B GIO DC V O TO

TRNG I HC BCH KHOA H NI

CHNG TRNH O TO
TIN S
CHUYN NGNH

HA L THUYT V HA L
M S: 62440119

c Hi ng Xy dng Chng trnh o to bc Tin s thng qua

ngy 15 thng 12 nm 2014

H NI - 2014
1

MC LC

Trang
PHN I
1
1.1
1.2
2
3
4
4.1
4.2
5
6
7
7.1
7.2
7.3
7.3.1
7.3.2
7.3.3
7.4
8

TNG QUAN V CHNG TRNH O TO

Mc tiu o to
Mc tiu chung
Mc tiu c th
Thi gian o to
Khi lng kin thc
i tng tuyn sinh
nh ngha
Phn loi i tng
Quy trnh o to, iu kin cng nhn t
Thang im
Ni dung chng trnh
Cu trc
Hc phn b sung
Hc phn Tin s
Danh mc hc phn Tin s
M t tm tt hc phn Tin s
K hoch hc tp cc hc phn Tin s
Chuyn Tin s
Danh sch Tp ch / Hi ngh Khoa hc

PHN II
9
9.1
9.2
10

CNG CHI TIT CC HC PHN

Danh mc hc phn chi tit ca chng trnh o to
Danh mc hc phn b sung
Danh mc hc phn Tin s
cng chi tit cc hc phn Tin s

PHN I

TNG QUAN V CHNG TRNH O TO

TRNG I HC BCH KHOA H NI

VIN K THUT HA HC

CNG HA X HI CH NGHA VIT NAM

c lp - T do - Hnh phc

CHNG TRNH O TO TIN S

CHUYN NGNH HA L THUYT V HA L

Tn chng trnh:
Trnh o to:
Chuyn ngnh o to:
M chuyn ngnh:

Chng trnh o to Tin s chuyn ngnh Ha l thuyt v Ha l

Tin s
Ha l thuyt v Ha l Theoretical and Physical Chemistry
62440119

(Ban hnh theo Quyt nh s 3446/Q-HBK-SH ngy 4 thng 9 nm 2014 ca Hiu trng
trng H Bch Khoa H Ni)
1
Mc tiu o to
1.1 Mc tiu chung
o to Tin s chuyn ngnh Ha l thuyt v Ha l c trnh chuyn mn su cao, c kh
nng nghin cu c lp v lnh o nhm nghin cu cc lnh vc ca chuyn ngnh, c t duy
khoa hc, c kh nng tip cn v gii quyt cc vn khoa hc chuyn ngnh, c kh nng trnh
by - gii thiu cc ni dung khoa hc, ng thi c kh nng o to cc bc i hc v Cao hc.
1.2 Mc tiu c th
Sau khi kt thc thnh cng chng trnh o to, Tin s chuyn ngnh Ha l thuyt v Ha
l
C kh nng tip cn v trc tip gii quyt cc vn chuyn mn thuc lnh vc Ha l thuyt
v Ha l.
C kh nng dn dt, lnh o nhm nghin cu thuc lnh vc Ha l thuyt v Ha l.
C kh nng nghin cu, xut v p dng cc gii php cng ngh thuc lnh vc Ha l thuyt
v Ha l trong thc tin.
C kh nng cao trnh by, gii thiu (bng cc hnh thc bi vit, bo co hi ngh, ging dy
i hc v sau i hc) cc vn khoa hc thuc lnh vc Ha l thuyt v Ha l.
2
Thi gian o to
H tp trung lin tc: 3 nm lin tc i vi NCS c bng ThS, 4 nm i vi NCS c bng
H.
H khng tp trung lin tc: NCS c vn bng ThS ng k thc hin trong vng 4 nm m
bo tng thi gian hc tp, nghin cu ti Trng l 3 nm v 12 thng u tin tp trung lin
tc ti Trng.
3

Khi lng kin thc

Khi lng kin thc bao gm khi lng ca cc hc phn Tin s v khi lng ca cc hc phn
b sung c xc nh c th cho tng loi i tng ti mc 4.
NCS c bng ThS: ti thiu 8 tn ch + khi lng b sung (nu c).
4

NCS mi c bng H: ti thiu 8 tn ch + 28 tn ch (khng k lun vn) ca Chng trnh Thc s

Khoa hc chuyn ngnh Ha l thuyt v Ha l. i vi NCS c bng H ca cc h 4 hoc 4,5
nm (theo quy nh) s phi thm cc hc phn b sung ca Chng trnh Thc s Khoa hc chuyn
ngnh Ha l thuyt v Ha l.
4
i tng tuyn sinh
i tng tuyn sinh l cc th sinh c bng Thc s vi chuyn ngnh tt nghip ph hp
(ng ngnh) hoc gn ph hp vi chuyn ngnh Ha l thuyt v Ha l. Ch tuyn sinh mi c
bng H vi chuyn ngnh tt nghip ph hp. Mc ph hp hoc gn ph hp vi chuyn
ngnh Ha l thuyt v Ha l, c nh ngha c th mc 4.1 sau y.
4.1 nh ngha
Ngnh ph hp: L nhng hng o to chuyn su thuc ngnh Ha l thuyt v Ha l.
Ngnh gn ph hp: L nhng hng o to chuyn su thuc cc ngnh sau Mi trng,
Sinh hc Thc phm, Hu c Ha du, Ha Hu c, Ha Phn tch v ngnh Ha ca
cc trng i hc K thut khc.
4.2 Phn loi i tng
C bng ThS Khoa hc ca H Bch Khoa H Ni vi ngnh tt nghip cao hc ng vi
chuyn ngnh Tin s. y l i tng khng phi tham gia hc b sung, gi tt l i tng
A1.
C bng tt nghip i hc loi xut sc vi ngnh tt nghip ng vi chuyn ngnh Tin s.
y l i tng phi tham gia hc b sung, gi tt l i tng A2.
C bng ThS ng ngnh, nhng khng phi l ThS Khoa hc ca H Bch Khoa H Ni
hoc c bng ThS tt nghip ngnh gn ph hp. y l i tng phi tham gia hc b
sung, gi tt l i tng A3.
5
Quy trnh o to, iu kin cng nhn t
Quy trnh o to c thc hin theo hc ch tn ch, tun th Quy nh 1035/2011 v t chc v
qun l o to sau i hc ca H Bch Khoa H Ni.
Cc hc phn b sung phi t mc im C tr ln (xem mc 6).
Cc hc phn Tin s phi t mc im B tr ln (xem mc 6).
6
Thang im
Khon 6a iu 62 ca Quy nh 1035/2011 quy nh:
Vic chm im kim tra - nh gi hc phn (bao gm cc im kim tra v im thi kt thc hc
phn) c thc hin theo thang im t 0 n 10, lm trn n mt ch s thp phn sau du phy.
im hc phn l im trung bnh c trng s ca cc im kim tra v im thi kt thc (tng ca tt
c cc im kim tra, im thi kt thc nhn vi trng s tng ng ca tng im c quy nh
trong cng chi tit hc phn).
im hc phn c lm trn n mt ch s thp phn sau du phy, sau c chuyn thnh
im ch vi mc nh sau:
im s t
8,5 10
chuyn thnh im A (Gii)
im s t
7,0 8,4 chuyn thnh im B (Kh)
im s t
5,5 6,9 chuyn thnh im C (Trung bnh)
im s t
4,0 5,4 chuyn thnh im D (Trung bnh yu)
5

im s di

chuyn thnh im F (Km)

