Journal of Physical and Chemical Reference Data Volume 13, 1984 Supplement No. 1 Heat Capacities and Entropies of Organic Compounds in the Condensed Phase Eugene S. Domalski, William H. Evans, and Elizabeth D. Hearing Chemical Thermodynamics Data Center, Chemical Thermodynamics Division, Center for Chemical Physics, National Bureau of Standards, Washington, DC 20234 Published by the American Chemical Society and the American Institute of Physics for the National Bureau of StandardsHeat Capacities and Entropies of Organic Compounds in the Condensed PhaseJournal of Physical and Chemical Reference Data David R. Lide, Jr., Editor The Journal of Physical and Chemical Reference Data (SSN 0047-2686) is published quarterly by the American Chemical Society (1155 16th St. N. W., Washington, OC £20036) and the American Institute of Physics (335 E. 45th St, New York, NY 10017) for the National Bureau of Standards. ‘Second:class postage paid at Washington, DC and additional maiing offices. 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The night of the U.S. Government to Untesticted copying for its own use of copyrighted material originating nts laboratories ‘or under its contracts is specifically recognized,Journal of Physical and Chemical Reference Data Volume 13, 1984 Supplement No. 1 Heat Capacities and Entropies of Organic Compounds in the Condensed Phase Eugene S. Domalski, William H. Evans, and Elizabeth D. Hearing Chemical Thermodynamics Data Center, Chemical Thermodynamics Division, Center for Chemical Physics, National Bureau of Standards, Washington, DC 20234 Published by the American Chemical Society and the American Institute of Physics for the National Bureau of StandardsCopyright © 1984 by the US. Secretary of Commerce on behalf ofthe United States. This copyright will 'be assigned to the American Insitute of Physics and the American Chemical Sociaty, to whom all, requests regarding reproduction should be addressed. brary of Congress Catalog Card Number 84-70908 International Standard Book Number 0-86318-447-8 ‘American Institute of Physies, Inc 395 East 45th Street New York, New York 10017 Printed in the United Statos of AmericaForeword The Journal of Physical and Chemical Reference Data is published jointly by the American Institute of Physics and the American Chemical Society for the National Bureau of Standards. Its objective is to provide critically evaluated physical and chemical property data, fully documented as to the original sources and the criteria used for evaluation. One of the principal sources of material for the journal is the National Standard Reference Data System (NSRDS), a program coordinated by NBS for the purpose of promoting the compilation and critical evaluation of property data. The regular issues of the Journal of Physical and Chemical Reference Data are published quarterly and contain compilations and critical data reviews of moderate length. Longer monographs, volumes of collected tables, and other material unsuited to a periodical format are published separately as Supplements to the Journal. This monograph, “Heat Capacities and Entropies of Organic Compounds in the Condensed Phase” by Eugene S. Domalski, William H. Evans, and Elizabeth D. Hearing is presented as a Supplement No. 1 to Volume 13 of the Journal of Physical and Chemical Reference Data. David R. Lide, Jr., Editor Journal of Physical and Chemical Reference Data " J. Phys. Chem. Ret, Data, Vol. 13, Suppl 1, 1984Heat Capacities and Entropies of Organic Compounds in the Condensed Phase Eugene S. Domalski, William H. Evans,” and Elizabeth D. Hearing” ‘Chemical Thermodynamics Data Center, Chemical Thermodynamics Division, Center for Chemical Physics, National Bureau of Standards, Washington, DC 20234 Heat capacities and entropies have been compiled for approximately 1400 organic ‘compounds in the liquid and solid phases. Values for the enthalpies and entropies of phase transitions—solid state, fusion, and vaporization—which were encountered as part of this evaluation and tabulation are included. An attempt was made to include articles which were published from about 1925 through most of 1982. Some earlier papers have been included which report data for compounds not otherwise studied. ‘Over 800 references have been examined and evaluated. The data given for each compound in the tabulation are: empirical formula, physical state, reference code, compound name(s), heat capacity, entropy, and, where available, phase-transition data, Wiswesser Line Notation for the compound, formula weight, and a rating which indicates the estimated overall quality of the reported data, Key words: condensed phase; entropy; evaluated data; heat capacity; organic compounds; phase transitions; WLN. 100 Canterbury Lane, Rockville, MD 20883 2447 Regina Drive, Clarksburg, MD 20871, 1 ‘J. Phys. Chem. Ref. Data, Vol. 13, Suppl. 1, 1984Contents Introduction.. eee Applicability of the Compiled Data... Scope of the Search Arrangement of the Data.. Definition: Acknowledgments... ; References for the Introductory Discussion Table of Heat Capacities, Entropies, and Phase Transition Propert Compound Name-Formula Inde Bibliography ... : 3 J. Phys. Chem. Ret. Data, Vol. 13, Suppl. 1, 19844 DOMALSKI, EVANS, AND HEARING 1. Introduction This paper provides heat capacity and entropy data on approximately 1400 organic compounds in the liquid and solid phases. Data on the enthalpies and entropies of phase transitions which have been determined from calorimetric measurements are also included. Over 800 references have been examined and evaluated. ‘The need for such a compilation has been voiced for many years by scientists and engineers in a variety of disciplines. Some of these disciplines are: chemical process engineering, thermodynamic data evaluation, cryogenics, chemical hazard assessment, thermochemis- try, resource conservation and recovery, solid state physics, combustion engineering, and hazardous waste disposal. ‘The information provided in this paper supplements two other NBS publications. The first is NBS Report 10487, Thermodynamic Data for Industrial Incinerators. The contents of this report were incorporated into an American Society of Mechanical Engineers (ASME) publication entitled: “Combustion Fundamentals for Waste Incineration” and have been available from ASME since 1974”, The compilative effort contained in NBS Report 10487 was sponsored by the ASME Research Committee on Industrial and Municipal Wastes, and the report lists data on the enthalpies of formation at 298 K for over 1000 organic compounds in the gaseous, liquid, and solid phases. The second publication is NBSIR 78-1479, Thermody- namic Data for Waste Incineration’. The general orientation of this report was to make thermodynamic data available on chemical mixtures, polymers, composite materials, solid wastes, and materials not easily identifiable by a single stoichiometric formula. The orientation of this report was directed at incinerator engineers involved in the disposal of waste materials. A total of 331 materials has been compiled with specific hheat capacity and gross heat of combustion being the major property entries. This publication has also been available from ASME under the same title since 1979* and was sponsored by the ASME Research Committee on Industrial and Municipal Wastes. 2. Applicability of the Compiled Data ‘The data reported here have a wide range of applicability. Heat capacity data are needed in the ‘adjustment of reaction enthalpies and entropies to various temperatures of interest in the condensed phase region and in the calculation of heat balances for physical processes. One of the more useful applications of entropy data is through combination with enthalpy data to obtain the corresponding Gibbs energies, AG", and equilibrium constants, K. Information on Gibbs energies allows one to calculate whether a particular reaction will occur spontaneously under specified conditions of temperature, pressure, activities and/or concentrations of reactants J. Phys. Chem. Ref. Data, Vol. 13, Suppl. 1, 1984 and products. At constant temperature and pressure, the standard Gibbs energy change is defined by: AG’ = AH - TAS’, where AH" and AS" are the standard enthalpy and standard entropy changes for the reaction under consideration at constant temperature, T. The superscript degree (°) indicates that the substance is in its standard state. For a pure liquid or solid, the standard state is the substance in the condensed phase under a pressure of one atmosphere. For a process in equilibrium at a given temperature and pressure, the Gibbs energy change is zero. For a process which occurs spontaneously at a given tempera- ture and pressure, the standard Gibbs energy change is negative, ie., AG" is less than zero. The following ‘equation relates the standard Gibbs energy change to the equilibrium constant, ic., AG" = -RTInK , where R is the gas constant, T is the absolute tempera- ture, and Ink is the natural logarithm of the equilibrium constant. This equation provides a means of determining whether a particular process or reaction is thermodynami- possible (spontaneous) under a specified set of conditions. In general, both the heat capacity and entropy data serve as a reference data-base for estimating and correlating thermodynamic properties for organic compounds for which no experimental data are available. 