L/O/G/O

Nhom 4_12KMT

PM2.5 TNG QUAN

GIA PAHs V HYDROXYPAHs VI CC YU T MA
TRONG NM V CC YU
T VT L, HA HC
GVHD: TS. T Thi Hin
ThS. Nguyn Ly Sy Phu

N i dung
1

3
4

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Gii thi u
Thc nghi m
Kt qua va thao lu n
Kt lu n

1. Gii thi u
cht c
hi bn
vng

PAHs,
OHPAHs
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t cc
nhin
liu
ha
Text
in
here
thch
v
cht thi
hu c

linh ng
cao,
d dng
di chuyn
ng di
bi gi

gy cc
bnh v
Textda
in
phi,
hochere
ung
th bng
quang

OH-PAHs
thng gy
c nhiu
hn so vi
PAHs tng
ng

cht gy nhim hng u tc

ng tiu cc n mi trng

2. Thc nghi m
naphthalene, acenaphthene, fluorene,
2.1. cc ha cht
phenanthrene, anthracene, fluoranthene, pyrene,

PAHs

OH-PAHs

Hoa cht
khac
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PAH-MIX 9 ca Tin s
benzo [] anthracene, chrysen , benzo []
Ehrenstorfer GMbH co cha
fluoranthene , benzo [k] fluoranthene benzo [a]
tich trong
pyrene,10ng/l
dibenzo cht
(, h) phn
anthracene,
va benzo [g,
h, i] perylene
acetonitrile
1-hydroxypyrene (1-OHPyr) v 2hydroxyphenanthrene (2-OHPh), cng
t Tin s Ehrenstorfer GmbH, 10 ng/l
cht phn tich trong acetonitrile

Analytical-thuc th loi
dichloromethane, acetone, hexane
v cyclohexane, HPLC-loi
acetonitrile v nc kh ion

3. Thc nghi m
3.2. Thu thp mu
Vi tri

Trung tm nghin
cu CIEMAT, cch
7km v phia ty bc
ca trung tm Madrid

S mu
T thng 1 nm
2008 n thng 11
nm 2008, thu
thp c 35 mu
(1 mu 1 tun)
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Thu
th p
mu

Thu thp
Ht mn (PM2.5)
thu thp trong b
lc si thy tinh x
l nhit (4000C
trong 24h)

Bo qun
cc b lc c bc
mt cch ring bit
trong giy nhm v
c lu tr trong t
lnh 20oC n khi
phn tich

3. Thc nghi m

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3. Thc nghi m
3.2. Chun
PAHsb mu
L vi sng s dng sau
40 pht nng nhit
ti 120oC ti ngun in
900V.
Cc b lc c ct
tng ming nh v t
mi l vi sng cng vi
20ml dichlororomethane.

OH-PAHs
B lc c ct thnh tng
ming.
siu m trong bnh kin cha
10 ml methanol (30 pht).
Sau khi mu 15 pht
trong mt t ng lnh

Cc cht c lc qua l (PTFE, 0,22 mm) v cc

dung mi bc hi di dng nito.
Cc cht chit xut l lng trong 1,0 ml methanol
v tim trc tip vo h thng HPLC.
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3. Thc nghi m
PAHs
3.4. iu kin sc
ky

phng php s dng l

Gradient.
H thngPha
sc ng,
k lng
25cao
pht
p Agilent
u tin1200,
l mt
vihn
mt
hp ct
axetonitrile/nc
tng tc C18
(45/55),
Supelcosil
t pht
(LC-PAH
25-30250
l x
Phng 100%
4.6 mm,
acetonitrile
kich thc
v ht 5
php
acetonitrile/nc
mm), c gia (45/55)
nhit
ti 30-37
36,7oCpht.
bngTbliu
l 1,5
mL/pht
khin v
nhit
th
tich
Jones
tim
mu
Chromatography
l 25 mL.
ct nng
7971-R HPLC v u d
hunh quang Agilent 1100.

Thit
bi

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OH-PAHs
ch isocratically. Pha
ng
H thng
l hhsc k lng
axetonitril/nc
cao p Agilent 1200
(60/40),t
nhng c
l flo
trang
l 1,0
b vi
mL/pht.
mt Eclipse
Khi
XDB
lng
C- tim
l
18(Agilent),
25 ml. Fluo
ctc
tch(150
pht
hin
x 4.6mm,
bc
5 mm)
sngduy tr
259/386nm
36,70C vvi
1 Agilent
2-OHPh
v
1.100
242/388nm
vi phun vi
t ng
1OHPyr,
cng vithi
1 Agilent
gian phn
1100
tich
u l
d7hunh
pht. quang