4,0

7
Ni dung chng trnh
7.1 Cu trc
Cu trc chng trnh o to trnh Tin s gm c 3 phn nh bng sau y.
Phn
Ni dung o to
A1
A2
A3
CT ThS KH
HP b sung
0
4TC
(28TC)
1
HP TS
8TC
TLTQ
Thc hin v bo co trong nm hc u tin
2
CTS
Tng cng 3 CTS, mi CTS 2TC
NC khoa hc
3
Lun n TS
-

Lu :
S TC qui nh cho cc i tng trong l s TC ti thiu NCS phi hon thnh.
i tng A2 phi thc hin ton b cc hc phn qui nh trong chng trnh ThS Khoa hc
ca ngnh tng ng, khng cn thc hin lun vn ThS.
Cc HP b sung c la chn t chng trnh o to Thc s ca ngnh ng chuyn ngnh
Tin s.
Vic qui nh s TC ca HP b sung cho i tng A3 do ngi hng dn (NHD) quyt nh
da trn c s i chiu cc hc phn trong bng kt qu hc tp ThS ca th sinh vi chng
trnh ThS hin ti ca ngnh ng chuyn ngnh Tin s nhng phi m bo s TC ti thiu
trong bng.
Cc HP TS c NHD xut t chng trnh o to Thc s v Tin s ca trng nhm trang
b kin cn thit phc v cho ti nghin cu c th ca LATS.

7.2 Hc phn b sung

Cc hc phn b sung c m t trong quyn Chng trnh o to Thc s chuyn ngnh
K thut ha hc hin hnh ca trng H Bch Khoa H Ni.
NCS phi hon thnh cc hc phn b sung trong thi hn 2 nm k t ngy c quyt nh cng
nhn l NCS.
7.3 Hc phn Tin s
7.3.1 Danh mc hc phn Tin s
TT

M S

CH7100

TN HC PHN

GING VIN

ng hc v c ch cc phn ng
xc tc phc
Cu trc lin kt ha hc v nhng
CH7101 c trng ha l ca cc cht xc
tc phc

Mt s ng dng thc tin ca

xc tc phc

CH7102

4
5

CH7103 Quang ha hc
CH7104 Cc phng php cng hng t

7.3.2 M t tm tt hc phn Tin s

6

TN
CH

KHI
LNG

GS. TSKH Nguyn

Vn Xuyn

3(3-0-0-6)

GS. TSKH Nguyn

Vn Xuyn

2(2-0-0-4)

2(2-0-0-4)

2
2

2(2-0-0-4)
2(2-0-0-4)

GS. TSKH Nguyn

Vn Xuyn
TS Trn Vn Anh
TS Trn Vn Anh

CH7100 ng hc v c ch cc phn ng xc tc phc

Cung cp cho NCS chuyn ngnh ha l thuyt v ha l v cc lnh vc c lin quan nhng
kin thc v: Quy lut ng hc, c ch v cc iu kin ti u ca phn ng xc tc phc ph
thuc rt nhy cm, a chiu, nhiu bin vo cc yu t nh hng khc nhau: Cu trc phn t, cc
c trng vt l v ha l, tng quan nng ca cht xc tc, cc cht phn ng, pH mi trng.
Cc c trng ng hc: tc v hng s tc phn ng, cc hng s tc phn ng giai on,
nng lng hot ha, bc chung, bc ring ca phn ng, phng trnh ng hc tng qut. Cc c
trng c ch: S to thnh v phn hy phc trung gian hot ng c to thnh gia xc tc phc
v cc cht phn ng, chu trnh oxi ha kh thun nghch, s pht sinh v hy dit gc t do, cc
trng thi ha tr ca kim loi, cc loi c ch mch gc, phn t, hn hp, ni cu, ngoi cu, s
c ch, mi quan h gia nhit ng hc, ng hc v c ch ca phn ng xc tc phc...
CH7100 Kinetics and mechanism of catalytic reactions by complexes
PhD students of theoretical chemistry and physical chemistry and related fields will be provided
with fundamental knowledge about thermodynamics, kinetics, mechanism, their relations and
optimal conditions of the complex catalyst reactions depending upon different influential factors
such as molecular structure, physical and physiochemical properties, concentration correlation of
catalyst, reactants and pH of medium.
To study problems mentioned above, it is necessary to use physical and physicochemical
methods of thermodynamics, kinetics, electrochemistry, inhibitors and concurrents, electron
absorption spectroscopy of molecules (UV-VIS), atomic absorption spectroscopy (AAS), infrared
spectroscopy (IRS), Raman spectroscopy (RS), Gas chromatography (GC), Mass-spectroscopy
(MS), Electron paramagnetic resonance (EPR), Nuclear magnetic resonance (NMR), Magnetic
chemistry, etc.
CH7101

Cu trc lin kt ha hc v nhng c trng ha l ca cc cht xc tc phc

Trn c s l thuyt hin i ca ha hc lng t, ha l, ha hc phi tr,... cung cp cho

nghin cu sinh chuyn ngnh ha l thuyt v ha l v cc lnh vc c lin quan nhng kin thc
c bn v: Cu trc electron, cu trc hnh hc, cc tnh cht nhit ng hc, ng hc, in ha,
quang hc, t hc, c ch hot ng, hot tnh, chn lc xc tc... c trng cho mi dng phc
cht ca kim loi chuyn tip vi ligan c bn cht khc nhau ng vai tr xc tc (xc tc phc):
phc n nhn, a nhn, phc hn hp kim loi, phc hn hp ligan. Cc cht xc tc phc ny
c xem l m hnh ha ca cc cht xc tc sinh hc, do , c tnh u vit hot tnh v chn
lc rt cao nhit v p sut thng v s dng lm xc tc hu hiu cho nhiu phn ng ha
hc khc nhau: oxy ha, hydro ha, hydroxyl ha, carbonyl ha, carboxyl ha, polime ha, oligome
ha...
CH7101 Structure, chemical bond and characteristics of complex catalysts
On the basis of modern theories of quantum chemistry, physical chemistry, coordinate chemistry,
etc, PhD students of theoretical chemistry and physical chemistry and related fields will be provided
with fundamental knowledge on electron structure, geometrical structure and properties of
thermodynamics, kinetics, electrochemistry, optics, magnetics, acting mechanism, activity and
selectivity typical for every type of mono-, polynuclear-, mixed metal-, mixed ligand complex
catalysts formed by transition metal ions and various ligands. Considered as models of biocatalysts,
the complex catalysts have superiorities such as very high activity and selectivity at normal
temperature and pressure for many different chemical reactions including oxidation, reduction,
hydrogenation, carbonization, carboxylation, polymerization, oligomerization, etc.
CH7102 Mt s ng dng thc tin ca xc tc phc
Cung cp cho sinh vin chuyn ngnh Ha l thuyt v ha l v cc lnh vc c lin quan
nhng kin thc v: C s khoa hoc, k thut thc nghim, hiu lc ca mi phng php: ph hp
7