3. Scope of the Search References containing heat capacity data for organic compounds were located by a search of the files of the Chemical Thermodynamics Data Center at the National Bureau of Standards; additional references were located through the Bulletin of Chemical Thermodynamics’, the International Critical Tables‘, the Landolt i Physikalisch-Chemische Tabellen’, supplement, of Thermophysical Properties of Mattes ‘The original papers were examined to obtain the data given here, to determine what corrections should be applied, and to evaluate qualitatively the reported ‘measurements. ‘An attempt has been made to include all significant papers published from about 1925 through most of 1982; in addition, a few earlier papers which report data for compounds not otherwise studied have been included. References 6 and 7 above contain most of the literature prior to 1925 and can be consulted by the reader interested in the historical development of measurements and data on the heat capacities of organic compounds. ‘The aim of the search was to obtain heat capacity and entropy data for organic compounds in the condensed phase at “room temperature”; however the temperatureHEAT CAPACITIES AND ENTROPIES OF ORGANIC COMPOUNDS 5 range included is about 200-450 K. This extended range ‘was chosen so that the user would have, where possible, values for temperatures of interest, even if “room temper- ature” was not included. This would also allow the reader to extrapolate to temperatures outside of the reported range. In addition to the heat capacity and entropy data, val- ues of the enthalpy and entropy of phase transitions ~ solid state, fusion, vaporization, and sublimation - obtained from calorimetric measurements are included. No specific search for these phase transition properties was made; the data reported were obtained as a by- product of the heat capacity search . Corrections for relative atomic mass (atomic weight), temperature scale, and energy units have been made, where appropriate. Values reported at “298 K” with the ice point taken as 273.1, 273.15, or 273.16 K are assumed to be at 298.15 K; the correction for this small change is much less than the precision and accuracy of the data. Correction for the energy units in most measurements made since about 1930 is likewise within the uncertainty of the data and has usually been omitted. Older data are of a lower precision, so that the correction is not needed. ‘Transition temperatures are, in general, those reported by the investigator. It was felt that the effort necessary to convert each investigator’s temperature scale to the present scale was not warranted. Thus, the reported values may have a systematic error of up to 0.1K. Fortunately, the modern high-precision measurements are usually based on the current 1968 International Practical Temperature Scale. 4, Arrangement of the Data The table of heat capacities, entropies, and phase transition properties given here contains the data entries for the various compounds. The entries in the table are arranged in the order of the empirical formulae of the compounds; isomers are further separated by their Wiswesser Line Notation. Under a given chemical species the data from the pertinent papers are included. The data from each paper form a separate entry, complete with identification of the source. When there are several entries for a compound, they are arranged chronologically by year. For each entry the data given are: compound empirical formula, physical state, reference code, compound name(s), followed by values for the heat capacity, entropy, and, where available, phase-transition data. The entry is completed by the formula weight, the Wiswesser Line Notation for the compound, and a graduated indication of the quality of the data. The formula given is the empirical formula for the compound; water of hydration is shown as (7)H,O. The elements are arranged in the order C, H(, T), followed by the other elements in alphabetical order of their chemical symbols One or more names are given for each compound. No attempt has been made to adhere to a rigorously systematic nomenclature. Common names and systematic ‘names are used; alternate names have been given freely. Al names used appear in the Compound Name-Formula Index in section 9, which should assist the reader who is aware of the compound name but not its empirical formula. ‘The bibliography is given in Section 10. The reference code is of the form XXAAA/BBB N where XX are the last two digits of the year of publication of the paper, AAA the first three letters of the last name of the first author, and BBB those of the last name of the second author (jf present). Authors after the first two are disregarded. N is a digit from 2 to 9 used to indicate a second, third,...... paper with the same year and author codes. Thus, 60BRO/SMI 2 refers to a paper by Brown and Smith appearing in 1960, the second one with authors BRO... and SMI... 45PIT is a 1945 paper by Pitzer. The full citation appears in the bibliography, arranged according to the reference codes. For years before 1900 the reference codes are in bold face type. Where the authors have given a table of smoothed values for the heat capacity, the value at 298K (interpolated if necessary) or the value nearest to that temperature is given. If the experimental measurements are represented only by a smoothing equation, this is used to calculate the value given. If only the unsmoothed experimental results are given by the authors, one of these is given, with the appropriate temperature. Such a selection is accompanied by a remark. ‘The third-law entropy is given at 298 K or at the tem: perature closest to this temperature. The value is that obtained by the authors; we have not reintegrated the heat capacity data to reevaluate the entropy. Phases are indicated by g, liq, c, c,ll, etc. In general, no attempt has been made to specify the crystalline form of the solid phases; cyl, is used for the form stable at the normal melting point. For each phase transition, the appropriate process, i.e, c/lig, the temperature in kelvins, the enthalpy and entropy change for the isothermal process, and, where appropriate, the pressure, are given. The entropy change AS is taken as AH/T unless indicated otherwise. Energy values are given in both calories and joules; the calorie is defined as 4.184 J. As most of the data are reported in calories, the value in joules is obtained by multiplying by 4.184; usually the same number of decimal places is retained. Occasionally, rounding errors occur and the conversion from calories to joules (or vice versa) is not exact. Pressures are given in kilopascals; one standard atmosphere is taken a5 101.325 kPa. The Wiswesser Line Notation is used to represent the structure of the compound”. ‘The formula weight is based upon the 1979 IUPAC Table of Atomic Weights. When the formula weight differs from that originally used by the authors, appropriate corrections to the values have been made. ‘An indication of our general evaluation of the data reported is given as A (high quality), B (good), C (average), D (low quality). This rating is based upon the J. Phys. Chem. Ret, Data, Vol. 13, Suppl. 1, 19646 DOMALSKI, EVANS, AND HEARING method used, the details of the measurements as reported, the number of measurements, purity of the sample, calibrations, and corrections applied to the data; it is intended as a guide to those data we feel are more reliable. In addition, the number of significant figures given for the numerical values indicates roughly the quality of the data. In general, papers which are rated as, being of high quality provide a detailed description of the cryostat used, the experimental procedure, the purity and characterization of the sample, calibration results, both raw and smoothed data for the temperature range over which measurements were made, and comment on the precision or accuracy of their data. An absence of numerical or descriptive information or poor agreement with a detailed and accurate study can lead to a low rating. Al of the names used to identify the compounds are included in the Compound Name-Formula Index with the appropriate empirical formulae. Prefixes, such as tert,, ortho-, a, 1,2- (but not Iso) are disregarded in the alphabetization of the names. ‘The sequencing of the compounds is based on the empirical formula. The formulae are sorted alphabetically by the first atomic symbol, then by the number of atoms of this element present (the Hill Indexing System"). In this compilation C, carbon, is always the first element. This arranged list of formulae is then sorted by the second atomic symbol (H, hydrogen, if present) and then by the number of atoms of this element. The sorting proceeds alphabetically thereafter for each element present. The following list illustrates this scheme: c col, CHCI, CH CO, GHCIO, GHC), CHC CH Tsomeric compounds are further sorted by their Wiswesser Line Notatior CHO 202 CH,0C.H, 301 C,H,OCH, QiY1&1— (CH,),CHCH,OH QX18181 (CH,),COH Q¥2&1—C,H,CH(CH)OH 5. Definitions Heat Capacity. The heat capacity may be defined as the ratio of the energy supplied to a system to the tempera- J. Phys. Chem. Ret. Data, Vol. 13, Suppl. 1, 1984 ture change in the system. The heat capacity may be an average value over a temperature range or the limiting ratio over an infinitesmal temperature change. If the system is maintained at constant volume, the heat capacity, C,, is the ratio of the change in internal energy with temperature, QUART), - If the system is maintained at constant pressure, the heat capacity, C,, is the ratio of the change in enthalpy with temperature, HAT), ‘The heat capacity reported in this compilation is the value at constant pressure and is that corresponding to a gram formula weight (or mole) of a specified substance. In simple terms, it is sometimes described as the amount of energy needed to change a gram-formula weight of substance by one kelvin. Experimentally, the heat capacity is obtained by measuring the enthalpy change over a small temperature change and is referred to the midpoint of the temperature range: C, = AH/(T;-T)), (T;-T,)/2. The measurements are usually made with the sample under its own vapor pressure; the correction to the standard pressure, 101.325 kPa (1 atm) is usually negligible for solids and liquids below their boiling point. In some papers, data are reported for mean temperatures over a large temperature range; these are noted as “mean temperature” and the temperature given refers to the midpoint of the experiments nearest to 25 °C. Entropy. The entropy, S, of a system is a measure of its randomness and is related to the number of possible available states of energy for a collection of atoms or molecules. The number of available energy states and thus the amount of randomness increases with tempera- ture and the entropy of a substance at constant volume or constant pressure will be greater at a high temperature than at a low temperature. If the number of available states for a group of atoms