FIN chela A §0 Ho va ten SV: TRUGG JU TRAU Ma sé TT: Maso SV: AOR, CN-Ad BAI TUONG TRINH Bai 1: XAC DINH DO DAN DIEN DUONG LUQNG CYC DAI CUA CHAT DIEN LY MANH VA CHAT BIEN LY YEU 1. Mue dich: . = 4 ee Al ung may BAB eli vi Jui ih ig se noe 5 “ein au shuld php we tind €B de din cy hdhg ce dit. chan chil on (et race) va itl Si eH cot) oan bd mb pha Hwee jee de dn Ain aitehe, lady wer anengas ‘ae Cant deh iy le laa II. Nguyén tic va co sé ly thuyét: , tha ede chin dung deh eva cde. chitt alan ki enank CHseooNa, HEL, Nlael Va ang db din atin Dowd dein dln nding Ke cba ede clung clich Aa. pha. Gil ab dn chin cing (Beng theo bail tt: Ne A000 (Ke ~ Kio) a= MeL Ke ® Kin] en Nd Rug | 8 clean nny cli mide pha. clang. cli . Nau Kyo Ke fico 48 he quae Kao. dan chin Ling cute hai hus voc-ainh Ak plultrgtrinh Voblrausch Ac= 2,- AVE in Ghdthag HRéing bike Lats pha Rabe Me =f (FE) ogo Eli We =0y ae & a WN din ‘hin dit Wing ctlrthal aula chit dient yste CH, COvM ale, : ade Hoh aid lip-4 oto bly dion hig Wace ea ce ea, si gi Sh Ut ON Yo enseGo = Ao, ef coonla + Votes ad De ntactILL. Thye nghi¢m: Trinh bay cfc burde thye nghigm 4] Clan bi A. gin 2 alt, hak ye cut bedag mice, he tb passant dn Mas de Jia nl be Senet . Bhi nkar AL ASH ofa onike eat a | his Ri MES 5 xd Aint cin ebisnchieag otsdet ofa, CHCOONa, He? Ne — Pha Wont ete dd ee! bing dette Be clung li Ae pha Vie Be Db. Gres lend ce >. — Cho cB vice brn cH ahiat, AE ¢ id Ending ve nhadae phew. — Rea sash ibn oe bain inde tk chow hc i ut MK L Op Soar Asa’ den cia del “8 long, ie a a Rén-tin nha "eile cngseudan ak , J A in age Biv dhin at van del Ano oho dd argh RnR abn cu ee et ES CRE clin Ads chvclink 6. fers ~ Girk Ave cae dai hang — Dang ti d= 4) Bia PE qauy tanger lin va phuittg bi aay «Xae aaah a vshlrauschy, rie bie | Actualase. ee — Ap fot Debye-Gnaagen eB AE 36 ioblenueets 3 nficts 1B, vfdn ae ce lt vi Ay. dpe ca ci CH 2, HEL, Nace. So nahh eBincch _Girh 2, So tinh od gig fi Auk onghudin 8.28 Vo gid i tect. Sart Faeayser ead solu ee Binh| Dung dich ding dé pha loing Dung djch sau khi pha loang Nong | Thétichdy | Dyngcu | Thétichsau | Dung ‘Nong 49 | d&phaloang | dingdé lay | pha lodng ding ny a6 cm) | Cook) — | dumgedich | (mL) | Pha toing | (4) 1 [400.164] 00,00 Pruret A000 Rid |[4,.0.101 2 [4,00.10'| 0,00 touret Aoo, 00 Fict___|6,00.107 3_|aooi0'} 40,00 toured 400,00 Feel 4,00 16% a Court 260,00 Fiat 2:00.10 5 |aovi% SCO. | bunt Aov,00 Fict 00.10" 6 |e0004 A500 ) | bet ACO,00 Frat ite) ; eeTV Két qua va tinh toan: “1. Xe dinh 46 din dign dwong lugng téi han ~ Sinh vién tién hanh 6n nhiét va do 46 din dign cia céc dung dich HCI, CHyCOONa va NaCl. Lan lugt dién gid trj vao bang, vé cdc 43 thi A= f(VC). Xéc dinh Aotruc tigp tir dé thj va tir phuong trinh hdi quy. Xéc djnh hé sé Kohlrausch hop. Néu céc nhfin xét. Bang 4: Chit dign ly: HCI Binh om) | 0) | Coston’) | Cat) | Cee og!) TL iop.ts| 0 Stu | OG FY 2 Teco] 290 | des | [oaue AQ 3 [gco.0?] 29,2 AG te | 0,200 Wg 4 [a,00.107 | 029,0 48,3 eS OAM has oe AiserS | | o,A00 4D © | 4c0.t0} a0 | Aus — fOoSuR | 4A Hel ob we Writer eyCneoe a 6 des Sedna eat ae i kb quan _ 1000.8 = Os ose ee woe aes = 848 (cw ag") 00. ee « Gobbtebn tig ut cho ec hinkecn (ai Ve cifre dé thi r=4We) hu, Ave phuldag tinh KE quy y= — Sead, + 4+IO,Mo inf A) Vix Ao yer 490,46 Wem aq') S 89% + Quyda ve Note, BAC: Qa Me Ata Ne. = esis 2a oes Toe 0015 % <0 J " 2 Deas = Tene Lee (ed-29)) 9 RE = AIM =A630_ ; > A+O,01S-4 Gra titre bang ee Cente) ee = SIS Cc? eg t)HAE AS Udhlrouseh: Gl ASH: y= Hebel — Seanth tein 8 ys BIC. Az 2244.2. + AAT= © 2299. MOK + CHAT = A494. Rangel: Chat dién ly: CH;COONa Binh |_| eee) | © | work og 1 | 400.10" € | & SHS | OSG 25,2, ies ese 5 oaus | AS 3 | poo? 26 | 4068 ws pate] 26,6 4 [900.107 28,4 | 0,563 nS | O44. 2b 5 |y,00.107| 88,4 | O92 KE | 0,100 cu 6 [50.109] ag,6 | 004M w& [0 SAB 30,4 COONa 6 6 ating 2 ae Eo of, na sa Rs > Gas On Bie letorktdy be hee fot aint, ta Has it being a0 Ga 2, o Pang dH 4 GUAR) fart puttin ir gay: 4 B ony T+hO4EF (Hino) BOF onl, = 00,61 Somted' = )evencoona raja NE ponte » A a8 alt fc ey lar = AT +o cpa £008 + 0.406.408 Ret, - S008 + 40,9 s Reeagoons = Ne tytoora C+ ef 20 -as]) i 203, 6% 2 ADB 8 ean cert 9 igo, = gent ACN na) Gia tite, being: 5 ei e00 N= M0 C&.ent. eq) # Alsing 26 Koflranteh : “Tardethi, A= 298,28 biden 8Ry= ZOU. AsOQHAT ELIS = O29G. 203674 HIT = M3, IE = G0284 615, 02 ve (eq*?) Hinh 1. Dé thi A = fC) ciia chat dign ly HCL 0 0.05 on 0.15 02 0.25 03 0.35 ve (eq?) Hinh 2. Dé thi A = fVC) ctia chat dign ly CHsCOONave (eq?) (bows) ¥ AWC) ctia chat dién ly NaCl Hinh 3. Dé thi Ahangs : Chat dign ly: NaCl Binh “hag |e cns.ew) |__| gs ont ig’)| 1 0.0 Pag AA ,23 we OBIE Ah 2 [600.10] 284 Taeoe fous | 198 3 [x @.10*| 224 eg o,a00_ | ABY 4 | 9.00.10? | ang HTS | AB 5 | ov] 28 | ASCH wE | o,400 6 |s,c0.107] 22,0 |o608us |[o,osev | lod eae Nal ob Aiden ing A) Cus Ryo Ot of, ie Cah haat of aig bp chit din i HCl ta rds big Ubu 8. e a Dube N= fC) eth ie phutng “th As que ie — HYG Hort S107 Chinn & = XE = 210 Ak Somt og! qld, chirh VE XE Nuce, AR 48 nhutt Me aay boding + 2 OAL to De _ 070208. 50,0P + vole, 1644 o = - yt he $0,084 6,34 — = 0,080 ROS eee RE g [A+ eGo -25 Nl 5 = —MOAe = ogy ee 6 em eG) (one A+ 0,080. 5 Cha te tre bhdng : DES ae = AMO 29 Sew, 24) acthing AB Kohlouseh » Chaffee 149,46 — CUbhtoan Btn. Pg = O99F.Ay + AAT = 0299. lOAL+ ETAT, = 498,59 _ 3w 2 lin chin Wing eit Ad ct cua Ch, Coot &SCElfuk nghain ) 25%. LS%, et Xo eacoow = Ko, CA Cone. oer ~ Ao, Mack = Ah 24) + #QYIO — Ban = BEAST CS emt ) Cohiba: HEE, coy 390,56 4 o% Gl ln cil La ob dai eda cH coo & rhittt ds AR sqlucin soe ao Teco = Ao, ater + Nee Dene 2 AVOAL +2056 — S10;AL= 583,44 (S.em?.2q') * nade ca ath ip sak A eg A ela clag dk aie eg g dhe a8 dip dain aatng i lg in Aha Xam xe RENE nhan et an nh A, mul Et asthe lchbrousch cle op pha Ace waa AE cele. SE a Nidn xet: — Cae a Wuthg thee, aghiin hate das chink VEoKC. da. Men hen hee being, Pai aay cbthé clo tai agi, Raw Ha, Ahi » Aobechn uci drank linkedin £8 Shc pies wid he is dee act) ng abo hive o~ opthi enh Bch . GPE Hi She "QaAG Wh sds dn clay ok dat “ayewe “hile quan: Adhi Ai 88 Mefleauech lei thi, 218 cldin dan ol ale ot Nan nt aay Ach bp Ugvérhayét Debye ood yale ult fi A= ot OF, te le At E tyertih da 2, 1A, bhi Av scinh qulee ode Sit CH,COOH, Hel, cHt,Coonlec, Nace le “cel fey ag ‘elitr eda acid cao hen to vor mad , ly we linfrds ea teh itn ec tet Ache yey ? Keng syeooy 40 HE phic bd Recir focan 8 din ott olga Hie Aerts ien Zeng ia co bik Hate, nko ie Gi,coo—> linhadS OF leh her g hee Hi A alleen ict pie te guy Nate Fi tei ty fagetca, vad a ku chs deci hal cue ede yiy 8 (ahd ds, Hcl pee Ie Ki inh Aoan sit dang Mi Ae of va PPS ob ie BOR Bt Win? eke ty ? ‘erin co Axo Mop Ud»Bangi CRat dian by Hee ; 2 7 e e t - c Xu eh & (ec) Cons.onr) (S.omt.2g') 4go.iS' | 24,0 rue 0, 346 Bay L | Goo. | M40 hh OAS Aon W001 | &9,0 AG Q,Q00 AY }# goo.igr| 29,0 it O, Aud Loe Aov.io™ | Bd, ee 0,400 | ke © | 2,00.103 | 84,0 A HBL Qos4y Lae ang & —_——_—— Chat din ly: CHyeoonla ah | C T ve x 4 [00.0 | 23.8 | oy | Aat \ febeeas [cont vin | eee 224s | Lua | 5 [hoo 5* | 29.8 6% Oto _| [asy Pe 0h 0, aaa || aaa ~ T © [avis | 99,9 4,84 oso} fags | op. 1S? 4 6, 5o4 06,0548 & | 400. 