NAMA : PANDU FEBRIYANTO

NOMOR : 131011001
TUGAS THERMODINAMIKA TEKNIK KIMIA 2

Penentuan Titik Didih/Boiling Point

Diketahui :
Cairan dengan komposisi : Xa = 0,4 ; Xb= 0,3 ; Xc= 0,3
Pa = exp (14,95-3764/T)
Pb = exp (16,07- 4497/T)
Pc = exp (16,27-4934/T)
Pt = 76 cmHg
Titik didih cairan multikomponen berlaku persamaan :
f(T) = (Pa/Pt).Xa + (Pb/Pt).Xb + (Pc/Pt).Xc - 1 = 0
Nilai T dapat dicari dengan coba-coba atau dengan metode newton raphson
tebakan awal (Told)
eps
T

600
0.001

To
To+eps
To-eps

Pa'
Pb'
Pc'
600 5864.466 5297.551 3123.366
600.001 5864.527 5297.618 3123.409
599.999 5864.404 5297.485 3123.324

To
To+eps
To-eps

516.184 2117.574 1568.681 821.7145

516.185 2117.604 1568.707 821.7297
516.183 2117.545 1568.654 821.6993

To
To+eps
To-eps

455.3772 799.7699 490.1293 229.2986

455.378 799.7844 490.1399 229.3041
455.3762 799.7553 490.1187 229.2932

To
To+eps
To-eps

412.137 336.0013 173.9174 73.57117

412.138 336.0087 173.922 73.5733
412.136 335.9938 173.9127 73.56903

To
To+eps

385.6117 179.2686 82.10584 32.28959

385.613 179.2731 82.10832 32.29066

F(To)
F(To+eps)
F(To-eps)
F'(To)
Tnew
F(To)
F(To+eps)
F(To-eps)
F'(To)
Tnew
F(To)
F(To+eps)
F(To-eps)
F'(To)
Tnew
F(To)
F(To+eps)
F(To-eps)
F'(To)
Tnew
F(To)
F(To+eps)

63.10607
63.10683
63.10532
0.752912
516.184
19.5809
19.58122
19.58058
0.322018
455.3772
6.049162
6.049302
6.049022
0.139897
412.137
1.745356
1.745422
1.74529
0.0658
385.6117
0.39508
0.395118

To-eps

385.6107

179.264 82.10336 32.28851

To
To+eps
To-eps

375.1915
136.7 59.38961 22.63236
375.192 136.7036 59.39151 22.63315
375.1905 136.6963 59.38772 22.63157

To
To+eps
To-eps

373.7431 131.4875 56.69421 21.50789

373.744 131.4911 56.69604 21.50865
373.7421 131.484 56.69239 21.50713

F(To-eps)
F'(To)
Tnew
F(To)
F(To+eps)
F(To-eps)
F'(To)
Tnew
F(To)
F(To+eps)
F(To-eps)
F'(To)
Tnew

0.395042
0.037915
375.1915
0.043245
0.043274
0.043215
0.029858
373.7431
0.000732
0.000761
0.000703
0.028852
373.7178

n raphson

NAMA : PANDU FEBRIYANTO

NOMOR : 131011001
TUGAS THERMODINAMIKA TEKNIK KIMIA 2

Penentuan Titik Embun/Dew Point

Diketahui :
Campuran uap dengan komposisi : Ya = 0,44 ; Yb= 0,31 ; Yc= 0,24
Pa = exp (14,95-3764/T)
Pb = exp (16,07- 4497/T)
Pc = exp (16,27-4934/T)
Pt = 76 cmHg
titik embun uap multikomponen berlaku persamaan:
f(T) = (Pt/Pa).Ya + (Pt/Pb).Yb + (Pt/Pc).Yc - 1 = 0
Nilai T dapat diketahui dengan coba-coba atau dengan metode newton raphson
tebakan awal (Told)
eps
T