or molecules is greater in one configuration than in another, the entropy will be greater. Entropy and heat capacity are related mathematically by the following expressions: at constant volume, ds, = (C,/T)AT, and at constant pressure, ds, = (C,/T AT. The (calorimetric) entropy is obtained by integration of the measured values of C,/T from the lowest tempera- ture of measurement to the reported temperature. Various extrapolation methods have been used to extrapo-HEAT CAPACITIES AND ENTROPIES OF ORGANIC COMPOUNDS 7 late from the lowest experimental temperature to zero kelvin. Appropriate values of the entropies of phase changes are added. The entropy at zero kelvin is taken as, zero for the stable crystalline state, with the addition of residual (zero point) entropy, not removed by the extrap- lation, due to random ordering, optical isomerization, multiple electronic ground states for the molecule, etc. Thus, S; = $3 (zero point) + fo” (C,/T)AT (extrapola- tion) + fn? (C,/T)AT + A/T; (phase change) + Sn? (C,/T)AT + AHy/T, (phase change) + Sp” (C/T MMT. Phase Transitions. A process by which a substance undergoes a change of physical state, i., solid-solid, solid-liquid, solid-gas, or liquid-gas, is known as a phase transition or phase change. The phase change is accompanied by a transfer of energy (commonly referred to as latent heat) and a change in volume while both tem- perature and pressure remain constant. For a phase change which is carried out reversibly (i.e. under equilibrium conditions) at a constant temperature and pressure, the total Gibbs energy for a given mass of substance remains unchanged. If there is an enthalpy (or heat) change, then it follows that there will also be an entropy change for the process, because: AH ~ TAS = 0, or AS = AH/T. It should be noted that these equations are applicable only for the temperature and pressure at which the two given phases are in equilibrium. For phase changes - solid-solid transition, fusion, sublimation, vaporization - encountered in the table in section 8, AH refers to the isothermal enthalpy change at the transition temperature. Corrections can be applied for premelting effects to reduce the observed measurements to the isothermal state. The pressure, unless specified, is that of the substance at the transition temperature; the correction to standard pressure is usually negligible at ordinary pressures for solid transitions and fusions. The entropy is taken as AH/T and refers to the phases at the equilibrium pressure; this restriction is significant only for gases. Exceptions are indicated in the table in section 8. ‘Some investigators have reported the measurement of, anomalous phase changes in which the volume and entropy are continuous, but the heat capacity is discontinuous. During such phase changes no latent heat is present and the shape of the curve of the heat capacity plotted as a function of temperature often resembles the Greek letter lambda at the transition point and is called a “lambda transition”. In order to differentiate these anomalous transitions from ordinary phase changes, it has become customary to identify ordinary phase changes as phase changes of the first order and atypical phase changes as those of the second order. The discontinuity which occurs in a first order transition is a commonly observed phenomenon, however, the discontinuity associated with a second order transition has been more difficult to identify and/or interpret. Sometimes the discontinuous nature of the heat capacity is questioned in ‘a second order transition because experimental measure- ments show a peak or hump at the transition temperature rather than an unambiguous discontinuity. ‘A phase change which is accompanied by changes in entropy and volume and whose first-order derivatives of the Gibbs energy with respect to temperature and pressure change discontinuously is known as a phase change of the first order, S=-QG/T)», V= @G/aP), ‘A phase change which is accompanied by changes in the hheat capacity, volume expansivity, and isothermal com- pressibility and whose second-order derivatives of the Gibbs energy with respect to temperature and pressure change discontinuously is known as a phase change of the second order, G/T = @S/T)p = - G/T», Ks (®G/aP*),, QV/AP, = BV = QV/2T)p = @G/2TP)rp, where x is the molar isothermal compressibility and is the molar volume expansivity. The relationship between these parameters is given below by Ehrenfest’s equations”. For one mole of substance: AP/AT = [CD - COVITHBE - BOY), AP/AT = [B(D - BOVI«H - where i and f represent the initial and final states of the phase change. 6. Acknowledgments The authors thank Elton Caviness, Joyce J. Grimes, Ruby N. Boyd, and Jennifer C. Colbert for their efforts in the early stages of this work in the NBS Chemical ‘Thermodynamics Data Center. We also express our thanks to William J. Wiswesser for proof-reading the individual Wiswesser Line Notations for all of the organic compounds for which data have been tabulated, to Nancy W. Young for inputting the compiled data into the computer for machine manipulation and tabulation purposes, and to Carla G. Messina and Constance L. Seymour for their help in merging computer files, editing, and introducing data-format modifications. Financial support for this effort is acknowledged from the NBS Office of Standard Reference Data. 7. References for the Introductory Discussion 'G. T. Armstrong and E. S, Domalski, Thermodynamic Date for Industrial Incinerators, NBS Report 10487 (May 1972). J. Phys. Chem. Ret. Data, Vol. 13, Suppl. 1, 19848 . DOMALSKI, EVANS, AND HEARING 2ASME Research Committee on Industrial and Municipal Wastes, Combustion Fundamentals for Waste Incineration, 212 pp, American Society of Mechanical Engineers, New York, NY (1974). %B. S. Domalski, W. H. Evans, and T. L. Yobe, Je, Thermadynamic Data for Waste Incineration, NBSIR 78-1879 (August 1978) “ASME Research Committee on Industrial and Municipal Wastes, ‘Thermodynamic Data for Waste Incineration, 160 pp., American Society ‘of Mechanical Engineers, New York, NY (1979). °R.D. Freeman, Editor, Bulletin of Chemical Thermodynamics, Nos 20-23, (1977-1980), E. F. Westrum, Je, Editor, Bulletin of Thermody. ‘namics and Thermochemistry, Nos. 6-19 (1963-1976). SE. W. Washburn, Editorin-Chiet, Intemational Critical Tables of ‘Numerical Data Physi. Chemistry and Technology, §, MeGraw-Hill Book Co., New York, NY (1925) “Landolt Birnstein, Zohlenwerte und Funktionen aus Physik, Chemie, Astronomie, Geophyik und Technik, Sechste Auflage, unter vorbereitender Mitwirkung von J. D'Ans, A. Eucken, G. Joos, W. A. J. Phys. Chem. Ref, Data, Vol. 13, Suppl 1, 1984 Roth, herausgegeben von J. Bartels, H. Borchers, P. Ten Broggencate, HL, Hausen, KH. Hellwege, Kl. Schifer, E. Schmidt, Il. Band, igenschaften der Materie in Ihren Aggregatzustinden, 4. Teil, Kalorische Zastandsgrsten, herausgegeben von KI. Scher, and E. Lax, Springer-Verlag, Berlin. Gottingen Heidetberg, (1961). *Y, S, Touloukian and T. Makita, Specific Heat of Nonmetallic Liulds ‘and Gases, 6, in Thermophysical Properties of Matter, Plenum Press, New York, NY (1970) °Y. S. Touloukian and T. Makita, Specific Heat of Nonmetallic Liguids and Gases in Thermophysical Properties of Matter, Supplement 0 6, Plenum Press, New York, NY (1976) E.G. Smith and P. A. Baker, Editors, The Wiswester Line-Formula ‘Novation, 3rd Eaition, Chemical Information Management, Inc. Cherry Hill, NJ (975). "IN, E, Holden, Pure App. Chem $2, 2349-2384 (1980). 3B, A. Hil, J. Amer. Chem. Soc. 22, 478-494 (1900) P, Bhrenfest, Proc. Amsterdam Acad. 36, 183-157 (1933)c HEAT CAPACITIES AND ENTROPIES OF ORGANIC COMPOUNDS 9 © MIAC/PAR Graphite; Carbon, graphite Heat Capacity 2955K, C, = 2031 cabmor\K* 8498 Jot 'K" “Temperature range 93-294 K. Value is unsmoothed experimental datum. Entropy 2BIK, $= 136 cabmolK" 5.69 Jmol'K Extrapolation below 90 K, 0.182 ealmol-K" Molecular Weight 12.0110 Wiswesser Line Notation C Evaluation A(C).B(S) ‘Acheson No. 38 graphite © sarrT Diamond; Carbon, diamond Heat Capacity 28796K, C, = 1.355 calmolK* 5669 Jmol 'K" “Temperature range 70-288 K. Value is unsmoothed experimental datum. Entropy DISK, S$ = 0885 cabmorK" 2.488 Jmol 'K* Extrapolation below 70.8 K, 0.0077 cal-mol”-K". Molecular Weight 12.0110 Wiswesser Line Notation C Evaluation A(C).B(5) © SSDES/TYL Graphite, Acheson; Carbon, graphite Heat Capacity 298.15K, | C, = 2.038 calmol\K 5527 Jmol." ‘Temperature range 13-300 K Entropy 2RISK, S = 1372 calmorK" 5.740 Jmol." Molecular Weight 120110 Wiswesser Line Notation C Evaluation A. © SSDES Graphite; Carbon, graphite Heat Capacity 298.15K, C, = 1.874 cabmol.K* 7841 Jmol-K" ‘Temperature range 17-300 K Entropy 29BISK, S$ = 12895 calmol 5.3953 Jmol "K* ‘Molecular Weieht 12.0110 ‘Wiswesser Line Notation C Evaluation A © STDES/TYL, Graphite, Acheson, irradiated; Carbon, irradiated graphite Heat Capacity 298.15K, CG, = 2.136 calmol-K" 18937 Jmol 'K" ‘Temperature range 13-300 K Entropy RISK, $= 1492 calmot"K" 6283 Jmol 'K" Molecular Weight 12.0110 Wiswesser Line Notation C Evaluation A ‘Stored energy of about 475 cal g” c . Table of Heat Capacities, Entropies, and Phase Transition Properties © S8DES/MOR Diamond; Carbon, diamond Heat Capacity 277.68, C, = 1.2686 calimol-K* 5.3078 J-mol-K"" ‘Temperature range 13-277 K. Value is unsmoothed experimental datum. Entropy 100.00K, = 00172 calmot\K"t 0.0720 Fmot-K" Agreement with DeSorbo (1953) data above 100 K. Molecular Weight 120110 Wiswesser Line Notation C Evaluation A. © avic Diamond; Carbon, diamond Heat Capacity 298.15K, C, = 1462 calmot Kt 6117 Fob“ ‘Temperature range 273-1073 K ‘Molecular Weight 12.0110 ‘Wiewester Line Notation C Evaluation A © ssmco Graphite; Carbon, graphite Heat Capacity 300K, G, = 208 calmot .K*! 