4 0 \wes/ | Rang 3: - Chatain ty : Nace oar | © | T x 4 {aco | 29,4 Abt £ [6.00.87 | 24,5 2204 5 | 400.6 | 23.9 220 A | son. | 4,8 wld § |.400.10" | 0,0 Qa & [000° | 30,0 2284MA sOSV: jolldand Bai 1: XAC BINH DO DAN DIEN DUONG LUOQNG CUC DAI CUA CHAT DIEN LY MANH VA CHAT BIEN LY eT CAU HOI CHUAN BI Of C&u 1: a) Dinh nghia a6 din dign rigng, 49 din dign mol, 46 din dign dwong lugng va don vi clia ching? Trinh bay cdc yéu t6 chinh anh huréng dén d6 din dién cia dung dich dign ly ? b) Tai sao a6 din dign riéng cé tinh céng ma 46 dan dién dong luong thi khéng ? Tinh 46 din dién riéng cue hén hop gém HCI 0,05M va KNO; 0,1M_ cho biét 4$ din dign duong hung tuong tmg Paci = 429 S.cm’dlg™ va xnos= 146 Scm7dlg"? ye Le af -06 dém-dan rig, La gid aofich clio oer aien 8 nang , eds itn exer Wier eld ord chearh Ey Shin wn fee le phish fo grils dome (a sent) ~ 6 din dan anol Yyleats donation oer Min duntfdech non qua SAdn ox 2 ity ohn Leva chef in too co th Son dah ha Al htc IS (Abt, {T'en melt ~. 2 Ve dicta Wing Malic dy Aan ca As dang dah dim ui itn ok fry Sc ofl tk et in oe Midd St gg Gh. Tema), pe gn . Mon - ~ Chi yi t€ coh Juithg dérrab clin dhitn cia dng dk Qn le Lan tt eft iva clang, ins, big 28 cheek, dct de. b/ 06 cin chin cit Why cft-tih Sing chro cht ving Vex nit 28 ditig ania dinh rah Jding the 7 obo. ode GE AE det ag Dcbn Lidteg i nq eng Abe, ft ce Aen Cuts thy clo Ae A AAS: 0 ae Lodger cae ny eau, ? if wg = Bud = Kyee + Graves 2 2 Ara-C + aces Mae POS = Cail soni Cau 2: a) Cho biét van t6eTuyét d6i (linh 46) cua ion va df dan dién duong long cue dai cia dung dich dign ly ia gi? b) Cho biét pham vi ép dung cia dinh tugt Kohirausch? VE d8 thi minh hoa va chi ra céch tinh 2, va hé s6 Kohlrausch A trén 46 thi? Néu cach xéc dinh 2 cla dung dich acid acetic? af. Vb $8 hangin dng cae ery Adis extol A Alan-tnddg AAP being A altBe qe la link Abeta ica. . j d 08 dfn en 7 eae ire ily ade datvdetn & enn AS 6 cuing lod lg Ileg & ig A NB og eybl Dish Wat chleusch clp durg-teng tate Lip ede cbt dan li IGA alk we cab Big ich old enc spel hn wjae Ube hou rh Aue wld Dlg ce chigogt 2 Hiv uy 1= 4G), Ae a8 A 1a —tanac, Lb tena is he bBo squid on Lhtag Resqug VE (nal 2) ; _ Sen ii lll i, Ran ele. geno ies Veli dévion dat bitty ta Shan ot, cd, chit cian li amanh CHyCCONa , Nace, +02. © é Ae, eH, Coott = Aceujcoonta + Ae-aee ~ Mo, rlace ‘Cu 3: a) Hing sé dign oye la gi? Trinh bay ngdin gon nguyén tic higu chinh hing sé dién crc? b) Tai sao phai 6n dinh nhiét 46 dung dich truéc khi do 46 din? Tai sao cdc dung dich acid (HCI, HS0j....) hotic bazo (NaOH, KOH, ....) lai c6 46 dan cao vuot trdi so voi céc dung dich muéi? Tir 6 giai thich tai sao viéc pha cac dung dich HCI trong bai thy tap phai that chuan cod i c O04 4 eee) 21H djl ty ¢ Sin dur dich Lin RE At in ance $i Mea ro | os ey v “hh nemars aks =K - Garde = Ae Com) por Lg, Aeeang 48 in cube. | . > = Nepufin ie Au cht ditiog weatanede © At dburg del ofusiin weet ete ate AG dén, chink WS. a enbit EA, GIo ve abet BE ap chive 2 | Gs whan Being S8ai8n cule: 06 san tren cork gic Ahad dE ade ata lchadin thin crush 1B Ve Uy ob gibt alu! a ; me Kye U. re Bante >, 2p ope a 8 bf 86 clined clang eek fi da uit, vitals. Dede oo dob wat as tie fhi“atercAt chon ldo api tiv ds din dey e e, dabinaicey 2 ; Dx ded base (do OF) Z Sh didnt 8 dd acicl (clot e(d a ds ee iz abel usin to ma (a 1a to tha oF hi i oe beg Gb ce een, i ig Hi EB opis er ae 9 lo lin che. dd cae hte cid he Nie pha ROE pw tat hv do ‘eb Wifi Lah ai Aah ants EAT cag cot aia atin ab Aiaylin rt (Bs vt AB olétn doce 2 2 unio dau 86 en’ “ aeHo va tén SV: TRUGNIG- TU TRAM Maso TT: MaséSV: A014.298 en-Ad BAI TUONG TRINH Bai 2: PHUONG PHAP CHUAN DQ DQ DAN XAC DINH HANG SO PHAN LY CUA CHAT DIEN LY YEU BANG PHUONG PHAP BO DO DAN I. Muc dich: “Sie a Ay do Tae oh ly ato aedes, Gin Sud phutén d oa “cain Re 2 ee ees ~ Gam Jae puting phd) xae'dinh Aang 46 é phan ly ala, acid yee var baz gin bang ato’ “AS ch IL Nguyén tie va. co sé ly thuyét: Hing A® ain a Ke ela, “hecoor dite xa xa think cla veo hide thud 5 30 t aE De®) Tint A 8, Aeon do dey De cho chute clan dl va ot Sb ehh in ach dic Gat Load HP CHeCeone <= Meet Ee) “e Osiney AS lhe tae ot Ne). Uadutetish dit waa AE AS! qe etka ag iv cpg fr tinh va ala dé ction’ Aoi her cites Ara tha ite td bit thik ong hain tre. Ca) ing AS CH, Co chet. Kae chin’ d, ig lng ote. ae la fle ghia hop A ees dé ct ach oats! G_ cene= CE Sees lo Neote 424 Bychen a hs eps Natt la tai Aeeun Frain Loo « a) Nd Vatoart II. Thye nghigm: Sinh vién trinh bay 16 rang cdc bude thi nghiém. # Chun bi hi tah — Ruta Aach va onuibe, ech ode dung ou ~ Bk ie ot Wy mde Ro dt ls ded cua ube ies ruth dif &y8. orf 4 Pa ekg dich ae = Phi 80 ml. chang dlich CHcooH QAN +8 cl lib OS cha om 4 40,00 eb ne did wr pha cho Va cb 480m gach cb Ren Thim Advang jac rude, Kt. it tin fog te vee Fes nha, ie elo Yao dung dich 200 cho clung lich, ue CAE & Chink gfe vbr Ui gf 38 A cin 4 el Maite ©, 0 HL lun dich Such Naot 6, 400 n) +E ‘He Mt a 1 hd oh Might hi bin 88 ds a baat aes fam cio a Whi Reich Nao Ain wa lr pent P = Cho tidig 4,00 rel. clung clich chuity NaWH veo ce VE Ip lar Haw dc enka’ Ain . Niguhg Adri Hii dung dich cfusdin i, velo Liz 920, 00 mL. - ee Ahi Le Arison). XAC Lis Nat aig ae lung lich vila pha . * ae lam vide va clo dé defn Ca lung cide CHcrOH vita phar 6 tin pha chi So ml ecle es “clich wih aicag as gh erg bang. be clang did da pha vaio ci Som.8 trang 08 bo ng chinks dung diy 22 Aifn - Cho ca cbt dy eich i pha vaso bes & ant what . Che” dung dich én rar ve arin ‘ion Ruta sad didn ik trie Li do = DoS dai cura™bdi dung dich it Aube loang cae. Gi gia Ai ds dé vat vit AS veo bain Ze lai"didh ode Va Nek thule ii Lath en va oe Uy Ba AV. 2, Xée dinh hang sé phan ly cia CH;COOH. ca ven Ifp bang tinh ton pha dung dich CHsCOOH véi ndng 46 chinh xéc Tell Bak | Dangdich cing Gi pha lees Dung dich Aantebs pha locing | | a “Thad tach (ay Dang cu “Pati iy Met 8 i pha loung | dang af (4 | ph a) ved Shan ish | aca a 4105 50,00, Pipa = & [¥,00.107 60,00 Pipet | AOU, 00| |ssow?] 80,00 | pipet | dov,00 | Ad [ane A wort] shoo | Pipt | asovo | Rel [pow S |aro.to*} 60,00] Piper AGO, OO Rot }e,saw? EB Wro.wr] 26,00 | Pipet | A00,0 Fiol |] 3,38.109 | F [ii5*} AsO Pipet A000 Bet 4195.16? IV Két qua va tinh toan: —— an 1, Xée djnh ndng 49 cia cia dung dich pha CH;COOH: Dung bing két qua Nogij = AO-OOm | yao = OCON ves 46 thj biéu di&n méi quan hé K = f(Vysox)- Xde dinh Via va tir d6 xée dinh Corscoon q A Niniac nt) | 2 (us | Naiaott (nd) | RLuSeri®) | Vycaort Corl) | % Cu8.c8)| 6,00 ALGO 43, AGS 6.00 S440 | Anyoo AGU A 6540 | AS 00 othdO 4,00 SIO | AMD | Ad Dung te 9 = 4 nao) er Hf alee Aink A. - Nha chun (ei dln gay ca doth. Lik gine iim we Glink hh AB Hh Ania Yd AE in sk phidog toh ih guy. y= Bs BH SAH var Y = e209, ACHOY er fr Ae Arca 6 elim gy o> Nut = FO mL Néig ES eta clang lich acid pha la ——. N ~ Noyes Nit _ @x00. & 80 a euerow = me = = 0 08 ON) = ¥, 90.1507} noe a a Necoout A0;90 Fiat wg lS a cai lat ch veg, AO ete ang lich pha locny « Ny = Naa Naa Nd tink. nl bao Ege we Pha = —T>— OS ; Fars mi = $28.10" (ni) arg bh hood bi 0 Lae, bang ee® (Sco?) th Nu 10 ‘Vwaon (mt) Hinh 1. Duéng chudn d6 a6 dan dung dich CH}COOH bang dung dich NaOH abe Nfan xe, Wing chukin ASAE clin Caco bi ban desu gia ou lsicbingdén nd Nao an a gee He Gebthich ~ Medi a6 din akin oa. lung clic giton clo-teo-tfcc mud, cue baz manh Ne ceiel yeu lo CHgeoonla.Uudr CHycoorVa 6 eitng eusien VA Cisco WE acid