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Process of PO & PKO
Process of PO & PKO
FORNPO
SPECIFICATIONS
PORAMSTANDARD
FFA(aspalmitic)
M&l
lV (nrrjs)
M . p (t ' c )
AOS(Cc3-25)
max
0.25o/o
0.1%max
50-55
JJ-JY
sulphuric
by thisprocessis spittedwithmineralacid(usually
Thesoapproduced
calledacidoil (Table2).
acid)and soldas a by-product
TABLE2.
TotalFattyMatter
M&l
FFA(aspalmitic)
95%min
3o/o fidx
50%min
TABLE3.
FFA(aspalmitic)
M&l
lv (Wjs)
M.pt(" c)
AOS(cc3-25)
Color(5%"cell)
0.25o/o
max
0.1Y0max
50-55
33-39
20 red max
FOR NB/RBD
PORAMSTANDARDSPECIFICATIONS
PALM OIL
0.1%max
FFA(aspalmitic)
0.1okmax
M&l
M.pt(" c)
JJ-JV
AOS(Cc3-25)
"
(5%
cell)
3
or
6 redmax
Lovibond
Color
TABLE 5.
FFA(aspalmitic)
O.1o/o
max
M&l
0.1o/omax
lVWrjs)
19 max at time of shipment
Colot(5% " Lovibond
cell) Red 1.5max
TABLE6,
Saponifiable
Matter
M&l
FFA(aspalmitic)
95%min(basis97%)
1.0o/o max
70o/omin
TABLE7.
(PKFAD)
PALMKERNELFATTYACIDDISTILLATE
FOREXPORT
SPECIFICATIONS
FFA(aspalmitic)
M&l
TFM
50%max(basis97%)
1o/o ftlAX
95% min
anddeodorized
or RBDoil.
as a refined,bleached
Theoil leavesthe deodorizer
as
NBD
oils.
RBD
oils
are
the
same
of
Exportspecifications
of palmand palmkernelolls
Fractionation
In orderto caterfor a wide rangeof markets,the Malaysianrefinersalso offer
products
thanpalmoilor palmkernel
and'moreliquid'(olein)
whichare'harde/(stearin)
of fractionation.
througha simpleprocess
oil. Theseareaccomplished
as follows. The
Fractionation
of palmand palmkerneloils can be described
the
foundin the oil havedifferentmeltingpoints. At certaintemperatures,
triglycerides
lower melting temperaturetriglycerideswill stay liquid while the higher melting
will crystallizeinto solid separatingthe oils into both liquid
temperaturetriglycerides
(olein)andsolid(stearin)fractions.Thefractionscanthenbe separatedby filtration.
palmoleinis the premium
that in palmoil fractionation,
It is worthmentioning
productand the palmstearinis the discountproduct. However,the reverseis true for
products.
palmkerneloilfractionated
of palmoil
Fractionatlon
of palm oil into palm olein and palm stearinis
In Malaysia,fractionation
processes
viz dry anddetergentfractionation.A third
usingtwo typesof
accomplished
feasiblefor the normaloleinmethod,whichusessolvent,is no longereconomically
(Figurc1).
stearinftactionation
Yield (o/o)
Liquid
Fraction
Solid
Fraction
65-85
15-35
Figure1.Fractionation
of PalmOil
Dry fractlonation
The more commonof the two processes,dry fractionation,
operatesin the
followinglashion(AppendixVI). The oil is kepthomogenized
at about70'C beforethe
start of crystallization.The idea is to destroyany crystalspresentand to induce
crystallization
in a controlledmannerin the crystallizers.Crystalformationand growth
occursas the oil is agitatedand cooledusingchilledwatercirculationin the jacketsor
coolingcoilsof the crystallizers.
Coolingcanbe governed
eithertheoil or
by controlling
watertemperature.
Whenthe oil reachesthe required
temperature,
usuallyaround22"C,coolingis
stopped.Theoil,whichappearsas a thicksemi-solidmass,termedslurry,nowcontains
stearincrystalsin liquid olein and is ready for filtration. The slurry is then fed
continuously
to a filterin a controlledmanner.Thetypesof filtersusedare drumrotary
filters (Stockdale)and stainlesssteel belt filters (Florentine)which operatesusing
vacuumsuctionto separatethe liquidolein from the stearincrystals(AppendixVll).
Over the last eight years or so, membranerecessedplate FilterPresses,using
'squeezing
techniques',
havegainedpopularity.
Generally,
biggercrystalsare requiredfor easeof filtration
usingthe vacuum
suctiontypefilters. However,this tendsto makethe crystalsgrouptogetherin clumps
whichwill occludepartof the liquidand,as a result,someoleinis lostin the stearin.
DRYFRACTIONATION.PRODUCTCHARACTERISTICS
Palmolein
Cloudpoint("C)
lodinevalue(Wrjs)
Meltingpoint('C)
Palmstearin
8-10
56-59
22-24
42-46
48-52
PALMSTEARIN
FROMMEMBRANE
FILTERS
lodinevalue (\ fijs)
Meltingpoint("C)
33-37
52-54
SUPEROLEIN
FROMPALMOILBY DRYFRACTIONATION
lodinevalue(Wrjs)
Cloudpoint("C)
SlipMeltingpoint,('C)
80-65
J - O
13-16
Detergentf ractionation
Beforethe introductionof membranefilters,detergentfractionationenjoyeda
distinctadvantageover dry fractionationby offeringabout 15% more olein yield. In
Malaysia,
detergent
fractlonation
is onlycarriedoutwithcrudeoils.