858 Jmol K" ‘Temperature range 298-1723 K Molecular Weight 12.0110 Wieweser Line Notation C Evaluation A ‘Special Spectroscopic Electrode Grade SPK, © TOLUT/VOL Graphite; Carbon, graphite Heat Capacity 298.15K, C, = 2.146 calmotK" 8979 I mot'K" ‘Temperature range 7-320 K Entropy 2RISK, $= 1419 calmol-K* 5937 }morK" extrapolation below $0 K Molecular Weight 12.0110 Wiswesser Line Notation C Evaluation B Prepared by electrode technique from petroleum coke and coal tar pitch. Heat treated at 3000°C. © ‘OLUT/VOL, Graphite; Carbon, graphite Heat Capacity 298.13K, C, = 2.025 calmot"'.K" 8473 JmotK* Temperature range $2-315 K Entropy 2RISK, $= 1.349 calmolK" 5.644 Jmol\K" T extrapolation below $0 K ‘Molecular Weight 12.0110 Wismesser Line Notation C Evaluation B ‘Sample with density 2.0 gem” prepared from petroleum coke and coal tar pitch by heat treatment under pressure at 2400 °C. Density of 2.1 gem” obtained by same process ‘with addition of metal catalysts. Both heat treated at 300°C. ‘J. Phys. Chem. Ref. Data, Vol. 13, Suppl. 1,10 c DOMALSKI, EVANS, AND HEARING ‘Table of Heat Capacities, Entropies, and Phase Transition Properties — Continued © TOLUT/VOL. Graphite, pyrolytic; Carbon, pyrolytic graphite Heat Capacity 298.15K, C, = 1.925 calmolK* 8084 Jmol \K* ‘Temperature range $1-311 K Entropy DRISK, $= 1298 calmorK" 5431 Jmol. ‘T extrapolation below 90K Molecular Weight 120110 ‘Wiswesser Line Notation Evaluation B Prepared by deposition from methane on hot graphite surface (2100 °C). Heat treated at 3000 °C. © TOLUT/VOL. Graphite, natural Taiguinski; Carbon, natural graphite Heat Capacity 298.15K, C, = 1.925 cabmol \K 8056 Jmor.K"* ‘Temperature range $1-311 K Eatropy 29815K, S = 1298 calmor'K* 5431 JmotK™ ‘T extrapolation below 50K Molecular Welght 12.0110 Wieweaser Line Notation C Evahuation—B Values are taken as those of pyrolytic graphite. © TOLUT/VOL. Carbon, baked; Baked carbon Heat Capacty 298.15, C, = 2211 calmol-K* 9251 Jmol" ‘Temperature range 52-302 K Entropy DBISK, $= 1482 calor K" 6201 Jmol \K" ‘extrapolation below 50K Molecular Weight 12.0110 ‘Wawesser Line Notation C Enluation (amor) TOTAK/WES Carbon glasy; Glassy carbon Heat Capacity 298.15K,C, = 2.085 calmol-K* 8598 Jmol -K" ‘Temperature range $350 K Entropy 985K, 5) = 1406 calmotK" 5883 Senot“K" Values actually $-S, there may be a residual entropy. ‘Molecular Weight 12.0110 Wiswesser Line Notation C Evaluation A. © ‘72SHE/BEL Graphite; Carbon, graphite Hest Capacity 298K, GC, = 1.94 calmor"-K* 8.12 JmolK: “Temperature range 273-3650 K, C, calculated from ‘equation applicable tothe temperature range 273-1000 K. Molecular Welght 12.0110 Wiswesser Line Notation C Evaluation B J. Phys. Chom. Ret, Data, Vol. 13, Suppl. 1, 1984 co SOTAY/GRO Graphite; Carbon, GPCO graphite Heat Capacity 300K, C, = 2015 calor K* £43 Smo! K Temperature range 300-2400 K ‘Molecolar Weight 12.0110 ‘Wiswesser Line Notation Evaluation A cB, Gig) S9BEN/THO ‘Bromotrichloromethane Heat Capacity 298K, C, = 38.7 cal mot'K* ‘Mean value 25 to $0°C ‘Molecular Weight 198.2740 Wiewesser Line Notation GXGGE Evaluation C ao, © 39FRE/HIL ‘Tetrabromomethane; Carbon tetrabromide Heat Capacity 298K, C, = 35.0calmol K" 148.4 Imot'K* ‘Temperature range 298-423 K Phase Changes elie 3200K, AH = 1420 calmol* 5941 Jmot! AS = 4.44 cabmol-K"* 18.57 JmotK" liq 362K, AH = 945 calmol 3954 Jmol" AS = 2.60 calmolK* 1089 ImorK* ‘Molecular Weight 31.6270 ‘Wiswesser Line Notation EXEEE Evaluation B or, ©) S6MAR/STA ‘Tetrabromomethane; Carbon tetrabromide Heat Capacity 306K, C, = 30.75 calmot\K 128.66 Smol\K" ‘Temperature range 22 t0 84°C Phase Changes ell/ed 3200K, AM = 159¢calmot! 6669 Fmot AS = 498 cal mol KC 20.84 Jmol-K"! Molecular Weight 331.6270 Wiswesser Line Notation EXEEE. Evaluation B CBr, Gig) 48KUR ‘Tetrabromomethane; Carbon tetrabromide Heat Capacity 373K, G, = 388 calmor.K 162.3 Jmol“ Temperature range 960 182°C, mean C, thee temperatures Molecular Weight 331.6270 Wiswesser Line Notation EXEEE Evahation =D car, dig SIBUF/FLE Dichlorodifluoromethane; Freon 12 Heat Capacity 290K, C, = 303 calmot'K* 1268 Jmol K" Heat capacity measured at 230 K and 290 K using two different methods. C, at 230 K is 25.4 calamot -K" Molecular Weight 120.9138 Wiswesser Line Notation GXGFF Evaluation = CHEAT CAPACITIES AND ENTROPIES OF ORGANIC COMPOUNDS "1 ‘Table of Heat Capacities, Entropis, and Phase Transition Properties — Continued cao ig) ‘Carbonyl chloride; Phosgene Heat Capacity 280K, C, = 2409 calmot.K"" 100.79 Jmot-K" 48GIA/ION ‘Temperature range 15-280 K Entropy 201K, $= 4735 cal-mot'K* 198.11 mor K"! AA value of Sof 1.63 cal-mot"'K" has been added to the calorimetric value of Son-So- Phase Changes efiiq 14837K, AH = 1371 cabmol 5736 Jmol! AS = 9.43 calmol.K"! 39.46 J-mol-K"! lig/g 280.71K, AH = 5832.calmot" 24401 Jmol AS = 2078 calmot"s 36.93 Jmol K" P= 101325 kPa ‘Molecular Weight 98.9164 ‘Wiswesser Line Notation GVG Evaluation =A. cao (ig OGIA/OTT ‘Carbonyl chloride; Phosgene Heat Capacity 160.55K, C, = 24.62 calmol-K"" 102.59 ImotK* ‘Temperature range 13-160 K. Valve is unsmoothed experimental datum. Entropy 280.76 K, $= 46.08 calmoK" 192.80 fmol“ Data for liquid from 48G1A/JON Phase Changes ell ig 139.19K, AW = 1131 calor! 4732 Jmol? as ollig 14209K, AW = 1335 cal-mot! $886 Imot AS = 9.40 calmot"K* 39.31 Jmol\K oltiq 14537K, AH = 1373 calmor! 3743 Jmol AS = 9.4 calmol.K"! 39.52 Jmol \K Molecular Weight 98.9164 Wiewesser Line Notation GVG Evaluation A. car Gig) s0BEN/MCH Fluorotrichloromethane; Freon 11 Heat Capacity 298.15K, C, = 30.28 calmol\K* 126.7 Jmol ‘Temperature range 261-347 K, Data calculated from equation. ‘Molecular Weight 137.3684 ‘Wiawesser Line Notation GYGGF Evaluation B car Gig) 4108B/GAR ‘Fluorotrichloromethane; Freon 11 Heat Capacity 298.15K, C, = 2905 calmol'\K* 121.55 Jmol-K" ‘Temperature range 15-290 K. Value for saturated liquid. Entropy DRISK, S = 5392 calmolK* 225.60 Jmol -K"! ‘Value for saturated liquid Phase Changes hig 162.68K, AH = 1647.6 calmot 6693.6 Fol" as lig’ 29040K, AH 25209 Jmol" AS = 2075 calmot" 8681 Jmol-K? P= 9033 ka Molecular Weight 137.3684 Wiewesser Line Notation GXGGF Evaluation A. © ‘TATA/CHI ‘Tetrachloromethane; Carbon tetrachloride Heat Capacity 46K, C, = 10.57 calmot"-K" 4422 Jmol -K" ‘Temperature range 3-46 K, “Molecular Weight 153.8230 Wiswesser Line Notation GXGGG Evaluation =A. Gig) 2LAT ‘Tetrachloromethane; Carbon tetrachloride Heat Capacity 290K, C, = 320calmol 1339 Jmol -K" ‘Temperature range 39.1-290 K Entropy 298K, S$ = 49.1 calmol\K* 205.4 J.mol\K" Phase Changes oll/e 246K, AH = 1100 calmot 4600 I:mor* AS = 49calmol’K! 205 Jmol-K"! liq 249K, AH = 644 calmot! 2694 Jmol! AS = 26calmol.K" 1038 Jmol-K"* ‘Molecular Weight 153.8230 Wiswesser Line Notation GXGGG Evaluation B ig) 24WIL/DAN ‘Tetrachloromethane; Carbon tetrachloride Heat Capacity 303K, C, = 30,8 calmof.K" 1289 SmorK" ‘Temperature range 303-330 K, equation only. Molecular Weight 153.8230 Wiswesser Line Notation GXGGG Evaluation = C Giay 25WIL/DAN ‘Tetrachloromethane; Carbon tetrachloride Heat Capacity 2952K, Cy = 30. calmot"K* 1280 Jamot.K"! ‘Temperature range 20 0 50°C ‘Molecular Weight 1538230 Wiswesser Line Notation GXGGG Evaluation B J. Phys. Chem. Ret. Data, Vol. 13, Suppl. 1, 196412 DOMALSKI, EVANS, AND HEARING ‘Table of Heat Capacities, Entropies, and Phase Transition Properties — Continued ca, lia) SORIC/WAL, ‘Tetrachloromethane; Carbon tetrachloride Heat Capacity 2981K, C, = 3.2calmol\K* 1305 FmotK ‘Temperature range 293-323 K Molecular Welght 153.8230 Wewesser Line Notation GXGGG Evaluation C ca, ig) 33 KOL/UDO ‘Tetrachloromethane; Carbon tetrachloride Heat Capacity 283K, C, = 302 calmol\K" (One temperature Molecular Weight 153.8230 Wieweaser Line Notation GXGGG Evaluation C ca ia) 34KOL/UDO 2 ‘Tetrachloromethane; Carbon tetrachloride Heat Capacity 2833K, C, = 30.2calmotK* 1264 Jmol -K"* ‘One temperature ‘Molecular Weight 153.8230 ‘Wiswesser Line Notation GXGGG Evaluation C ca, dig) s7sTu ‘Tetrachloromethane; Carbon tetrachloride Heat Capacity 298.1K, C, = 31.70cabmol\K" 132.63 mor -K" ‘Temperature range 90-320 K Eatropy 2081K, $= $24.cabmotK" 219.2 Jmol K* Extrapolation below 91 K; 17.76 cal:molK" Phase Changes ell/ed 22563K, AH = 1100 calmot 4602 Jmol! AS = 4.88 calmol.K"* 2640 Jmol K+ ellig 25037K, AH = $81 calmol* 2431 Jmol AS = 232 calmor/K" 9.71 Jmol'K" ‘Molecular Weight 153.8230 ‘Wiswesser Line Notation GXGGG Evaluation B(C),C(S) ca, dig) 37V0L ‘Tetrachloromethane; Carbon tetrachloride Heat Capacity 298K, G, = 31.8 calmol"K" 133. FmolK" (One temperature Molecular Weight 153.8230 Wiewesser Line Notation GXGGG Evaluation B ca, Gig) 39PHI ‘Tetrachloromethane; Carbon tetrachloride Heat Capacity 3012K, GC, = 31.8 calmolK* 133.1 mot" (One temperature ‘Molecular Weight 153.8230 ‘Wiswester Line Notation GXGGG Evaluation C J. Phys. Chem. Ref. Data, Vol. 13, Suppl. 1, 1984 ca, cig sizHD ‘Tetrachloromethane; Carbon tetrachloride Heat Capacity 281K, C, = 31.6 calmol'K" 1322 Jmol." ‘Temperature range 5 to 46°C Molecular Weight 153.5230 Winwesser Line Notation GXGGG Evaluation C cay tig) ssHIC700 ‘etrachloromethane; Carbon tetrachloride Heat Capacity 298.15K, C, = 3147 calmol\K" 131.67 mot" “Temperature range 15-300 K Entropy DWRISK, S = $1.25 calmol'K* 21439 Jmol -K"! Phase Changes ole 225.38K, AH = 1095 calmot 4582 Jmol"! AS = 46calmolK" 20,33 Jomor-K"! oiq 2503K, AH = 601 calmol* 2515 Jmol" AS = 2.40 calmot"-K* 1005 Jmol -K-* ‘Molecular Weight 153.8230 ‘Wiswesser Line Notation GXGGG Evaluation A ca ai 48KUR Tetrachloromethane; Carbon tetrachloride Heat Capacity 298K, CG, = 30,8 calmot XK" 1288 Jmol ‘Temperature range -20 to 72°C, mean C, four temperatures. Molecular Weight 153.8230 Wiewesser Line Notation GXGGG Evahation =D ca, ig) SsSTA/TUP ‘Tetrachloromethane; Carbon tetrachloride Heat Capacity 298K, C, = 31.69 calmol\K" 132.59 mot -K* Temperature range 295-339 K ‘Molecular Weight 153.8230 ‘Wiswesser Line Notation GXGGG Evaluation B coy iy STHAR/MOE. “Tetrachloromethane; Carbon tetrachloride Heat Capacity 300K, C, = 31.29 calmot".K* 1309 JmolK* “Temperature range 243-303 K Molecular Welght 153.5230 Winmesser Line Notation GXGGG Eraluation —— B cy ig) STRAS/OAN ‘Tetrachloromethane; Carbon tetrachloride Heat Capacity 293K, G = 31.AcalmotK" 1318 JmolK" ‘Temperature range 293-333 K ‘Molecular Weight 153.8230 ‘Winwesser Line Notation GXGGG Evaluation CHEAT CAPACITIES AND ENTROPIES OF ORGANIC COMPOUNDS 13 ‘Table of Heat Capacities, Entropies, and Phase Trans ca, Gig) TIDES/BHA ‘Tetrachloromethane; Carbon tetrachloride Heat Capacity 298K, C, = 31.3 calmol-K* 1310 Fmor'K" ‘Temperature range 298-318 K ‘Molecular Weight 153.8230 Wiswesser Line Notation GXGGG Evaluation B ca, dia) 