3:.

21

(lom)X

:
0.5
:
-1 : I
0.5
2I-(aq) I2(aq) +2e:
: S2O82
2e + s2o82-(aq) 2so42-(aq) :
-2 :
0.5
nS2O82- =C2V2=2,010-3mol
0.5
nI-=10-1C1
(nim)t
02
-3 :
)2 SO42-(aq

)I2(aq

3-

5
5

)2I-(aq

)S2O82-(aq

10-1C1

210-2

)2x(t

)x(t

)10-1C1- 2x(t

)210-3 -x(t

Xmax2

Xmax

10-1C1- 2xmax

210-3 - xmax

-4 xmax=3x0.5x10-3 = 1,510-3mol :
-5 C1 :
:
2-3
nS2O8 =2.10 - xmax = 210-3 - 1.510-3= 510-4mol
1
C1- 2Xmax=0-10 :
2xmaxI
=-1C1
10

dx 1

td V(s) = V

v= 410-4mol/Lmin

=810-5

0.5

1.0
0.5

a
v
=V
S

0.5

):SO42-(aq
= V2
1

dSO42-
dt

)2x(t

0.5

0.5

C1 =310-2mol/L
-6 :

5.0 01

0.5
dx 2

= vVs
SO42- ....2
.1... 2 dt
Vs= :
-4
V2=2V V2 =810 mol/Lmin
0.5

0.5

 -7 : t1/2

xf/2 x(t1/2) =: t 1/2 2.5min

0.5

0.5

:
-1 - 55 :
82

0.5-
- :
A
137
0
+ e
Z
55
- 1- 1 :
:
:

0.5
Z=56

0
+ 1- e

137
Ba
56

,+,
X

Cs
A=137

137
Cs
55

- MeV :

A2
X : = (Z.mp + N.mn mX)C EL =1120.9MeV
-1 EL
Z
EL= 1.79310-10j
EL
= MeV8.18
A

0.5

-2 :
-2 - :N0
0.5
N0=4,41015
0.5
-3
- : 0.5.
t1/2 = 30ans
- .
0.5
Ln2
=
- :
t1/2
0.5
-10 -1
= 7.3910 s = Ln 2
-
0.5

t1/2

0.5

0.5

- :A0
A0 = N0
6
A0 = 3.25210 Bq

0.5
0.5

- A: A =A0e-t
:
4.35 = N
:
n1 = N0 - N
0.5

A = 3.220106Bq

0.5
A

=noyaux 1015
n1:
13
n1 = 510 noyaux

x=1.136%

0.5