p (benzene),

atm
0.001
0.001
0.002
0.005
0.010
0.020

Moles adsorbed/g gel x 10^5

70
90
110
130
14.0
6.7
2.6
1.1
22.0
11.2
4.5
2.0
34.0
18.0
7.8
3.9
68.0
33.0
17.0
8.6
88.0
51.0
27.0
16.0
78.0
12.0
26.0

Plot the isosteric heat of adsorption vs. the amount

ln
ln p
70
90
110
-7.6009024595 -8.873868 -9.610818 -10.55741
-6.907755279 -8.421883 -9.097012 -10.00885
-6.2146080984 -7.986565 -8.622554 -9.458802
-5.2983173665 -7.293418 -8.016418 -8.679712
-4.605170186 -7.035589
-7.5811 -8.217089
-3.9120230054
-7.156217 -9.028019
-8.885395

70
0.00014
0.00022
0.00034
0.00068
0.00088

90
0.000067
0.000112
0.00018
0.00033
0.00051
0.00078

110
0.000026
0.000045
0.000078
0.00017
0.00027
0.00012

130
0.0000113
0.00002
0.000039
0.000086
0.00016
0.00026

adsorbed.
130
-11.39071
-10.81978
-10.15195
-9.361163
-8.740337
-8.254829

n
slope
intercept
c
70 1.567216716 6.290554675 0.018063925
90 1.50598178 6.81449872 0.0108352097
110 1.402572654
7.3225 0.0054032027
130 1.154702809 5.543990882 0.0082196512
const theta =
2.62753
T
1/T
ln P
70 0.014285714 7.804555358
90 0.011111111 8.269343746
110 0.009090909 8.677447236
130 0.007692308 6.659484881

1/P

1/T
0.0142857
0.0111111
0.0090909
0.0076923

1/theta
70
2000 7142.8571
1000 4545.4545
500 2941.1765
200 1470.5882
100 1136.3636
50

90
14925.373
8928.5714
5555.5556
3030.303
1960.7843
1282.0513

110
38461.538
22222.222
12820.513
5882.3529
3703.7037
8333.3333

130
88495.575
50000
25641.026
11627.907
6250
3846.1538

slope
intercept
70 3.154982 1049.5017
90 6.8949162 1522.8686
110 17.250744 4168.0496
130 43.675961 2951.3687

slope
intercept
parameter 92.014199 6.8824171
stdev
205.35458 2.2244618
R^2
0.0912276 1.0178144

delHa/R
delHa/R
-92.0142 -1121.304