@) P&G Chemicals Delivering solutions, creating value MATERIAL SAFETY DATA SHEET 1. Product and Company Identification Material name CE-810 Version # 26 Revision date 10-07-2011 cas# 57762-39-4 MSDS Number MESEO Product Code 99281148 Product use Production of amides, methyl ester sulfonates, rolling ols, low-volume solvents, and mete working fluids. ‘Synonym(s) METHYL OCTANOATE * METHYL DECANOATE Manufacturer The Procter & Gamble Company Procter & Gamble Chemicals Sharon Woods Innovation Center 11830 Reed Hartman Highway Cincinnati, Ohio 45241 1-800-477-8899 or 1-513-626-6882 PGChemMSDS.IM@pg.corr CHEMTREC: 1-800-424-9300 U.S. and Canade CHEMTREC: 1-703-527-3887 For calls originating elsewhere 2. Hazards Identification Emergency overview CAUTION! Flammable. EYE AND SKIN IRRITANT Flammable liquid and vapor may be ignited by heat, sparks, or open flames. Containers may ‘explode when heated. Vapors may travel to souree of ignition and flash back If product is heated, vaporization can occur. Eye, skin, and upper respiratory initation can ocour, Potential health effects Eyes May cause minor to moderate imitation. skin Mildly initating to skin with prolonged exposure, Inhalation Breathing vapors may cause inebriation and nausea, Ingestion May cause inition ofthe gastrointestinal tract. Potential environmental effects None known. 3. Composition Information on Ingredients Components cas# Percent FATTY ACIDS, C6-12, METHYL ESTERS 37762-39-4 100 4. First Aid Measures First ald procedures Eye contact Flush thoroughly with water for at least 15 minutes. Get medical assistance, Skin contact Wash the skin immediately with soap and water. Remove contaminated clothing. Get medical attention ifimitation develops and persists. Wash clothing separately before reuse Waterial name CE-810 ens us MISDS Ne, 99281148 Versior #:06 Revision date: 1007-2011 Print date: 10-07-201° WeInhalation Ingestion 5. Fire Fighting Measures Extinguishing media Suitable extinguishing media Uncuitable extinguishing media Protection of freighters Specific hazerds arising {rom the chemical Protective equipment and precautions for freighters. Special protective equipment for fire-fighters Fire fighting equipmentinstructions Move to fresh ar. Ifbreathing stops, provide artificial respiration. If breathing is difficult, ove oxygen. Get medical attention immediately. Get medical attention immediately. Never give anything by mouth to a victim who is unconscious ors having convulsions, induce vomiting only under the instruction ofa physician SMALL FIRES: Use CO2 or dry chemical. Water fog LARGE FIRES: Use foam Cool containers with flooding quantities of water unt well affer fire is out ‘Vapors may travel to the source of ignition and flash back. Water may be ineffective Carbon monoxide with incomplete combustion, ‘Wear self-contained breathing apparalus and protective clothing, ‘Wear self-contained breathing apparatus and protective clothing, Not available 6. Accidental Release Measures. Personal precautions Environmental precautions Methods for cleaning up 7. Handling and Storage Handling Storage Specific uses ‘Wear self-contained breathing apparatus and full protective clothing Dike fow of spilled material using soil or sandbags to minimize contamination of drains, surface and ground waters, \Ventilate the area, Eliminate sources of ignition Contain spill, Absorb with earth, sand or other non-combustible material and transfer to containers {or later disposal, Use clean non-sparking tools to collect absorbed material Handle in accordance with good industrial hygiene and safety practice ‘Avoid contact with skin and eyes. Avoid contact with clothing. Wash thoroughly after handling Ground end bond containers when transferring material. Use spark-proof tools and axplosion-proof equipment, Empty containers contain product residue and can be dangerous, folow all hazard wamings and precautions even efter container is emptied. Keep away from sources of ignition Keep away from heat, sparks, and