th electron phn t (UV vis) ph hng ngoi (IRS), ph Raman, ph hunh quang, ph hp th
nguyn t (AAS), cc ph , ph khi lng (MS), sc k, cng hng t electron (EPR), cng
hng t ht nhn (NMR), ng hc, cc cht c ch, cc cht cnh tranh c ng dng
nghin cu xc nh cu trc phn t, thnh phn, bn nhit ng, hot tnh, chn lc, c ch
hot ng, cc tnh cht vt l v ha l c trng khc cng nh iu kin to thnh ti u ca mi
dng phc cht ng vai tr xc tc. Trn c s tng hp ra cht xc tc phc hu hiu, thch
hp cho mi loi phn ng ha hc.
CH7102 Some practical applications of complex catalysis
The research outcomes on synthesizing complex catalysts, thermodynamics, kinetics,
mechanism of catalysis, their relations and optimal conditions of catalytic reactions are applied to
solve various actual practical problems such as:
Establishing scientific and experimental bases for improving and innovating technological
processes.
Applying in industrial processes: isomerization, hydroxylation, hydroformylation, oxidation,
hydrogenation, polymerization, oligomerization, synthesis of organic compounds.
Using in waste water treatment and environment protection.
Microanalysis of super-clean materials by means of catalytic kinetic method.
Color bleaching in paper and textile industries.
Keeping and preserving the quality of industrial products, food, pharmaceutical and
agricultural products.
Producing multi-, medium- and micro fertilizers for higher productivity of plants.
CH7103 Quang ha hc
Hc phn cung cp cho sinh vin kin thc c bn v phn ng quang ha, cc giai on ca
phn ng quang ha nh kt qu mt qu trnh kch thch phn t. Ngoi ra, hc phn b sung cc
kin thc v nhng cht mang c tnh quang ha trn v d zn, ng dng ca quang ha trong
cc phng php phn tch Ha l hin i trn v d Laser, Ph quang electron, Ph Raman, ...
CH7103 Photochemistry
The subject provides PhD students with basic knowledge on photochemical processes as a result
of molecular excitation. Moreover, knowledge on photochemical sensitive substances (sensitive to
ozone, for example) and application of photochemistry in modern physico-analytical methods,
such as Laser, Photoelectron spectroscopy, Photoemission spectroscopy, Photolysis are also
provided.
CH7104 Cc phng php cng hng t
Hc phn cung cp cho sinh vin kin thc l thuyt c bn v hin tng cng hng t,
nguyn l cc phng php cng hng t cng nh ng dng ca chng trong nghin cu hin
i.
CH7104 Magnetic resonance spectroscopy
The subject provides PhD students with the basic theoretical background on the magnetic
resonance phenomena, basic principles of the magnetic resonance spectroscopy as well as their
applications in modern research.
7.3.3 K hoch hc tp cc hc phn Tin s
Cc hc phn Tin s c thc hin linh hot, ty theo cc iu kin thi gian c th ca ging
vin. Tuy nhin, nghin cu sinh phi hon thnh cc hc phn Tin s trong vng 24 thng k t
ngy chnh thc nhp trng.
7.4

Chuyn Tin s

Mi nghin cu sinh phi hon thnh 3 chuyn Tin s, c th ty chn t danh sch hng
chuyn su. Mi hng chuyn su u c ngi hng dn do Hi ng Xy dng chng trnh
o to chuyn ngnh ca Vin K thut ha hc quyt nh.
Ngi hng dn khoa hc lun n ca nghin cu sinh s xut ti c th. u tin xut
ti gn lin, thit thc vi ti ca lun n Tin s.
Sau khi c ti c th, NCS thc hin ti di s hng dn khoa hc ca ngi hng
dn chuyn .
Danh mc hng chuyn su cho Chuyn Tin s
HNG CHUYN SU

TT

M S

CH7150

Xc tc phc

CH7151

Xc tc phc trong bo v mi trng

CH7152

4
5

CH7153
CH7154

Phng php ng hc xc tc trong

phn tch vi lng
Cng hng t electron
n mn v bo v kim loi

CH7155

Mt s phng php x l nc thi

NGI HNG DN
GS. TSKH Nguyn Vn
Xuyn
GS. TSKH Nguyn Vn
Xuyn
GS. TSKH Nguyn Vn
Xuyn
TS Trn Vn Anh
TS Trn Vn Anh
TS Trn Th Thanh
Thy

TN
CH
2
2
2
2
2
2

8
Danh sch Tp ch / Hi ngh khoa hc
Cc din n khoa hc trong nc trong bng di y l ni NCS c th chn cng b cc kt
qu nghin cu khoa hc phc v hon thnh lun n Tin s.

a ch lin h

nh k
xut bn /
hp

1 Tp ch Ha hc

70 Trn Hng o

6 s/1 nm

2 Tp ch Khoa hc cng ngh

S 1 i c vit, H Ni

6 s /1 nm

3 Ha hc ng dng

139 L c

4 s /1 nm

S
TT

Tn din n

Cc tp ch, hi ngh khoa hc

quc t chuyn ngnh

PHN II

CNG CHI TIT CC HC PHN

10

9
Danh mc hc phn chi tit ca chng trnh o to
9.1 Danh mc hc phn b sung
Danh mc hc phn b sung c th xem chi tit trong quyn Chng trnh o to Thc s K
thut ha hc.
9.2
S
TT
1

Danh mc hc phn Tin s

M S

CH 7100

TN HC PHN

TN TING ANH

Kinetics
and
ng hc v c
mechanism
of
ch cc phn ng
catalytic reactions by
xc tc phc
complexes
Cu trc lin kt Structure, chemical
ha hc v nhng bond and physicoc trng ha l chemical
ca cc cht xc characteristics
of
tc phc
complex catalysts
Mt s ng dng Some
practical
thc tin ca xc applications
of
tc phc
complex catalysis
Quang ha hc
Photochemistry
Cc phng php
Magnetic resonance
cng hng t

CH 7101

CH 7102

CH 7103

CH 7104

10

cng chi tit cc hc phn Tin s

CH7100

KHI
LNG

Khoa/Vin
B mn

3(3-0-0-6)

