Read spin angular momentum from Greiner.

HYDROGEN ATOM:
Here we want to calculate the energy eigen values and energy eigen states
of the electron.
^
H = E

=(

^p 2
2m

e
r

2
2
Now, ^p =

=
Here

^L2

{ ( )

1 2
1
r
+ 2 ,
2

r
r
r

2 ,

{ ( )

1 2
L
r
2 2
2
r r
r r

2m
e
(E+ )
2
r

=0

Use of separation of variables:

(r

, ,

R (r )
Y( ,
r

2
Separation constant: l(l+1)

1)
2)

Rl
r

L2 Y lm ( , )

2 mE e2 l(l+1)
+
r
2
r2
{}

Rl (r )

2 l(l+1)Y lm ( , )

=0

With (1) l = 0,1,2.

(2) l m l
effectively

dv = 1

or,

Rl ( r ) R l (r )
0

dr = 1

Y has orthogonality.
Conditions: (1) r 0
(2) r
FOR r 0:
d 2 Rl
dr 2

l (l+1)
Rl
r2

=0

try a power series for this,

2
So, (1) r

Rl

2
= r {1+ a1 r + a2 r + }

2
l(l+1) r
=0

Here (i) =(l+1)

(ii) =l

(i) and (ii) together (1)

FOR r
2

d Rl
dr

using

+
2

2 mE
Rl
2

=0

2 mE
=
2

Solution:

Rl

r
r
= A e +B e (2)

From (1) and (2)

Rl (r )

(l +1) (r)
= r e
F(r)

Using (i) z = 2r and

k=

me 2
2

Final form,
d2 F
z dz 2

+ (2l + 2

dF
dz

(l+1 k)F = 0 Kummers

differential equation
2

General solution of

d
dx 2

+ (c

d
dx

a =0

(1c)
A 1 F 1 (a ; c ; x)

is ( x) =
+B x
c+1 ; 2 c ; x)
1F1(a

1F1 (a ; c ; x) =

a
c

x
=c

=1+
F=

c1 F1

!
a x
( )
c 1!

a(a+1) x 2
c (c +1) 2!

+ ..

(l+1 k ; 2l+2 ; 2 r )

n
Set, l+1 k = r

where

nr =0,1,2

k=

nr

+l+1 = n

here n principal quantum number and

nr

radial quantum number

Here l = 0,1,2.
En

Energy eigen value

lmn

l r
nr
(r) = N nl r e
, 2l+2, 2 n r ) Y lm ( ,)
1F1(
n

= N nl
Where,
n=

1 e 2
2 a0 n2

N nl

Rnl (r )
Y lm ( , )
r

( n+l ) !
1
( 2 l+1 ) ! 2 n ( nl+ 1 ) !

3
(l + )
2

3
2
0

(2 )a
n

nr +l+1

here n,m,l are dependent on each other.

Read pauli spin matrix, stern gerlac experiment, spin angular
momentum..commutation and other relation.