First we need SimID's...

Enter:
testingcheats true
sims.get_sim_id_by_name yoursimfirstname yoursimlastname
This command will print a number at the end, similar to: 775464154248314888
Make note of this number, it's your sim's unique id, I recommend making a copy s
omewhere if you'll be using these commands a lot.
Then run the command again for the other sim you're wishing you edit relationshi
ps for:
sims.get_sim_id_by_name targetsimfirstname targetsimlastname
Make note of this sim's ID as well.
Destroy a relationship:
Now we destroy the relationship (because were a horrible person;)):
relationship.destroy yoursimID targetsimID
Add Relationship Bit
(This lets you modify the type of relations between two sims. It also requires s
im ID)
relationship.add_bit yoursimID targetsimID relationshipBit
NOTE: You can not REMOVE a bit, you'll have to override it with another. For exa
mple setting family_husband_wife will override family_brother_sister
The available family relationshipBits are as follows:
romantic-Married
family_husband_wife
family_grandchild
family_son_daughter
family_brother_sister
family_grandparent
family_parent