B GIO DC V O TO

CHNH THC

( c 5 trang)

THI TUYN SINH I HC NM 2014

Mn: HA HC; Khi A
Thi gian lm bi: 90 pht, khng k thi gian pht
M thi 259

H, tn th sinh:..........................................................................
S bo danh:............................................................................

THI GM 50 CU (T CU 1 N CU 50) DNH CHO TT C TH SINH.

Cho bit nguyn t khi ca cc nguyn t:
H = 1; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; P = 31; S = 32; Cl = 35,5; K = 39;
Ca = 40; Fe = 56; Cu = 64; Br = 80; Ag = 108; Ba = 137.
Cu 1: Polime no sau y trong thnh phn cha nguyn t nit?
A. Poli(vinyl clorua). B. Polibutaien.
C. Nilon-6,6.
D. Polietilen.
Cu 2: Cho cc cht: axit glutamic, saccaroz, metylamoni clorua, vinyl axetat, phenol, glixerol, Gly-Gly.
S cht tc dng vi dung dch NaOH long, nng l
A. 6.
B. 3.
C. 5.
D. 4.
Cu 3: Pht biu no sau y l sai?
A. Cc kim loi kim c bn knh nguyn t ln hn so vi cc kim loi cng chu k.
B. Cc kim loi kim c mu trng bc v c nh kim.
C. Cc kim loi kim c nhit nng chy tng dn t Li n Cs.
D. Cc kim loi kim u l kim loi nh.
Cu 4: Dn hn hp kh gm CO2, O2, N2 v H2 qua dung dch NaOH. Kh b hp th l
A. CO2.
B. O2.
C. H2.
D. N2.
Cu 5: Kh X lm c nc vi trong v c dng lm cht ty trng bt g trong cng nghip giy.
Cht X l
A. NH3.
B. CO2.
C. SO2.
D. O3.
Cu 6: C ba dung dch ring bit: H2SO4 1M; KNO3 1M; HNO3 1M c nh s ngu nhin l (1),
(2), (3).
- Trn 5 ml dung dch (1) vi 5 ml dung dch (2), thm bt Cu d, thu c V1 lt kh NO.
- Trn 5 ml dung dch (1) vi 5 ml dung dch (3), thm bt Cu d, thu c 2V1 lt kh NO.
- Trn 5 ml dung dch (2) vi 5 ml dung dch (3), thm bt Cu d, thu c V2 lt kh NO.
Bit cc phn ng xy ra hon ton, NO l sn phm kh duy nht, cc th tch kh o cng iu
kin. So snh no sau y ng?
B. V2 = 3V1.
C. V2 = 2V1.
D. 2V2 = V1.
A. V2 = V1.
Cu 7: Cht tc dng vi H2 to thnh sobitol l
A. saccaroz.
B. xenluloz.
C. tinh bt.
D. glucoz.
Cu 8: Phn ng no di y thuc loi phn ng oxi ha - kh?
A. AgNO3 + HCl AgCl + HNO3.
B. NaOH + HCl NaCl + H2O.
C. 2NO2 + 2NaOH NaNO3 + NaNO2 + H2O.
D. CaO + CO2 CaCO3.
Cu 9: Cho 0,02 mol -amino axit X tc dng va vi dung dch cha 0,04 mol NaOH. Mt khc
0,02 mol X tc dng va vi dung dch cha 0,02 mol HCl, thu c 3,67 gam mui. Cng thc
ca X l
A. HOOC-CH2CH(NH2)-COOH.
B. CH3CH(NH2)-COOH.
C. HOOC-CH2CH2CH(NH2)-COOH.
D. H2N-CH2CH(NH2)-COOH.
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Cu 10: Cho anehit no, mch h, c cng thc CnHmO2. Mi quan h gia n vi m l