CNHH

2(2-0-0-4)

CNHH

2(2-0-0-4)

CNHH

2(2-0-0-4)

CNHH

2(2-0-0-4)

CNHH

nh
gi

ng hc v c ch cc phn ng xc tc phc
Kinetics and mechanism of catalytic reactions by complexes
1. Tn hc phn: ng hc v c ch cc phn ng xc tc phc
2. M hc phn: CH7100
3. Tn ting Anh: Kinetics and mechanism of catalytic reactions by complexes
4. Khi lng:
3(3-0-0-6)
- L thuyt:
45 tit
- Bi tp:
- Th nghim:
5. i tng tham d:
Tt c NCS thuc chuyn ngnh Ha l thuyt v Ha l
6. Mc tiu ca hc phn:
Hc phn ny nhm mang li cho NCS:
- Cc kin thc nng cao, hin i ca chuyn ngnh Ha l thuyt v ha l v phn ng cc
xc tc phc
- Rn luyn kh nng t duy khoa hc.
- Rn luyn k nng thc nghim cho vic nghin cu cc phn ng xc tc phc, to c s khoa
hc v thc nghim cho vic gii quyt nhiu vn thc tin khc nhau c lin quan
7. Ni dung tm tt:
- Phn ng xc tc phc l m hnh ca cc phn ng sinh hc
- Cc phng php vt l v ha l nghin cu phn ng xc tc phc
- Nhit ng hc, ng hc v c ch ca cc phn ng xc tc
8. Nhim v ca NCS:
- D lp:
- Bi tp:
9. nh gi kt qu:
- Mc d gi ging:
11

- Kim tra nh k:
- Thi kt thc hc phn:
10. Ni dung chi tit hc phn:
PHN M U
Gii thiu mn hc
Gii thiu cng mn hc
Gii thiu ti liu tham kho
CHNG 1: ng dng cc phng php vt l v ha l nghin cu phn ng xc tc
phc
1.1 Phng php nhit ng hc
1.2 Phng php ng hc
1.3 Phng php cc cht c ch v cc cht cnh tranh
1.4 Phng php in ha hc
1.5 Phng php ph dao ng (IRS, Raman)
1.6 Phng php ph hp th electron phn t (UV-Vis)
1.7 Phng php ph pht quang phn t
1.8 Phng php ph hp th nguyn t (AAS)
1.9 Phng php sc k v ph khi lng (GC/MS)
1.10 Phng php cng hng t electron (EPR) v cng hng t ht nhn (NMR)
1.11 Phng php ha t
1.12 ng dng tin hc
CHNG 2: ng hc cc phn ng xc tc phc
2.1 Phc cht ng vai tr xc tc cho phn ng
2.1.1 Cu trc thnh phn hng s bn v cc c trng ca cc cht xc tc phc
2.1.2 Hot tnh v chn lc ca cht xc tc phc
2.1.3 b tr trong phn ng xc tc phc
2.2 Phc trung gian hot ng
2.2.1 S to thnh t cht xc tc phc v cc cht phn ng
2.2.2 Cu trc, thnh phn, hng s bn v cc c trng ha l
2.3 Phn ng to thnh phc trung gian hot ng
2.3.1 S ph thuc tc phn ng v cc yu t nh hng khc nhau
2.3.2 Bc ring ca phn ng
2.3.3 Phng trnh ng hc ca phn ng
2.4 Phn ng xc tc phc
2.4.1 S ph thuc tc phn ng v cc yu t nh hng khc nhau
2.4.2 Bc ring, hng s tc v nng lng hot ha ca phn ng
2.4.3 Phng trnh ng hc v cc iu kin ti u ca phn ng
2.4.4 Mi quan h gia cc thng s nhit ng hc v ng hc ca phn ng
2.4.5 Mi quan h gia thng s cu trc v thng s nng lng ca phn ng
CHNG 3: C ch ca phn ng xc tc phc
3.1 C ch vn chuyn electron gia cc cu t hp thnh phc trung gian hot ng
3.1.1 C ch vn chuyn electron ni cu
3.1.2 C ch vn chuyn electron ngoi cu
3.2 S phn hy phc trung gian hot ng
3.2.1 S pht sinh v hy dit cc gc t do
3.2.2 S thay i cc trng thi ha tr ca ion kim loi
3.2.3 Chu trnh oxy ha kh thun nghch- ngun pht sinh gc t do v hon nguyn cht xc
tc phc
3.3 C ch cc phn ng xc tc phc
12

3.3.1 nh hng ca cc cht c ch tng tc c th vi cc gc t do v ca cc cht cnh

tranh n tc phn ng xc tc phc
3.3.2 Tc phn ng sinh mch v cc yu t nh hng
3.3.3 Phng trnh ng hc phn ng sinh mch
3.3.4 C ch ca phn ng xc tc phc
- C ch mch gc
- C ch phn t- ion
- C ch hn hp
11. Ti liu hc tp:
Nguyn Vn Xuyn (2007), Cu to phn t v lin kt ha hc, Nh xut bn Khoa hc v K
thut, H Ni.
12. Ti liu tham kho:
[1] o nh Thc (2007), Mt s phng php ph ng dng trong ha hc, Nh xut bn i
hc Quc Gia H Ni.
[2] T Vn Mc (2003), Phn tch ha l: Phng php ph nghim nghin cu cu trc phn t,
Nh xut bn Khoa hc v k thut, H Ni
[3] Nguyn Vn Xuyn (1994), Xc tc ng th oxy ha kh bng phc cht mt nhn v hai
nhn mt s ion kim loi chuyn tip, Lun n tin s khoa hc Ha hc, Trng i hc Bch
Khoa H Ni, H Ni.
[3] Trn Th Minh Nguyt (2002), Nghin cu tnh cht catalaza v peroxidaza ca phc cht
mt s kim loi chuyn tip vi etylendiamin, Lun n tin s ha hc, Trng i hc Bch
Khoa H Ni, H Ni.
[4] V Th Kim Loan (2008), Xc tc ng th oxy ha- kh bng phc cht ca ion kim loi
chuyn tip, Lun n Tin s ha hc, Trng i hc Bch Khoa H Ni, H Ni.
[5] Nguyn Vn Dng (2010), Nghin cu tnh cht catalaza v peroxidaza ca phc Co(II)Axit citric, Lun n Tin s ha hc, Trng i hc Bch Khoa H Ni, H Ni.
[6] Nguyn Vn Xuyn, Trn Th Minh Nguyt (2001), Xc tc phc, Cc bo co khoa hc Hi
ngh xc tc hp ph Ton quc ln th 2, H Ni, tr 127-160.
[7] G. Henrici-Olive, S. Olive (1997), Coordination and Catalysis, Verlagchimie-WeinheimNew- York.
[8] Cristopher Masters (1981), Homogeneous Transition- Metal Catalysis, London New York
Chapman and Hall.
[9] Piet W.N.M. VanleenWen, Keij Morokuma and Jooph. Van Lenthe (1995), Theorical Aspects
of Homogeneous Catalysis, Kluwer Academic Publishers.
[10] Surit Bhaduri, Doble Mukesh (2000), Homogenous Catalysis Mechanisms and Industrial
Application, A.John Wiley and Sons Publication, New York- Chichester-Weiheim- BrisbaneSingapore-Toronto
[11] W. P. Kwar, B.M.Voeler (2003), Rates of hydroxyl radical generation and organic compound
oxidation in mineral-catalyzed Fenton-like system, Environ.Sci.Tech, 37,pp 1150-1158
[12] Maria Papadaki, Jun Gao (2005), Kinetic models of complex reaction systems, Computers and
Chemical Engineering, 29 (11-12), pp 2449-2460
[13] Syuhei Yamaguchi, Hideki Masuda (2004), Basic approach to development of enviromentfriendly oxidation catalyst materials, Mononuclear hydroperoxo copper(II) complexes, Sc.
And Tech of Advanced materials, 20. pp 1-14.
[14] Udai P Singh, Vaibhave Aggarwal and Asish K. Sharma (2007), Mononuclear cobalt (II)
carboxyllate complexes: Synthesis, molecular structure and selective oxygenation study,
Inorganica Chimica Acta, 360 (10), pp 3226-3332
[15] Anirban J.S, Jubaraj B.B (2007), Synthesis and Characterisation of dinuclear and
mononuclear cobalt (II) benzoate complexes, Polyhedron, 26(6), pp 1347-1355

