Test de aptitudini nr.

2
8QLWDWHDFRODU/LFHXO7HRUHWLFDiaconovici-Tietz5HL D
SURI0HLO0LUFHD Iacob

clasa a XII-DWLLQ HDOHQDWXULL

,]RPHULDRSWLF

RU

1. $OHJH LUVSXQVXOFRUHct:

D1XPUXOPD[LPGHVWHUHRL]RPHULHVWHGDWGHIRUPXODn.

$GHYUDW_)DOV

D,QWUHSHUHFKHDGHHQDQWLRPHULH[LVWRUHOD LHRELHFWLPDJLQHvQRJOLQG

$GHYUDW_)DOV

2. 6FULH LvQVSD LXOOLEHUGLQID DFRORDQHL$OLWHUDFRUHVSXQ]WRDUHGLQFRORDQD%

A

1. enantiomerul levogir

a. amestec echimolecular a doi enantiomeri

EURWHWHSODQXOOXPLQLLSRODUL]DWHVSUHGUHDSWD

2. racemicul

FL]RPHUFXGLVWDQ HGLIHULWHvQWUHVXEVWLWXHQ L

3. enantiomerul dextrogir
4. mezoforma

GURWHWHSODQXOOXPLQLLSRODUL]DWHVSUHstnga
e. compus cu mai multe centre de chiralitate,
dar optic inactiv din cauza simetriei.

3. 3UH]LQWXQVLQJXUFHQWUXGHFKLUDOLWDWH
A. cloroformul

B. metanul

C. 2-cloropropanul

D. 2-clorobutanul

E. nici unul

4. Referitor la 2-bromo-3-FORUREXWDQVXQWFRUHFWHDILUPD LLOH

SUH]LQWGRXFHQWUHGHFKLUDOLWDWH

SUH]LQWGLDVWHUHRL]RPHULH

QXPUXOGHVWHUHRL]RPHULHVWH

FXSULQGHRPH]RIRUP

5. In lumina plan-SRODUL]DWXQGHOHHOHFWURPDJQHWLFHRVFLOHD]vQWU-un singur plan, perSHQGLFXODUSHGLUHF LDGHSURSDJDUHGHRDUHFHOXPLQDQRUPDOHVWHWUHFXWSULQWU-o

SULVP1LFRO

6. &DUHVXQWDVHPQULOHLGHRVHELULOHvQWUHSURSULHW LOHIL]LFHDOHHQDQWLRPHULORU
7. 3URSULHWDWHDVXEVWDQ HORUGHDURWLSODQXOOXPLQLLSRODUL]DWHDIRVWGHVFRSHULWvQDQXO
GHFWUH

8. 6HFRQVLGHUXUPWRDUHOHIRUPXOHGHSHUVSHFWLY
COOH

(1)

(2)

COOH

H
H3C

NH2

(3)

H
H3C

COOH

(4) COOH

NH2
H3C

Cl
Br

&DUHIRUPXOFRUHVSXQGHXQXLFRPSXVRSWLFLQDFWLY"

&HFRQILJXUD LLFRQIRUPFRQYHQ LHL5-6DXFRPSXLLRSWLFDFWLYL"

([LVWUHOD LLGHHQDQWLRPHULHvQWUHVXEVWDQ HOHRUJDQLFHFXIRUPXOHOHGHPDL

sus?

6FULH LIRUPXODGHSURLHF LH)LVFKHUSHQWUXFRPSXXOFXIRUPXOD

,QGLFD LRUHDF LHSULQFDUHFRPSXVXOFXIRUPXODVIRUPH]HXQFRPSXVRSWLF

activ.

9. Pentru arderea a unui mol dintr-XQDOFRROPRQRKLGUR[LOLFVDWXUDWFHFRQ LQHDWRPL

de carbon SULPDULVHIRORVHVFOLWULGHDHUvQFRQGL LLQRUPDOHFX226WDELOL L

GHQXPLUHDDOFRROXOXLLQXPUXOL]RPHULORUFHFRUHVSXQGIRUPXOHLVDOHPROHFXODUH

Barem de notare
Itemi obiectivi

Total 25 puncte

D$OHJHUHGXDO

a1) AdHYUDWD$GHYUDW

2 x 2 puncte

b) Tip pereche

1d 2a 3b 4e

6 puncte

c) Complement simplu

3 puncte

d) Complement grupat

6 puncte

H&DX] efect

6 puncte

Itemi semiobiectivi

Total 35 puncte

D&XUVSXQVVFXUW

6 puncte

(QDQWLRPHULLPROHFXOHORUFKLUDOHDXSURSULHW LIL]LFHLGHQWLFHFXH[FHS LDFRPSRUWULLID 

GHOXPLQDSRODUL]DW
b) De completare

J.P. Biot

c) ,QWUHEULVWUXFWXUDWH

25 puncte

formula (2)

6 puncte

S (1); R(3); R(4)

vQWUHL

6 puncte
5 puncte

COOH
H

4 puncte

4 puncte

Cl
Br

UHDF LDGHDFLODUHVDXGHHVWHULILFDUH
Itemi subiectivi

3UREOHP

4 puncte
Total 30 puncte

-'HWHUPLQDUHDQXPUXOXLGHPROLGH22
VO2 = Vaer / 5 = 134,4 L ; n = VO2 / Vm = 6 moli

4 puncte

- Determinarea formulei moleculare a alcoolului

alcool monohidroxilic saturat : CnH2n+2O

3 puncte

CnH2n+2O + 3n/2 O2 n CO2 + (n+1) H2O

2 puncte

3n /2 = 6 n=4 C4H10O

3 puncte

H3C CH CH2 OH
|
CH3

3 puncte

-'HWHUPLQDUHDL]RPHUXOXLFHFRQ LQHDWRPLGHFDUERQSULPDUL

- Scrierea celor 9 izomeri inclusiv a izomerilor optici

15 puncte