4. Kt qua va thao lu n
3.1 Xac inh PAHs va OH-PAHs trong khng
khi vi thi gian 1 nm.
- Nhng s liu v nng (pg/m3) ca cac hp
cht cng vi mt lot cac gia tri khac c ghi
nhn hang tun t thang 2 nm 2008 n thang 11
nm 2008 ti cac trm khi tng
- Tng nng ca OH-PAH va PAH nm trong khoang
t 175 n 2125 pg/m3; i vi pyrene, fluoranthene,
phenanthrene, chrysene, benz[]fluoranthene and 2hydroxyphenanthrene th lun lun xut hin nng
cao.
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4. Kt qua va thao lu n
Nng ca 2-OHPh nm trong khong 12 n 200
pg/m3 v 1-OHPyr l 3 n 60 pg/m3. Trong khi nng
ca 1-OHPyr c th so snh vi nhng trich dn
ca Kishikawa (Kishikawa et al., 2004) th chng ta
khng th tm thy nhng ti liu tham kho v
2-OHPh.

Hm lng ca cc cht cn li l
di ngng gii hn pht hin

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4. Kt qua va thao lu n

Hnh 2: Nng trung bnh ca PAHs v OH-PAHs theo ma

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4. Kt qua va thao lu n
4.1 Phn tch nhn t
Ma Trn D Liu
(Ma Trn X)

Gm nmu =35, nbin =26

(bin ha hc v vt l)

kch thc n x m
(35 hng v 26 ct)
Tng: 910 gi tr d liu

Nhn xt:Kim tra trc quan cng c nhiu kt lun nh tnh c

th c rt ra t bng nhng tip cn ph hp hn cho vi c
gii thch thi cn s dng phng php a bin
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4. Kt qua va thao lu n

Khi cc bin
c coi l
khc bit
ng k vi
cc bin khc

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Bc u
tin l chun
ha cc d
liu

Sau
s dng th
nghim
Bartlett
xc nh s
tng quan

4. Kt qua va thao lu n
Hnh 4a. I VI YU T F1 cho thy r:
S ng gp tch cc ca tt c cc bin PAHs v cc
dn xut hydroxy ca chng v tt c cc ch tiu
nhim: PM2.5, PM10, NO, NO2, NxOx, v SO2.
Cc yu t p sut kh quyn, hng gi v m
tng i cng ng gp tch cc.
Ngc li, nng ozone (O3) v cc i lng vt l:
nhit , tc gi, bc x mt tri v tia cc tm,
c nh n thy gp phn tiu cc n yu t ny ( F1).
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4. Kt qua va thao lu n
4.2 Phn tch cm
Phn tich cm cng gip miu t d liu theo hai
chiu nhng trong trng hp ny s dng 100%
thng tin c sn

Thng qua phn tich nhn t, chng ta c th miu

t bng d liu ban u trong hai chiu v do
nhc n thng tin quan trng c du trong bng
trong khi lm vic ch vi 57,7% ca cc d liu ban
u
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4. Kt qua va thao lu n
Qua nhn ta thy, Mt trong nhng cm c cng mt
s cc tinh cht vt l, tc gi, nhit , bc x
mt tri v cng nh sng tia cc tim UV, cng
vi mc ozone.
Trong cc cm ln khc xut hin cc bin cn li.
Trong cc cm ny, nhng nhm khc xut hin
nh c hnh thnh bi OH-PAHs hoc cc yu t
ha hc khc (NO, NO2, v.v)

Mi tng quan gi PAH, OH-PAH

vi cc yu t vt l ha hc
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5. Kt lu n
Tng nng PAH v OH-PAH thay i t 175
n 2.125pg m-3 trong khu vc bn thi
Pyrene, fluorene, phenanthrene v chrysene lun
xut hi n nng cao
Nng OH-PAHs 2-hydroxyphenanthrene dao
n g 12-200 pg m-3 v ca
1-hydroxypyrene 3-60 pg m-3
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5. Kt lu n
Mi tng quan tich cc cng c pht
hin gia nhng thay i trong OH-PAHs v
PAHs. iu ny c th cho thy s tn ti ca
khng ch cc phn ng quang ha v phn
ng vi ozone (tng quan nghch vi Iuv v
O3), m cn nhng phn ng ha hc khc
gia PAHs v cht gy nhim mi trng
khc

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Thy c mi quan h nghch ca PAHs

v OH-PAHs vi nhit , nng ozone,
bc x mt tri v cng bc x UV;
PAHs v OH-PAHs thay i r rng theo
ma, tng ln trong nhng thng lnh v
gim i trong nhng thng nng trong nm.

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Cam n thy c
va cac bn a
lng nghe
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