72ARE/MIL, ‘Tetrachloromethane; Carbon tetrachloride Heat Capacity 25610K, C, = 31.5 calmolK" 131.8 Jmol K* ‘Temperature range 243-256 K. Valve is unsmoothed experimental datum. Phase Changes lig 248.70K, AH = 442 calmnol 1848 Jmol” AS = 180.cabmol.K* 1132 Smal elig 25028K, AH = 611 calmot* 2558 Jmol AS = 244 calmorK" 10.22 Fmot stable phase Molecular Weight 153.8230 Wiswesser Line Notation GXGGG Evaluation A ca, Gig) 738UB/RAS Tetrachloromethane; Carbon tetrachloride Heat Capacity 296.15K,C, = 31.3 calmot“X! 130.8 mol" “Temperature range 298-323 K “Molecular Weight 153.8230 Wiswesser Line Notation GXGGG Evaluation -B coy iy 75GRO/BEN “Tetrachloromethane; Carbon tetrachloride Heat Capacity 298.18K, C= 31.82 ealmor-K" 131.9 Jmol" One temperature Molecular Welght 153.8230 Winwesser Line Notation GXGGG Evaluation B cy Gi) 16FOR/BEN ‘Tetrachloromethane; Carbon tetrachloride Heat Capcity 29818K,C, = 31.40 calmot-K* 13136 Smo" One temperate Molecular Weight 153.230 Wiawesser Line Notation GXGGG Evaluation B cc, tig) T9WIL/FAR ‘Tetrachloromethane; Carbon tetrachloride Heat Capacty 298.15K, C= 31.40 calmol“K: 131.36 Jmol" One temperature ‘Molecular Weight 153.8230 ‘Wiawesser Line Notation GXGGG Evaluation B ca, cig) 8 Properties — Continued 19GRO/HAM ‘Tetrachloromethane; Carbon tetrachloride Heat 315 calmolK 131.6 Fmt" Capacity 298.15K, C, (One temperature Molecular Weight 153.8230 Wiswesser Line Notation GXGGG Evaluation B ca, a tia) S2TAN ‘Tetrachloromethane; Carbon tetrachloride Heat Capacity 298.15K, C, = 31.39 calmol 131.34 Jmol ‘Temperature range 293.15, 298.15, 303.15 K, Data at three temperatures. Molecular Weight 153.8230 Wieweaser Line Notation GXGGG Evaluation A. ae, tia 9SMI/PAC2 Tetrafluoromethane; Carbon tetrafuoride; Freon 14 Heat Capacity 145K, CG, = 19.14 calmot * © $0.08 Jmol .K"! ‘Temperature range 12-145 K, See also 69SMI/PAC. Estropy MS12K, S$ = M41 calmol'K? 143.97 Jmol K* Phase Changes ele 627K, AH = 408.5 calmot 1709.2 5-mot AS = 5.36 cabmor" 2241 Jmol" liq 8956K, AH = 1702 cabmot" 7121 Jmol AS = 1.90 calmol.K? 7195 Jmol'K" lia/e 145.12K, AH = 2823.6 calmol" 1814 mot" AS = 19.46 calmot"'K* 81.41 JamorK" P= 101325 kPa ‘Molecular Weight 88.0046 Wiswesser Line Notation FXFFF Evaluation A CuBr, ia) 32TRE ‘Tribromomethane; Bromoform Heat Capacity 298K, C, = 32.3 calmol XK" 135.1 Jmol “K* (One temperature “Molecular Weight 252.7309 Wiewesser Line Notation EYEE Evaluation B cum, Gig) 48KUR ‘Tribromomethane; Bromoform Heat Capacity 298K, CG, = 31.2 calmolK" 1305 mot" ‘Temperature range 9 to 147°C, mean C, four temperatures. ‘Molecular Weight 252.7309 Wiswesser Line Notation EYEE. Evaluation —-D J. Phys. Chem. Ret. Data, Vol. 13, Suppl. 1, 196414 DOMALSKI, EVANS, AND HEARING ‘Table of Heat Capacities, Entropies, and Phase Transition Properties — Continued CHAR, Gig) 40BEN/MCH ‘Chlorodifluoromethane; Freon 22 Heat Capacity 298.15K, CG, y= 2727 ealemol 114.10 Jamol-K"* ‘Temperature range 256-328 K, Data calculated from ‘equation. ‘Molecular Weight 86.4687 ‘Wirwesser Line Notation GYFF Evaluation = B cHCR, Gia) STNEL/WHL CChlorodifluoromethane; Freon 22 Heat Capacity 232.50, C, = 22.23 calmol’.K"! 93.01 Jmol ‘Temperature range 16-230 K Entropy 23250K, $= 43.00calmot"'K" 179.91 SamolK* Phase Changes ell/ed 59K, AH = 16 calmer! 67 mot" AS = 0.27 calmol “K"! 114 Jmol. Actype transition lig 11573K, AH = 9855 calmol* 41233 Jmol AS = 852 calmotK" 35.63 Jmol-K" lig/e 232.50K, AH = 4832 calmo! 20217 mor! AS = 2078 calmotK* 8695 Jmol-K P= 101.325 kPa ‘Molecular Weight 86.4687 Wiswesser Line Notation GYFF Evaluation A CHAE Gig) 40BEN/MCH Dichlorofluoromethane; Freon 21 Heat Capacity 298.15K, CG, = 112.6 Fmot"-K* ‘Temperature range 261-338 K, Data calculated from equation, ‘Molecular Weight 102.9233, Wiswesser Line Notation GYGF Evaluation B CHa, Gig) 24WIL/DAN ‘Trichloromethane; Chloroform Heat Capacity 303K, C, = 27.9 calmol K* 116.7 Famot 'K* Temperature range 295-315 K, equation only. ‘Molecular Weight 119.3779 ‘Wiswesser Line Notation GYGG Evaluation C cHa, Gig) 25WIL/DAN “Trichloromethane; Chloroform Heat Capacity 2932K, C, = 27.6calmol"K" 115.3 Jmor'K" ‘Temperature range 20 10 50°C. Molecular Weight 119.3779 ‘Wiswesser Line Notation GYGG Evaluation B J. Phys. Chem. Ret. Data, Vol. 13, Suppl. 1 cHa, Cig) Trichloromethane; Chloroform cue, Heat Capacity RIK, SG S2RIC/WAL = 210 calmotK* 113.0 5mot\K" ‘Temperature range 293-323 K ‘Molecular Weight 119.3779 ‘Wiswesser Line Notation GYGG Evaluation big) c ‘Trichloromethane; Chloroform Heat Capacity 3036 K, (One temperature ‘Molecular Weight 119.3779 ‘Wiswesser Line Notation GYGG Evaluation cHa, Gig) “Trichloromethane; Chloroform Heat Capacity c 298K, G G 39PHI 334 calmol.K 139.7 Jmol -K 4#8KUR = 280 calmolK" 17 Emo K* ‘Temperature range -52 to 51°C, mean C, four temperatures. Molecular Weight 119.3779 ‘Wiswesser Line Notation GYGG Evaluation cHa, Cig) ‘Trichloromethane; Chloroform cua, D SSSTA/TUP Heat Capacity 298K, Cy = 27.29 calmol"\K* 114.18 SamolK? ‘Temperature range 284-329 K Molecular Weight 119.3779 Wiswesser Line Notation GYGG Evaluation B di STHAR/MOE, ‘Trichloromethane; Chloroform Heat Capacity 300K, C, = 27.11 cabmot" 113.4 Fmot=K: ‘Temperature range 243-303 K ‘Molecular Weight 119.3779 ‘Wiswesser Line Notation GYGG Evaluation cia, ia) ‘Trichloromethane; Chloroform cur, Heat Capacity B 290K, G GTRAS/GAN 27.8 calmol“K* 1162 Jmol ‘Temperature range 283-333 K Molecular Weight 119.3779 Wiswesser Line Notation GYGG valuation co) c ®2VAL/BRO “Trifluoromethane; Fluoroform; Freon 23 Heat Capacity 190.97 K, G = 20.6 calmol 86.46 Jmol -K- ‘Temperature range 15-190.97 K Entropy 19097 K, s = 36.10 calmor'K* 151.08 J.mol'K*HEAT CAPACITIES AND ENTROPIES OF ORGANIC COMPOUNDS 15 Table of Heat Capacities, Entropies, and Phase Transition Properties — Continued Phase Changes fig NIT9TK, AH = 970.calmot 4058 J-mol" AS = 822 calmot'K" 34.40 Jmol \K° lig’ 19097K, AM = 3994 calmot 16711 Jamot" 2091 calmolK- 87.50 Jmol -K" P= 101.325 kPa ‘Molecular Weight 70.0141 ‘Wiswesser Line Notation FYFF Evaluation A. CHO, © 7SFER/SAN “Lithium formate Phase Changes ell/ed 496K, AH = 430calmol" 1800 Jmol" AS = 087 calmol-K" 3.6 Jmol -K" elfiq S46K, AM = 3870 calmol 16190 J-mot AS = 7.1 cabmol”.K" 29.7 mol-K* Molecular Weight 51.9587 Wiswesser Line Notation VHO LI Evaluation HN Gig) S9GIA/RUE Hydrogen cyanide Heat Capacity 300K, C, = 1697 cabmol 71.00 Smol-K" ‘Temperature range 15-300 K Entropy 29886K, $= 2701 calmol hk: 11301 Smot.K* Phase Changes near 170K, AW = 3.8 calmol” 159 Jmol" AS = 0022 cal-molK" (0.092 Jmol 'K"" Second order transition hig 25890K, AM = 2009 calm! 3406 Jmol" AS = 173 calmot"K* 32.34 mot." li’s Q8SK, AH = 6027 ealmol! 25217 Smet AS = 20.17 calmot"K* 16.38 Jmol" P= 101325 kPa Molecular Weight 27.0256 ‘Wiawesser Line Notation NCH Evaluation A a) cowes/CHA Sodium formate Heat Capacity 298.15K, C, = 19.76 calmol\K" 87.68 Fmt" ‘Temperature range 350 K Entropy 29813K, $= 24.60calmot.K! 103.76 Jmol \K" Molecular Welght 68.0075, ‘Wiawesser Line Notation VHO.NA Evaluation A CHM, ©) ‘Sodium formate Heat Capacity 340K, 883 Jmol K" ‘Temperature range 340-560 K ‘Molecular Weight 68.0075 ‘Wiswesser Line Notation VHO NA Evaluation B CHORD ©) {1SFER/SAN ‘Rubidium formate Phase Changes ell/ed 368K, AH = @calmot! 250 3mot! AS = 0.16 calmot' 07 Fork" ‘Molecular Weight 130.4855 ‘Wiswesser Line Notation VHO RB Evaluation C cH, © Polyethylene; Marlex $0 polymer Heat Capacity 298.15K, C, = 6283 cabmot"K" 62DAVEVA 3 26.29 Smol-K ‘Temperature range 20-310 K, Data for “Marlex 50” (low pressure) polythene, Entropy 29815K, $= $907 calmot-K* 24,72 Jmol K" Molecular Weight 14.0268 ‘Wiswesser Line Notation /*1*/ Evaluation =A CH, © @2DAVEVA3 Polyethylene; Rigidex 50 polymer Heat Capacity 29815K, C, = 6219 calmorK* 2602 Jmot'K" “Temperature range 20-310 K, Data for “Rigdex 50° (ow pressure) polythene. Entropy 2981SK, $= 5.863 calmot.K" 2453 Jmot'K" Molecular Welght 14.0268, ‘Wiawesser Line Notation *1*/ Evaluation A cy, © @Davevas Polyethylene; W.N.C. 18 polymer Heat Capacity 298:15K, CG, = 7.761 calmolK* 3247 Jmol" “Temperature range 90-300 K, Data for “W.N.C. 18° (high pressure) polythene, Entropy DRISK, $= 622 cabmot'\K* 2602 Jmol 'K"* Data extrapolated from 90 K. Molecular Weight 14.0268 Wiswesser Line Notation /*1*/ Evaluation A ay, © 6sWUN Polyethylene; Marlex $0 polymer Heat Capacity 298.15K, C, = 5.23 cabmol\K"" 21.88 Jmol “Temperature range 180-410 K. Valves per gram formula weight. ‘Molecular Weight 14.0268 ‘Wiswesser Line Notation /*1*/ Evaloation A ‘99% Crystallinity, extrapolated to 100%, Number-average ‘molecular weight, 9800, weight-average = 130000. J. Phys. Chem. Ret. Data, Vol. 13, Suppl. 1, 198416 DOMALSKI, EVANS, AND HEARING ‘Table of Heat Capacities, Entropies, and Phase Transition Properties — Continued a, © TCHA/BES Polyethylene, branched Heat Capacity 298:15K, C, = 7.22 calmotK’ 3020 Jmol -K" “Temperature range 2-360 K. Values per unit formula weight Eawopy—-2981SK, $= 619 calmol'K"! 2591 Seno K" Values are $5, Molecular Weight 140268 ‘Wiswesser Line Notation /*1*/ Evasion A Branched polyethylene, SRM 1476, Density 09247 gem” at 23°C Hy, © 73CHA/BES Polyethylene, branched, annealed Heat Capacity 298.15K, C, = 723 calmot'K*! 30.26 J mol-K" ‘Temperature range 2-360 K Entropy RISK, Values are $-S, Molecular Weight 14.0268 ‘Wiawesser Line Notation /*1*/ Evaluation A. Branched polyethylene, SRM1476, annealed. Density 0.9272 gem’ at 23°C. on, © TACHA/BES. Polyethylene, linear Heat Capacity 298.15K, CG, = 6.14 calmolK* 25.68 Jmol "K- “Temperature range 2-360 K. Values per unit formula Entropy 9BASK, $= 5.86 calmol“K* 2452 Jmol“ Values are $5, Moleenlar Weight 14.0268 Wiswesser Line Notation /*1*/ Evaluation A Linear polyethlene, SRM 1475. Dens 23°C cH, © THCHA Polyethylene linear high density Heat Capacity 298.18K, C= S40 calmot\K" 22.60 Jmol “K"! ‘Temperature range $-360 K. Value per monomer unit Entropy 298.15K, $= 3.30 cabmot"K* 2302 Jmol" Value per monomer wnit. SS. ‘Molecular Weight 14.0268 ‘Wiswesser Line Notation /*1*/ Evaluation A Extrapolated to 100% crystal samples. ty, from data on other J. Phys. Chem. Ret. Data, Vol. 13, Suppl. 