400
0.01

To
To+eps
To-eps

Pa'
Pb'
Pc'
400 254.678 124.8983 51.16215
400.010 254.7379 124.9334 51.17793
399.99 254.6181 124.8632 51.14637

To
To+eps
To-eps

383.309 169.0586 76.55047 29.90058

383.319 169.102 76.5739 29.91062
383.299 169.0153 76.52704 29.89054

To
To+eps
To-eps

386.6142 183.864 84.62669 33.3789

386.624 183.9103 84.65216 33.38992
386.6042 183.8177 84.60124 33.36788

Jadi mulai terjadi pengembunan pada suhu 386.8312C

F(To)
F(To+eps)
F(To-eps)
F'(To)
Tnew
F(To)
F(To+eps)
F(To-eps)
F'(To)
Tnew
F(To)
F(To+eps)
F(To-eps)
F'(To)
Tnew

-0.32355
-0.323744
-0.323356
-0.019385
383.309
0.115594
0.115244
0.115943
-0.034973
386.6142
0.006726
0.006416
0.007036
-0.030994
386.8312

wton raphson

NAMA : PANDU FEBRIYANTO

NOMOR : 131011001
TUGAS THERMODINAMIKA TEKNIK KIMIA 2

Penentuan Titik Embun/Dew Point

Diketahui :
Uap dengan komposisi : Ya = 0,44 ; Yb= 0,31 ; Yc= 0,24
Xa = Za/(L/F+Ka*(1-L/F))
Xb = Zb/(L/F+Kb*(1-L/F))

Pa'
Pb'
Ka
Kb

Pt = 1 atm
titik embun uap multikomponen berlaku persamaan:
f(L/F) = Xa+Xb-1=0
Nilai T dapat diketahui dengan coba-coba atau dengan metode newton raphson
tebakan awal (T L/F)
eps
L/F

0.2
0.01

To
To+eps
To-eps

Xa
Xb
0.2 0.623174 4.348623
0.210 0.593882 4.142752
0.19 0.655506 4.576025

To
To+eps
To-eps

0.36051 0.009188 0.912514

0.371 0.009323 0.911885
0.35051 0.009057 0.913143

To
To+eps
To-eps

-1.219447 0.002792 1.023999

-1.209 0.002805 1.023208
-1.229447 0.00278 1.024791

To
To+eps
To-eps

-0.875762 0.003291 0.997489

-0.866 0.003308 0.996739
-0.885762 0.003274 0.998241

F(To)
F(To+eps)
F(To-eps)
F'(To)
Tnew
F(To)
F(To+eps)
F(To-eps)
F'(To)
Tnew
F(To)
F(To+eps)
F(To-eps)
F'(To)
Tnew
F(To)
F(To+eps)
F(To-eps)
F'(To)
Tnew

3.971797
3.736634
4.23153
-24.74482
0.36051
-0.078298
-0.078791
-0.0778
-0.049557
-1.219447
0.026791
0.026012
0.027571
-0.077953
-0.875762
0.00078
4.63E-005
0.001515
-0.073428
-0.865139

2.081116
0.934022
0.002738
0.001229

wton raphson

NAMA : PANDU FEBRIYANTO

NOMOR : 131011001
TUGAS THERMODINAMIKA TEKNIK KIMIA 2
Penentuan Suhu Pendingin Agar 65% uap A dan B Mengembun
Diketahui :
Campuran uap dengan komposisi : Za = 0,44 ; Zb= 0,31 ; Zc= 0,24
Pa = exp (14,95-3764/T)
Pb = exp (16,07- 4497/T)
Pc = exp (16,27-4934/T)
Pt = 76 cmHg
Xa=Za/(L/F)+K*(1-(L/F))
Xb=Zb/(L/F)+K*(1-(L/F))
Xc=Zc/(L/F)+K*(1-(L/F))
neraca massa komponen berlaku persamaan:
Xa + Xb + Xc - 1 = 0
Nilai T dapat diketahui dengan coba-coba atau dengan metode newton raphson
tebakan awal (Told)
450
eps
0.01
T