acdlic tt phén ly. Vi Cll COON leona Suce baz manh vii acicl yi nin phn ly Skt Ahén—tao-tReh CH,C00 va~ Kan GIG" oes anid lam choXeSin babe, phn ly esta aerd ecole ChyCOOH = CH,COO + Hchuen clich acing, pRechi, Leim cyicin FH], cle Asc da Racin, be 0 Vin Red)" dm = Cake arn Naot va Ahi AS dandan cies muir, CscOON carg ist att ohare a8 dan din cia HCOOH nin elo én cue clung clich ect adit Aang Doan BC Hen diaih ) — Sear Li ttt iar eitiy ut \leg , AB clen cue. durey cicf-ting heurh Ber ae Cade ead a tg em cary ty ofan0 005 01 015 02 025 03 035 04 045 05 ac Hinh 2. Duong biéu dién 1/2. = f(.C)J &. Xele duh Kang 88 phan ly. ta. CH, court (+) Lp bing tink ton vibe 46th xe dinh hing s6 phan ly va d6 dn dign duong lugng eve dai. So snh véi gid tr] so trong sé tay va néu nhan xét. Baby’ : stt| c |T@ol K Ey 1a aC | AUK Oo) i8.cm)} Bork eg!) | (Clot ug) FMI} 24.9 | AbdLo | Wd O,udS O.AGA | 0 52 Ae4.0"} 273 | S250 | AV ©,084D OBS | fi S2 Ay20.10"| 97,3 | 30,0 | vat 0,056” 0,230 | Aol 60.107} 24, | Mot | ang | 00402 |oded | 2,69 9a? | 27a | snd | sho ©,0294 OMS | Qos 95.107 124.3 | eed | Ae | 0,026 0,082 | 6% Fie a} mf al wl wel a i ae HEAS ofl cua eH,coott. e 344,65 + 0,0206, 4019 %. Neto. A _oolkg £5 + O,OL06. = OIF X= Ree x 549,654 40,9 gi x, $90, 56 8 Fa 2. Eye NE ty oe on “4 “ feng dertey, Derearecoi e Pe go Las ox (o4,.3- 45)] 390,52 erat QOS L) = FO, IS Sem? eq') + Ganbtoxn gibi reg bag 3: —____. Kye ee 5 ys mee rr Rar | en ° €Ap dung ding ti cho bah. Die) ike AFCO: HoHOIOF _ pence YD Sem eg" Cn 529.10 - ne gag? gt Ko - = SA GMI yy gS PRA” Towss® bon, BRA Sete che ode bank con lai, thin te bang 26 ld & a Qrbng elo fi eee 4Che) ‘usted, ta that Alte Ay thing & & fu i ae Y= QotltHc + Qo00b i Hl ao Gu & tonx=— » = = fb. 10° “ee mae? & Rae” Gam, Hoke — «Gi dae Kau bien ellde. ho bing adhd Ite pr = 580 7 A pla cid eka C6t0H a ty Ae ye Aas. jas. 6 ake nifandt ik Shs bah delet ode ic Aide, Tabet + tie wa =a re nica de oe aes Jy NO Ged Uta > Kab coh duly net (sate 4 < eee) — Gabi 3 Le dg Abide ree hat Nang, 9 ‘4 fang 6 8 icy BM af u Met me ~ Gia thi %o xce din WAH. Ae=, ime MOL Screg’, it [4 tov, gate rae alk“ Sha dva gichi-de eng being Lia D8 6 Aha nein lx, 2 ox. Wk tub Myce ole A infu de det ate = havc nia hl arg eta pha 48 cin d Wig ste Ca at do cin git hed hel hun ve a qt thin a! ch ous Ri nbted Hh « as jovi chute HU Ul 7 2 phdp may cS daca hay oO Er Oe icon th 6 Bn cua acid Ba cb Ah CLR ede den ley (rate dir yi ay ling pay gma fee fa chat hin ly fe do fa Mo fulcang an que lh. a cueMa sb SV: AOMMRSe2 CN-45 Ho va tén SV: TRUONG 0 TRAM Ma soTT: Bai 2: PHUONG PHAP CHUAN BQ DQ DAN XAC DINH HANG SO PHAN LY CUA CHAT BIEN LY YEU BANG PHUONG PHAP BO BQ DAN afte re CAU HOI CHUAN BI Lo Cu 1: Hing sé phén ly la gi? Hay dura ra phuong trinh dong thing c6 dang 1/A = (AC) dé tinh hing s6 phan ly K, cia mt acid yéu (6 hing s6 phin ly lon K,> 10°)? — Xek ort acid you phan ly thao pfutagtrrh s Ath <= Hh AT “Wing £6 chan lang atte. phein dng orn & niet xde Cink Ele al fing 58 Phenly eu afid, Ju Iw’ or 4 8° ear ge bITa Z Eas Lae _ 96 dan din cuichy sg Ne wa dé das Aan die lig ow cc yg tan JH quae. Res Ce Ca Lact def Uy) Voge UAT 2 te. AeMAoIE ; Bal Ana A-Oc/ Ag) a At EOL ~ fu 2: Ve dé thj minh hoa ham s6 1/2.= f(AC) 6 trén ew 1 va chi ra céch tinh Ky va ho ola acid yéu trén 46 thj ? Tai sao khong ap dung phuong php trén 6 tinh 2, cla cdc chat dién ly yéu? DE nghj phuong php tinh 2, cia céc chit dign ly yéu higu qua hon cho vi dy véi dung dich NH,OH? 4 os - . ps Ao hé Pod din dia nln lich, eH goo * ROD pee Ae au Dy cote . Voy pe Consign =A). Mary gH A RC inv Or Heng 58 voreile toh aAunh vi Xo- ules 1NE muffin dB coh ee dish Abictung AB ee wt Miner pfu phe evay Haig iid de ta in (A 3 fy 2 a dan of aka Hak aa Wi sede bedi gpien lie AB Meyda Ait bg 8. en ecafchdin Kear chien chang we Anuuyor = Aerie + Aoatacne Renee Oo Cfu 3: So sinh phuong phip chudn 49 46 din va chuin 46 thé tich? Trinh bay céch xéc dinh diém tuong duong (minh hoa tryc tiép bing 43 thj) cho cdc trudng hop sau: 1. Chuin 46 dung djch acid acetic biing dung dich kali hydroxid 2. Chuin 46 dung dich ammoniac bing dung djch axit chlohydric 3. Chuin d6 dung dich acid acetic bing dung djch ammoniac 4. Chuin 46 dung dich natri hydroxid bing dung dich acid sulfuric Se it a ha cs REE, bean en va ch cain xc tenth akin aS * i otaay coanet 46 ‘die. batva otra ” ~ Oa chun 6 Lhin «sca & clan tithe Aig clute « cetbsd: aut Eas HP a lve ctu plas ie pact i di Sa, len ale ic AREAC cag a bu ~ bag AB atin dang dich ofan pis ih hdr eat tin clungelich fn in, ular onan “tency th en Aran bi ainhy WBA ala. Ss locum aids cn rag suit t a ae, Be dy da. oe ne ita Cah xa hinh alin ting ces oe diy ( B46 apts obey 3 hacen Bagh se tS Meee4,0 Ma so TT: eN- 43 BAL TUONG TRINH Bai 3: XAC DINH HANG SO PHAN LY CUA CHAT DIEN LY YEU BANG PHU‘ONG PHAP CHUAN BO DIEN THE Ho va ten SV: TRUONG 10 TRAM Ma sé SV: AOA QAy, L. Mye dich: = Chin Jada hn a Uh > Spr os - Ai uth do 20) can caw 48 Abn hee va. pratt ee canes, tg 4 ng Suip cuss dA Rd ade ehh dadig 86° OL. oe ties va eo si ‘ote thuyét eee ly cha cht eae ud ain 106 by bin fie pedp cRukn ia ae apy e f med hin ole ha tinh cath aim dian ote ché-thi Gad. cd you phan by thac tinh: HA = ta aT Wah eek ted wt a THA] Teng qua tinh ofuldn alg act huge cin ac mud rl dang baz. Lan cia aie the + Now —> Naf + 4,0 nla as Peel sheng Hitt Bahn HA » biqua ex? HHA] = Cacid - fA) ve (A) - 4s Cad fin aie Kas Gace) but] - Ss cath) Ly lg fo ta hag yesh ig ay lager Col — La) ot pes phan log T Cruthr +E] Nhl vay, db de hah @, (, oa mot acid your te cling det. pth = 4X) vA pha? : Count — HY ce atta de th X= logs ey Pye “ : ; chsh la pe Wicd 0 xFT dig Wbp acicl ett ye ar oe FH) K Couusk cel Coad Whi dS pth = pla log cid Casi “Teng —hritig Agp nai, oi. atin veg fic at gute. ithg acel “acon j 1d pits pl. d Aiud Wy , eb HRS rit ro hae dpe didn old xde tink pt, Abi sao la pKa ea! Aa et Veda Vad xtc dhitig. cong chu ILL. Thye nghigm: * Chun acid yin bing baz mank : ee being Nadtt 0,A00N ak dung ci thi phenclphhulain cle bit Vip ( @huiin-ths) A000 mb HE 04 OAM cho ved beclar 100ml dd cb cde “ihn “chia xhe 25,0 mk rey Pit c&. vito rndy Adawsir ee, Addy clés dung dich. Tt a fan elie, wid dung dich, Ghi afeun pt. NU, caval non Otcund en te eer te end di Meity che oh oki oan — lap is bd reg ae Chicane Naot thin vae aida aut com GoBML - Lap lai tha tacais Aiki ptt teong Abt ngot Leann clin tau bike orhday. = Chudn tilp ver third Nava then veo om’ lan le O50 we - Ding Adi ZVvwoe = ARNG 2 ne = Rite sachs chi ade vi lung ou. Witte ht refi _ Wag EER pH= 4 Uae) aE ae doh chia ke Vega Ata AAC, O4 he Neat ay UE Nae» Nyai= OS Neto x8 Uy 38 ba , fag do Ai ptt= &) che chim titi Aik, he fl ve ple, oka esol, yee — Soaanh gia thule argfsin va" ye obi teng s6-tay Nhe yd. yyHinh 1. Duong cong chudn dé acid oxalic bing NaOH 0.100NIV Két qua va tinh toan: > 1. Xéie dinh diém twong duong va ndng a9: A. Thé tich dung djch C2H,O,; A0,COmL Thé tich nue (ml): 25° Nong d§ dung dich NaOH: © 4001 Nhigt 46 dung dich: 04,4 Vuuon | PH [APH | Vaso | pH | 47! | Vuwon | pH | aot | (ml) AV (ml) AV (ml) AV ooo [aa AsO | 34S [ors [49,90 | 886 [aco Os0_ |atS | oogs | 42,00] asa | oO MH [AS 9S | G00 | Ru Ao | 446 ojos [ws | B64 | a2 [to 00] 6,49 | 4, ¥0 [aso [nF [oo6 | 1900 [pas [oe [20,05 [6,38 [5x0 400 [Al 04 | 48,50_| $84 | HAY] 86,40 | G15 J] 9.60 280 | 13s [ook [Asm | 3,92 Lore Pod, 18?] 