L : y= mx +3 meets y— axis at B(0, 3) and the arc of the parabola y= 16x, 0 £4 < 6 at the point F(x,, yp). The tangent to the parabola at F(x), y,) intersects the yraxis at G(0, y,). The slope m of the line L is chosen such that the area of the triangle EFG has a local maximum. Match List I with List IT AMc'setecTthe correct answer using the code given below the lists : UG PAL :y=mxt3,y— HF H Ay AO, 3) WN Wass F AM y?= 16x, 0

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