Xa

To
To+eps
To-eps

450
450.01
449.99

Xb
Xc
0.11037 0.11672 0.152116
0.11035
0.1167 0.152094
0.11038 0.116739 0.152138

To
To+eps
To-eps

343.95417
343.96
343.94417

0.48720 0.417738 0.352127

0.48715 0.417718 0.35212
0.48724 0.417758 0.352134

To
To+eps
To-eps

380.70195
380.71
380.69195

0.31932 0.317844 0.309246

0.31928 0.317811 0.309229
0.31936 0.317877 0.309263

To
To+eps
To-eps

374.98925
375.00
374.97925

0.34479 0.336319 0.318517

0.34474 0.336288 0.318502
0.34483 0.336351 0.318533

F(To)
F(To+eps)
F(To-eps)
F'(To)
Tnew
F(To)
F(To+eps)
F(To-eps)
F'(To)
Tnew
F(To)
F(To+eps)
F(To-eps)
F'(To)
Tnew
F(To)
F(To+eps)
F(To-eps)
F'(To)
Tnew

-0.620799
-0.620858
-0.620741
-0.005854
343.9542
0.257063
0.256993
0.257133
-0.006995
380.7019
-0.053589
-0.053683
-0.053496
-0.009381
374.9893
-0.000374
-0.000467
-0.000282
-0.009234
374.9487

Berdasarkan hasil coba -coba diperoleh suhu pendingin sebesar 374.9487 C

74.9487 C

NAMA : Churriyatul Ainiya

NOMOR : 131011005
TUGAS THERMODINAMIKA TEKNIK KIMIA 2
Penentuan Suhu Pendingin Agar 65% uap A dan B Mengembun
Diketahui :
Campuran uap dengan komposisi : Za = 0,44 ; Zb= 0,31 ; Zc= 0,24
Pa = exp (14,95-3764/T)
Pb = exp (16,07- 4497/T)
Pc = exp (16,27-4934/T)
Pt = 76 cmHg
Xa=Za/(L/F)+K*(1-(L/F))
Xb=Zb/(L/F)+K*(1-(L/F))
Xc=Zc/(L/F)+K*(1-(L/F))
neraca massa komponen berlaku persamaan:
Xa + Xb + Xc - 1 = 0
Nilai T dapat diketahui dengan coba-coba atau dengan metode newton raphson
tebakan awal (Told)
415
eps
0.01
T

Xa

To
To+eps
To-eps

415
415.01
414.99

Xb
Xc
0.19147 0.2048161 0.2357598
0.19144 0.2047856 0.2357354
0.19150 0.2048466 0.2357842

To
To+eps
To-eps

371.67967
371.69
371.66967

0.35989 0.3466707 0.3234285

0.35984 0.3466398 0.3234142
0.35993 0.3467015 0.3234428

To
To+eps
To-eps

374.97211
374.98
374.96211

0.34487 0.3363738 0.3185435

0.34482 0.3363421 0.3185282
0.34491 0.3364055 0.3185589

F(To)
F(To+eps)
F(To-eps)
F'(To)
Tnew
F(To)
F(To+eps)
F(To-eps)
F'(To)
Tnew
F(To)
F(To+eps)
F(To-eps)
F'(To)
Tnew

Berdasarkan hasil coba -coba diperoleh suhu pendingin sebesar 374.9487 C

To
To+eps

374.9487
374.96

0.34497 0.336448 0.3185794

0.34493 0.3364163 0.3185641

F(To)
F(To+eps)

To-eps

374.9387

0.34502 0.3364797 0.3185948

F(To-eps)
F'(To)
Tnew

ode newton raphson

-0.367954
-0.368039
-0.367869
-0.008494
371.67967
0.0299858
0.0298948
0.0300769
-0.009107
374.97211
-0.000216
-0.000308
-0.000124
-0.009234
374.9487

-9.2E-009
-9.2E-005

9.23E-005
-0.009233
374.9487