9,22 |] 9,20 $00 [ASS Too’ [ansd [ota [ory [2020 [9,75 | 10,20 iD _ | AGS [OB 4,00 | #O¥ [| ow | foes | avo2 | Cyd 4 [age [aor [asso aug [oa [20,30 ]r0a4 | 80 HO | 499 |Owoe |Ae,oo layers | O18 | 30,36 | 0, % | 3.00 BOO fos | OAs [AG SO | 4193 | Haw A0,ho | AoUe | A,4o FD [tod | 0, OF | Goo | 4.43 | O20 | 80,6 | 40,58 | Ad [6.00 [aav [oro | aso [asd [aro | 20,60 [40% | Awe 6.50 }820 [ore [avoo | Aree] 0,26 |, 6 | 4a,8 | 430 FOO [2 Lory [AY SO | AWO | Ove | 0,80 [40,9 | O80 ae ABP OAS Ago0 | 4,949 | o,3e | 80,40 | adioo | 0 40 oo | tus [oa [asso | 628 [osx [ eaoo | mor | oro go [am Tore [ssi] 33 [aco [doo [nae [33 g,06 [&oF | o22 [Ay 60][ 38 [avo [eon [ayud | ov 990 [39 | Oag [4S 70][o,s0 [420 [aaco [asa [ore 40,00 [ade [os [449s Poca [] aro] 2e,00 | 4e0 | ose 40,80 [342 [ose [aato | seslf xwo | 83 s0 [ance | gaz anoo [528 Tose [rages [5,43 [aco [bed [aan [oar XAy dung dé thj pH va (ApH/AV) theo Vion Xée dinh diém tong duong thit nhét, diém tuong durong thir hat aie cong hues ptt Oe) va * dy te i xheelinh cht Nis) = Ad a fay me Nagy = OS Niue = —2. Xae dinh Ky va Ky Néu céng thite lién hé pH v6i pK va C#* pit= ph ~ ley eae acid — [a*] a+ Cat] Sinh vién lap cdc bang sé ligu. Dyng cdc dé thj xdc dinh pK, ti dé tim K,. Cho nhén xét vé cdc gid’ tri Kay va Ky thu duge. ‘Thé tich trong dwong thir nht: 40,06 mL Ong: a Vhaon PH [W0.Ca [iC Cats [IO Cae x IgX (al) oe) Gu) cy) 4,00 Art ASR O38 | Ath O,B8t | -OUe Abo AS gos O;UMa A GR ©, 354 =O, 44 &UO Al Qld Osh ASS 0/301 | 0,524 8,80 ANS of OL Ot Ay HA OQ) &IU_ | — OFZ 4,00 Age ANG Ot | A138 286 | -0, 8492 510 Aad AAO | 409 | AZo 0,234 |- 0,625 4,00 ASE ASS Ay 0d A\AO OM |—Ob&t SO Add Ay HA Ady AOR OAV | 0,74 00 los Aa ARS Or S94 | OAT _| - OTS So | otod | ad Ate | 0) VA | O due [|~o 36 G00 ty 990 | Aub OFLA | ALL | -0 Ab 6.50 A210 O88 | Ast 0,654 | dod | - 0,98 HOO | &.2% OAL | AGT 550 | 0,0806 | -4,0% "SO hi d4 | OU | Ate O24 | 00654 |-A) BH @,00 Aiud | OAD | A, RE ©,342_| 0444 | -1220 Axe) ob G 0,389 ADS 0, 288 | 0,034 | AGS WA / 6Hinh 2. Dé thi pH = eee ace cho diém twong diong thit nhdt «de cae ta vo - Me Co Not 7 os Mi ys ttle aad band ~ io? Nos Al al ee ben (Fes Nancie uc) Neds Vat \ Cag = UOe=Brao). OA ece (wt (WD 96,00 +o _ Cc — 400, 0,00 _ JG, COt 4,00 ye Sed = Cased —H) | 4 SLMOF- ATH or = 0, 378 Cai CT dH 16h + Ah (ot Bah ton iéng 12 cho he N cheny Mhecing Om aia, Hae Ae bang 2 oe = AISTHinh 3. Dé thi pH = f(logX) cho diém trong dieong thit hai Le a DANG tim Cuag = Se) Rawert oy Aad Coaar Cee oh a Net = Nilo N= 4200 ) . 080,12 - A400). ©, to z Coss eg WM Couns = eer SQ. mw) - i + , = Cont = EH] Aeas* 929 10# Xe ee a I IO eg ay Come + — o6t4 1624 £29.10" ‘ Geb tg A ca ede ARG tg, Hg 142g a die bing ».Thé tich tuong duong thit hai: 30,12 mL 3: NAOH PH [aceCaxe |] 10-Cmuti | 10% Cus x 1gX (aL) (wa) (My | CM) ALSO 564 Argo Oy SAY Qi L49 AG O, WoY Ab OO be Aue 0,613 ATT fh DU O, HS AD 5,84 ABE Ov x03 Aas Ae ©, £40 Abo $92 Ais 804 A\20 LiS% © AMb Aus 2.99 Ada ost | Aon Aer ©,094 AS, 00 408 AOL 98% | 0,984 Ah © HOY AGO IAG OUe 4,08 0,692, O35 | -0,07” AG,OD Was O%O8 Aide OSG OR | -6, Abe AG, 80 43d O. 40d A Ze O4oe 0) S94 - 0,284 At00 Aad 0, $00 Aid 634% | o44t | _o3m AX AiG Oon44 AMY Oaas |O349 | -o,ust Ag, 60 4, 06 ©, 400 ASO 249 Oss | -0, 994 ABD. be 80 6,30 ASS 0, WX 0.494 |-O7u5 1 Dahg aethi pt =p llogX) cho thick Wehg ditng hae abit Cenk 4) Hua itd Ting AB gée claw Eaitry és g Plus 2 Ring tink Ac quy =~ 7B + A MSY chinh lit pla, ctta. cred oxalic AAG 2 y= 8510" Cia trite “eng A doy Buce. B= Th. lw®x Wg dé afi pl = 4Ulogr) cho tf tech “ih ig Clty fue of tha aie phat Anak Aa g Y= - O99 a (Hak 3) "ny te cua hag uy chain a pha, pKa aos $ tn 848,105 Cid Fe Frng soda: y= S167 a V. Két lugn: Muc alich eta bint gh dat eat Arlee , phuitty 4, Php Ce, Ab Hi ob AE at cag AE ve ish Reng 8 6 ee Phu ghitp nay actin Bh 4o va i ity phap wind ts Aili, outa 2 eid phn by ei ake Ahan xet: = Coe gid. te Ky Kade mghiim cb 42 chin lady 20.v & enya z rh gid wattle do Bt of 10 See Wea, Ahad Az (a ren Uy a 5 WALL dui Lech Acting 40% fot Eeiopiee hap’do nay Av OAS chink xe heim Reh pludiig phap Mele Vier Nia Vhong iti xcu dinh dtc tilp te Rude dito pan tilp 2 Nite, dodo Nyti Lan chute, obi druding sae ul, d dat la ede _——ptt Ho SV: TRUONG 10 TRAM Ma 86 M& sb SV: JosH2o9, eON-AD Bai 3: XAC DINH HANG SO PHAN LY CUA CHAT BIEN LY YEU BANG PHUONG PHAP CHUAN DO DIEN THE opie CAU HOI CHUAN BI EZ Cau 1: Trinh bay nguyén tic cta phuong phép chudn d6 dign thé (cho tnrng hop pH)? Vé hinh ‘minh hoa cho trusng hgp chuin 4 CHsCOOH bing NaOH va NH bing HCI? Chun dé aliin thi Rep pi: chudn tS cetd—hax 408 clung dan cue Sle ik NA in Hd Ato ae boebn-Hakn pra deat quel ha ny ating bitte xi Ainh a natal fs att se SE, ee driin duffig chbirds tarlaciy bedi clin pls fuse qudethit dian cue £ vais dung clidh Sutin fom van ye “ah ey cong. aaa oc 148 chug lp. 5 gol A ry 1 L i ror ! 1 ° BE ; ae 48 £0, To WO fo Yuen ao 40 te Zio Oo a @ yee Cau 2: Hay cho bié pH truée diém tuong duong, tai diém trong duong va sau diém trong yong thay d6i nhu thé nao trong qué trinh chudn d§ CH;COOH bing NaOH? Trinh bai phurong hip xée dinh K, eta acid axetic trong truémg hip nay? Ve hinh minh hoa? - Gini Aim clung dich Saeiel y% 4) =» Ja tam. pt elle Ta dint pase Ufa sade area pe acies] eh fan Nasi, a4 Byte gia, > Cetera “et Chase aim ntl ac A Py a Ay nhl clo on odo Laven so é las he ain ring of‘ [acid} Gy Dias 4 oe Cia de pits plat pera]: Karol acid WicAn ( vb Vgsy hy Aig Cail ty uth se nip AiR Wb a ARE nhc in Nao Vy, Larg acid lot (2 ver Nya — Ve Niue dy p= pias p HN Gardin Ne Nhs dhe pts pl, Alh2 vay co ARE xe dnb Ale pl we hgeoow By UG, afl i ona dice Vey Chunk Aron 8 Aah A caw A; Gps bomt vay V=GOmL eb pha= pits Aas 5: ai , tai i chudn 46 thé (chudin d6 thé tich) dung dich axit oxalic See rifetercaie det aera eae a ign thé? Trinh iy nein gon phuong phap thyc nghiém cla qué trinh chudn 46 dign thé dung dich anit oxalic bing dung dich NaOH. = ~ Cin phe cudin RS clang clich viel Onalie snide debi dp dung chusticls bra Phi lg cud Al RE le xd tink hk dabr dy dt 8 Lh fib hs boooki whim hi Pat Lschin cee i ig af Noo rong Mheting Nyy vi xc clin TRS B-taorell bit hihi wcle ote \ yeh Pritt pap lute tnghim * (© Vay A000 mL-H,C,0,, choir erlen 880 rmL- Chadin fhS haing Naoteown) 972 lun ar chordlpbtalan =) Veda Cee ¢ ~ A . eee ga eli lin Suh xc 250ml re am n ao hy © NRHthy OSL wae OABON ves cli LS tae, dg ib age 88 Sratinh, Ofienhin git oH HEN THM. Whey lau “Talon wi @ Vip ll bade» clih oh ys. Cidmclt-bil Nast mvt wk, palmar a : a vaio Yuet) Ll lin Abi ping St nt. lam hip Bani. ©) Balin hip VORA nlaok Rin vas lh Lz G.Souk. dy Ahi EN nuow ® Aad y Peay oF OOr nd.Ho va ten SV: TRUGNG 10 TRAM Ma 86 TT: _ Ma sbSV: jolbddd enl-4d f BAI TUONG TRINH Bai 4: XAC DINH THE BIEN CUC OXY HOA KHU VA HANG SO CAN BANG CUA PHAN UNG OXY HOA KBU BANG PHUONG PHAP DIEN THE KE I. Myce dich: Gin Ana phate, phap do ah landing En bang cla K Akn ek , e © Aue “cindy can ola RE Chien fice ae wal fhelp cad de ante od dg 2 wei Aha chudin coe ctlen cu or hot Lhe: IL. Nguyén tie vA co’ sé ly thuyét: Yeclink ARE chad cua FE FEVER beng udm dlé oviheds dhe? st Kat hudin Mind, hike helt ledende dona ee Me sey eH A 50, Nace a ae an Trg AB. lb 0b on hig sia. ping on fila Abu , rae Mande SH" cre Aunt + Ath Wide Wag Aithg , Tun; | rat