13

[16] Kassinos D, Varnava N, Micheal C, Piera P (2009), Homogenous oxidation of aqueous

solution of a7trazine and fenitrothion through dark and photo-Fenton reactions, Chemosphere,
74(6), pp 866-872.

14

CH7101
Cu trc, lin kt ha hc v nhng c trng ha l ca cc cht xc tc
phc ng th
Structure, chemical bond and physico-chemical characteristics of complex
catalysts
1. Tn hc phn: Cu trc, lin kt ha hc v nhng c trng ha l ca cc cht xc tc
phc ng th
2. M hc phn:
CH7101
3. Tn ting Anh: Structure, chemical bond and physico-chemical characteristic of complex
catalysts
4. Khi lng:
2(2-0-0-4)
- L thuyt:
- Bi tp:
- Th nghim:
5. i tng tham d:
Tt c NCS thuc chuyn ngnh Ha l thuyt v Ha l
6. Mc tiu ca hc phn:
Hc phn ny nhm mang li cho NCS:
- Cc kin thc nng cao, hin i ca chuyn ngnh Ha l thuyt v ha l v cc cht xc tc
phc.
- Rn luyn kh nng t duy khoa hc.
- Rn luyn k nng vn dng nhng kin thc vo nghin cu khoa hc v gii quyt nhng
vn thc tin v xc tc phc v cc lnh vc c lin quan.
7. Ni dung tm tt:
- Xc tc phc l m hnh ha tm hot ng ca xc tc sinh hc (enzym)
- Cc l thuyt hin i v s to phc gia ion kim loi chuyn tip vi ligan c bn cht
khc nhau
- Cu trc, lin kt ha hc, thnh phn v cc c trng ha l ca cc cht xc tc phc.
8. Nhim v ca NCS:
- D lp:
- Bi tp:
9. nh gi kt qu:
- Mc d gi ging:
- Kim tra nh k:
- Thi kt thc hc phn:
10. Ni dung chi tit hc phn:
PHN M U
Gii thiu mn hc
Gii thiu cng mn hc
Gii thiu ti liu tham kho
CHNG 1: Mi quan h tng h gia xc tc sinh hc v xc tc phc
1.1 Xc tc sinh hc l m hnh xc tc phc hon ho
1.1.1 c im cu trc tm hot ng ca cc cht xc tc sinh hc
1.1.2 C ch vn chuyn electron ca tm hot ng ca xc tc sinh hc
1.1.3 Cc tnh cht u vit v hn ch ca cc cht xc tc sinh hc
1.2 Xc tc phc l m hnh ha tm hot ng ca xc tc sinh hc
1.2.1 Ch to (tng hp) cc cht xc tc phc trn c s m phng theo cu trc, thnh
phn, c ch vn chuyn electron ca tm hot ng xc tc sinh hc.
1.2.2 u nhc im ca cc cht xc tc phc
1.2.3 Vn d th ha cc cht xc tc phc ng th
CHNG 2: S to phc gia ion kim loi chuyn tip (Mz+) v ligan (L) trong dung dch
15

2.1 c im cu trc electron v cc c trng ha l ca Mz+

2.2 Bn cht ha hc v s phn loi ligan
2.3 Cc l thuyt hin i v s to phc gia M z+ v (L)
2.3.1 L thuyt lin kt ha tr (VB)
2.3.2 L thuyt t hp tuyn tnh cc orbital nguyn t thnh cc orbital phn t
(MOLCAO)
2.3.3 L thuyt trng ligan
2.4 Nhit ng hc s to phc trong dung dch
2.4.1 Cu trc, thnh phn, bn nhit ng ca cc dng phc c to thnh
2.4.2 Hm to thnh v t phn nng ca mi dng phc
2.5 Xc nh dng phc ng vai tr xc tc
2.5.1 Hot tnh, chn lc xc tc
2.5.2 Cc tiu chun mt dng phc tr thnh cht xc tc
2.5.3 Mi quan h bin i tng ng gia tc phn ng xc tc v t phn nng
ca dng phc tng ng.
CHNG 3: Tc dng ca s to phc xc tc
3.1 Tng bn thy phn ca M z+
3.2 Tng hot tnh v chn lc xc tc
3.3 Thay i th oxy ha- kh ca Mz+
3.4 Thay i c ch ca phn ng
3.5 Xc tc cho cc phn ng b ngn cm bi quy tc bo ton tnh i xng orbital phn t
3.6 Hot ha cc cht phn ng
11. Ti liu hc tp: Nguyn Vn Xuyn (2007), Cu to phn t v lin kt ha hc, Nh xut
bn Khoa hc v K thut, H Ni.
12. Ti liu tham kho:
[1] Nguyn Vn Xuyn (1994), Xc tc ng th oxy ha kh bng phc cht mt nhn v hai
nhn mt s ion kim loi chuyn tip, Lun n tin s khoa hc Ha hc, Trng i hc Bch
Khoa H Ni, H Ni.
[2] Trn Th Minh Nguyt (2002), Nghin cu tnh cht catalaza v peroxidaza ca phc cht
mt s kim loi chuyn tip vi etylendiamin, Lun n tin s ha hc, Trng i hc Bch Khoa
H Ni, H Ni.
[3] V Th Kim Loan (2008), Xc tc ng th oxy ha- kh bng phc cht ca ion kim loi
chuyn tip, Lun n Tin s ha hc, Trng i hc Bch Khoa H Ni, H Ni.
[4] Nguyn Vn Dng (2010), Nghin cu tnh cht catalaza v peroxidaza ca phc Co(II)Axit citric, Lun n Tin s ha hc, Trng i hc Bch Khoa H Ni, H Ni.
[5] Nguyn Vn Xuyn, Trn Th Minh Nguyt (2001), Xc tc phc, Cc bo co khoa hc Hi
ngh xc tc hp ph Ton quc ln th 2, H Ni, tr 127-160.
[6] G. Henrici-Olive, S. Olive (1997), Coordination and Catalysis, Verlagchimie-WeinheimNew- York.
[7] Cristopher Masters (1981), Homogeneous Transition- Metal Catalysis, London New York
Chapman and Hall.
[8] Piet W.N.M. VanleenWen, Keij Morokuma and Jooph. Van Lenthe (1995), Theorical Aspects
of Homogeneous Catalysis, Kluwer Academic Publishers.
[9] Surit Bhaduri, Doble Mukesh (2000), Homogenous Catalysis Mechanisms and Industrial
Application, A.John Wiley and Sons Publication, New York- Chichester-Weiheim- BrisbaneSingapore-Toronto
[10] W. P. Kwar, B.M.Voeler (2003), Rates of hydroxyl radical generation and organic compound
oxidation in mineral-catalyzed Fenton-like system, Environ.Sci.Tech, 37,pp 1150-1158
[11] Maria Papadaki, Jun Gao (2005), Kinetic models of complex reaction systems, Computers and
Chemical Engineering, 29 (11-12), pp 2449-2460
16