A. m = 2n + 1.
B. m = 2n.
C. m = 2n - 2.
D. m = 2n + 2.
Cu 11: Thy phn hon ton 4,34 gam tripeptit mch h X (c to nn t hai -amino axit c cng
thc dng H2NCxHyCOOH) bng dung dch NaOH d, thu c 6,38 gam mui. Mt khc thy phn
hon ton 4,34 gam X bng dung dch HCl d, thu c m gam mui. Gi tr ca m l
A. 6,53.
B. 7,25.
C. 8,25.
D. 5,06.
Cu 12: Cho cc phn ng xy ra theo s sau:
in phn
X1 + H2O
X2 + X3 + H2
c mng ngn
BaCO3 + K2CO3 + H2O
X2 + X4
Hai cht X2, X4 ln lt l:
A. NaOH, Ba(HCO3)2. B. KOH, Ba(HCO3)2. C. KHCO3, Ba(OH)2. D. NaHCO3, Ba(OH)2.
Cu 13: Hn hp X gm Al, Fe3O4 v CuO, trong oxi chim 25% khi lng hn hp. Cho
1,344 lt kh CO (ktc) i qua m gam X nung nng, sau mt thi gian thu c cht rn Y v hn hp
kh Z c t khi so vi H2 bng 18. Ho tan hon ton Y trong dung dch HNO3 long (d), thu c
dung dch cha 3,08m gam mui v 0,896 lt kh NO ( ktc, l sn phm kh duy nht). Gi tr m gn
gi tr no nht sau y?
A. 9,0.
B. 9,5.
C. 8,0.
D. 8,5.
Cu 14: trung ha 20 ml dung dch HCl 0,1M cn 10 ml dung dch NaOH nng x mol/l. Gi tr
ca x l
A. 0,3.
B. 0,4.
C. 0,1.
D. 0,2.
Cu 15: T 6,2 kg photpho iu ch c bao nhiu lt dung dch H3PO4 2M (hiu sut ton b qu
trnh iu ch l 80%)?
A. 64 lt.
B. 40 lt.
C. 100 lt.
D. 80 lt.
Cu 16: Ancol X no, mch h, c khng qu 3 nguyn t cacbon trong phn t. Bit X khng tc dng
vi Cu(OH)2 iu kin thng. S cng thc cu to bn ph hp vi X l
A. 4.
B. 2.
C. 3.
D. 5.
Cu 17: Cho hn hp gm 1 mol cht X v 1 mol cht Y tc dng ht vi dung dch H2SO4 c, nng
(d), to ra 1 mol kh SO2 (sn phm kh duy nht). Hai cht X, Y l:
B. FeO, Fe3O4.
C. Fe3O4, Fe2O3.
D. Fe, FeO.
A. Fe, Fe2O3.
Cu 18: Pht biu no sau y l sai?
A. Dung dch glyxin khng lm i mu qu tm.
B. Anilin tc dng vi nc brom to thnh kt ta trng.
C. Dung dch lysin lm xanh qu tm.
D. Cho Cu(OH)2 vo dung dch lng trng trng thy xut hin mu vng.
Cu 19: Thy phn cht X bng dung dch NaOH, thu c hai cht Y v Z u c phn ng trng
bc, Z tc dng c vi Na sinh ra kh H2. Cht X l
A. CH3COO-CH=CH2.
B. HCOO-CH2CHO.
C. HCOO-CH=CH2.
D. HCOO-CH=CHCH3.
Cu 20: Hn hp X gm axit axetic, propan-2-ol. Cho mt lng X phn ng va vi Na, thu c
0,448 lt kh H2 (ktc) v m gam cht rn Y. Gi tr ca m l
A. 3,28.
B. 2,40.
C. 3,32.
D. 2,36.
Cu 21: Thy phn 37 gam hai este cng cng thc phn t C3H6O2 bng dung dch NaOH d. Chng
ct dung dch sau phn ng thu c hn hp ancol Y v cht rn khan Z. un nng Y vi H2SO4 c
140oC, thu c 14,3 gam hn hp cc ete. Bit cc phn ng xy ra hon ton. Khi lng mui
trong Z l
A. 42,2 gam.
B. 40,0 gam.
C. 34,2 gam.
D. 38,2 gam.
Trang 2/5 M 259

