A. Oxi ha isobutan thnh t-butyl hydroperoxit v t-butuy ancol.

Phn ng xy ra bi dng oxy lng trong dy thit b phn ng c khy ni tip, cc dng vo t song
song trong thit b t nm ngang. Phn ng xy ra m khng cn xc tc, nhng bm lin tc 1 lng
nh axit citric gip ngn nga s hnh thnh lng ln sn phm ph. iu kin hot ng cn thit: nhit
110-1300C, p sut 3-3,5MPa, v thi gian lu khong 7h cho mt lng isobutan chuyn ha l 35%.
Tng sn lng hydroperoxi v alcohol l 94 phn mol v t l mol 2 sn phm khong 1.2
Dng oxy c make-up v hi lu tr li thit b phn ng vs dng isobutan mi a vo v hi lu, t
l nng oxy v isobutan c gi di 8% khi lng m bo mc ngoi gii hn chy n di.
dng kh tr kim sot t l nng ny.
Nhit ta ra t qu trnh chuyn ha c loi b bng s bay hi 1 phn vo mi trng phn ng, bao
gm ch yu l isobutan, n c ngng t li v hi lu trc tip sau khi lm mt v flash trong giai
on 2.kh thot ra t flash p sut cao, ch yu cha oxy, n c tra li thit b phn ng oxyhoa sau
khi nn li. kh thot ra t thit b flash th hai vi p sut thp, giu dng isobutan cn d n cha trong
2 thp hp th, vi s a l 35 v 20 a, hot ng vi p sut 3MPa, trong s c mt ca ethyl acetate,
sau kh hp th bi stripping.
Cc isobutan ha tan trong dng cht lng c rt ra t l phn ng cng nh b thu hi trn cng ca
thp chng ct, p sut 0,15MPa(15 a). Cc hp cht oxy ha thu c y thp th 3 v thp nh
hp th sau a sang chng ct phn on (10 a) p sut thp 0.5MPa. Sn phm nh (distillate)
bao gm dung mi,isobutan cn d v 1 t t-butyl alcohol, n c a sang giai on nh hp. dng vt
cht ra ch yu bao gm hydroperoxide v t-butanol,
B. Epoxi ha propylene.
Epoxy ha xy ra trong pha lng. cht xc tc s dng cho mc ch ny thng l dung dch moliden
naphtenat 5% KL trong hn hp ca t-butyl hydroperoxide v alcohol. Nng kim loi trong mi
trng phn ng khong 0,05% KL. iu kin hot ng nhit gia 80-110C, p sut 3-4MPa, trong
thit b phn ng nhiu giai on, trong s c mt ca propylene d ( t l mol peroxit/ancol/proylen l
1/1/3). Thi gian lu l 0,5-1h/1 giai on, tng thi gian lu l 2,5h. vi khong 1h trong giai on u
tin th 50% hydroperoxit phn ng. mi ln chuyn ha, propylene l 15% cn hydroperoxit l 90 n
95%. chn lc propylene oxit v ancol t 85 v gn 95 % tnh theo peroxide. Nhit phn ng c
loi b t phn ng u tin bng cch lm lnh bn thnh bng dng hi lu,trong bn thit b cn li,
kt hp trong 1 v duy nht c lm lnh trung gian. Trong tng giai on, nhit vo l 80C v nhit
ra l 100C.
Dng t phn ng chng ct u tin loi b propylene khng th o ngc