1, 1984 cH, © Polyethylene, linear high density Heat Capacity 298.15K, CG, 14CHA = 5.49 calmot-K* 22.98 Jmol"K* “Temperature range 3-360 K. Value per monomer unit. Entropy DRISK, $= $.5Scalmol\K* 23.22 Jmol Value per monomer unit. SS, Molecular Weight 14.0268 Wiswesser Line Notation /*1*/ Evaluation A. Density 0.93 gem” at 23°C. Pressure crystallized. ay, © TACHA Polyethylene, linear high density Heat Capacity 298.15K,C, = 873 calmol-K" 23,96 Fmot "K" ‘Temperatare range 5-360 K. Value per monomer uni Entropy 2981SK, $= 565 calmol"-K" 23.64 Jot." Value per monomer unit. $-,. Molecnlar Weight 14.0268 Wiswesser Line Notation /*1*/ Evaluation A. Density 0981 gem” at 23°C. Slow-melt crystallized cH, © 7SCHA/WES Polyethylene, branched, DYNH CT-1660 Heat Capacity 298.15K, C, = 7.70 calmol\K* 32.20 Jamot"K"! ‘Temperature range $-350 K. Values per CH, unit Entropy DBISK, $= 630calmol"K" 2637 Jamol-K- Does not include zero-point entropy. ‘Molecular Weight 14.0268 ‘Wiswesser Line Notation /*1*/ Evaluation =A Branched polyethylene density 091g.em” oH, © TSCHA/WES Polyethylene, linear, Marlex 50 polymer Heat Capacity 29815K, C, = 5.92 calmol\K* 24.19 Jmol'K" ‘Temperature range 5-350 K. Values per CH, unit Entropy DRISK, S = 3.73 cabmol*K" 24.08 Jmol K" Does not include zero-point entropy. ‘Molecalar Weight 14,0268 ‘Wiswesser Line Notation /*1*/ Evaluation A. Linear polyethylene, density 0.973 gem” CH. © T6CHA Polyethylene, linear high molecular weight Heat Capacity 2981SK, C, = 597 calmol\K* 2497 Smot'K" ‘Temperature range $-380 K. Value per monomer unit. Entropy QAISK, S = 527 calmolK" 22.08 JmolK" Value per monomer unit. $S,- ‘Molecular Weight 14,0268 ‘Wiswesser Line Notation /*1*/ Evaluation A. Produced by Ziegler-type vapor polymerization. Molecular weight 27-30 x 10%. Approximately 45% crystalline. Data for quenched sampleHEAT CAPACITIES AND ENTROPIES OF ORGANIC COMPOUNDS 7 ‘Table of Heat Capacities, Entropies, and Phase Transition Properties — Continued ap, ig) ‘Dibromomethane; Methylene bromide Heat Capacity 298K, C, = 304 calmol"s 1272 Jmol ‘Temperature range -22 to 98 °C, mean C,, four temperatures. Molecular Weight 173.8348 Wiewesser Line Notation EIE Evaluation D CHB, Cig) STHAR/MOE, ‘Dibromomethane; Methylene bromide Heat Capacity 300K, C, = 25.17 cabot \K"* 103.3. FmotK" “Temperature range 243-303 K Molecular Weight 173.8348, ‘Wiswesser Line Notation E1E Evaluation B cH, Cig) S7PER Dichloromethane; Methylene chloride Heat Capacity 292.5K, C, = 241 cab 100.8 JmorK" ‘Temperature range -$8 to 19°C. Value is unsmoothed experimental datum. ‘Molecular Weight 4.9328 Wiswesser Line Notation GIG Evaluation B cH, Gig) SPER 2 Dichloromethane; Methylene chloride Heat Capacity 292.3K, CG, = 240 calmolK" 10:5 Fmot"-K* ‘Temperature range -$8 to 19°C. Value is unsmoothed ‘experimental datum. Molecular Weight 84.9328 Wiswesser Line Notation GIG. Evaluation B cA, Gia) 40RIE ichloromethane; Methylene chloride Heat Capacity 298.1K, GC, = 239 calmol"K* 100.0 F¢mot"-K* ‘Temperature range -47 to 41°C Molecular Weight 84,9328 Wiswesser Line Notation GIG Evaluation =A. cH, Cig) IRIE Dichloromethane; Methylene chloride Heat Capacity 298K, C, = 239 calmolK* 100.0 Fmot"-K* ‘Temperature range -47 to 41 ‘Molecular Weight 84.9328 ‘Wiawesser Line Notation GIG Evaluation A. CHA, Cig) 48KUR Dichloromethane; Methylene chloride Heat Capacity 298K, C, = 309 calmol"-K" 129.3 FmotK" ‘Temperature range -76 to 41 °C, mean G, four temperatures. Molecular Weight 849328 ‘Wiswesser Line Notation GIG Evaluation =D aH, i) 48KUR ‘Ditodomethane; Methylene iodide Heat Capacity 298K, C, = 320calmol“K* 1339 Jomot-K! “Temperature range 1210 164°C, mean C, three temperatures. “Molecular Weight 267.8358 Wiswesser Line Notation 111 Evaltion Ho, © SeDALAVE Polyorymethylene Heat Capacity 300K, C= 8.1 calmot.K* 339 Jmol K" “Temperature range 300-333 K, mean value. Vale per monomer unit Molecular Weight 300262 Wiawesser Line Notation “01*/ Evaluation B ° 2DAVEVA Polyorymethylene Heat Capacity 300K, G, = 1023 calmolK* 42.79 Jmol" ‘Temperature range 20-300 K, Data given for Delrin. Data also given for trioxan copolymer where C,(300 K) = 9.83 calmol, 41.11 JmorK" Entropy 30K, S = 1067 calmer" 44.65 Jmol -K"! ‘Temperature range 20-300 K, Data given for Delrin. Data also given for trioxan copolymer where S(300 K) = 10.33 calmol”-K", 43.21 Jmol UK" ‘Molecular Welght 30.0262 Wiewesser Line Notation /*O1*/ Evaluation A. HO, Gig) SIRE ‘Methanoie acid; Formic acid Heat Capacity 298 K, = 228 calmot 95.6 Jmol'K ‘Temperature range 291-385 K Molecular Weight 46.0256 ‘Wiewesser Line Notation VQ Evaluation —-D HO, Cig) 20G1B/LAT ‘Methanoic acid; Formic acid Heat Capacity 291.5 K, = 235 calmot"'K* 98.3 Jmol" ‘Temperature range 71-292 K. Valve is unsmoothed experimental datum, Entropy 28K, S 342 calmotK* 143.1 Jmol -K Used Berthelots value, 2420 cal-mol" for AH fusion. Extrapolation below 70 K, no details. Molecular Weight 46.0256 Wiewesser Line Notation VHQ Evaluation B(C).C(S) HO, Gig) Methanoic acid; Formic acid Entropy 281K, Ss Extrapolation below 90 K, 7.1 calol.K". Revision of previous data. ‘Molecular Weight 46.0256 ‘Wiewesser Line Notation VHQ Evaluation = C J. Phys. Chem. Ret. Data, Vol. 13, Suppl. 1, 198418 DOMALSKI, EVANS, AND HEARING ‘Table of Heat Capacities, Entropies, and Phase Transition Properties — Continued HO, Gig) 34RAD/UL “Methanote acid; Formic acid Heat Capacity 290K, C, = 239 calmor'K 100.0 FmotK"* (One temperature Molecular Weight 46.0256 ‘Wiewesser Line Notation VHQ Evaluation = C CHO, Gia) asto/ris “Methanoic acid; Formic acid Heat Capacity 298.1K, C, = 2367 calmol\K"* 99.08 Jmol "K"* ‘Temperature range 15-200 K Entropy 2RISK, $= 31.81 calmot-K" 131.84 SmorK" Includes 0.69 cal mot"-K"! for zero-point entropy. Phase Changes eiq 28140K, AH = 3031 calor! 12678 Fol" AS = 10.77 cal-mot"-K* 4808 Jmol =" Molecular Weight 46.0256 ‘Wiewesser Line Notation VHQ Evaluation = A CHS, ig) SGAT/KRE ‘Dinydrosulfide carbon sulfide; Trthiocarbonie acid Heat Capacity 273K, ‘= 355 calmolK" 146.5 Jmol K" ‘Temperature range -95 to 20°C Entropy 28K, S= S2ealmolK* 218. Fmot-K" Extrapolation below -95°C. Estimated uncertainty 6 ‘eal mol." Phase Changes eiq 2463K, AH = 2010 calmol {410 Jmol AS = 82calmol'K" 34.1 Jmol “Molecular Weight 110.2068 ‘Wismesser Line Notation SUYSHSH Evaluation —-B(C,.D(S) CH,DO ig) “Methanol-dj; Methyl alcohot-< Heat Capacity 270K, C, = 1904 calmol.K 49STA/GUP. 79.66 3mol-K" “Temperature range 90-270 K ‘Phase Changes oll/ed W6LIK, AW = 1558 calmot* 651.9 Jmol" AS = 097 calmorK* 4.05 Jmol. K"! Mig 135K, AH = 726calmot" 3038 Imo! AS = 4.18 calmor.K" 1751 Smor"K" Molecular Weight 33.0682 Wiswesser Line Notation Qt &1H-2 Evaluation = B 4. Phys. Chem. Ret. Data, Vol. 13, Suppl. 1, 1984 cH Gig) ‘Bromomethane; Methyl bromide Heat Capacity 280K, C, = 1884 cabmot" 7883 Jmol 'K" ‘Temperature range 15-280 K Entropy 216T1K, $= 37.08 calmot-K" 155.14 Jmol -K"! Phase Changes ell/ed V7A78K, AH = 113 calmot" 473 mor! AS = 065 calmot"K* 2.72. 3motK" eliq 17947K, AM = 1429 calmot" 5979 Jmol" AS = 7.96 cakmol.K"! 333 Jamol-K lig’ 21671 K, AH = S718 calmot 23912 Jmol" AS = 2065 calmol.K" 36.42 J.molK" P= 101325 kPa Molecular Weight 94.9387 Wiewesser Line Notation El Evaluation A. CHB Gig) 48KUR Bromomethane; Methyl bromide Heat Capacity 283K, C, = 27.4 calmol =k" 1166 Imor-K* ‘Temperature range -67 t0 9°C, mean Cy three temperatures. ‘Molecular Weight 94.9387 Wismesser Line Notation El Evaluation =D CHA tig) 24SHO ‘Chioromethane; Methyl chloride Heat Capacity 298K, C, = 194 calmot-K* 41.2 JmolK" ‘Temperature range -30 to 40 ‘Molecular Weight 50.4877 ‘Winwesser Line Notation G1 Evaluation C cua ig) ‘Chloromethane; Methyl chloride Heat Capacity 293.13K, C, = 193 calmolK" 808 Jmol “K" “Temperature range 243-303 K, C, reported at 20 (0.382 calg”K'" and at 30°C = 0.390 cakg'\K". “Molecular Weight 50.4877 Wiewester Line Notation GI Evaluation B 40AWB/GRI aC Gig) 40MES/AST ‘Chloromethane; Methyl chloride Heat Capacity 249.67K, C, = 1807 calmot 75.60 JmolK" “Temperature range 12-249.67 K. Value is unsmoothed experimental datum. Entropy 24894K, = 3248 calmo-K" 140.08 JmotK"HEAT CAPACITIES AND ENTROPIES OF ORGANIC COMPOUNDS 19 Table of Heat Phase Changes cig 17S48K, AH = 1537 calmot” 6431 Jmot! AS = 8.16 calmot-K" 36.66 Jmol-K"? lige 24894K, AH = 5147 calmot 21835 Jomot™ AS = 2063 cal mol'K* 8651 Jmol“! P= 101325 kPa ‘Molecular Weight 50.877 ‘Wiswesser Line Notation GI Evaluation A ‘Correction in 4OMES/AST 2 CHAFOP Gig) Methyiphosphonyl chloroftuoride Heat Capacity 298.15K, C= 3661 calmol (GAFUR/REL 183.17 FmotK: ‘Temperature range 15-335 K Entropy 2B1SK, S = S172cabmol\K* 216.40 Fmot-K Phase Changes hig 250.10K, AH = 2833 calmot 11883 Jmol" AS = 11.30calmorK" 47.28 Samol Molecular Weight 116.4593 Wiswesser Line Notation OPGF1 Evaluation A CHAP ©) (AFUR/REL Methylphosphony dichloride Heat Capacity 298.15K, CG, = 31.34calmol*K" 131.12 mor ‘Temperature range 15-338 K Entropy 2881SK, $= 3940 calmolK" 164.84 Im Phase Changes hig 306.14 K, AH = 4320 calmot 18076 Jmol" AS = 14.11 calmolK" 59.08 Jamot 4K"! Molecular Weight 132.9139 Wiswesser Line Notation OPGG1 Evaluation A CHLE,OP Gig) (4FUR/REI Methylphosphonyl difluoride Heat Capacity 298.15K, CG, = 3469 calmol.K"! 148.14 Jmot ‘Temperature range 15-335 K Entropy 298ISK, $= 49.79 calmolK" 208.34 Fol" Phase Changes cfg 23634K, AH = 2839 cabot" 11878 mot" AS = 1201 calmolK* 50.26 Jmol "K"! Molecular Weight 100.0047 Wiswesser Line Notation OPFFI Evaluation A pacites, Entropies, and Phase Transition Properties — Continued CHA Gi Todomethane; Methyl iodide Heat Capacity 298K, C, ‘Temperature range -56 to 35, temperatures Molecular Weight 141.9392 Wiewesser Line Notation 11 Evahation —-D a Gig) Todomethane; Methyl iodide Heat Capacity 300K, G, Temperature range 243-303 K Molecalar Weight 181.9392 ‘Wiewesser Line Notation I1 Evaluation B CL dig) Todomethane; Methyl iodide Heat Capacity 298.2, Temperature range 293-308 K Molecular Weight 141.9392 Wiewesser Line Notation 11 Evaluation A. HNO Gig ‘Methanamide; Formamide Heat Capacity 292 K, One temperature ‘Molecular Weight 45.0408 ‘Wiswesser Line Notation ZVH Evaluation —-D HNO Gig) ‘Methanamide; Formamide Heat Capacity 298 K, ‘One temperature Phase Changes fig 21S72K, AH = as = Molecular Weight 45.0408 ‘Wiewesser Line Notation ZVH Evaluation B CHNO Gig) ‘Methanamide; Formamide Heat Capacity 293K, ‘Temperature range 293-373 K Molecular Weight 45.0408 Wiewesser Line Notation ZV Evaluation C CUNO Gig) ‘Methanamide; Formamide Heat Capacity 298.15K, C, = (One temperature Molecular Weight 45 0408 Wiewesser Line Notation ZVH Evaluation A. 48KUR 35.4 calor“ 148.1 Femol K+ STHAR/MOE, 19.76 calmol.K"! 