Prop=f(V)

CURVA DE VALORACIN
25000.0000

Prop.

20000.0000

15000.0000

10000.0000

5000.0000

0.0000
0

10

15
V (mL)

Pgina 1

20

25

Prop(corr)=f(V)

CURVA DE VALORACIN
25000.0000

Prop. (corr)

20000.0000

15000.0000

10000.0000

5000.0000

0.0000
0

10

15
V (mL)

Pgina 2

20

25

CALCULO

ANLISIS III (QFB)

M. en Q. Julio Csar Botello Pozos

HOJA DE CALCULO PARA CURVA DE VALORACIN

aA
in )

bB

cC

CoVo

ag )

CV
b

AP E) CoVo ( a / b ) CV
a

P E)

DP E)

( c / b ) CV
( c / a ) CoVo

CV ( b / a ) CoVo

Cond experiment. :
Co
Vo
C

( c / a ) CoVo

coef. estequiomtricos :
0.1 M
10 mL (multiplos de 5mL)
0.1 M

a
b
c

1
1
1

V otros
10 mL
Keq 300000000

Etapa
APE
APE
APE
APE
APE
APE
APE
APE
APE
APE
APE
APE

Sistema
0
1
2
3
4
5
6
7
8
9
10
11

V (mL)
0
0.2
0.4
0.6
0.8
1
1.2
1.4
1.6
1.8
2
2.2

V total (mL)

20 0.000E+00
20.2 1.374E-09
20.4 2.833E-09
20.6 4.383E-09
20.8 6.029E-09
21 7.778E-09
21.2 9.636E-09
21.4 1.161E-08
21.6 1.371E-08
21.8 1.595E-08
22 1.833E-08
22.2 2.087E-08

Pgina 3

[A]eq

[B]eq

5.000E-02 0.000E+00
4.851E-02 6.803E-11
4.706E-02 1.389E-10
4.563E-02 2.128E-10
4.423E-02 2.899E-10
4.286E-02 3.704E-10
4.151E-02 4.545E-10
4.019E-02 5.426E-10
3.889E-02 6.349E-10
3.761E-02 7.317E-10
3.636E-02 8.333E-10
3.514E-02 9.402E-10

CALCULO

APE
APE
APE
APE
APE
APE
APE
APE
APE
APE
APE
APE
APE
APE
APE
APE
APE
APE
APE
APE
APE
APE
APE
APE
APE
APE
APE
APE
APE
APE
APE
APE
APE
APE
APE
APE
APE
APE
PE
DPE

12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51

2.4
2.6
2.8
3
3.2
3.4
3.6
3.8
4
4.2
4.4
4.6
4.8
5
5.2
5.4
5.6
5.8
6
6.2
6.4
6.6
6.8
7
7.2
7.4
7.6
7.8
8
8.2
8.4
8.6
8.8
9
9.2
9.4
9.6
9.8
10
10.2

22.4
22.6
22.8
23
23.2
23.4
23.6
23.8
24
24.2
24.4
24.6
24.8
25
25.2
25.4
25.6
25.8
26
26.2
26.4
26.6
26.8
27
27.2
27.4
27.6
27.8
28
28.2
28.4
28.6
28.8
29
29.2
29.4
29.6
29.8
30
30.2

2.358E-08
2.647E-08
2.956E-08
3.286E-08
3.639E-08
4.018E-08
4.425E-08
4.862E-08
5.333E-08
5.841E-08
6.390E-08
6.985E-08
7.631E-08
8.333E-08
9.100E-08
9.939E-08
1.086E-07
1.188E-07
1.300E-07
1.425E-07
1.564E-07
1.721E-07
1.898E-07
2.100E-07
2.331E-07
2.599E-07
2.913E-07
3.285E-07
3.733E-07
4.282E-07
4.970E-07
5.856E-07
7.040E-07
8.700E-07
1.119E-06
1.535E-06
2.368E-06
4.867E-06
3.162E-04
5.033E-06

Pgina 4

3.393E-02
3.274E-02
3.158E-02
3.043E-02
2.931E-02
2.821E-02
2.712E-02
2.605E-02
2.500E-02
2.397E-02
2.295E-02
2.195E-02
2.097E-02
2.000E-02
1.905E-02
1.811E-02
1.719E-02
1.628E-02
1.538E-02
1.450E-02
1.364E-02
1.278E-02
1.194E-02
1.111E-02
1.029E-02
9.489E-03
8.696E-03
7.914E-03
7.143E-03
6.383E-03
5.634E-03
4.895E-03
4.167E-03
3.448E-03
2.740E-03
2.041E-03
1.351E-03
6.711E-04
1.054E-05
1.667E-07

