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Data Tables:
Part 1
Voltage of Each Half-Cell versus the Zinc Electrode
Voltage
Anode
Zn vs Ag
1.298
Zn
Zn vs Cu
.852
Zn
Zn vs Fe
.435
Zn
Zn vs Mg
.835
Mg
Zn vs Pb
.380
Zn
Predicated and Measured Cell Potentials
Anode
Cathode
Equation for
Cell Reaction
Cu
Mg
Mg(s) + Cu2+
(aq) -> Mg2+
(aq) + Cu(s)
Cu
Fe
2Fe(s) + 3Cu2+
(aq) -> 2Fe3+
(aq) + 3Cu(s)
Fe
Ag
3Ag(s) + Fe3+
(aq) -> Ag+
(aq) + Fe(s)
Pb
Mg
Mg(s) + Pb2+
(aq) -> Mg2+
(aq) + Pb(s)
Cu
Pb
Pb(s) + Cu2+
(aq) -> Mg2+
(aq) + Pb(s)
Ag
Cu
Cu(s) + Ag+
(aq) -> Cu2+
(aq) + Ag(s)
Cathode
Ag
Cu
Fe
Zn
Pb
Predicted
Potential
2.696
Measured
Potential
1.870
.344
.426
.804
.792
2.231
1.928
.215
.182
.460
.446
Part 2
Voltage
.813
Zn(s)|Zn2+(1.0M)||Cu2+
(.0010M)|Cu(s)
Equation for Cell Reaction
Zn(s) + Cu2+(aq) -> Zn2+
(aq) + Cu(s)
Anode
Zn
Predicted Potential
1.103
Cathode
Cu
Measured Potential
.813
Part 3
Zn(s)|Zn2+(1.0M)||Ag+(Unknown
Voltage
.690
Anode
Zn
Cathode
Ag
M)|Ag(s)
Equation for Cell
Reaction
Zn(s) + 2Ag+(aq)
-> Zn2+ (aq) +
2Ag(s)
Calculated[Ag+]