[H3PO4]= 0.

1-x1=
[H2PO4^-]= x1-x2=
[HPO3^2-]= x2-x3=
[PO4^3-]=x3=
[H3O+]=x1=
[OH-]=Kw/[H3O+]=
charge balance equation
cation=
anion=
mass balance equation
total H3PO4=
toal species=

Solubility of Ca3(PO4)2
Ksp=
2.00E-29
Ka1=
7.11E-03
Ka2=
6.34E-08
Ka3=
4.50E-13
pH=
[H3O+]=

4.00E+00
1.00E-04 M

0.0766544791 M
2.33E-02 M
6.34E-08 M
1.22E-18 M
0.0233455209 M
4.283477E-013 M

0.0233455209 M
0.0233455843 M

0.1 M
0.1 M

pH= -log[H3O+]=

s0lubility= [Ca2+]
[Ca2+]= 3/2*total of phosphate
total of phosphate=
[H3PO4]=
4.93E+09 [PO43-]
[H2PO2-]=
3.51E+11 [PO43-]
[HPO42-=
2.22E+08 [PO43-]
total of phosphate=
3.56E+11 [PO43-]
total [PO43-]=2/3*[Ca2+]
3.56E+11 *[PO43-]=
2/3*[Ca2+]
[PO43-]=
1.87E-12 [Ca2+]
Ksp=
[Ca2+]^3*
2.59e-05*ca)
s= [Ca2+] 0.0004033029 M

s=

7.137091E-007

H= -log[H3O+]=

Ka1=
Ka2=
Ka3=

7.11E-03
6.34E-08
4.50E-13

C-H3PO4=

1.00E-01 M

Ka1
x1^2+Ka1*x1-Ka1*C=0
a=
1
b=
7.11E-03
c=
-7.11E-04
x1=
0.0233455
second eq (Ka2)
Ka2*x1-Ka2*x2=x1*x2
Ka2*x1= (x1+Ka2)*x2
x2=(Ka2*x1)/(x1+Ka2)
x2=
6.34E-08
3rd eq (Ka3)
x3=(Ka3*x2)/(x1+Ka3)
x3=
1.22E-18
1.631796

Solubility of Ca-Phosphate as a function of pH

[Ca2
+]

6
5
4

3
3 or s in M
[Ca2+]

8
pH

10

12

-1
14

pCa

Solubility of Ca3(PO4)2
Ksp=
2.00E-29
Ka1=
7.11E-03
Ka2=
6.34E-08
Ka3=
4.50E-13
pH=

4.00E+00

[H3O+]=

1.00E-04 M

s0lubility= [Ca2+]
[Ca2+]= 3/2*total of phosphate
total of phosphate=
[H3PO4]= 4.93E+09
[H2PO2-]= 3.51E+11
[HPO42-= 2.22E+08
total of phosphate= 3.56E+11
[Ca2+]= (Ksp/(2/3*1/koef)^2))^(1/5)

pH

[H3O+]
0
0.5
1
1.5
2
2.5
3
3.5
4
4.5
5
5.5
6
6.5
7
7.5
8
8.5
9
9.5
10
10.5
11
11.5
12
12.5
13

1
0.316228
0.1
0.031623
0.01
0.003162
0.001
0.000316
0.0001
3.16E-005
0.00001
3.16E-006
0.000001
3.16E-007
1.00E-007
3.16E-008
1.00E-008
3.16E-009
1.00E-009
3.16E-010
1E-010
3.16E-011
1E-011
3.16E-012
1E-012
3.16E-013
1E-013

