PHYPRNI Quiz No. 3 (Part I) Solve the following problems: 1. Ten grams of helium at 290 K and 3 atm pressure is mixed adiabatically with 8.0 g of hydrogen at 360 K and 3 atm to yield a mixture whose pressure is also 3 atm. Assuming the gases are ideal, calculate the total entropy of mixing. (10 pts.) Four moles of methane, originally at a pressure of 8.4 atm and 28°C is allowed to expand adiabatically until the final pressure is 900 mm Hg. Calculate the AS (system), AS (surr) and AS (total) for the process when (10 pts.) (a) The expansion takes place reversibly (b) The expansion takes place against a constant pressure of 850 torr (©) The change involves a free expansion 3. (a) Calculate the entropy change involved in transforming 120 g of gaseous ethanol (CaHsOH) at 100°C and 1 atm into liquid at 0°C and 1 atm, (b) If the temperature of the surroundings is 0°C, calculate the AS (surr) and AS (univ) for the process in letter (a) (12 pts.) 4. Calculate AS, AG and AA for 2 moles of butane gas on expansion from a volume of 5 L to a volume of 12 Lata constant temperature of 260 K, (a) assuming butane is an ideal gas (13 pts.) (b) assuming butane is a Van der Waals gas with a= 14.66 atm-L? mol b= 0.1226 L molt 5. Given: 4 FeS2(s) + 11 O2(g) > 8 SO.(g) +2 Fe20,(s) Calculate the AS of reaction at 800°C (10 pts.) 6. For the reaction: Ha(g) + Ch(g) = 2HCI(g) ACp = -11.48+6.11x109T +4.67x105T? (mol! K") (IS pts.) (a) Find an expression of AH as a function of temperature (b) Calculate AH at b.1) 850K b.2)240K (c) Find an expression of AG as a function of T (d) Calculate AG at d.1) 850K 4.2) 240K (e) Calculate AS at €.1)850K ¢.2)240K.——— ie “He tgy 45-(gy STOR OK Pa—Saten P+ Sct: mh, = lg) m2 £20 oe Def Pea ol Wy + 2g + 4-0 mol : TET 70 420 (ne Kast (mes) AN Rag, BHO | Tie Oy, Or ae (scey =0 € e~reyerdy oe . (rom) (2) Mee (20-F - 6ST ~ URS 5040 - |¢T 19:35 G92. 5 Ep Bee as tas ffi AS, 2.5 mol ew (eng) dT —_a.5 mol_(-314) neem) T BS 8S mol (S\(65m) nee - 25 (oon) [EE) 37 "90 o BS Th | Fa a= My, R7n Pe Fj a — TY iS, > (40 sol [28 (4.0 oe) CDM) In pero i M22) . we} v a AS a Cod at The bachOe bSpix 2 DS Ab Tse, aes 3 | Y METHANE! «. n= 4 moles _Chy = torcs mm Hg : Pls &4 abn Py = 400 mm Hey pe*05 “O + soe SK r sine — ° | 1) irreversine gxpostin Peg = 850 tre Sea 35.31 ea} — qo oo Bue gw Gi- Ge OE bud op-R = Ww L wali 0 eee eel = as. 496 iggeste- 1, =a 4 BEY T= 4p 2 — Se ees bi ae a b Ser aT = nR In Pe a Pr . "BI io 700 Psy = (A) (83 tt ee, nee) TE —bS 2 34 eee Beit Bg BS, i : = = 3f SS pige= 0 ae a es Sel 7 ‘ Gry2 ee eos Sag \ a J ie B OSs ee BS 2 = (© (314) n{ 3 ao a “4 2 L: LL {Bsa — wea iat: [20 q GOH (ethomal) _ comattent preene! CO) am) age. 2 G08 Eats on ae GusOW gy Py Gas On ws, Hy on - wae ey Ssh AS, = n@ In__352 GHYO Bs "i BS =f 20 Voc gg a) tw 380 ‘ea AN oo 3B J bs ee BS, 2 nD hg a : A Ro {000 5 “(A pst a n sett AS. = =30), 397 2 He SG. en Ss Gans 3 a ; es eee Oe Vieni In 223, Sy Gee UL a) ln 2p MS, = = a9 BS oy 2 aK a ee = + b) An, = Were (025 Bay = —h Bava Gy > pe (4.5) (W000) DA, “fal os) stan) oe TS = 3S ey Bi = -113305. 84 Sa (a3 - 282) AY = AW + DAL + DH, ann ~ “Te 2323-34. 2 C3S74.53 + Clases. y) 4 Cartas | Djs 2 = 22935, $C) += 19g20-% JGay 2 “40. BJ 95, ee sug, > 189420. J BS. «ago. WJ 236 Sav snes DSi Sas —*PSare + dos SSF 4 1. Wes Je er ; F Req'd: AS, BG, bb T_+ comston} = 200 6 {sotherma) _procese Nis SE Niele N= _2 moles ideal gas ° DS > al + chk Ve - BS + (ams) (es = OSea IF, Sot LAA =nRT, P, (st) = (amo1) (0+ 06206) (20) (pe £4 atm 2, > WRTe P, Cit) >(2 mos)( 0.006) (200) bs 3. 56 atm BG = ART In 2 = [ae 3. 69) | Bas (2)(6319) (200) In rs2) Van der Wools gas AS = WR jp _Y2-nb Von = cw 6S = M919) mw (e= USAT pS aa R ff =. aR ae = Venb Ve Fos (2)(0.00906 (260) ST (nec), = = 2(0. peep ~s Pos 2d atin 3 P= sete = Wa Varn’ Negi f, <2 (0.08006 ) (240) = 2? (Hee) p= 2(0. re) he P, + 3.223 abn Bases NP net ap : wet on & BGR el Be - f A | BG = 4317-37 Js 4S tf lg = 69) = 3 Req'd? DSexy Soo .. . Sees {ee = ©) Soy > ¢ Ce.) + oe) = foro) iS BSc bp = “9 : = 4 (62.1%) — 1 (29.355) Dons ie Saxe , 8 y Alei 2% 6. Wigt Seay = HL oy = age + GN KITT + 4.67 x10 c+) a te Ao4_n0 rat = bu = |depdT ¢ G é ba ((-leae + ONKO + 4ct KO ay ac : i by GT + GK Ty - heal 4, 2 T oe mk 30 o < 2h) - bl bh ee @) ph, &) Wa = “PH + (= 2.1) (1000) 767 bi = lrae20_J ~leqo20 = - 4a (27) + Gn x Gas)” - 467K" 4G iz 29% ~|g4G2o iG a Aus -IpTo4 3.058 x0? 7? — 4.67 wih — 179903. 1 : = v Te rae, i pa ge 2 ee @ T= 4| —— _# ou ia ° 8G, = dB a BS P8655 SGren me ») AG + —190. 6s (ooo) = = 190 =i z 7 = 190000 J = MAE In Cogs) - 3. OSS KIO (agg) - 293.5 x10 _ =e Is, 298 a = 639.597 = -SAl.93gq +t Coes F Ee w 3 x 1 ) DG = (Ep gy 43-055 KOT - acto -1199G.15) dT T a ‘Te fs bes = [fais + a. osy x? — 4.67 «108 -_ ar) ay TL am r S56 =~ (ae In 43.058 xT 40x +t reaoh T -3tl PG = Ie gbin T_— 3. O55, KOT — 2.335A10s — rests Ir SG = Wag In T - 3.055 KlOPT - 2. 355 ro) GOR JS ~4TTSD + rs + BG = WagTint - 3.085 xo 2-2. SER 1799B. IS — 1. IT =ie = So ganar ay ie ___@ 240. — BS eee 22 02 Fh Kee B Sot \ BCp it tad oe BS mp2 EOS ye: —= Se, = Sy OS, = 2 Cla) = 223-09 = 130. aad Bsa 2 2.0 I ee é = bS= 20. 06 +t \ “48 4 oie 4 469 xJ0™ y = " Pp ae So = a 006 Sica He eee ‘ 6. 1 Ko 4 4,6r x10 p>