nh’ tiin ofn hing Ake quiftctinh b& & ante i cult i I ret nl’ fan olin bing ais quifat tah be cap : - clthethée Lube Le op, 2, SR)? Cacti Ln np cn da. qu bcp Unc Ee Chests? + 6068 loglkinaeT® Ted 2 » fe e Tut _ in “hidg Aig the ose theyre dst oget za Ee Eesyme + oS loq CA] t c oO aoe €-€2; apr + Gog loc, N cs wer * Gorsleg SP (Ut tats 9 Ee Ete thé chin Vet a 18IIL Thye nghigm: Phuong trinh phin img chudn dé: SFé*+ MnO, + SHT > Néng d6 dung dich KMn0,: ©, 0.25 Thé tich m4u FeSO, : 40,00 mL Nit ats thi ngfuin : o%C, Bang s6 liéu thye nghiém: opt Aut + Abo Vuntnos | Eqs | AE/AV | Vimnos | Eas | AE/AV | Vicnnos | Eao | AE/AV (mL) | (my) (mL) | (mV) @E) | @y) Qw [avs 900 | saa [ar [Ges [sor [| couo O80 | Ad | AG JOS | sa9_ | Ao | 9:90 | Aono | uszo 400 | Aso | AK GAO 530 | 20 99S AQ@d |_A20 ASO Hay | Av Gus 5d8_ | Ao | 40,0 | Aoth | 260 QO | A%> | ab G20 | say | AO | Av,Of | Aox4 | gcd SO Aud | 22 9.28 53+ | eo 40,40 | 204% | 1GO 300 | Aug | AL | 920 $39 | AO | Avzo_| co _| 0 6s0_ | usa | @ Hi25__ | Sag | eO | 40,30 | Aor | 0 4,00 Ast | 40 ie) SAS | GO 40,HO | AMD £0. ASO | Hes [ae | Iu | av | co | uoso fag | 0 550 14 AO 9180 SSB | Ago | MOO Mw | Ab 600 | wat | so | OSS | sce | vo | aso | wow | ab GO 4RS | vo J,G¢0 Sbd ALD | AR,00 Addy | AO AC | AVG | az Ios SH }| Ago | AsO | MKD | PB 450 AGG Au 9,40 SYA | OO | A300 | Mat] ¥ &oo | 50d | 4 9.45 sa8 | 340 | apse [aA | 8 450 | sy | ao | 590 [eft] a9 | anoo [uso | a | ANSO_ | ise | & ASCO | Musk | 4TV Két qua va tinh toan: 1. Vé dé thi biéu dign sw phu thuGc ctia Eg, va AE/AV vao V. Tim Vig 1200 1100 + 7000 1000 00 + | E (mv) 800 ‘OE/AV 3000 2000 11000 | 600 500 400 300 a 2 4 6 8 mo mw ‘Viaanos (mL) Hinh 1. Puéng cong chudn dé dung dich Fe** bing dung dich KMnO, 0.025N Pag ACBL E = AU) vi aiding vi phn AE/AV= cain A aE AR, Hu ute Aah Cat Aah A ta. xclo'dink chile Nag = 8, 8% mL. 4 Nhe) in2. Xée dinh thé dign cure chudin E°psre2+ ‘Thé cia dign cue so sinh tai nhiét d6 thi nghiém la: 0,199 V Tinh thé dign cc oxy héa khit theo Eq, E,, va nhiét 49, ndng d6 cdc ion Fe™, Fe* L&p bang tinh toan va vé 48 thi Bresso: theo Ig[V/(Vie-V)] Xéc dinh E°sesira+ va n tir dd thj. Tinh hing s6 edn bing K ea &. NAN = AOL 5 Chor Sain td Vl = 3,00 mb ater N = 4,00mL i Cling ie tanh ean : Epotpar = Eft Cy. cdnh Vv = _ NV “Xs Na logx = bog — Nua-v egy Nuk Qa: Da sid add N= 8,00mL , 4 <6 Epot/pt = OAKS + 0,499 = O,6h4(y) L = 200 = gna) 2 Lam tea OHO 4,92- 5,60 Birkin thing tt cho 7 dim och li te aide being sous Womb) [ ea) [ewe OD] x | ley x [Epa 3,00 omy | oot | ono [-osst | 4s 5,0 0,454 0,654 Os54 | -oast 4,00 O,ASe © 656. 0, 684 = 0,44 ERS) O)KeD OR © vHe | - 40% F15Q 044d 0, GAL A, at 0, OH €,00 OMAY O) 6th Ast 0,496 6,80 3, ARS O, 68% A, 96 0,83, 4,00 0, 4G 0, G83 ead O,agk Daag dethi Epanpet = 4 llog x) hu BiB ink 2: 6Hinh 2. Bé thi bidu dién- Epestjre2 = flogX) Phat tah Epayegs =4 Clog) ob lang E of SOORT. N rey pet = Ecerppe + “ae Vy Dang dA Estyper = flog x) thucelibbe phaser th fi quy | ys 0,6659 + GOssex Sug res Epoymt = 0,666 Si dinth dood tae BEN 2 os ky = - tana. F —_ SoeNéu cdc nhan xét vé két qua thu durge — Cid Hi thd chin ade Rudin Efseypue 8 Ty = SC Hu cae bé Ade enghutin la 0,666 V , rai ich -19,STo bo VR gabe “ihe jit rer sotuy 8 cing ahit as la GAY. ‘ 3 Cid HAR agfubin alo chfbe gin vip xf vee gad hi by thus _ Theo Uy thanget, bea phen ving cifn afk cha op REM FE as Rie = ft Ad 2 taodir led Gad APRL ta xe Anh Aithe 28 2 tuo dé la Aoe A. Niue vay gee hi hate again Akin Ring chide. oan teen Alsip vty Uy hale” _ Gab nbutng, nein 1d Arn ARE thy prutty phap ce ‘valk A vk dung shoan-foan co RE aide ep clung”ae do tht: chasdn cia obadabn el, cing nf Aut cing 1 uit pny cn ee lay afin ARE hd Afy ich tke fle agln vn sai Uich so vb gid-bi Wf haf. Diy La do sui 48 creng qué beidh Hak ngfellm ch? Adbing pra 0 phatcng prep, bh net“ pheng Abictiin Jah Va 88°C, Frag Abii may de obi 2S, bid vbw cae gach ld ghi ledd 1a ode pth ala Alek aig te duit chinb VE o&EC,, 9% Aut Uh coe vest phat te Re 26 net cat at hong may vi sa Paes rf a van wren Arend, Aeliing chép ath AikoV. Két luan: Macdich oie. bar Afi mgfuim da chat cbiée . = Sle chin cng clin bang ofa Ad. cidn Jaca tts Aas, che ARE Gul fais Aen by clin 0& dung bein chat aide nds vcs of ain elo ee Ai. Teen boc the enghi ha, clung may lo chuyéin clung lad Att As Act cing clita in phuldig phatp A caung , a vee ti Aaa the. gia dith cle 40 2cnb elorua ne we (anode) vi dain aie chithi PE ain earthode) Tick Rep cing haw. Ni cuing vis edn tdng aflst rong clin ce. ORP. = Wg tht alo dhitée “Ri dvi anh, oper litn ate we clung club, ed oft thi x6 cn bing ofa ban phen Wagrcn ole. Dols soda Af eba Be din at oft a git ti clo. abn obo 215 40 veo Gin ade Ao rcinh. Grabs AR “ciin uke, chutéin {hut we cle Fen Arca hax. chinks lic git ts HE hg th Lh 40 scr Vda Lin Sule SHE. Tay whan Alin cafe SHE co onB A nfulee Ain out Aleta » cing bink Na rip itm do cote. gay nb. Jord, rath ly st on cee atin ode loa of (nfut abbr ok clorur bac tray caloman Yc thay thd. SHE Trng baitht ongfuim tu Me clung Ain cle 40 Aarla let olorur bee. Var thi, ain of rin thang SHE el wc link Exyete = Exteerucbec + Ecbmabalst = Ey + Egoudef = Piha, pip chad 8 ahdn hd to bn iin sl Minling ada he eng, a Th chufinds Ad dS xd atin Vg clsa phan bing Putin £5 oxi hoa Bie. Nifut abe toch basy eng oma 8.86 li Afauye APE chun Eco iin ode chiah hang thi eve tou thir iin Ve Lys Nhat ay sie dung pluthy pap chun dé ain the ai quip wach ohich wdc E% do gph Net Aehdig ade sui 26 cht thi nlue chuancls $ret => NAP vay, Aig gut quéclarh thi mefiien, gui 4RE chat chu titn cake BY Ful thou chide Wi Ej gee = © 666 Vo 8Ho va tén SV: TROCHIG TU TRAM MaséSV: 4014252 Bai 4: XAC DINH THE DIEN CYC OXY HOA KHU'VA HANG SO CAN BANG CUA PHAN UNG OXY HOA KHU BANG PHUONG PHAP BIEN THE KE oment * { ee CAU HOI CHUAN BI a Au 1: a) C6 bao nhieu logi dign oye oxy héa kh, ké ra vi néu sy khéc biétgitta ching? ») Tai sao phai chudn 49 Iai (chun d9 thé tich) dd Fe™ truge khi am thi nghigm? c) Trong phong phép chudn d9 dign thé dd Fe’* bing dd KMnO,, hay cho biét thé dign cue trudc va sau diém trong dirong thay 46i nhu thé nao va chi 16 cdc cp oxy héa kiir xudt hién trong ting giai doan? Tai sao? a) C8 loot Ben cxf oxi how ! Maton Ke hh ta qo: pin deg alin ouk Lda thaydin trang tou oxi Aca oka ten, wig Mog lain Pay fe lo lg filola cin Sel aas gidn p ACE deout dB oP dang oxiketi die. _ in ede ow fet Bh al tp pre. re ig, ok ety ain Raw 4b ais bie oni hia cng ud-thanh phn cat 4 chit hom g phanu ig. he cia chin ele phu fuse, ce fl da lech b]& Yo eth Kan dbs oxi Anche tanh Fe sheng gues drah bio quan, niengale Fe Rw chugelih hay aa “tuo tha peor ney pha xc - chil led rAle Ani el Fath Tide ie dn FES Bet va bad nchy TE Aonaz rit nh nn clon big AE id st bd ‘ndng AS var oengetha cba cep. Fet/ Fa”. ean i aH [Cutt cli? an ‘de qeuyeeclonh bir etp (UnOq Mutt * Ricaet aAstyg ase ‘Viet ph ate nate tis ch iy To" Bike dung dich KMn0,2 Va chi racfch tinh méng 9 mol cia dung dich Fe™ biét néng 46 dung djch KMnO, li 0.0250N va thé tich chuan Visio, = 10,000ml, va thé tich Vee = 5,00 ml ? b) Néu thay dung dich FeSO, béing dung dich FeCl,thi két qua chudn 46 ion Fe bling dung dich KMnO, cé gi thay d6i khong? Tai sao? Viét phuong trinh minh hoa néu 6? of Une + GHt 4+ SFY opt + Untt4 ALO ee Nao 0, Nee = Nawod Newer A ee gos! leat , 5 —Si Crag ee x 2 < —s (0100 Qu) €/ Ne Aha F804 Bing FeCl, HR dk qué cludin ElS ci-thay ct clo ten Ch edi Dedud, cb tht tele dung ver KnOe vie lain ayy, Ua deh thetic chm le huts AS FP mae saiab-thud, QPMnOe +R” +1GH* 5 Qin*t +5CL, +70 = Cau 3: Cho biét vai trd ctia dd H,SO, {rong phan ting trén? Néng 46 H* inh huéng dén thé oxy héa khit cia c&p oxy héa khir nao (Fe"/Fe** va Mn0,"/Mn"*)? Viét phuong trinh ban phan img oxy héa khtt ctia cdc eXip oxy héa khir Fe?