82.68 Jamot kK @LOW/MOE 19.78 calmol.K"! 32.76 JmorK" WAL 25 calmot' 105 Jamot\K" 65S0M/COO 25.7 calmot"“K! 107.6 S-motK" 1907 calmol* "7980 Jmol 692 cal mot"-K* 2898 JmolK GTRAS/GAN 25.1 cabmol-K! 105.2 mol.K"! 74VIS/SOM 25.84 calimotK" 108.11 mor'K" J. Phys. Chem. Ref. Data, Vol. 13, Suppl. 1, 198420 DOMALSKI, EVANS, AND HEARING ‘Table of Heat Capacities, Entropies, and Phase Transition Properties — Continued CHNO Gig) TIVOR/PRI Methanamide; Formamide Heat Capacity 298.15K, C, = 2584 calmot\K" 108.11 mol One temperature Molecalar Welaht 45.0908 Wianeaser Line Notation 2VH Evalation A CHNO, Gia) orwaL ‘Nitromethane Heat Capacity 289K, C, = 25 calmolK* 105 Jmol ‘One temperature Molecular Weight 61.0402 ‘Wiawesser Line Notation WN1 Evaluation =D CH.NO, Gig) ‘Nitromethane Heat Capacity 298K, ‘Temperature range 288-343 K. Equation only. ‘Molecular Weight 61.0402 ‘Wisweseer Line Notation WN1 Evaluation = C CH.NO, Gig) Nitromethane Heat Capacity 298.15K, C, 4TION/G1A. ‘Temperature range 15-300 K Entropy DRISK, $= 41.05 calmorK" 171.75 SmolK* Phase Changes fig 2UATTK, AH = 2319 calmor" 9703 Jmol AS = 9.47 calmot -K* 39.64 Jmol \K" lig’ 29R1SK, AH = 9147 calmot" 38271 Jano! AS = 3068 calmot"-K* 128.36 JsmolK" Po = 499kPa ‘Molecular Weight 61.0402 ‘Wiswester Line Notation WN1 Evaluation A. CHNO, Cig) SOHOU/MAS ‘Nitromethane Heat Capacity 313K, CG, = 260calmot"-K* 108.8 FmorK" ‘Temperature range 313-363 K ‘Molecular Weight 61.0402 Wieweaser Line Notation WNI Evaluation B CLNO, Gig) @BER/WES ‘Nitromethane Heat Capacity 308K, GC, = 25.39 calmol KC" 106.22 5mol\K" “Temperature range 308-873 K, ‘Molecular Weight 61.0402 Wieweaser Line Notation WNI Evauation = B J. Phys. Chem. Ret. Data, Vol. 13, Suppl. 1, 1984 CHNO, Cig) S3GRA/SMI Methyl nitrate Heat Capacity 2982K, C, = 37.57 calmol'\K" Temperature range 13-295 K Entropy 882K, S 216.98 Jmol -K* Phase Changes hig 1902K, AH = 1970calmor" 242 mol AS = 1036 calmot"K* 4933 Jmol “Molecular Weight 7.0396 ‘Wiawesser Line Notation WNO Evaluation A CHNO © SIGRE/WES Sodium methoxide Heat Capacity 298.15K, CG, = 1660 calmolK* 6845 Samol 'K" “Temperature range 3-340 K Entropy RISK, $= 2643 calmol “XK 110.8 Snot -K" Phase Changes "Anomolous region near 34 K with excess enthalpy of 11.5 ‘calaol, excess entropy of 0.43 cal-mol 'K Molecular Weight 54.0239 ‘Wiswesser Line Notation O1 NA. Evaluation =A. CHNO ©) 20G1B/LAT ‘Urea Heat Capacity 2980K, C, = 27.6 calmol-K"" 1155 5mot'K" ‘Temperature range 86-300 K. Value is unsmoothed ‘experimental datum. Entropy 28K, $= Al calmotK" 172. 3.motK" Extrapolation below 86 K, no details. ‘Molecular Weight 60.0554 ‘Wiewesser Line Notation ZVZ Evaluation —B(C).C(S) CHO ©) SBPAR/HUF Urea Heat Capacity 2980K, G, = 22.38 calmorK* 93.64 Jmol -K" ‘Temperature range 93-298 K. Value is unsmoothed experimental datum, Entropy 2981K, $= 252calmol 105.4 Jmol “K"* Extrapolation below 90 K, 7.93 cal mot K". Molecular Weight 60.0554 Wiswesser Line Notation ZZ. Evaluation —B(C).C(S) ano © 40CAM/CAM Urea Heat Capacity 293K, = 164 calmot'K* 68.6 Jmot-K" (One temperature Molecular Weight 60.0554 Wiswester Line Notation ZVZ Evaluation CHEAT CAPACITIES AND ENTROPIES OF ORGANIC COMPOUNDS 2 ‘Table of Heat Capacities, Entropies, and Phase Transition Properties — Continued HNO © 46RUE/HUF Urea Heat Capacity 298.15K, C, = 22.26 calmol'K"* 93.14 JmorK* ‘Temperature range 19-318 K Entropy 298.1SK, $= 2500 calmol.K- 104.60 Jamol"-K" ‘Molecular Weight 60.0554 Wiswesser Line Notation ZVZ Evaluation A. HNO ©) 66SAs/YOK Urea Heat Capacity 298.15K, C, = 21.5 calmot'K* 90.0 Jmol K" ‘Temperature range 90-298 K Molecular Weight 60.0554 Wiswesser Line Notation ZVZ Evaluation A. cuNS ©) TOVAN/WES ‘Ammonium thiocyanate Heat Capacity 298.15 K, 29.98 calmot"K" 1254 Fmot"'K" ‘Temperature range 5-340 K Entropy 2981SK, $= 33.82 calmor hk" 140.2 Fmot'K" ‘Molecular Weight 76.1160 ‘Wiswesser Line Notation NCSH &211 Evaluation =A CHNO, (0) 7BKRI/LIC Nitroguanidine Heat Capacity 298K, CG, = 309 calmolK"! 1293 Imot-K" ‘Temperature range 200-460 K. Equation only. Molecular Weight 104.0682 Wiswesser Line Notation WNMYZUM Evaluation C cho © 2SMAA/WAL ‘Methanol; Methyl alcohol Heat Capacity 173K, C, = 25.calmor'\K* 105 Jmol -K"! ‘Temperature range 93-173 K Phase Changes fig 116K, AH = 525 calmot" 2196 Imo" AS = 30calmolK* 125 bmolK* ‘Molecular Weight 32.0420 Wiewesser Line Notation QI Evaluation C Ho ©) STAHL/BLA ‘Methanol; Methyl alcohol Heat Capacity 205K, C, ‘Temperature range $-28 K Entropy 125K, S = 0267 calmot.K LIT Samol Molecular Weight 32.0420 Wiswesser Line Notation QI Evaluation A. CHO Gig) S1REI “Methanol; Methyl alcohol Heat Capacity 298K, CG, 853 Jmol “K" ‘Temperature range 288-335 K Molecular Weight 32.0420 Wiswesser Line Notation QI Evaluation D CHO Gig) OOWAL ‘Methanol; Methyl alcohol Heat Capacity 291K, CG, = 19 calmol\K* 19 Jmol. One temperature ‘Molecular Weight 32.0420 Wiewesser Line Notation QI Eralzation —-D CHO Gia) 25PAR ‘Methanol; Methyl alcohol ‘Heat Capacity 290.1 K, 19.1 calmor'K"! 79.9 FemolK" ‘Temperature range 89-290 K. Value is unsmoothed experimental datum. Entropy DIK, $= 326calmol\K* 1364 Famot"-K? Extrapolation below 90 K, 9.74 calmol XK" Phase Changes | ele. 16LIK, AH = 141 calmot 390 Jamol" AS = 088 calmol\K" 3.66 Jmol =" liq 153K, AH = 739 calmot 3176 Jmol" AS = 433 calmol'K? 18.12 Fmot-K? ‘Molecular Weight 32.0820 Wiswester Line Notation Ql Evaluation — B(C).C(S) CHO Gia) 2KEL $ Methanol; Methyl alcohol Heat Capacity 2920K, C, = 19.1 cabmol 79.9 Jmol ‘Temperature range 16-293 K. Value is unsmoothed experimental datum, Entropy 298:15K, S Phase Changes lied. IST4K, AH = 1543 calmo! 645.6 Jmol" AS = 098 calmol’s 4.10 JamolK eg 152K, AH = 7570calmol* 3167 Jamo!" AS = 432 calmol.K* 18.08 Smol-K* Molecular Weight 32.0420 Wiswesser Line Notation Ql Evaluation B J. Phys. Chem. Ref. Data, Vol. 13, Suppl. 1, 198422 DOMALSKI, EVANS, AND HEARING ‘Table of Heat Capacities, Entropies, and Phase Transition Properties — Continued CHO dig) 29PAR/KEL ‘Methanol; Methyl alcohol Entropy DRIK, $= 31.0 calmolK" 129.7 Jmol kK" Extrapolation below 90 K, 8.2 calmot"-K" Revision of previous data, Molecular Weight 32.0420 Wiewesser Line Notation QI Evaluation == C CHO ig) 20MIT/HAR ‘Methanol; Methyl alcoho! Heat Capacity 270K, CG, ‘Temperature range 190-270 K, Molecular Weight 32.0420 Wiswesser Line Notation QI Evaluation B co ia) SIFIO/GIN Methanol; Methyl alcohol Heat Capacity 313.1K, C, = 1997 camo kK"! 83.56 Jmol-K" ‘Temperature range 40 to 110°C Molecular Weight 32.0420 Wiswesser Line Notation QI Evaluation A 39PHT HO Cig) ‘Methanol; Methyl alcohol Heat Capacity 308K, C, = 20.7 cal-mor-K* 866 morK"™ (One temperature ‘Molecular Weight 32.0820 Wiswesser Line Notation QI Evaluation C HO ig) 49sTA/GUP ‘Methanol; Methyl alcohol Heat Capacity 270K, C, = 1811 calmol\K 15171 SmolK" ‘Temperature range 90-270 K Phase Changes eer 1S78K, AH = 170cabmot" 711 Smet! AS = 108 cabmotK"* 431 Jmol!K" liq 134K, aH as 1801 Jmol ‘Molecular Weight 32.0420 ‘Wiswesser Line Notation QI Evaluation B CHO Gig SoHOU/MAS Methanol; Methyl alcohol Heat Capacity 323K, C, = 206calmol"-K* 86.2 Jmol-K" ‘Temperature range 323-353 K ‘Molecular Weight 32.0420 ‘Wiewesser Line Notation QI Evaluation B J. Phys. Chem. Ret. Data, Vol. 13, Suppl. CHO Gia) e@oswi/zie Methanol; Methyl alcohol Heat Capacity 311K, 19.3 cakmol.K" 808 Jmol K" ‘Mean value 21 to $6 Molecular Welght 32.0420 Wiewesser Line Notation QI Evaluation = C KAT CHO ia) Methanol; Methyl alcohol Heat Capacity 2982K, C, = 205 calmol 4 85.8 Jmol K" ‘Temperature range 10 0 60°C Molecular Weight 32.0420 ‘Wewesser Line Notation QI Evaluation B a0 Cig) TOPAZ/PAZ, Methanol; Methyl alcohol Heat Capacity 313.2K, CG, = 20.8 calmol\K* 85.8 Jmol"K" (One temperature Molecular Weight 32.0820 Wiewesser Line Notation QI Evaluation B CHO ig) TICAR/WES ‘Methanol; Methyl alcohol Heat Capacity 298.15K, C, = 19.39 calmol \* B1L13 JmorK" ‘Temperature range 5-332 K Entropy 28ISK, S$ = 30.40 calmol'K 127.19 SmotK* Phase Changes, ele 1S734K, AH = 1520calmol! 6360 Jmol" AS = 097 cabmol.K 4.08 Jmol olAiq 17559K, AH = 768.5 calmol* 32154 Jmol"! AS = 4.38 calmot-K* 18.31 Jmol “K Molecular Weight 32.0420 ‘Wiswesser Line Notation QI Evaluation A CHO Gig) TIDES/BHA ‘Methanol; Methyl alcohol Heat Capacity 298K, C, = 2000 cabot .K 83.7 Jmol ™K" ‘Temperature range 298-318 K ‘Molecular Weight 32.0420 ‘Wiswesser Line Notation QI Evaluation B ‘REL CHO, Orthoformic acid Heat Capacity 298 K, 155.6 Jmol" ‘Temperature range 293-406 K Molecular Weight 64,0408 Wiewesser Line Notation QYQQ Evaluation —-DHEAT CAPACITIES AND ENTROPIES OF ORGANIC COMPOUNDS Table of Heat Capacities, Entropies, and Phase Transition Properties — Continued cus Gig) 42RUS/OSB Methanethiol; Methy! mereaptan Heat Capacity 280K, C, = 21.28calmot".K* 89004 Sot." ‘Temperature range 15-260 K Entropy 2.2K, $= 3901 calmot\K* 163.2 Jmol sK* Phase Changes elVel 1376K, AH = $25 calmot? 219.7 Jmol AS = 038 cabmotK* 1.40 Smot-K"! etiq 180.16K, AH = 1411 calmot" 5904 Jmol AS = 9.40 cabmol.K" 39.32 Jmol SK lig’ 279.12K, AH = $872 calmat" 24568 Jmol AS = 21.04 calmol.K" 88.02 Jmol \K" P= 101.325 kPa Molecular Wetght 48.1026 Wiswesser Line Notation SH Braluation A CHN ig) STAST/SIL, ‘Aminomethane; Methylamine Heat Capacity 25928K, CG, = 2433 calmot.K? 101.80 J-motK ‘Temperature range 14-259 K. Value is unsmoothed experimental datum. Entropy 2WRISK, S = 359 calmol-K* 1302 FmolK" For superheated liquid, using extrapolated heat capacities. Phase Changes fig 179.70K, AH as lig/e 26684K, AH = 6169 calmol" 25811 Jmol AS = 23.129 calmolK* ‘Molecular Weight 31.0572 ‘Wiewesser Line Notation Z1 Evaluation =A CHAINO,S,+12H,0 (0) 68ASH/STE Methyl ammonium alum Heat Capacity 300K, GC, = 188.2 calmol\K? 787. Lmor'K" Temperature range 5-300 K Entropy 300K, S$ = 1826 calmol-K* 764.2 mor'K" Phase Changes oll/ed 176.18K, AS = 232 calmolK? 