flame. Keep away from possible contact with incompatible substances, Store in a coo! dry place in accordance with 29 CFR 1910-106)NFPA 30, Follow bulk handling and storage procedures as noted above 8. Exposure Controls / Personal Protection Engineering controls Personal protective equipment General Eye /face protection Local exhaust is recommended Mechanical - may be necessary if working at elevated temperatures orn enclosed areas. Provide ventlation to meet exposure limits. Observe good industrial hygiene practices ‘Avoid contact with eyes. Avoid contact with skin, Avoid breathing (heated) vapors. Boots, Apron. Eye wash fountain and emergency showers are recommended. Wear suitable protective clothing Goggles or face shield with goggles, dependent upon potential exposure. Material name CE-810 MISDS Ne, 99281148 Versio #: 06 Dory Revision date: 10-07-2011 Print date: 107.201" 2leSkin protection Respiratory protection Environmental exposure controls 9, Physical & Cher Appearance Physical state Form Color Odor (Odor threshold oH Vapor pressure Bolling point Melting point/Freezing point Solubility (water) Relative density Flash point Flammability limits in ar, upper, % by volume Flammability limits in ar, lower, % by volume. ‘Auto-ignition temperature Viscosity Nile gloves are recommended. Dependent upon degree of potential exposure, additonal personal protective equipment may be required, such as chemical boots and full protective clothing None required for ambient temperature, although an appropriate NIOSH/MSHA approvec air-purifying respirator should be used if @ mist or vapor is generated. A NIOSH/MSHA approved selF-contained breathing apparatus or ei-supplied respirator is recommended i the concentration exceeds the capacity of cartridge respirator. WARNING: Air purifying respirators do not protect ‘workers in oxygen-deficient atmospheres Contact Procter and Gamble for specific Community information al Properties Liquia Liqui. Not available Water white to Yellow. Musty, Not available Not available <= 5mm Hg @72 F (22.0) 330 °F (185.6 °C) @ 760 mm Hg (101.3kPa) -20°F (-28.9°C) @ 760 mm Hg (101.3kPa) Negligible @ 72 F (22 C) 0.87 @ 25725 4128 °F (53:3 °C) Pensky-Martens Closed Cup Not available Not available Not available 3eP at ambient temperature 10. Chemical Stability & Reactivity Information Chemical stability Conditions to avoid Materials to avoid Hazardous decomposition oroducts Hazardous polymerization Stable at normal conditions Reacts with strong base to produce methanol. Oxidizing agents, Strong bases. Carbon monoxide with incomplete combustion, Hazardous polymerization does not occur. 11. Toxicological Information Toxicological date Constituents Test Results METHYL OCTANOATE (111-11-5) Other Rabbit: Based on C810 ME Mixtures. Undiluted-mile transient eye iitation Acute Oral LD5O Rat: 20.5 glke Acute Oral LDSO Rat: Based on C8-10 ME. Expected to be greater than 23 g/kg of body weight Impurities Test Results METHYL HEXANOATE (106-70-7) Dermal Rabbit: Skin initation - Pll=2.78 (OECD Test Guideline 404) Waterial name CE-810 WDE MISDS Ne, 99281148 Versior #:06 Revision date: 1007-2011 Print date: 10-07-201° aleImpurities Test Results Acute Oral LD5O Rat >= 5 ghkg Further information (Based on P&G data for related C8-10 methyl ester mixtures.) ‘Acute Oral Toxicity: Practicelly non-toxic. The acute oral LD50 for rats was greater than 23 glk of body weight. Eye Imitation: The application of undiluted material to the rabbit's eye produced only mile transient iritation Skin Initation: 24 hour human patch test indicated that undiluted product produced mild imitation, The initancy was less than the result produced by a 4% aqueous soap solution 12. Ecological Information Ecotoxicological data Product Test Results FATTY ACIDS, 06-12, METHYL ESTERS (67762-39-4) .C50 Bluegill (Lepomis macrochirus): 423 mall 96 hours Practically non-toxic, Constituents Test Results METHYL OCTANOATE (111-11-5) L.C50 Bluegil (Lepomis macrochirus): 423 mall 