*/Fe”* va MnO,’/Mn™* va phuong trinh Nernst dé ching minh cho su anh huéng nay? ~ ~ ~ oe ” — Ne h6 cha 4804 cung op Hohe pda doy got rack tein ait tie wo ton BS lean obSy8n dik Cn bing Feit & Fem Fétaung phat. ~ Nog ds Hf dink Aritag Serf chee ccip MuaO$7] dur a9 Che bein Ainein me _ Cac e 2 eny rau . FeO > Fete © funOQ, + SHt 452 > Alt 4 ALO oy 305RT LA) a OAR ABORT Leunois ITH)” “Lo teu) : Ew> Efeures + E 2 @) = Cranoz a /aae +Xn be du ude Uke or Ho vi ten SV: TRUONG TW TRAM Maso TT: eN-Ad MasdSV: AU#LDL BAI TUONG TRINH Bai 5: KHAO SAT DONG HQC CUA PHAN UNG IOD HOA ACETONE VOI XUC TAC AXIT BANG PHUONG PHAP QUANG I. Muc dich: “im Aula Chuldhg phap Adnto até Heng hee exter phe Bdo cts 2, ea cat he cde pbs dig Bo als Ay - Cin hus. pluterg phép xdedink bae vec nding Ltt Ret Rea cha. phn vs Wen hn te aig ta ol he. pn vy II. Nguyén tie va co si IY thuyét: Teena, rnin tniéng acid, cockene cho pian cng . theo phatg tink now Ae Cou +, 2 uye-c-ew,D 4 HT : ° - O° Ce hie ce phan eng aloes agi onled car a ee @ot Se Hie-G- cits 4 +t oO e-G-Ct, a Eon +X ow He Go + tt We-C=CH 4g Hy Aye SAL +2 Ce 0K ALC G- ALT SS 4e-G- aT + Ht ee ~ 0 BE 8 hk aie AE nef, , mgisrte. xke cbuh chs plating Wah 4, oe Gg Ws" os ATAVEN] DE atin ching lei, phikrg ctinhlee 2 fad angfatim eb Mbp v&. Aha Shas Weng, mga tort Yooh hse ak Vin ee ces hel aint aa ven ae anh de het. 43 pre og tNev d8 phandag aie. xée ink hry que “lo dip thas ponies Fa} va CST, do SY ofict may 1a Lchiat thay quang » los cb thE theo ela we-HRay AG niéng AS efi cfadngHheng quad hip thu quang . Chen a ie AB ela chung hong quad fp thu. quong tue sng Az SCSam, dba até ep 2&2 AM Wen, 2 3S A= eL( Cyt G,) 5 ve MCG) | dé oF ‘ > facta el at . Hang 28 vin fae obo. phan Sg Aik velo tanh chile, vaw ASA t= (tia 4@). C58 cdfuth & bry Boas. T), ee — chun ho “TG * tale wg axe-vel 7 se ela CAEN) 7 ae Ng a feat hots iteVinh-tct hit x8 © elon) ge ck aang Jur quip ayfin ti Ink = 4 O/T). Git tam = - Ea swap Eye “Rekones (Oo phtith Arkarius clam [nfe- id= SP WO. Thye nghigm: “I = WE quang phe RE ,ch8 A dink wa chedbbutce, adnq VE SE nim tha, chink KAO NO chang dich 26 26h 4a mide 3b dun dé phe dd ~ Pha cde hen hip co-theiih, plain calc ausk “thin aude ty cach wach mute oem . Che En chant mahect ffs shen tne. ght af tht chim = © “Thien rade ain wach alte Hay lig ae 2th WE due AB Lal veo binh Ait athict = fod itp “ha quang min tphdb. Sun Mi to Ad bs duung dled eng, cunette vau aren co eld nivp. 2p lei dfhas the dé ob 040 dus nie orox thi mahi « CR ding dee chinh shes geen nit man sao cho Whi 83. 8-10 chikin ARE New cio I. bang fa. _ bag ran lam Aug aung ob te. nghiim a Et dalam Ai qian beng: Pe dia bp pin tg “IN _[ nhstds (%e) | HeL4L00M Onl) |2, OncrsmGniy reetene (mL NEL 4 _| #oheng 3,00 Ao Ago | Thimdén Som &_.| Aoheng $,00 0 AO | Thim'alén Om 3 | Pohang [5100 Ao AO | Thimain Genk 4 | + phing S00 ho A\oo Tam din Dank S| aye 3,00 Ao Aw0 | thin dds SOL b Asx 3,06 40 AO Thin din mLBing 48 La thude enghitm : Binh I ‘Binh 2 Binh 3 t Chik) A t (pelt) A 7 t (pha) 3 AOI a O koe ol Adu 40 A,O6e Ad ©, bot I AyoH | _At A032 Ag ©, AAD Ab AyOaS Lt 2,999 Xf | ©, 284 ot 0, 9% 34 OSG bf 0/346 ay 0. 9A __ Ag ONSg Sh Oy Qte Sy 0.494 | Go 0,440 +4 OG ay, O52 | OH OGG SH | Oe go OSA AAK Oo, SAh ts O,dte Aue Oo, 4aS = | 4BS Odd 44 | odab _ | —_— ax? Binh 6 t a t r : 3) Aan 2 Aut a re 7 7.084 ‘AO Ade AR G9St zo ALOIS AS AO? At oan of oda 8 0,884 ae aa jt 9,408 38 OAs at OU st 636 Sb G S88 bh a Es 0,68 & Sid a a a+ vty ats oes a = AR Orbak U. Aktt (phat) Hinh 1. Duong biéu dién bién thién d6 hdp thu quang A theo thoi gian t cho binh 1 $8 3 8 3 ee eer eo ‘ySuenb nia dey oa thu quang A theo thai gian t cho binh 2 (phat) ip bién thién dé hi dién Hinh 2, Duong biéu‘86 hp thu quang A e ‘06 hp thu quangA a 03 ‘t(phiit) Hinh 4. Duong biéu dién bién thién d6 hap thu quang A theo thai gian t cho binh 4‘t(phit) hdp thi quang A theo thoi gian t cho binh 5 ién do dién bién thi wuenb nya dey oa Hinh 5. Duong biéu vauenb nua dey oa thu quang A theo thoi gian t cho binh 6 (phat) dp ién do Hinh 6. Duong biéu dién bién thiIV Két qua va tinh todn: 1, Trinh bay céch tinh todn, xdy dymg 48 thj dé tinh K cia phan tng 2, Néu cfc nhan xét vé gid tri K thu duge, Phan uf areal beg hin 6 gi bac O theo 2. bungie ehintan 66 Top ta quay A= 4) che dkcthe hin i 6) ib pRthg chin AL quy. cake. andr fi p dacothictiah A theo d cich ot Die! _ ACE _ tan« €o,0046 z a _ = Cachd: r= TF ries HMA Ton 4,095.16 Fu pet i we A095. 107 _ re a a Ae Teel = “at oceans O10 ut oA Cac8 2: cant 3B gé hag ge K Sco = tlt 29 (phd) ;. he _ 4,099 A= STE TAIN ~ Gn A at a5, O27 Gocco = CHET" 94 Banh -ocun titing be “2 cfio ed Ahk nghtim coh la tet ell being Ait quia. sea Badnaet inh teen Avdng 48 Bhi AB phan din tng: iw] fad_[Ca*) | tanec he ee pe oT rye] 1 [oz [ocGe]-ocows [1.0995 [tdtnnes [109s.to%] GG. 104 | Gite.104 2 [ott] oc6ee]-o,0089 [oui [ares [aaneioe| saa tot | Sta 1% 5 [o40 | o,c6]- cot [ainoe [702k [rosa ® | 9.10% | Grd. 164 & [ow [oscl-ooo1d [a reco | iec.2d [azar ws] G 40.10% | Ge o4 s & = OAT | 0,000 ]-O,012F | A MAAS | 96,52 48 $.10° | ASA. 13 AGA. (3 at fooecd|-oosio [413206 | 42,60 asuaioS] AiG? | A ee o> ae Ran xét: Gad te Afi. dil 8 of coh ti bing mou. Nfue Vey, ati-tich Arisng as. ea han ieee et cath ity die AB Tat a phon cig Aa “nl hay aa i otay dh ning d “ae a oe boda eke ech “RE oighiion oe 6, lin cig Ai. AD de tha as nist a phe dng. Rada, Aig 16-HedS of phacthude vow val Ab Wa Ati i ty — 2. Xéle ahink bie phan ng theo oni tee ci Pha ee cin ng = ALD ITAPLATE xi Atnshin 1 dong v= ACT AT EA eo (By) > Mga! TE © bg Bagg -alyt 2eretie0 5ee agri Ae 5 . (UAL fal, 4,09” Ott, we” ACR, ye leg = blog Tay, "8 Fea0 ~ blog Gy PbAOlee vit gin — LH tog EL, 4,085 oo os > (i) lapse lg Hes tog ae atone aesOng et Suy re: phuitng tanh ao oc that, Ui hbdo 254 tah fun Lee “4 wath Wacko] ognen la: Ahep va hung Aninh con Fret 8 eRib ae dei. Nhuva eda Nha ie weiner Yin! . x ed hos ace. sheng nin acd le Sdn ving bac A theo [acetone] i bac © theo (ny No na tz fe 3 A. Xale dinh nlang, Wing eee phén i _ St plus Aude Yona Hog 26 Hee AS vow what i aité tanh hay trey 4 tanh Arrhenius: Unrk= ln - S = > Ee Ende «) Gi hades nghuin “ta Hi. atte ene Bdng 3: Sa phu thug otta hk van T. [ant [tat aco] ost OM AO) ink 4 | 23 3, 5M Gte.10% | - %800 5 38s SUS. Ay 44. eS — GANG & AS SAAS 4@.io® | 5,340 Coch A Gib teen Arnie the Gab bits thule & hone ve ag rea gh rer aghr sal | 4 = Xd TWA va: Ea= Ty pog) 08) Inga = 4699 Tha = WS AT OTN ive fs Eqs 2 S02 28 Mie. 4.840 Sind 2 94, 24T in| exe Wiva 6: Ey Ges 200) ote ALO Shmol & FA, nol i m6, Ee SGU OM BIS | Mibe .10.9.955,6 Tol = 408, 9 kT /mol + Xe IN Svea 6: Ege Cih--ail) anal i Jimol no n E,= SS Ht OND Sabslel Cached : be dinh E, ban phy pp Sh > cig ae ye (wn) C63) Tat eae pathg Wea: yond, Wye + 3,65: eke =H SRY D> Eye MiS8S.1 Bate = 9448 Tol = 96,8 14 aebo 103/7 (K2) Hinh 7. Duong biéu dién In(k) = f(10'/D) vkétluan: ue ch&h