[12] Syuhei Yamaguchi, Hideki Masuda (2004), Basic approach to development of enviromentfriendly oxidation catalyst materials, Mononuclear hydroperoxo copper(II) complexes, Sc. And
Tech of Advanced materials, 20. pp 1-14.
[13] Udai P Singh, Vaibhave Aggarwal and Asish K. Sharma (2007), Mononuclear cobalt (II)
carboxyllate complexes: Synthesis, molecular structure and selective oxygenation study, Inorganica
Chimica Acta, 360 (10), pp 3226-3332
[14] Anirban J.S, Jubaraj B.B (2007), Synthesis and Characterisation of dinuclear and
mononuclear cobalt (II) benzoate complexes, Polyhedron, 26(6), pp 1347-1355
[15] Kassinos D, Varnava N, Micheal C, Piera P (2009), Homogenous oxidation of aqueous
solution of atrazine and fenitrothion through dark and photo-Fenton reactions, Chemosphere, 74(6),
pp 866-872.

17

CH7102

Mt s ng dng thc tin ca xc tc phc

Some practical applications of complex catalysis
1. Tn hc phn: Mt s ng dng thc tin ca xc tc phc
2. M hc phn:
CH7102
3. Tn ting Anh: Some practical applications of complexe catalysis
4. Khi lng:
2(2-0-0-4)
- L thuyt:
- Bi tp:
- Th nghim:
5. i tng tham d:
Tt c NCS thuc chuyn ngnh Ha l thuyt v Ha l
6. Mc tiu ca hc phn:
Cung cp cho NCS:
- Nhng kin thc c bn, hin i v xc tc phc
- Rn luyn kh nng t duy khoa hc.
- ng dng cc kin thc vo gii quyt nhng vn thc tin cp thit c lin quan.
7. Ni dung tm tt:
- Loi phn ng xc tc phc cn chn p ng c yu cu ca vn thc tin cn c gii
quyt
- Dng phc ng vai tr cht xc tc tng ng vi cc c trng v cu trc, thnh phn,
bn nhit ng, hot tnh v chn lc.
- Cc kin thc v quy lut ng hc, c ch v iu kin ti u ca phn ng.
8. Nhim v ca NCS:
- D lp:
- Bi tp:
9. nh gi kt qu:
- Mc d gi ging:
- Kim tra nh k:
- Thi kt thc hc phn:
10. Ni dung chi tit hc phn:
PHN M U
Gii thiu mn hc
Gii thiu cng mn hc
Gii thiu ti liu tham kho
CHNG 1: Cc phn ng xc tc phc trong x l cc cht c hi bo v mi trng
1.1 Tnh u vit ca phn ng xc tc phc
1.1.1 Tc nhanh, chn lc cao nhit v p sut bnh thng
1.1.2 Nng sut cao, cht lng sn phm tt
1.1.3 Tit kim nguyn vt liu, nng lng, khng c cht thi
1.1.4 Di tc dng ca xc tc phc, O2(kk) v H2O2 tr thnh cc tc nhn oxy ha rt
1
mnh tng ng l O 2g v gc t do OH thay th cho cc cht oxy ha KMnO4, K2Cr2O7,
NaClO, Cl2t tin v c hi.
1.2 ng dng cc phn ng oxy ha cc cht c bng H2O2(O2) di tc dng ca cc xc
tc phc trong x l cc loi nc thi (sn phm l cc cht khng c hoc CO2 v H2O)
1.2.1 X l nc thi cng nghip dt nhum, xc tc l [CoL]2- hoc [Mn(En)2]2+
1.2.2 X l nc thi cng nghip giy, xc tc l [FeHLHCO3]
1.2.3 X l nc thi cng nghip ch bin thy sn, xc tc l [MnDETA]2+
1.2.4 X l chuyn ha phenol, xc tc l [CoL]21.2.5 X l r rc thi qua h sinh hc, xc tc l [MnHLHCO3]
1.2.6 X l chuyn ha thuc tr su 4,4-DDT, xc tc l [FeDETA]2+
CHNG 2: Cc phn ng xc tc phc trong i mi cc qu trnh cng ngh.

