CO 2

:
(Van der Waals equation):
1

+ 2 ( ) =

eq(1)

a,b :

=0

T c eq(2)
a=

eq(2)

=0

27 2 2
64

, b = 8

eq(3)

P c P c =7.377X106pa, T c =304.12k
= 3.656x101 (Pam6 mol2 )
= 4.284x105 (m3 mol1 )

1-1

: CO2

:
:(from NIST webbook)
http://webbook.nist.gov/chemistry/fluid/

1-2

 Compressibility factor

(Van der Walls equation)

Compressibility factor

(Van der Waals equation):

1

+ 2 ( ) =

eq(1)

= 2.303(Pam6 mol2 )
= 4.31x104 (m3 mol1 )

: compressibility factor

Van der Waals constant:

http://tpub.scu.edu.tw/scutwebpub/website/DocUpload/CourseTeaching/8000
0042200912315129_1.pdf
2