Xc nh ch s COD bng phung php icromat

Nguyn tc ca phng php ny l mu c un hi lu vi K2Cr2O7 v cht xc tc bc sunfat

trong mi trng axit sunfuric c. Phn ng din ra nh sau:
Cr2O72- + 14H+ + 6e 2Cr3+

7H2O

Qu trnh oxi ha c th c vit

O2

+ 4H+ + 4e 2H2O

Bc sunfat dng thc y qu trnh qu trnh oxi ha ca cc cht hu c phn t lng thp.
Cc ion Cl- gy cn tr cho qu trnh phn ng:
Cr2O72-

+ 6Cl- + 14H+

3Cl2 + 2Cr3+ + 7H2O

trnh s cn tr trn ngi ta cho thm HgSO4 to phc vi Cl-. Ngoi s cn tr ca ion Clcn phi k n s cn tr ca nitrit (NO2-), tuy nhin vi lng nitrit l 1- 1,2 mg/l th s cn tr ca
chng c xem l khng ng k, cn trnh nh hng ca chng th cn thm vo mu mt lng axit
sunfamic vi t l 10mg/1mg NO2 -.
Quy trnh phn tch:
-Chun b ha cht:
+ Hn hp phn ng: Ha tan 10,216g K2Cr2O7 loi PA c sy nhit 103oC sau thm
167ml dung dch H2SO4 v 33.3g HgSO4. Lnh v nh mc n 1000ml bng nc ct.
+ Thuc th axit: Pha 5.5g Ag2SO4 trong 1 kg dung dch H2SO4 c (d = 1.84) c th khuy hoc
cho Ag2SO4 tan ht mi s dng.
+ Pha dung dich chun kaliphtalat( HOOC6H4COOK): Sy s b mt lng kaliphtalat 120oC.
Sau cn 850mg kaliphtalat pha v nh mc vo bnh 1lt (dung dch ny c nng 1mg O2/ml).
-

Phng php xc nh: Ly vo ng ph mu (cuvet) 2.5 ml mu sau thm1.5 ml hn hp

phn ng va 3.5ml thuc th axit v. t cuvet vo my ph mu nhit 148oC trong 2h sau ly ra

v ngui n nhit phng. o mt quang bc sng 605nm.
Xy dng ng chun s ph thuc ca COD vo mt quang t phng trnh ng chun lp
c c th tnh ngc li gi tr COD khi o mt quang ca mu nc thi trong qu trnh x l.