18

2.1 Qu trnh oxy ha hi etanol thnh axetandehit 370-500C c thay bng s tng
hp axetandehit t etylen v O2 trong dung dch nc c xc tc bng phc palai-ng 2060C v 1 atm (qu trnh Waker)
2.2 Trn c s c ch mch gc v cc thng s ng hc c bn nh hng n s phn
b trng lng phn t cc polime m ngi ta thit lp c mt s c ch mi cho qu
trnh tng hp polistirn vi nng sut v cht lng cao
2.3 Cacbonyl ha metanol c xc tc bng phc cht Roi, ime ha, oligome ha, polime
ha anken vi s tham gia ca phc cht xc tc ng th Zeigler.
2.4 thay th cht oxy ha NaClO bng H2O2 oxy ha sorboza di tc dng ca xc
tc phc kim loi. Kt qu b qua c giai on axeton ha sorboza. Qu trnh cng ngh c
tin hnh trong iu kin thun khit, khng c cn b v kh thi gy nhim mi trng, t hiu
qu kinh t cao.
2.5 Ty mu trong cng nghip dt, giy v mt s ngnh cng nghip khc bng cch nghin
1
cu to ra cc h xc tc phc- ngun pht sinh ra cc tc nhn oxy ha rt mnh OH , O 2g dng
ty mu, ty trng t, la, bng, vi si, giyvi tc nhanh nhit thng, tit kim
nng lng, ha cht.
2.6 Chuyn ha parafin ca du m, kh CO v than thay th cho cc qu trnh hin hnh
c chn lc thp.
2.7 Kh CO2 t do v rng buc ( dng CaCO3) chim 99,9% ccbon t nhin nhit
thp c ngha tim nng ln- ngun nguyn liu mi cho cc hp cht hu c, khi m du m,
than v kh t nhin ang dn cn kit.
2.8 Chuyn ha nng lng mt tri thnh nng lng dng trong cng nghip c d tr
di dng ha nng ca cc sn phm phn ng quang hp nhn to (H2 v O2 hoc cc hp cht
hu c v O2), c xc tc bng phc a nhn, tng t nh tm hot ng ca cc cht xc tc
sinh hc trong qu trnh quang hp thc vt t nhin.
CHNG 3: Cc phn ng xc tc phc trong phn tch siu vi lng v mt s ng dng
khc
3.1 Phn tch siu vi lng bng phng php ng hc xc tc phc
3.1.1 C s khoa hc ca phng php: Da trn mi quan h ph thuc tuyn tnh tc
phn ng oxy ha c cht hu c c mu S cht ch th bng H2O2 vo nng ion kim loi
chuyn tip Mz+ cn c phn tch dng phc ng vai tr cht xc tc c hot tnh v chn
lc rt cao nhit v p sut thng. nhy ca phng php ~ppb.
3.1.2 Cc i tng cn phn tch cc cht liu siu sch cn c s dng trong cc lnh
vc cng ngh v k thut cao: Cc loi thuc th, cc cht bn dn, vt liu t, vt liu pht quang,
phn tch cc mu thc vt, xc nh nhim mi trng, m khng b nh hng bi cc
yu t khc
3.1.3 Xc nh vi lng Co 2+ trong t v trong thc vt, xc tc l [CoL]23.1.4 Xc nh hm lng vt Mn2+ trong bn t, xc tc l [MnDETA]2+
3.1.5 Phn tch vt v siu vt Mn2+ trong nc ngm v bt ngc trai, xc tc l
[MnEn2]2+
3.1.6 Xc nh hm lng vt Cu 2+ trong nc sng, h, nc ngm, xc tc l [CuGlu]
3.1.7 D bo v kh nng t lm sch nc t nhin v nhim mi trng
3.2 ng dng cc h xc tc phc trong nng nghip v cng nghip thc phm
3.2.1 Ch to cc loi phn vi lng bn l v bn gc c hot tnh xc tc cao lm tng
trng v tng nng sut cc loi cy trng: la, ng, ch, cc loi cy n qu,
3.2.2 S dng h xc tc phc Cu[Glu] vi H2O2 ct mch Alginate (mt loi
polysaccharide trong rong m) thnh cc oligoalginate c tc dng kch thch s ny mm ht thc
v tng trng cy la.
3.2.3 Ngc li i vi nhng phn ng oxy ha xc tc c hi lun tn ti v din ra
trong cc loi nng sn, thc phm, cc loi qu ti, cc loi ru vang, ch thnh phm, gy
bin cht, i thiu, c hi, cn phi nghin cu to ra cc cht chng oxy ha xc tc vi lng rt
19

nh, khng c hi, quy trnh x l n gin, t hiu qu kinh t cao trong vic bo qun cht
lng cc loi sn phm kh bo qun ni trn.
11. Ti liu hc tp:
12. Ti liu tham kho:
[1] Nguyn Vn Xuyn (1994), Xc tc ng th oxy ha kh bng phc cht mt nhn v hai
nhn mt s ion kim loi chuyn tip, Lun n tin s khoa hc Ha hc, Trng i hc Bch
Khoa H Ni, H Ni.
[2] Trn Th Minh Nguyt (2002), Nghin cu tnh cht catalaza v peroxidaza ca phc cht
mt s kim loi chuyn tip vi etylendiamin, Lun n tin s ha hc, Trng i hc Bch Khoa
H Ni, H Ni.
[3] V Th Kim Loan (2008), Xc tc ng th oxy ha- kh bng phc cht ca ion kim loi
chuyn tip, Lun n Tin s ha hc, Trng i hc Bch Khoa H Ni, H Ni.
[4] Nguyn Vn Dng (2010), Nghin cu tnh cht catalaza v peroxidaza ca phc Co(II)Axit citric, Lun n Tin s ha hc, Trng i hc Bch Khoa H Ni, H Ni.
[5] Nguyn Vn Xuyn, Trn Th Minh Nguyt (2001), Xc tc phc, Cc bo co khoa hc Hi
ngh xc tc hp ph Ton quc ln th 2, H Ni, tr 127-160.
[6] G. Henrici-Olive, S. Olive (1997), Coordination and Catalysis, Verlagchimie-WeinheimNew- York.
[7] Cristopher Masters (1981), Homogeneous Transition- Metal Catalysis, London New York
Chapman and Hall.
[8] Piet W.N.M. VanleenWen, Keij Morokuma and Jooph. Van Lenthe (1995), Theorical Aspects
of Homogeneous Catalysis, Kluwer Academic Publishers.
[9] Surit Bhaduri, Doble Mukesh (2000), Homogenous Catalysis Mechanisms and Industrial
Application, A.John Wiley and Sons Publication, New York- Chichester-Weiheim- BrisbaneSingapore-Toronto
[10] W. P. Kwar, B.M.Voeler (2003), Rates of hydroxyl radical generation and organic compound
oxidation in mineral-catalyzed Fenton-like system, Environ.Sci.Tech, 37,pp 1150-1158
[11] Maria Papadaki, Jun Gao (2005), Kinetic models of complex reaction systems, Computers and
Chemical Engineering, 29 (11-12), pp 2449-2460
[12] Syuhei Yamaguchi, Hideki Masuda (2004), Basic approach to development of enviromentfriendly oxidation catalyst materials, Mononuclear hydroperoxo copper(II) complexes, Sc. And
Tech of Advanced materials, 20. pp 1-14.
[13] Udai P Singh, Vaibhave Aggarwal and Asish K. Sharma (2007), Mononuclear cobalt (II)
carboxyllate complexes: Synthesis, molecular structure and selective oxygenation study, Inorganica
Chimica Acta, 360 (10), pp 3226-3332
[14] Anirban J.S, Jubaraj B.B (2007), Synthesis and Characterisation of dinuclear and
mononuclear cobalt (II) benzoate complexes, Polyhedron, 26(6), pp 1347-1355
[15] Kassinos D, Varnava N, Micheal C, Piera P (2009), Homogenous oxidation of aqueous
solution of atrazine and fenitrothion through dark and photo-Fenton reactions, Chemosphere, 74(6),
pp 866-872.
[16] Xchyov A.Ya, Travin C.O, Duka G.G, Xkurlatov Yu.L (1983), Katalitichexkie reaktxii
okhrana okrujausei xre. Stiintxa, Kisinev.
[17] Chen Weng Xing (2007), Photocatalytic oxidation of phenol in aqueous solution, J.Science in
China Series B, Chemistry, 50(3), June.