Cu 22: t chy 4,16 gam hn hp gm Mg v Fe trong kh O2, thu c 5,92 gam hn hp X ch

gm cc oxit. Ha tan hon ton X trong dung dch HCl va , thu c dung dch Y. Cho dung dch
NaOH d vo Y, thu c kt ta Z. Nung Z trong khng kh n khi lng khng i, thu c
6 gam cht rn. Mt khc cho Y tc dng vi dung dch AgNO3 d, thu c m gam kt ta. Gi tr
ca m l
A. 32,65.
B. 10,80.
C. 32,11.
D. 31,57.
Cu 23: t chy hon ton 13,36 gam hn hp X gm axit metacrylic, axit aipic, axit axetic v
glixerol (trong s mol axit metacrylic bng s mol axit axetic) bng O2 d, thu c hn hp Y
gm kh v hi. Dn Y vo dung dch cha 0,38 mol Ba(OH)2, thu c 49,25 gam kt ta v dung
dch Z. un nng Z li xut hin kt ta. Cho 13,36 gam hn hp X tc dng vi 140 ml dung dch
KOH 1M, sau khi cc phn ng xy ra hon ton, c cn dung dch thu c cht rn khan c
khi lng l
A. 14,44 gam.
B. 18,68 gam.
C. 13,32 gam.
D. 19,04 gam.
Cu 24: in phn dung dch X cha a mol CuSO4 v 0,2 mol KCl (in cc tr, mng ngn xp,
cng dng in khng i) trong thi gian t giy, thu c 2,464 lt kh anot (ktc). Nu thi
gian in phn l 2t giy th tng th tch kh thu c c hai in cc l 5,824 lt (ktc). Bit hiu
sut in phn 100%, cc kh sinh ra khng tan trong dung dch. Gi tr ca a l
A. 0,15.
B. 0,24.
C. 0,26.
D. 0,18.
Cu 25: Kim loi no sau y khng tc dng vi dung dch H2SO4 long?
A. Na.
B. Al.
C. Mg.
D. Cu.
Cu 26: Axit cacboxylic no di y c mch cacbon phn nhnh, lm mt mu dung dch brom?
A. Axit propanoic.
B. Axit 2-metylpropanoic.
C. Axit metacrylic.
D. Axit acrylic.
Cu 27: Cho 0,1 mol anehit X phn ng ti a vi 0,3 mol H2, thu c 9 gam ancol Y. Mt khc
2,1 gam X tc dng ht vi lng d dung dch AgNO3 trong NH3, thu c m gam Ag. Gi tr
ca m l
A. 10,8.
B. 16,2.
C. 21,6.
D. 5,4.
Cu 28: Hn hp kh X gm 0,1 mol C2H2; 0,2 mol C2H4 v 0,3 mol H2. un nng X vi xc tc Ni,
sau mt thi gian thu c hn hp kh Y c t khi so vi H2 bng 11. Hn hp Y phn ng ti a vi
a mol Br2 trong dung dch. Gi tr ca a l
A. 0,1.
B. 0,3.
C. 0,4.
D. 0,2.
Cu 29: Pht biu no sau y l sai?
A. Trong mi trng kim, Br2 oxi ha CrO2 thnh CrO24 .
B. Cr(OH)3 tan c trong dung dch NaOH.
C. CrO3 l mt oxit axit.
D. Cr phn ng vi axit H2SO4 long to thnh Cr3+.
Cu 30: Cht X c cng thc: CH3-CH(CH3)-CH=CH2. Tn thay th ca X l
A. 3-metylbut-1-in.
B. 3-metylbut-1-en.
C. 2-metylbut-3-en.
D. 2-metylbut-3-in.
Cu 31: Cho l Al vo dung dch HCl, c kh thot ra. Thm vi git dung dch CuSO4 vo th
A. tc thot kh tng.
B. tc thot kh khng i.
C. phn ng ngng li.
D. tc thot kh gim.
Cu 32: Cht kh no sau y c to ra t bnh cha chy v dng sn xut thuc gim au
d dy?
A. CO2.
B. N2.
C. CO.
D. CH4.
to
Cu 33: Cho phn ng: NaX(rn) + H2SO4(c) NaHSO4 + HX(kh).
Cc hiro halogenua (HX) c th iu ch theo phn ng trn l
A. HCl, HBr v HI.
B. HF v HCl.
C. HBr v HI.
D. HF, HCl, HBr v HI.
Trang 3/5 M 259

Cu 34: Khi nh t t n d dung dch NaOH vo dung dch hn hp gm a mol HCl v b mol
AlCl3, kt qu th nghim c biu din trn th sau:
s mol Al(OH)3
0,4
0

0,8

2,0

2,8

T l a : b l
A. 4 : 3.
B. 2 : 1.
C. 1 : 1.
Cu 35: H cn bng sau c thc hin trong bnh kn:

CO2 (k) + H2 (k) ;

CO (k) + H2O (k)
H < 0

s mol NaOH

D. 2 : 3.

Cn bng trn chuyn dch theo chiu thun khi

A. tng p sut chung ca h.
B. cho cht xc tc vo h.
C. thm kh H2 vo h.
D. gim nhit ca h.
Cu 36: Dung dch X cha 0,1 mol Ca2+; 0,3 mol Mg2+; 0,4 mol Cl- v a mol HCO 3 . un dung dch
X n cn thu c mui khan c khi lng l
A. 49,4 gam.
B. 23,2 gam.
C. 37,4 gam.
D. 28,6 gam.
Cu 37: C bao nhiu amin bc ba l ng phn cu to ca nhau ng vi cng thc phn t C5H13N?
A. 4.
B. 2.
C. 5.
D. 3.
Cu 38: Lin kt ha hc gia cc nguyn t trong phn t NH3 l lin kt
A. cng ha tr khng cc.
B. cng ha tr phn cc.
C. ion.
D. hiro.
Cu 39: Cho hnh v m t th nghim iu ch kh Y t dung dch X:

Hnh v trn minh ha phn ng no sau y?

o

t
NaCl + NH3 + H2O.
A. NH4Cl + NaOH
o

t
B. NaCl(rn) + H2SO4(c)
NaHSO4 + HCl.
H SO c,t o

2
4
C. C2H5OH
C2H4 + H2O.