The processinvolvescooling palm oil (crystallization)
and separationof its
(sodiumlaurylsulphatesolution)and an
fractions(fractionation)
aidedby a detergent
(magnesium
electrolyte
sulphate).
As in dryfractionation,
theoil in thecrystallizers
is cooledusingchilledwaterand
is aflowedto crystallize.Whenthe oil reachesa set temperature
of about22C, the
semi-solidmassis pumpedto the fractionation
stagewhereit is mixedwithan aqueous
solutioncontaining
the electrolyte
andthe detergentat the sametemperatures
as the fat
mass. Fractionation
is carriedout by centrifugal
techniques.
The electrolytehelpsin the agglomeration
of the oil dropletsformedduringthe
mixingprocess. The presenceof the detergenthelpsin fractionation
as it wets the
stearincrystals
anddisplaces
occluded
andentrained
olein.Thestearinfractionandthe
detergentthen from a discretephaseof higherdensitywhich is easilyseparatedby
centrifuging.
The lighterphaseleavingthe centrifugeconsistsof oleinandtracesof detergent.
Thisis washed,driedandthe oleinis sentfor storage.The heavierphasecontaining
mostof the detergentis heatedto meltthe stearinandthensentto a secondcentrifuge
wherethe stearinis separatedfrom the detergent.The stearinis then washed,dried
andstoredwhilethe detergentis recycled(Table11).
TABLE11. DETERGENT
FRACTIONATION.PRODUCT
CHARACTERISTICS
Palmolein
Cloudpoint('C)
lodinevalue(W'rjs)
Meltingpoint('C)
8-10
56-59
Palmstearin
32-38
tn
tE
High lV / SuperOlein
OF SUPEROLEINANDPALM
TABLE12. TYPICALANALYSIS
MIDFRACTION
Palmolein
Cloudpoint("C)
lodinevalue(VMjs)
Meltingpoint("C)
8-10
56-59
1l
Palmstearin
32-38
50-55
TABLE13,
PORAMSTANDARDSPRECIFICATIONS
FORPALMOLEIN
PRODUCTS
1.
CrudePalmOlein
FFA(AsPalmitic)
M&l
l.v. (\ r|js)
M.Pt'c (AOCSCc3-25)
5.0%max
max
0.25o/o
56 min
24 max
2.
Neutralized
PalmOlein
l.v.(Ws)
max
0.25o/o
0.1Yomax
56 min
24 max
Neutralized
& Bleached
PalmOlein
FFA(As Palmitic)
M&l
l.v. (Vvijs)
M.Pt'C (AOCSCc3-25)
Colot(5 %" Lovibondcell)
max
0.25o/o
0,1Yomax
56 min
24 max
20 Redmax
Refined,Bleached&
Deodorized(RBD)/
Neutralized,
Bleached&
Deodorized(NBD)
PalmOlein
FFA(As Palmitic)
M&l
l.v. (Wjs)
M.Pt"C (AOCSCc3-25)
Color(5 %" Lovibondcell)
O.1Vo
max
O,1omax
56 min
24 max
3 or 6 Red max
DoubleFractionated
PalmOlein
0.1o/ofiix
3.
5.
l.v.(Ws)
M.Pt'C (AOCSCc3-25)
Color(5 %" Lovibondcell)
0.1%max
60 min
19 max
3 Red max
12
TABLE14.
PORAMSTANDARDSPRECIFICATIONS
FORPALMSTEARIN
PRODUCTS
1.
CrudePalmStearin
FFA(As Palmitic)
M&l
LV. (Wrjs)
M.Pt'C (AOCSCc3-25)
5.0olom?X
U.ZC7o
max
48 min
44 min
2.
Neutralized
Palm
Stearin
l.v.(wjs)
0.25o/om?x
0 . 1 %m a x
48 max
44 min
Neutralized& Bleached
PalmStearin
FFA(As Palmitic)
M&l
l.V. (Wijs)
M.Pt"C (AOCSCc3-25)
Color(5 %" Lovibond
cell)
0.25o/omax
0.1Vomax
cb mtn
24 max
20 Red max
Refined,Bleached
&
(RBD)/
Deodorized
Neutralized,
Bleached&
(NBD)
Deodorized
PalmStearin
FFA(As Palmitic)
M&l
l.v. (wjs)
M.Pt'C (AOCScc3-25)
Colo((5 %" Lovibondcell)
0.2o/omax
0 , 1 5 %m a x
48 max
44 min
3 or 6 Red max
4.
TABLE15.
SPECTFTCATTN
FOREXPORTi|ARKETS(MEOMA):
PALIIIKERNELOIL FRACTIONATED
PRODUCTS
1.
CrudePalmKemel
Olein
5.0%max
0. 5% max
21 min
2.
CrudePalmKernel
Stearin
l.V.Mr'js)
5.0%max
0.5%max
8 max
3.
RBDPalmKernel
Stearin
FFA(As lauric)
M&l
l.v. (wijs)
Colot(5 %" Lovibond
cell)
0.1o/o
lnax
O.lYomax
21 min
Red1.5max
4.
RBDPalmKernel
Stearin
0.1%max
0.1Vomax
8 max
Red 1.5max
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