20

CH7103

Quang ha hc
Photochemistry

1. Tn hc phn: Quang ha hc
2. M hc phn: CH7103
3. Tn ting Anh: Photochemistry
4. Khi lng:
2(2-0-0-4)
- L thuyt:
- Bi tp:
- Th nghim:
5. i tng tham d:
Tt c NCS thuc chuyn ngnh Ha l thuyt Ha l
6. Mc tiu ca hc phn: Hc phn ny nhm mang li cho NCS:
- Cc kin thc nng cao kin thc v Quang ha hc
- Rn luyn kh nng t duy c lp ca NCS chuyn ngnh Ha l thuyt Ha l, chuyn su
Quang ha
- Cung cp cho sinh vin nhng thng tin khoa hc mi nht trong lnh vc Quang ha.
7. Ni dung tm tt: Hc phn cung cp cho sinh vin kin thc c bn v phn ng quang
ha, cc giai on ca phn ng quang ha nh kt qu mt qu trnh kch thch phn t. Ngoi ra,
hc phn b sung cc kin thc v nhng cht mang c tnh quang ha trn v d zn, ng dng
ca quang ha trong cc phng php phn tch Ha l hin i trn v d Laser , Ph quang
electron, Ph Raman,
8. Nhim v ca NCS:
- D lp:
9. nh gi kt qu: (cch cho im ging nh quy nh i vi Cao hc)
- Mc d gi ging:
- Kim tra nh k:
- Thi kt thc hc phn:
10. Ni dung chi tit hc phn:
PHN M U
Gii thiu mn hc
Gii thiu cng mn hc
Gii thiu ti liu tham kho
CHNG 1: Gii thiu chung
1.1
M u: Cc khi nim c bn
1.2
Cc giai on ca phn ng ha quang
1.3
ng hc cc phn ng ha quang
CHNG 2: Kch thch phn t v bin i ca phn t sau khi b kch thch
2.1
Hp th v pht x nng lng in t
2.2
H s Einstein v kh nng hp th
2.3
Nguyn l Frank-Condom
2.3
Hunh quang v Ln quang
2.4
Dch chuyn electron gia cc mc nng lng cng trng thi, dch chuyn cm
(singlet-triplet)
2.5
S Jablonski
2.6
Phn ly v tin phn ly
CHNG 3: Laser
3.1
Phng trnh Laser c bn
3.2
M t thit b laser
3.4
c im ca nh sng laser
3.5
Phn loi laser
21

3.6
ng dng ca laser
3.6.1
Ph laser (laser Spectroscopy)
3.6.2
Laser to Hunh quang (LIF)
3.6.3
Laser nh v, o v iu chnh (LIDAR)
CHNG 4: Ph quang electron (PES)
4.1
Nguyn l phng php
4.2
Ph quang electron trong vng cc tm
4.3
Ph quang electron vng tia X
CHNG 5: Ph Raman
5.1
Nguyn l phng php
5.2
Quy tc chn la Raman
5.3
Quang phn v tin quang phn
5.4
V d ph Raman
CHNG 6: Ha quang hc zn
6.1
S phn ng ha quang zn
6.2
c im phn ng ha quang zn
6.3
Vn thiu ht zn v bu kh quyn
11. Ti liu hc tp:
12. Ti liu tham kho:
[1 ]
Atkins, P.W. and de Paula, J. (2006) Physical Chemistry. 7th. Edn. Oxford Press
[2 ]
Pilling, M.J. and Seakins, P.W. (1994) Ozone deficit. V 265, pp.1831-8
[3 ]
Andrews, D.L. (2004) Lasers in Chemistry. Oxford Press

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CH7104

Cc phng php cng hng t

Magnetic resonance

1. Tn hc phn: Cc phng php cng hng t

2. M hc phn: CH7104
3. Tn ting Anh:Magnetic resonance
4. Khi lng: 2(2-0-0-4)
- L thuyt:
- Bi tp:
- Th nghim:
5. i tng tham d:
Tt c NCS thuc chuyn ngnh Ha l thuyt Ha l
6. Mc tiu ca hc phn: Hc phn ny nhm mang li cho NCS:
- Cc kin thc v cng hng t, mt mng l thuyt hin c s dng rng ri trong nghin
cu cu to cht
- Rn luyn kh nng t duy c lp ca NCS chuyn ngnh Ha l thuyt Ha l, chuyn su
v nghin cu cu to cht v ng hc cc qu trnh ha
- Hng dn sinh vin phng php nghin cu v thc nghim bng cc phng php cng
hng t (nu c thit b)
7. Ni dung tm tt: Hc phn cung cp cho sinh vin kin thc l thuyt c bn v hin
tng cng hng t, nguyn l cc phng php cng hng t cng nh ng dng ca chng
trong nghin cu hin i.
8. Nhim v ca NCS:
- D lp:
9. nh gi kt qu: (cch cho im ging nh quy nh i vi Cao hc)
- Mc d gi ging:
- Kim tra nh k:
- Thi kt thc hc phn:
10. Ni dung chi tit hc phn:
PHN M U
Gii thiu mn hc
Gii thiu cng mn hc
Gii thiu ti liu tham kho
CHNG 1: Tnh cht t v spin
1.1 Mmen t v s lng t t.
1.2
Tng tc vi t trng ngoi, khi nim t s hi chuyn, h s Bohn magneton
1.3 Th nghim Stern-Gelash v khi nim spin electron.
1.4
Mmen spin v s lng t spin
1.5
S lng t ha khng gian
CHNG 2: Cng hng t ht nhn
2.1
Mmen t ht nhn
2.2
Nng lng ht nhn trong t trng
2.3
Dch chuyn ha hc
2.3
Cu trc tinh
2.4
Vc t t ha
2.5
Chiu rng ca pick ph v tc phn ng
2.6
Hiu ng ht nhn Overhauser
2.7
Cng hng t ht nhn hai chiu.
2.8
Cng hng t ht nhn dng rn
CHNG 3: Cng hng t electron
3.1
Gi tr g
23

3.2
Cu trc Hyperfine
11. Ti liu hc tp:
12. Ti liu tham kho:
[1] Atkins, P.W. and de Paula, J. (2006) Physical Chemistry. 7th. Edn. Oxford Press
[2] Atkins (2004) Physical Chemistry. 6th. Edn. Oxford Press
[3] Joseph P. Hornak (2007) The basics of NMR.
[4] Web http://www.cis.rit.edu/htbooks/nmr/

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