CaO, t
D. CH3COONa(rn) + NaOH(rn)
Na2CO3 + CH4.
Cu 40: Nh t t n d dung dch NaOH long vo mi dung dch sau: FeCl3, CuCl2, AlCl3, FeSO4.
Sau khi cc phn ng xy ra hon ton, s trng hp thu c kt ta l
A. 1.
B. 2.
C. 4.
D. 3.
Cu 41: Cho X, Y l hai cht thuc dy ng ng ca axit acrylic v MX < MY; Z l ancol c cng s
nguyn t cacbon vi X; T l este hai chc to bi X, Y v Z. t chy hon ton 11,16 gam hn hp
E gm X, Y, Z, T cn va 13,216 lt kh O2 (ktc), thu c kh CO2 v 9,36 gam nc. Mt khc
11,16 gam E tc dng ti a vi dung dch cha 0,04 mol Br2. Khi lng mui thu c khi cho cng
lng E trn tc dng ht vi dung dch KOH d l
A. 4,68 gam.
B. 5,04 gam.
C. 5,44 gam.
D. 5,80 gam.
Trang 4/5 M 259

Cu 42: Cho ba mu vi (100% CaCO3) c cng khi lng: mu 1 dng khi, mu 2 dng vin
nh, mu 3 dng bt mn vo ba cc ng cng th tch dung dch HCl (d, cng nng , iu kin
thng). Thi gian vi tan ht trong ba cc tng ng l t1, t2, t3 giy. So snh no
sau y ng?
A. t1 < t2 < t3.
B. t1 = t2 = t3.
C. t3 < t2 < t1.
D. t2 < t1 < t3.
Cu 43: Cu hnh electron trng thi c bn ca nguyn t nguyn t X c tng s electron trong cc
phn lp p l 8. Nguyn t X l
A. Si (Z=14).
B. O (Z=8).
C. Al (Z=13).
D. Cl (Z=17).
Cu 44: Phenol (C6H5OH) khng phn ng vi cht no sau y?
A. Na.
B. NaHCO3.
C. Br2.
D. NaOH.
Cu 45: Hn hp kh X gm etilen v propin. Cho a mol X tc dng vi lng d dung dch AgNO3
trong NH3, thu c 17,64 gam kt ta. Mt khc a mol X phn ng ti a vi 0,34 mol H2. Gi tr
ca a l
A. 0,32.
B. 0,34.
C. 0,46.
D. 0,22.
Cu 46: t chy hon ton 1 mol cht bo, thu c lng CO2 v H2O hn km nhau 6 mol. Mt
khc a mol cht bo trn tc dng ti a vi 600 ml dung dch Br2 1M. Gi tr ca a l
A. 0,15.
B. 0,18.
C. 0,30.
D. 0,20.
Cu 47: Cho m gam hn hp gm Al v Na vo nc d, sau khi cc phn ng xy ra hon ton, thu
c 2,24 lt kh H2 (ktc) v 2,35 gam cht rn khng tan. Gi tr ca m l
A. 3,70.
B. 4,85.
C. 4,35.
D. 6,95.
Cu 48: Thc hin phn ng nhit nhm hn hp gm Al v m gam hai oxit st trong kh tr, thu
c hn hp rn X. Cho X vo dung dch NaOH d, thu c dung dch Y, cht khng tan Z v
0,672 lt kh H2 (ktc). Sc kh CO2 d vo Y, thu c 7,8 gam kt ta. Cho Z tan ht vo dung dch
H2SO4, thu c dung dch cha 15,6 gam mui sunfat v 2,464 lt kh SO2 ( ktc, l sn phm kh
duy nht ca H2SO4). Bit cc phn ng xy ra hon ton. Gi tr ca m l
A. 6,48.
B. 5,04.
C. 6,96.
D. 6,29.
Cu 49: Trung ha 10,4 gam axit cacboxylic X bng dung dch NaOH, thu c 14,8 gam mui. Cng
thc ca X l
A. C3H7COOH.
B. HOOC-CH2-COOH.
C. HOOC-COOH.
D. C2H5COOH.
Cu 50: Ha tan ht 1,69 gam oleum c cng thc H2SO4.3SO3 vo nc d. Trung ha dung dch thu
c cn V ml dung dch KOH 1M. Gi tr ca V l
A. 10.
B. 40.
C. 30.
D. 20.
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