2.

Chun dd baz yu
a. dd baz yu n chc
* CV = 0 => F = 0 (cha chun )
BOH + HCl BCl + H2O
Dd ( BOH) =>pHo=14- (pKb lgCo)
* 0 < CV < CoVo => 0 < F < 1
BOH + HCl BCl + H2O
Dd

C0V0 CV
BOH: Cb = V + V
0
CV
BCl: Cm =
V0 + V

Dd n baz yu

C0V0 CV
1 F
pH1 = 14 ( lg
) = 14 ( lg
)
CV
F

* CV = CoVo => F = 1
BOH + HCl BCl + H2O
C0V0 = CV
Dd (BCl) Cm =

pH t =

1
(
pK
n
2

C0 V 0
pK b lg
)
V0 + V

V0 + V

* CV > CoVo => F > 1

BOH + HCl BCl + H2O
CV C0V0
HCl:
Ca =
Dd
V0 + V
BCl

CV C 0 V 0
pH 2 = lg
V0 + V

ng cong chun :
Td: Chun 10ml dd NH4OH 0,1 M
(pKb= 4,8) bng dd HCl 0,1 M
NH4OH + HCl NH4Cl + H2O
CoVo
CV
F
Cng thc tnh pH
0,0 pHo= 14- (4,8-lg0,1)

pH
Ghi ch
11,1 Cha c.

0,5 pH0,5=14-(pKb-lgCa/Cm)

9,2

1,0 pHt = [14-4,8-lg(0,1)/2]

5,25 t

1,5 pH2= -lg[(15.0,1-10.0,1)/(10+15)] 1,6

Nhn xt
im tng
ng ti min
axit

Cht ch th
thch hp nht
cho php chun
ny l metyl
da cam, metyl