376

CHAPTER 12

Solutions
12.1. The reagents for these reactions can be found in the summary material at the end of Chapter 9. They are shown
again here:

12.2. The reagents for these reactions can be found in the summary material at the end of Chapter 10. They are shown
again here:
Br

O
CH3

HBr

Br

HBr

Br

H2SO4, H2O
HgSO4

1) xs NaNH2
2) H2O

H
H2

1) 9-BBN
2) H2O2, NaOH

Lindlar's
Catalyst

1) NaNH2

H2

2) CH3I

Pt

1) xs NaNH2
2) H2O

Br2

Na

Br

NH3(l)

Br

1) O3
2) H2O

Br

xs Br2

Br
O

O
+
OH

Br

Br
Br

O
Br

376

CHAPTER 12

Solutions
12.1. The reagents for these reactions can be found in the summary material at the end of Chapter 9. They are shown
again here:

12.2. The reagents for these reactions can be found in the summary material at the end of Chapter 10. They are shown
again here:
Br

O
CH3

HBr

Br

HBr

Br

H2SO4, H2O
HgSO4

1) xs NaNH2
2) H2O

H
H2

1) 9-BBN
2) H2O2, NaOH

Lindlar's
Catalyst

1) NaNH2

H2

2) CH3I

Pt

1) xs NaNH2
2) H2O

Br2

Na

Br

NH3(l)

Br

1) O3
2) H2O

Br

xs Br2

Br
O

O
+
OH

Br

Br
Br

O
Br