:

:5

71 71 11% 10%

:
0272 0221 : :
: ) ( PH ...
: .... : Ke
( ) ph ph H3O+
HO- KA

: regressi. . excel ph Vb ....

:



:

:

ph

/

PH H3O HO

.I

.7

.0

Ke

( )
ph
ph
H3O+ HO-
KA



ph
pKA /

:1
H3O+/H2O
H2O/HO .1
.2
.3 H3O+
HO .4 25 0C V=1L
.
.5
.6

.7 Ke

pKe= -logKe 25
0
C
:2
A B 25 0C
HO- A [HO-]=4,3.10-
4mol.L-1 pH BpHB = 3,2 :
PH A
.1
HO-
.2
B

.3
H3O+ HO-

simulation :
execl
regressi


PH


9
7 4

25 C

pKe = - log Ke

PH


H3O
HO-



)
(

ph


KA


KA

: 1 pH KA

.1 HA

.2
KA
.3 pKA= - logKA
.4 pH
H3O+/H2O
H2O/HO
.5
KA1 pKA1
.6
KA2 pKA2
:4 pH KA

S1 S2

.1

KA

.4

S1
(CH3COO
)H

S2
)(HCOOH

KA

.1
.2
.3
.4

KA(CH3COOH/
)CH3COO-
1,8 .10-5

CA=10-2mol.L-1

pH = 3,4

KA(HCOOH/
)HCOO-
1,8 .10-4

CA=10-2mol.L-1

pH = 2,9

PKA = - log K A

PH



KA

PH KA
PKA

HA

pH
C

pH
KA
pKA

.5 pH

.6 KA
.7 KA C

: 5 pH KA

S1 S2

S1
)(NH3

S2
)(CH3NH2

.1
.2
.3
.4

)KA(NH4+/NH3
6,3 .10-10

CA=10-2mol.L-1

pH
= 10,6

KA(CH3NH3+
)/CH3NH2
2,0 .10-11

CA=10-2mol.L-1

pH
= 11,4

B

pH
C

pH
KA
pKA

.5 pH

.6 KA
.7 KA ke
C

/
/

.II

.7

.0

.3

:
.1 PH PKA A/B
A B PH
N
/ NH3
.2
:
A B
.1 A/B
.2 A/B
.3 PH
A/B

PH
.4
/
Hind / ind

.5 Hind / ind

:2

PH

PKA
/







/

11 9
111

 .V

.1
.2
.3
.4
.5
.6
.7

PH

: 6

Va=20mL
Ca=10-2mol.L-1
Cb=10-2mol.L-1 pH
:

:
.1

.2
Ve=20
.3 ) pH=f(Vb


.4
)=g(Vb
.5 )=g(Vb
Ve

PH


:

70
722

:
71 70 72 9 : 727 722
: 1
: 1

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