96 hours (Based on C8-10 mixture} Impurities Test Results DODECANOIG ACID, METHYL ESTER (111-82-0) L.C50 Bluegill (Lepomis macrochirus): >= 1000 mgil 96 hours Microbiological Inhibition: None at 10,000 maf Aquatic toxicity Microbiological Inhibition: None at 10,000 magi 13, Disposal Considerations Disposal instructions Dispose of waste material according to Local, State, Federal, and Provincial Environmenta Regulations Do not dispose of via sinks, drains or into the immediate environment 14, Transport Information bot Basic shipping requirements Proper shipping name Esters, n.o.s, (METHYL OCTANOATE: Hazard class 3 Subsidiary hazard class None UN number una272 Packing group m ‘Aditionel information Special provisions. B1, 1B3, 14, TP1, TP2s Packaging exceptions 150 Packaging non bulk. 203 Packaging bulk 242 ERG number 127 Material name CE-810 ens us MISDS Ne, 99281148 Versior #06 Revision date: 10007-2011 Print date: 10-07-201° ale.) FLAMMABLE Y DOT 15, Regulatory Information US federal regulations Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f(2) Not regulated DEA Essential Chemical Code Number Not regulated Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310. 12(c)) Not regulated DEA Exempt Chemical Mixtures Code Number Not regulated CERCLA (Superfund) reportable quantity None ‘Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - No Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - Ne Section 302 extremely No hazardous substance Section 311 hazardous No shemical Inventory status Country(s) or region Inventory name (On inventory (yesino)* Australia Australian Inventory of Chemical Substances (AICS) No Canada Domestic Substances List (SL) No China Inventory of Existing Chemical Substances in China (IECSC) Yes Europe European Inventory of Existing Commercial Chemical Yes Substances (EINECS) Europe European Lis of Notifed Chemical Substances (ELINCS) No Japan Inventory of Existing and New Chemical Substances (ENCS) Yes Korea Existing Chemicals List (ECL) Yes New Zeeland New Zealand Inventory Yes Philippines Philippine Inventory of Chemicals and Chemical Substances, No (ics) Switzerland Switzerland FOPH No United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes “A7Yes" indicates that all components ofthis product comply wih the inventory requirements administered by the governing country(s) State regulations US - New Jersey Community RTK (EHS Survey): Reportable threshold Waterial name CE-810 ens us MISDS Ne, 99281148 Versior #:06 Revision date: 1007-2011 Print date: 10-07-201° BIEUS - Penneylvania RTK - Hazardous Substances: Listed substance Contains no Pennsylvania Right To Know hazardous substances 16. Other Information HMIS® ratings NEPA ratings Disclaimer Issue date This data sheet contains changes from the previous version in section(s): Health: 0 Flammability: 2 Physical hazard: 0 Health: 0 Flammabiity: 2 Instability: C The submission of the MSDS may be required by law, but this is not an assertion that the substance is hazardous when used in accordance with proper safety practices and noma handling procedures. Data supplied are for use only in connection with occupational safety anc health The information contained herein has been compiled from sources considered by Procter & Gamble to be dependable and is accurate to the best of the Company/s knowledge. The information relates to the specific product designated herein, and does not relate to use in ombination with any other material of any other process, Procter & Gamble assumes no responsiblity for injury tothe recipient or third persons, or for any damage to any property resulting from misuse ofthe controlled product, 10-07-2011 Product and Company Identification: Product and Company Identificatior Hazards Identification: Emergency overview Physical & Chemical Propertes: Multiple Properties Transport information: Proper Shipping Name/Packing Group Waterial name CE-810 WDE MISDS Ne, 99281148 Versior #:06 Revision date: 1007-2011 Print date: 10-07-201° 6le