ote, bai thi ng hubm clas tanh dng tng che Aci sect Jroe oe in gee ae cealae saad ek dia endng of filets Philp Aa he aoc ete Als See ies hm Wi ay duite ac lung = BE she Ahi hdie, exta. phein ving Rec" hiny Hock , tat Ad fey a8 ati yan 48 phén “Le typad nit AE cue Lhe we Se, ar lal 4 ws =i Aroxtt Ag. adie vderdinh Li Rhein sit fie lw EA dig fll fay cha hi Ua lie cull ge j dc sera! a shar Abnes Sa hs iy dg “Aocd ~ C8 che han sisi sty strait ely Seay ey eee mei lean chém ict, Torley,eN-4d Bai 5: KHAO SAT DONG HQC CUA PHAN UNG IOD HOA ACETONE VOI xUC TAC AXIT BANG PHUONG PHAP QUANG esfiutie CAU HOI CHUAN BI . i CAu 1: a) Viét phuong trinh phan ting iod héa acetone. Viét phuong trinh déng hoc cia phin img trén va cho biét bac cia phan ting vé mit ly thuyét. b) Tai sao néi phan img iod héa acetone trong truing hop thi nghigm nhw trong bai lai 1a phin img gid béc khéng? Viet lai phuong trinh van téc trong trudng hgp gid bac khong ? a} Phateng crn plan ing iod Area acehore Age- & eH, + Ty AC- & HT Hh +07 ei dg mlctic acid, phate rls deg dec eit phen tg: w= ALecoot, 1] a > tac “tiny quet = of b| Berg Chis an Ahé sngfun, rong ng AS ail icd tuBE a0 ues Ht Na aertene, Mido, thi cor ioc Cacelew] Ae Md ale troy Aaiot qua bah phan th voy, pos Ab thenk gee. bde O va a“ C4u 2: Trinh bay din ludt Arrhenius va dua ra phuong trinh chi méi lién hé gitta hing s6 van tc ~ ning long hoat héa. Ti 46 hay x4y dymg phuong trinh ham s6 InK theo 1/T va chi ra cdch xéc inh nang | fume hopt héa B, 1 40th (minh hoa bing 46 thi). 1 48 ph ok 4 | it ts phe ug % ao ge AS ie ie fil Ah Pirbonve: fez ACHAT Coy lig logant Avi Ink= Ina - = (4) wa)ig rth G2) oli AE Ahi \echiig thing ob Ait 6 go eB ve dung ab cre Lae Uni. ; : R 3 Chi xde Gib Eas cng AEH eT) Gai bi Elite ede dink tt Ina Ae 48 qc out aii An ay , Htanek= =F Eye~tooneR va Cfu 3; a) Trong qué trinh thyc tip, o6 cdin thiét phai lac ky hSn hop phan img khi vira dinh mirc xong truée khi do hay khong? Tai sao? ; b) Néu khdo sét d6ng hoc phan tng yéu cdu phai theo doi phan img dén 49 chuyén héa tic chdt khodng 2/3 (49 chuyén héa= [chét di phan tng] / [chat ban dau) thi voi bai thi nghiém niy phii do dén khi A= bao nhigu thi dimg lai? Gid sir tai thoi diém t, (t, rat gin voi t°) A=0.900. Néu dé bai yéu cu chi dy 10 gid tri A, hay 48 xudt céch Idy ding 10 gid trj A (céch tinh khoang thdi gian ldy mau nhu thé nao cho hop ly) 4é vin dim bao d6 chuyén héa 2/3. 4 Trag quainb Wuloteip ta, os tae Ae Aer -hbp plein ug As cia dink emutexong “bree Mido AL Ko ccaten phan bod attr tong AB. “Lé 2 4S 2 = +r et 7 . as cong dre. ea, quar thank mh ote Heo saclay b/ pai Rar cin, Cy rt gan vont) t= 0,550. 5 ebay No = Lellcte phendag] GC, Aye Hs hag : [ot bandit Gy = ae Say rH quag et ein At phen dg Aye A, (x 49.209 olfne mar Bai 6: NGHIEN CUU DONG HOC CUA PHAN UNG THUY PHAN ANHIDRIT AXETIC BANG PHUONG PHAP BO DQ DAN BIEN Ho va tn SV: TRUGNG T TRAM Mas6SV: AOMURdL, BAI TUONG TRINH L Mye dicks » ath J on . join , - Gain Aut plaiting ap xae dink ing £8 xdh Heo ome, in, uth being pidirng php code din then. ¢ IL. Nguyén tic va co so ly thuyée | UWhi cho (CHjeO)p wo wise, CHCO), thuiy phon tro ree CCC _ Ceo! + H,0 — .2CH, Coon a nh venti phan ung o> RlleHscolsl 4,0] i, KH co)8T € [H,0) od thi cor A) Mitng A heng aust qu rit, phdn tg, io i ve oe Maa eg at Ai COP chuta tom Adal tong Ret ul B gud taal» gud ich Fata. gud inal Gn ol hey ud ha ioc cat a Git ep tet Mri Nei sh ebeng Roc. RE nd fern nay cht Mhdo abt quo chink fey phaun ate a Us hor, Atlang ih re fi finding phe, aghns — Dang phd 8 ing Rec UG phtin ober pian sng bic A GCG! litn Mivés dé des Un (Koo- Ke) = (kyo~ ,) - Act 2 Mg Beth Wn leso- Ky) = ACL), DE He ghe ota chidte MA nO ie wee pence Hg, 6 goo cu duthg Ae aug CHa Ls ring etc de phnding 2 eeMIL Thye nghigm: Sinh vién trinh bay 6 ligu thye nghiém vao bang: V,,jeiny = kOe mE Thinghiém 1 Thi nghiém t T K K.—K | La(K.—K) | t (phut) T K K.—K | Ln(K..—K) coma | CO | Gas) | Cu) Co) | (nS) | Cus) | E Ao | 24 [ACOSO] SL ]-G.83 GC [aD | see | sas [-WEG | 1Z0 | ws | Aos4 | ar | -10,03 OS | 80 | GAS | US | -2 [Ayo | 24 [Aces | > |-10,42 AO | 80 | @9F | gos [~%, BAX] AHO | LG | AO | 2B | Io, 48 AS | 30 | FAD | dee | -495S | 10] 24 | ror | LD | -to RO | 80 | TR | 3rd |- BO | Aww | 24 [Age | as |-Aowt QS | 0 [Sie | wag f-sabd | AiO | 4 | dove | ax [4d 957 HO | 60 | FAS | fh |-¥iRt | 200 | &49 [409d | PF |—Me SS [2S] G_| goo |-gare | ano] 4 | aca] & | -iu AO [pas] $9 | sor |-V4d | 30,0 | ¥9 | Adod]| O 2 AS fas | 9tS | Ave | -8,590 | 350 | wa | dol | O = GO [AS [9DB | Aes _[-Ber [4,0 | 24 | Aol | O Zz SS |W | 949 | vse | -¥/F9 | G10 [AUS | ISA | ase _[-s18% fT @& [ans [4a _[aen [-e sas Ny AO [9G | IL9 fAly | - 4,08% iN BS [ai | 994 Aol | -9,09h Go [4S |Acod | 92 |-9,34 SF [ene fAoe | 83 |- 9,40 FO fos |Aoas | Ae | - 948 gs [44e | 099 | 69 |- 9.54 40,8} 24 |rons | GL | -9.69Ink.) + 4 | a i t(phiit) | Hinh 1. Bé thi In(in - x) = f(d khi khéo sdt phan img thy phdn déng pha ciia (CHsCO):0IV Két qua va tinh toan: 1. Xéy dug dd thi 48 tinh K cia phan tmg 2. Néu cde nhan xet vé gid tr K thu duge A] Chron Coo = AOA nS Tai thai thin + Os Ky- y= MOI S82= SAI pS = SAS \O"s Inlke -E)= WW Csa.ic®) = - 4564 _ Gabhtodin bade? cho we thé ahidin + can lar Hen ed bed = Dake AAR In leg— €) = 4b) tha ae phitig trish Ree guy y= ~OLO8AT - FOIE — Cah) ma Inley-r)= le(K- i) -ddt- Dodd k= 0, 2094. b (sar ») Hath toein tr nc Ds g ws Ben ditto A (55-865) wa (a -13,2) Ga & tan = eee = - ©2089 = Az 2098 (phi) aL off nifian yt: - _ ni Gi i Mag Meee AB ahi anh ta ale ot one phan ob dnc 4 thu phin at ha CRLOYO La ORO (Pht DG GOR 5 gil tit iy AE Mia 3 cing mbt do la O,eto6 (gia B aai Gch dbscarg + 0, Sa to Sh cgi anafuin . Nhat vay, Aang 48 ic 4 phdn loge m engin Arvin roan Jerép NO gp i yet e. _ te thi. inte cy= lnle- ke vo le- Ine, Jd, a nde ding fin tinh Ce osu wd Mea ay, Wi oti ae (Ga,c0),0 at whe the phan hy Ai pron ( (ALCo)O a are ding Doc git Boe A 7 16 0 OTe Richard £ DG:Pensoch , Couleen & Richaeleens Chami cal Enginting \ pdKA Made « Nuc dich cat bat ngfutin ca ala lk. Pi lols gf alee alos dén a dl chin ¥e lide phn thiy Shan Gayo ee bic A. Gath Arig 20-Heas pi Code xdc tink bin ck Ts ip) Whi xdectinh bin Huh mi sag php ih pain bc nike Va » Peay Shap does clin <6 +E ait clung ae Rhow cect ating hoc. cule phe ung eng de etc ne san aa © Hhcontng clin dan va ae dan a Fring qu rn phan di cg.Ho va tén SV: TRUONG WW TRAM Mi sé TT: Ma sb SV: AGA 42222 CN-4d Bai 6: NGHIEN CUU DONG HQC CUA PHAN UNG THUY PHAN ANHIDRIT AXETIC BANG ele PHUONG PHAP BO BQ DAN DIEN CAU HOI CHUAN BI ta Cau 1: Trinh biy phuong trinh dng hoe va thoi gian bin hiy ciia phin img ac 0, bac 1, bac 2, bac n. Néu anh huéng cia nhiét 46 dén téc dO phan img. Hay thiét ip phuong trinh déng hoc cia a ‘ing bec 1 khi qué trinh dng hoe duge nghién ctu thong qua 49 dn dign ? a Aextch Fi vee Hh qin ban ay (Gib st ci dhe Bc fs) “med TA) = (Alo ee ve dye Bhafsy ~ acd? tal in Neda tnt Bie ok rs gt Ane un, Bens A A i) vir ——— wage me) 4 ane - dp Bh: (ska phn Rath fan li P) A> nP a ae KK the, Toi tha citin Aid Ais phian tag CE=00)> yy = no Mei "GEOOM Ss Ke eet yoo ws acess “ng Heng a ts Mg Ch diva nin, coe oa Pinte vi BOG eS tho Go VE Ka K4 2 Cpooy ~ Cp 6 40 va_Cp,co -Cp,4 = Ce vei G 4 Aa kbant bette 1 Cor® Cli ng dB 4-0 ve tee te Baal Jods: Ge Gi > ry ene* 5 IninQ)= lal, ) = dee a Hay LnC ke Ke) = ln becom