1.053E-09
1.171E-09
1.296E-09
1.429E-09
1.569E-09
1.717E-09
1.875E-09
2.043E-09
2.222E-09
2.414E-09
2.619E-09
2.840E-09
3.077E-09
3.333E-09
3.611E-09
3.913E-09
4.242E-09
4.603E-09
5.000E-09
5.439E-09
5.926E-09
6.471E-09
7.083E-09
7.778E-09
8.571E-09
9.487E-09
1.056E-08
1.182E-08
1.333E-08
1.519E-08
1.750E-08
2.048E-08
2.444E-08
3.000E-08
3.833E-08
5.222E-08
8.000E-08
1.633E-07
1.054E-05
6.623E-04

CALCULO

DPE
DPE
DPE
DPE
DPE
DPE
DPE
DPE
DPE
DPE
DPE
DPE
DPE
DPE
DPE
DPE
DPE
DPE
DPE
DPE
DPE
DPE
DPE
DPE
DPE
DPE
DPE
DPE
DPE
DPE
DPE
DPE
DPE
DPE
DPE
DPE
DPE
DPE
DPE
DPE

52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85
86
87
88
89
90
91

10.4
10.6
10.8
11
11.2
11.4
11.6
11.8
12
12.2
12.4
12.6
12.8
13
13.2
13.4
13.6
13.8
14
14.2
14.4
14.6
14.8
15
15.2
15.4
15.6
15.8
16
16.2
16.4
16.6
16.8
17
17.2
17.4
17.6
17.8
18
18.2

30.4
30.6
30.8
31
31.2
31.4
31.6
31.8
32
32.2
32.4
32.6
32.8
33
33.2
33.4
33.6
33.8
34
34.2
34.4
34.6
34.8
35
35.2
35.4
35.6
35.8
36
36.2
36.4
36.6
36.8
37
37.2
37.4
37.6
37.8
38
38.2

2.533E-06
1.700E-06
1.283E-06
1.033E-06
8.667E-07
7.476E-07
6.583E-07
5.889E-07
5.333E-07
4.879E-07
4.500E-07
4.179E-07
3.905E-07
3.667E-07
3.458E-07
3.275E-07
3.111E-07
2.965E-07
2.833E-07
2.714E-07
2.606E-07
2.507E-07
2.417E-07
2.333E-07
2.256E-07
2.185E-07
2.119E-07
2.057E-07
2.000E-07
1.946E-07
1.896E-07
1.848E-07
1.804E-07
1.762E-07
1.722E-07
1.685E-07
1.649E-07
1.615E-07
1.583E-07
1.553E-07

Pgina 5

8.333E-08
5.556E-08
4.167E-08
3.333E-08
2.778E-08
2.381E-08
2.083E-08
1.852E-08
1.667E-08
1.515E-08
1.389E-08
1.282E-08
1.190E-08
1.111E-08
1.042E-08
9.804E-09
9.259E-09
8.772E-09
8.333E-09
7.937E-09
7.576E-09
7.246E-09
6.944E-09
6.667E-09
6.410E-09
6.173E-09
5.952E-09
5.747E-09
5.556E-09
5.376E-09
5.208E-09
5.051E-09
4.902E-09
4.762E-09
4.630E-09
4.505E-09
4.386E-09
4.274E-09
4.167E-09
4.065E-09

1.316E-03
1.961E-03
2.597E-03
3.226E-03
3.846E-03
4.459E-03
5.063E-03
5.660E-03
6.250E-03
6.832E-03
7.407E-03
7.975E-03
8.537E-03
9.091E-03
9.639E-03
1.018E-02
1.071E-02
1.124E-02
1.176E-02
1.228E-02
1.279E-02
1.329E-02
1.379E-02
1.429E-02
1.477E-02
1.525E-02
1.573E-02
1.620E-02
1.667E-02
1.713E-02
1.758E-02
1.803E-02
1.848E-02
1.892E-02
1.935E-02
1.979E-02
2.021E-02
2.063E-02
2.105E-02
2.147E-02

CALCULO

DPE
DPE
DPE
DPE
DPE
DPE
DPE
DPE
DPE

92
93
94
95
96
97
98
99
100

18.4
18.6
18.8
19
19.2
19.4
19.6
19.8
20

38.4
38.6
38.8
39
39.2
39.4
39.6
39.8
40

1.524E-07
1.496E-07
1.470E-07
1.444E-07
1.420E-07
1.397E-07
1.375E-07
1.354E-07
1.333E-07

Pgina 6

3.968E-09
3.876E-09
3.788E-09
3.704E-09
3.623E-09
3.546E-09
3.472E-09
3.401E-09
3.333E-09

2.188E-02
2.228E-02
2.268E-02
2.308E-02
2.347E-02
2.386E-02
2.424E-02
2.462E-02
2.500E-02

CALCULO

cttes fisicoqumicas :
KA
KB
KC

400000
0
10000

(cambiar solo los

datos en negritas)