[H3PO4] [H2PO4^2-]
[HPO4^-] [PO4^3-] Total
4.93E+21
3.51E+19 2.22E+12
1 4.96E+21
1.56E+20
3.51E+18 7.03E+11
1 1.59E+20
4.93E+18
3.51E+17 2.22E+11
1 5.28E+18
1.56E+17
3.51E+16 7.03E+10
1 1.91E+17
4.93E+15
3.51E+15 2.22E+10
1 8.43E+15
1.56E+14
3.51E+14 7.03E+09
1 5.06E+14
4.93E+12
3.51E+13 2.22E+09
1 4.00E+13
1.56E+11
3.51E+12 7.03E+08
1 3.66E+12
4.93E+09
3.51E+11 2.22E+08
1 3.56E+11
1.56E+08
3.51E+10 7.03E+07
1 3.53E+10
4.93E+06
3.51E+09 2.22E+07
1 3.53E+09
1.56E+05
3.51E+08 7.03E+06
1 3.58E+08
4.93E+03
3.51E+07 2.22E+06
1 3.73E+07
1.56E+02
3.51E+06 7.03E+05
1 4.21E+06
4.93E+00
3.51E+05 2.22E+05
1 5.73E+05
1.56E-01
3.51E+04 7.03E+04
2 1.05E+05
4.93E-03
3.51E+03 2.22E+04
3 2.57E+04
1.56E-04
3.51E+02 7.03E+03
4 7.38E+03
4.93E-06
3.51E+01 2.22E+03
5 2.26E+03
1.56E-07
3.51E+00 7.03E+02
6 7.12E+02
4.93E-09
3.51E-01 2.22E+02
7 2.30E+02
1.56E-10
3.51E-02 7.03E+01
8 7.83E+01
4.93E-12
3.51E-03 2.22E+01
9 3.12E+01
1.56E-13
3.51E-04 7.03E+00
10 1.70E+01
4.93E-15
3.51E-05 2.22E+00
11 1.32E+01
1.56E-16
3.51E-06 7.03E-01
12 1.27E+01
4.93E-18
3.51E-07 2.22E-01
13 1.32E+01

13.5 3.16E-014 1.56E-19

14
1E-014 4.93E-21

3.51E-08 7.03E-02
3.51E-09 2.22E-02

14 1.41E+01
15 1.50E+01

[PO43-]
[PO43-]
[PO43-]
[PO43-]

total [PO43-]=2/3*[Ca2+]
3.56E+11 *[PO43-]= 2/3*[Ca2+]
[PO43-]=
1.87E-12 [Ca2+]
Ksp=
[Ca2+]^3*2.59e-05*ca)
s= [Ca2+] 0.000403 M

oef)^2))^(1/5)

D
[Ca2+]
pCa
1.80304E-044 1020.951 -3.009005
1.74923E-041
258.01 -2.411637
1.59404E-038 66.02463 -1.819706
1.21900E-035 17.49869 -1.243005
6.24680E-033 5.024287 -0.701074
1.73306E-030 1.630959 -0.212443
2.78016E-028 0.590734 0.228608
3.31480E-026 0.227046 0.643885
3.51356E-024 0.089342 1.048943
3.57137E-022 0.035452 1.450361
3.56220E-020 0.014121 1.850138
3.47377E-018 0.00565 2.247954
3.19825E-016 0.002287 2.640777
2.50999E-014 0.000956 3.019729
1.35490E-012 0.00043 3.366176
4.00634E-011 0.000219 3.660344
6.71317E-010 0.000124 3.905179
8.15631E-009 7.55E-005 4.122093
8.68415E-008 4.70E-005 4.327539
8.76138E-007 2.96E-005 4.528309
8.43290E-006 1.88E-005 4.724989
0.000072478 1.23E-005 4.911835
0.0004558189 8.48E-006 5.071552
0.0015328825 6.65E-006 5.176896
0.0025421799 6.01E-006 5.220835
0.002754376 5.92E-006 5.227799
0.0025421932 6.01E-006 5.220836

s=

7.14E-007

0.0022449798 6.17E-006 5.210036

0.0019694689 6.33E-006 5.198664

H2S system
pKa1=
pKa2=

7
13

Ka1=
Ka2=
[H2S]=

6.00E-37 3.00E-11
[S2-]
Cu2+
Mn2+
3 1.111111E-022 5.40E-15 2.70E+11
2
2.5E-022 2.40E-15 1.20E+11
1
1E-021 6.00E-16 3.00E+10
0.1
1E-019 6.00E-18 3.00E+08
0.01
1E-017 6.00E-20 3.00E+06
0.001
1E-015 6.00E-22 3.00E+04
0.0001
1E-013 6.00E-24 3.00E+02
0.00001
1E-011 6.00E-26 3.00E+00
0.000001
0.000000001 6.00E-28 3.00E-02
1.00E-007
0.0000001 6.00E-30 3.00E-04
1.00E-008
0.00001 6.00E-32 3.00E-06
1.00E-009
0.001 6.00E-34 3.00E-08
1E-010
0.1 6.00E-36 3.00E-10

[H3O+]

0.0000001
1E-013
0.1 M