Ky) = Het C4u 2: a) Viét phuong trinh phin tng thity phan anhidric acetfe. Tir 46 viét phuong trinh dong hoe cho phan tmg trén va cho biét bac cita phan tng vé mat ly thuyét. ) Tai sao goi phan (mg thiy phan anhidric axetic trong trudng hgp nhur bai thye tp la phan img gia bac 1? Viét lai phuong trinh déng hoc trong trudng hop gia bac 1. al ete phein id wing (CHsC0)y+ 11.0 > 2c, Court lee Hig he prin ihe. ar = Bafa) 1A Sh, Kh ae tg | & mtn= ot. Nhif aye amet dg fee pre tng la babf T baw hile fis aa co TCHCOY,) < HO, aman oor hut 8 cua nase eng ha da east ua tanh phn uf ae [1,0] = ens. ete, bh rhe oe oa Nik duit dang + v= K fete] vn Las. censt) Phen of ung & be gle la A Phuthg-tani-e a8 phen ings v= X[CH,co) dae ph tg: HCO] Darg ich phén: Unf gooy) = laf cea ,c0), 1, - Lt Cu 3: a) Trong bai thy tép, khi ldy anhidric axetic 06 thé sir dung éng dong hay khong? Tai sao? Vi sao phai 48 anhidric axetic tan hétrdi moi bit dau tinh t, va bat ddu do’ b) Tai sao d6 din dign ting lién tuc trong qué trinh phan tmg? Dya vao db higu gi a8 biét phan tng thiy phan két thaic? i/ OWE me cig deng Ai fay onic. acdic. Ve bea Hate 4 ah eae ase sprig ute dis Las tie may oe ns can Me ley chish Kae anviche ale oa oa nee Phu ctr deh ex Pho ray se eee gieti ds din chu? AbD Wha ide ctecha tt, Areng Jaa phan or ce ae ee Eng ther dn Sonat 6 e Lise Bo Dy Hake vie vlna REEE Dal con ghana Sarl rho. mds iki he dt Va acdc. Abn dén aan , acid acglic a Aan.7 eae) ghan og a acid Hg den: “ind gmerg neal, Lo lathe Ie gc CaP Blsjcia Ha 43 he oa “Rtg phen ‘Eihes hi Cacid qin wah oe , cae ts nin og ef ain A gi iatnt onfed ce Wards te bat phn wll hic, aHig va tén SV: TRUONG TU TRAM Ma sd TT: g Ma sé SV: ACAA42D2 CN-4d y BAI TUONG TRINH Bai 7: KHAO SAT CAN BANG HAP PHY CUA AXIT AXETIC TREN THAN HOAT TINH I. Mue dich: , ° —Girn hist Fae phap xe dhinhols Aoi phu cus. cts hin thant i ~ Ko clung ane unk Langmuir vai Freundlich até ong+é, cfn bang Jey CO EE ET a te ee eg pla II. Nguyén tic va co sé ly thuyét: Dung, clich CHC var ening dS Ahay AR va ular ont lithe, abe gn fed sae te ith a piu chat coli 2 ops ron, Ads-aAz xde Minh nods Bn bina Ne Ae lik Vitec ba ger an bing M6 hen pm &Cinmel/g ) az N&Co-Cer) , m NAN le thttich chang cicf Ds - CHsCooHt Lo et ee ee bg a 5 . ng om la Lutng thy Mars Digg ing bic hp ch a i iadamee) Fong ict 4 bn Bo diy fae Bae "a By hyn dh beng main oli a AAG) dt xclc chin ae Va hating ch p= gee 2 ee ‘ep clung bin Fad, loga= log A + 4 gt cn lading Hip phar Ie chy tht loga= flag neato wt ab Realif 4 Keb? Xo chinh Mig wera. itI. Thye nghiém: IIL] Xée dinh igi ndng dp cita dung dich CH;COOH do PTN cung cép Né ag d6 duong lugng ciia dung dich NaOH PTN cung cp la: ©, AN Be Aich efuanrels Lei CHCOOHO.SN aed = SOOmL — 3 | Gad: Ni Nn, #YO Noveid = Nao Ns oy 296," | Naetd = Coe Nocid = ©,096M JIL.2 Hép phy va chudn dp dung dich sau hdp phy _7 Phan img chudn 46: Gt, CCOH + Nav > GHeCOONu + 4,0 Néng 46 duong lugng cia dung djch NaOH do Phong thi nghiém cung cdp la: ©, 1N Beng of Binh Dung dich NaOH Dung dich CH;COOH sau hp phy vi | V2 Vs Vow Vnin | Nong 4 (M) (mL) | GL) | (mL) (mL) (mL) L [asno | 4s.36 [asias | 4s,sr 5100 0, 50F 2 [Ala | Aas | Aba | AMAT 5,00 0, £98 3 | 4,30 | 20,30 | 40.90 | 40,0 Sw 0,206 4 | adas | 2,20 | 1,20 | 3,22 0,00 Add = 920 | 9,38 | F130 g, 28 A, OO ©, 093% fe A190 | ALGO | A4IJO M4, 90 028,00 ©0896 + 6.25 | GHO | BHO | G33 ofS, 00 0, 0257 2 Nip Nneoet and Cores = i Vind AEE Mo fin A: a 6, bF.0,4 Centp = oe = 6,404 (M) ' a 4TV Két qua va tinh toan: Viét phuong trinh Langmuir va dang tuyén tinh cia phuong trinh Langmuir Ue es te a= 4&- > Jang tayentinh « eee Gt 4 tien er Go. bok on 7 Viét phuong trinh Freundlich va dang tuyén tinh cia phuong trinh Freundlich a-her 5 Dans, tiaysortath lega= loge tog Cer e Lép bang s6 ligu tinh toan va xay dung dudng dang nhiét hdp phu Tir dd thj tim aa. Va Kpreanatich V2. Nhén xet vé sw hdp phy ctia CH;COOH trén than hoat tinh. Bang: Binh | mean | Coan ai (q) | a) | ca) | Gem O09 | Gn) A, Ox | 0, 34F | 030% | 0,SFO | 3,06 AO’: = 0,008 F]-O,54D $00 | 0 AF] 0,235 | AAD 3,58 0,982 | 0.0544 |_ o,sag 2958 | 0.93% | 0,206 | no | WIS [0,934 |0,0509 |-ocge 3,00 | ove | oise | 8% | AsV | Add |-o04s9 +o, 939 3,02 | OU | 0,093 | O, Sed. | 10,8 AUG —_|-0,0650 |-1,082 SOL | 00742] 0.054 | OLSL | Uc8 AA | OAM [425° 3,09 | 0,596 | GO: OuS | 393 BAG =O, 354A |-ASGS ea Gabon ait (a6 Ua C Vd Bio binh 4) ic, = Cosel, cp. 800 80, _ ost (uw) Coad = Nie (A000 V (Cox Cente) 400 CO #8421207) 5,986 (mma fy) ~ ~ Aros Coonp a 1c Va Iga 1gC ale la] af ol of ji F fan i a> SY ‘Be oe oom 3.26 (M') ; = A & log @ = logy (0,804) 2-0, 51836 9 Lamten - 9,543 log as log (©,980) = ~0,008344 — Lam-ten - ©0084 & 930 = A/Ok (¢q.mmet")Cash toc tener be cho cat. bahar | ler fea tha Ate, be 8 laws dutig ain ig mat Pap pu Chink); ity ating att re as: thle a na’ ve Froundlich Chih 8),ta cb: A 4 oe tuyentnh | ee ieee ace “ya sey ey hu dite 4 Y=0, 28844 0,02S4x, Ce D> ays oar = 4,04 (mmol| ly) 2 He A fis = 2 bay a aoe. ae DU wu reune| < clung a ee Pha woot th Cue: y= oon het ges 9 426,200 0208959 va lyk = OH Ihe Aue wR ta oe kD ts coe phat Inuit ogi Ic ee ee 2M) the AB tp chu aie vial HAAS Aone as 408 mull. V. K&t lugn: ) Maca oie ge da det ee, hs abla tui Ah oh Na x i asthe wit cody Aix “ta feo hane md Junk iad wwii gia tr a Rén, ig 4 co rg Fie pha ella. COOH mn Ahan » haskich ie bing tne Finb leang pair olainh xc Ach ond-teitheo mb Sanh Froundllich & Nhtoxet Hed we gek Ayo fu dete A ing dig whit | Aap 6 hua ailing 2 nur 08 ab chil a qld Co Au? chenh nba hur tL Sh hip fhe 4,7) lech le do me fy theo md Ainb Lean ia ak pha, Adivclo Aép fhaloda lep. Cai A Cis ae eee Langer Abin amb. chunh xcie can big ap pra vi Adi 6 ocey rover ih: 4 ep a de bp (is ee ps Chet bat a-tag ean ia) Lie Say as ip ngs Ra Frouncllich AE an8-4é, cn bag —03 033 036 039 024 0.27 0.15 018 0.21 0.03 0.06 0.09 0.12 ° ccm) Hinh 1. Duong dang nhiét hdp phu tuyén tinh Langmuir Hinh 2. Duong dang nhiétlogic) Hinh 3. Duong déing nhiét tuyén tinh FreundlichSV: TRUGNIG TO TRAM AOAMIGL, Bai 7: KHAO SAT CAN BANG HAP PHY CUA AXIT AXETIC TREN THAN HOAT TINH wf fl) CAU HOI CHUAN BI ea C4u 1: Dinh nghia hp phy va hip thy. So sénh hap phy vat ly va h4p phy héa hoc. Hap phy axit axetic [én than hoat tinh 14 hap phy vat ly hay héa hoc? Viét phuong trinh tinh 46 hdp phy a (ghird don vi)? — Hep phy, li ad dung cla 4 ot we ete fs dag a long ctl ain Ci tiok ap pacts aegis ja bag ~tip fa la ‘tig ect toh de i Se Pic tein vad he. cach vee oan b8 vat leh Li hig ah Ve Te Sn | writ ie hee Leal Vin Az Lehi ety Can dr wal) URE hea hee (ad-tro dl 2) Nhat The plow 1. Chothmtaxetic o> pit axitaoete db = 2.. Lic 45-50 phut it axit acetic 3,_Loc lay dd FA chudn 46 A eae khi ding 48 chiza than B. Erlen chita dd C. Erlen chita dd axit + dd axit acetic axit axetic sau Khi loo acetic 48 chudn 46 a] Erlen oe dis dhs vec toch Si = Nutle len treng At 4c ge “rink hip ” lide [En eng Ae (Gm es eh ning ce fp fi lu Sr. ote “gn tg Dap pha ae Ds aing Gen © okt cin tack (a nbigelt Cay Aaa hy Paid sb -ihctan daa” Ain Naot Vafiich acid REE B, atin mile (Enteng@ Aheng obey anh Tatlin quali cue dB vith hear Ca tage, Meng Uf Phan Lac hc apt lcia dé deo can bain 4 hp hu. . Nau, Leieterg & qianangain ti er e6 on being eal Sb lugn “kite uo nengecte che Aeicng per tea Sate, g hal tory nrg tne bomb) on (ied hc fedon ob en aldo