[C]eq

Prop

Prop'

0.000E+00
9.901E-04
1.961E-03
2.913E-03
3.846E-03
4.762E-03
5.660E-03
6.542E-03
7.407E-03
8.257E-03
9.091E-03
9.910E-03

20000.0000
19415.8416
18843.1373
18281.5534
17730.7692
17190.4762
16660.3774
16140.1869
15629.6296
15128.4404
14636.3636
14153.1532

20000.0000
19610.0000
19220.0000
18830.0000
18440.0000
18050.0000
17660.0000
17270.0000
16880.0000
16490.0000
16100.0000
15710.0000

Pgina 7

CALCULO

1.071E-02
1.150E-02
1.228E-02
1.304E-02
1.379E-02
1.453E-02
1.525E-02
1.597E-02
1.667E-02
1.736E-02
1.803E-02
1.870E-02
1.935E-02
2.000E-02
2.063E-02
2.126E-02
2.188E-02
2.248E-02
2.308E-02
2.366E-02
2.424E-02
2.481E-02
2.537E-02
2.593E-02
2.647E-02
2.701E-02
2.754E-02
2.806E-02
2.857E-02
2.908E-02
2.958E-02
3.007E-02
3.056E-02
3.103E-02
3.151E-02
3.197E-02
3.243E-02
3.289E-02
3.333E-02
3.311E-02

13678.5714
13212.3894
12754.3860
12304.3478
11862.0690
11427.3504
11000.0000
10579.8319
10166.6667
9760.3306
9360.6557
8967.4797
8580.6452
8200.0000
7825.3968
7456.6929
7093.7500
6736.4341
6384.6154
6038.1679
5696.9697
5360.9023
5029.8507
4703.7037
4382.3529
4065.6934
3753.6232
3446.0432
3142.8571
2843.9716
2549.2958
2258.7413
1972.2222
1689.6552
1410.9589
1136.0544
864.8649
597.3154
337.5497
331.1925

15320.0000
14930.0000
14540.0000
14150.0000
13760.0000
13370.0000
12980.0000
12590.0000
12200.0000
11810.0000
11420.0000
11030.0000
10640.0000
10250.0000
9860.0000
9470.0000
9080.0000
8690.0000
8300.0000
7910.0000
7520.0000
7130.0000
6740.0000
6350.0000
5960.0000
5570.0000
5180.0000
4790.0000
4400.0000
4010.0000
3620.0000
3230.0000
2840.0000
2450.0000
2060.0000
1670.0000
1280.0000
890.0000
506.3246
500.1007

Pgina 8

CALCULO

3.289E-02
3.268E-02
3.247E-02
3.226E-02
3.205E-02
3.185E-02
3.165E-02
3.145E-02
3.125E-02
3.106E-02
3.086E-02
3.067E-02
3.049E-02
3.030E-02
3.012E-02
2.994E-02
2.976E-02
2.959E-02
2.941E-02
2.924E-02
2.907E-02
2.890E-02
2.874E-02
2.857E-02
2.841E-02
2.825E-02
2.809E-02
2.793E-02
2.778E-02
2.762E-02
2.747E-02
2.732E-02
2.717E-02
2.703E-02
2.688E-02
2.674E-02
2.660E-02
2.646E-02
2.632E-02
2.618E-02

328.9807
326.8196
324.6920
322.5940
320.5239
318.4809
316.4640
314.4728
312.5067
310.5651
308.6475
306.7536
304.8828
303.0347
301.2090
299.4051
297.6228
295.8615
294.1210
292.4008
290.7007
289.0202
287.3591
285.7170
284.0935
282.4883
280.9013
279.3319
277.7800
276.2452
274.7274
273.2261
271.7411
270.2722
268.8191
267.3815
265.9592
264.5520
263.1596
261.7817

500.0507
500.0340
500.0257
500.0207
500.0173
500.0150
500.0132
500.0118
500.0107
500.0098
500.0090
500.0084
500.0078
500.0073
500.0069
500.0065
500.0062
500.0059
500.0057
500.0054
500.0052
500.0050
500.0048
500.0047
500.0045
500.0044
500.0042
500.0041
500.0040
500.0039
500.0038
500.0037
500.0036
500.0035
500.0034
500.0034
500.0033
500.0032
500.0032
500.0031

Pgina 9

CALCULO

2.604E-02
2.591E-02
2.577E-02
2.564E-02
2.551E-02
2.538E-02
2.525E-02
2.513E-02
2.500E-02

260.4183
259.0689
257.7335
256.4117
255.1035
253.8085
252.5266
251.2576
250.0013

500.0030
500.0030
500.0029
500.0029
500.0028
500.0028
500.0028
500.0027
500.0027

Pgina 10