9.70 Jmol -K"" 90K Anomaly: Schottky type anomaly between 65 and 120 K, maximum at 90 K, entropy estimated to be between 6 and 9 Jmol -K- 176 K Anomaly: Due to free rotation of methylammonium ‘group (CH,NH,}; observed entropy change at 176.18 K is, 9.70 Jmol -K" Molecular Welght 467.3442 Wiswesser Line Notation AL Z1& S-O4*2 QH-12- Evaluation A CHAN © s6AST/ZIE ‘Methylammonium chloride Heat Capacity 298.15K, C, = 21.73 calmol.K 90192 Jmol .K"* ‘Temperature range 12-298 K Entropy 28K, $= 33.11 calmolK* 138.53 Jmol -K* Using metastable II below 220 K gives $ =33.15 ‘cal mol KC" Phase Changes clei 204K, AH = 425 calmol” 1778 Jot" AS = 193 calmol.K"! 807 Fmot “K* ole 264K, AN = 614calmot! 2820 Jmol AS = 255 calmol.K? 10.66 Iemot sk" Molecular Weight 67.5181, Wiewesser Line Notation Z1 &GH Evaluation A. cane © AISAT/SOG 4 ‘Semicarbazide hydrochloride Heat Capacity 323K, C, = 343 calmol K* 143.5 mor K* ‘Temperature range 0 to 100°C. Mean valu. Molecular Weight 111.5309 Wiswesser Line Notation ZVMZ &GH Evaluation C ‘Same data in 40SAT/SOG 5. CHS, Cig) SIAST/FIN Methylhydrazine Heat Capacity 298.15K, C, = 32.28 calmolK* 134.93 JmolK" ‘Temperature range 15-298 K Entropy 298.15K, $= 39.66 calmo'K* 165.94 Jmot'K* Phase Changes hig 220.79K, AH = 2490 calmot 10418 Samo 28 calmol-K" 47.19 Smol-K" lig/e 20815K, AH = 9648 cal mol’ 40367 Janol* AS = 3236 calmot"\K* 13539 Jamor-K" P= 6a kPa ‘Molecular Weight 4600718 Wiewesser Line Notation ZI Evaluation A HNO, ©) 28CLU/HAR ‘Ammonium carbamate Heat Capacity 295:5K, CG, = 3131 ealmolK* 131.00 Jamol.K" ‘Temperature range 13-296 K Molecular Weight 78.0706 Wiswesser Line Notation ZVQ &ZH Evaluation B J. Phys. Chem. Ref, Data, Vol. 13, Suppl. 1, 196424 DOMALSKI, EVANS, AND HEARING Table of Heat Capacities, Entropies, and Phase Transition Properties — Continued cKNS ©) TOVAN/WES Potassium thiocyanate Heat Capacity 298.15K, C, = 21.16 calmol'\K* 88.53 Jmol'K" ‘Temperature range 5-340 K Entropy DISK, So Molecular Weight 97.1760 ‘Wiswesser Line Notation K SCN Evaluation A COS Gig) STKEM/GIA Carbonyl sulfide Heat Capacity 220K, 1703 calmol-K" 7128 Jmot*K" ‘Temperature range 20-220 K Batropy M291K, S = 3288 calmotK"! 13631 Jmol-K" Phase Changes fig 13433.K, AH = 1130calmot 4728 Jmot! AS = 841 calmolK" 35.20 J.mol-K"! lig’ 22291K, AH = 4423 calimot" 18506 Jmot AS = 19.84 calmor 4K" $3.02 Jmol -K" P= 101325 kPa Molecular Weight 60.0708 Wisweaser Line Notation SCO Evaluation A Gig STBRO/MAN carbon disulfide Heat Capacity 29743K, G, = 18.17 calmol-K* 7602 Jmol" ‘Temperature range 15-297 K. Value is unsmoothed experimental datum. Entropy 28B.ISK, = 36.10 calmolK" 151.0 }mol"K* Phase Changes rig 16L11K, AM = 1049 calmer" 4989 Jmol AS = 651 calmot"-K* 2724 Jmol." ‘Molecular Weight 76.1310 ‘Wiswesser Line Notation SCS Evaluation A Gig 39MAZ3 Carbon disulfide Heat Capacity 293K, C= 18.6 cabmolKt 718 Snot -K" “Temperature range -100t0 20°C Molecular Weight 76.1310 Wiawesser Line Notation SCS Evaluation C io 39PHI Carbon disulfide Heat Capacity 3012K, C, = 182calmol*K* 76:1 Jmol 'K" One temperature “Molecular Weight 76.1310 ‘Wiswesser Line Notation SCS Evaluation = C J. Phys. Chem. Ref. Data, Vol. 13, Suppl. 1, 1984 cs, tio Carbon disulfide Heat Capacity 29481K, CG, ‘Temperature range 710 31 °C. Value is unsmoothed experimental datum. Molecular Weight 76.1310 Wiswesser Line Notation SCS Evaluation B tig SSSTA/TUP Carbon disulfide Heat Capacity 298K, CG, = 1888 calmol.K" 7899 bol 'K" ‘Temperature range 286-317 K ‘Molecular Weight 76.1310 Wiswesser Line Notation SCS Evaluation B 65GAT/DRA Heat Capacity 298 K, 21.2 cabmorK* 88.7 Jmot"K" ‘Temperature range -190 to 50°C Entrony 298K, $= 395 calmolK 165.3 JmalsK* Phase Changes fia 293K, AH = 1520-cabmol! 6360 Jmol AS = 66 calmot".K* 27.7 Sot K" Molecular Weight 169.9310 ‘Wiswesser Line Notation -SE-C-SE- Evaluation B CBF Gia) K0s/ZH0 1,2-Dibromotetrauorocthane Heat Capacity 298.15K,C, ~ 40582 calmot"'K* 1708 Jmol“ ‘Temperature range 8-300 K Entropy D9EISK, $= 71.86 calmor.K! 299.4 Jmol -K" Phase Changes iq 16283K, AH = 16818 calmot" 7036.7 Set AS = 1033 calmot 4322 Jmol"K" Molecular Weight 259.8236 Wiswesser Line Notation FXFFEXFFE, Evaluation A CaF, Gig SIOLI/GRI Chlorotrifluoroethene; Chlorotrluoroethylene; Trifluorochloroethene; Trifluorochloroethylene Heat Capacity 24480K, C, = 29.26 calmot K"" 122.42 Fmol-K" ‘Temperature range 16-245 K Entropy UA8OK, Sm $2.74 calmorK" 220.66 Jmol -K"! Phase Changes fig MSOK, AW = 1327.1 cabmol* 3552.6 Jmol" AS = 1156 calmol.K" 4828 J.mol-K" Molecular Weight 116.4702 Wiswesser Line Notation GYFUYFF Evaluation A.HEAT CAPACITIES AND ENTROPIES OF ORGANIC COMPOUNDS 25 Table of Heat Capacities, Entropies, and Phase Transition Properties — Continued Car, © S2HOF Polytrifuorochloroethylene; Plytiuorovinyl chloride Heat Capacity 298K, C, = 243 calmol 'K 1017 Sot Temperature range 0 to 241°C. Values given for air-quenched and slow-cooled samples. Valves per ‘monomer tnit slow-cooled samples, Unsmoothed experimental datum Molecular Weight 116.4702 ‘Wiawesser Line Notation /*XGFXFF*/ Evaluation B (COR), Gig) STYAR/KAY Poiytrituorochloroethylene; Polytrifluorovinyl chloride Heat Capacity 298K, C, = 27.8 calmol K" 1163 Fol ‘Temperature range 298-373 K. Equation only. Values per Molecular Weight 116.4702 Wiswesser Line Notation /*XGFXFF*/ Evaluation B OF, Gig SSAST/WIL Pentafluorochloroethane Heat Capacity 23404 K, 34.72 calmol"K" 145.27 Jmol -K" ‘Temperature range 15-234 K. Value is unsmoothed experimental datum. Entropy 23408K, $= $9.28 calmor sk" 2248.03 Fork! Phase Changes olive 8024K, AN = 628 calmol 2628 Jmol AS = 7.83 calmol-K" 32.75 Jmol -K" olfiq VAT1K, AH = 449 calmot" 1879 Jmol"! AS = 258 catmor-K! lige 260K, AH 19410 mot" AS = 19.82 calmot-K" 82.93 mol-K"! P= 101325 kPa Molecular Weight 156.4670 Wiswesser Line Notation GXFFXFFF Evaluation A 37PER 2,2-tetrafivoroethane; Freon 114 Heat Capacity" 293.3K, —C, = 406 cal mol"\K* 169.9 Fmot-K" ‘Temperature range -188 to 20°C. Value is unsmoothed experimental datum. ‘Molecular Weight 170.9216 Wiswesser Line Notation GXFFXGFF Evaluation C Probably a mixture of isomers, COR dig) STPER 2 1,2-Dichloro-I,1,2,2-tetrafluoroethane; Freon 114 Heat Capacity "293K, C, = 40.6 calmot 169.9 JmorK" ‘Temperature range -188 to 20 °C. Value is unsmoothed experimental datum. Molecular Weight 170.9216 Wiewesser Line Notation GXFFXGFF Evaluation C Probably a mixture of isomers. Shows peaks in heat capacity at -180 °C, -1407°C, and -100°C, which may be glassy transitions, COR Cig) 81KOL/KOS 1,2-Dichloro-1,12,2-tetrafluoroethane; Freon 114 Heat Capacity 298.15K, C, = 392 calmol-K: 164.0 Jmol"“K* ‘Temperature range 8-300 K Entropy 2ORISK, $= 674.calmol"K" 282.0 Jmol. Phase Changes el/el ——1083K, AM = 289.7 calmol! 1212 Jmol" AS = 265 calmol.K" 11.09 }motK* oll/e 146K, AH = 6281 calmol” 2628 Jmol! AS = 4.67 calmol 195 Jmol-K liq 18082K, AH = 361 calmol 1510 Jmol" AS = 200 calmol".K’ 836 Jmol =k" ‘Molecular Weight 170.9216 Wiswesser Line Notation GXFFXGFF Evaluation A. COR Cia) 38RIE 1,1,2-Trichloro-1,2,2-rifuoroethane; Freon 113, Heat Capacity 2982K, C= 42.3 cabmol\K* 171.0 Fmt K" ‘Temperature range -30 t0 61°C Molecular Weight 187.3762 Wiswesser Line Notation GXGFXGFF Evaluation B cor, io SORIE -Trichloro-12,2-triluoroethane; Freon 113 eat Capac” 382 C, = 823 calmot'K* 177.0 SmotK* ‘Temperature range -30 to 61°C Molecular Weight 187.3762 Wiswesser Line Notation GXGEXGFF Evaluation B Car, dia 40BEN/MCH 11,2-Trichloro-1,2,2-tifluoroethane; Freon 113 Heat eapacity 29815K, C, = 4297 calmol.K? 179.8 Jmol" ‘Temperature range 243-336 K, Data calculated from equation, Molecular Weight 187.3762 Wiswesser Line Notation GXGFXGFF Evaluation B ‘J. Phys. Chem. Ref. Data, Vol. 13, Suppl. 1, 198428 DOMALSKI, EVANS, AND HEARING ‘Table of Heat Capact Phase Changes eled 10398 K, AH = 893 calmot* 3736 Jmol AS = 859 calmolK? 35.93 Jmol -K* liq IB.I0K, AN = 642 calmot! 2686 Jmol* AS = 371 calmol™.K 15.52. .morK" lig/e 198.87, 82.88 Jmol'K* P= 101325 kPa “Molecular Weight 138.0124 ‘Wiswesser Line Notation FXFFXFFF Evaluation A CHDBr, (ia) s9WUY/TUN 1,2-Dibromoethane~<, Heat Capacity 310K, G, = 34.69 calmot.K* 145,14 Jmol -K" One temperature Molecular Weight 190.2802 Wiswesser Line Notation E2E. &2-1/2-1/2-1/H-23 Evaluation = C. GHA, Gig) 33TRE/WAT ‘Trichloroethene; Trichloroethylene Heat Capacity 298K, C, = 29.8 calmot"-K" 1247 mot K: ‘One temperature ‘Molecular Weight 131.3889 Wiewester Line Notation GYGUIG Evaluation = B GHA, Gig) 48KUR “Trichloroethene; Trichloroethylene Heat Capacity 298K, C, = 28.7 calmolK* 1204 FmotK" ‘Temperature range 12 to 80°C, mean C, three {temperatures ‘Molecular Weight 131.3889 ‘Wiewesser Line Notation GYGUIG Evaluation =D CHOC Cig) SIREL 2,2,2-Trichloroethanal; Chiora; ‘@,a,a-Trichloroacetaldehyde Heat Capacity 298K, CG, = 362 calmof\K* 151.3 Jmol -K"* ‘Temperature range 294-383 K Molecular Weight 147.3883 Wiswesser Line Notation VHXGGG Evaluation =D CHa, Gig) 48KUR Pentachloroethane Heat Capacity 298K, GC, = 469 calmol\K* 196.2 Fmot"sK" ‘Temperature range 16 to 154°C, mean C,, three temperatures. Molecular Weight 202.2949 ‘Wiswesser Line Notation GYGXGGG Evaluation =D ‘J. Phys. Chem. Ref. Data, Vol. 13, Suppl. 1, 1984 Entropies, and Phase Transition Properties — Continued HDB, Cig 1.2-Dibromoethane-12-, Heat Capacity 310K, C, = 3397 calmot-K: 142.13 Jmol 49WUY/TUN (One temperature Molecular Weight 189.8740 Wiswesser Line Notation E2E. 82-1/2-2/H-22 Evaluation C CMDB, Gia) 49WUY/JUN 1,2-Dibromoethane-,1-¢, Heat Capacity 310K, = 3433 cabmotK"! 143.64 Jmol (One temperature Molecular Weight 189.8740 Wiswesser Line Notation E2E &2-1/H-2 2 Evaluation C CHO, © Dibromoethanoic Heat Capacity 301.37K, C, = 29.80calmol’.K" ‘Temperature range -180 to 37°C. Value is unsmoothed experimental datum. ‘Molecular Weight 217.8446 ‘Wiswesser Line Notation QV YEE, Evaluation B CHa, ig) 48KUR 141,2,2-Tetrabromoethane Heat Capacity 298 K, 39.6 cabot \K! 168.7 Jmol “Kt Temperature range 15 to 132°C, mean C, three temperatures. ‘Molecular Weight 345.6538, Wiswesser Line Notation EYEYEE. Evaluation =D CHC, dia) 48KUR 1.2-Dichloroethene;1,2-Dichloroethylene Heat Capacity 298K, C, = 268 cabmol\K" 112.41 mor ‘Temperature range -31 t0 54°C, mean C, three temperatures. Molecular Weight 96.9438 Wiewesser Line Notation GIUIG Evaluation =D CHa, — Cig S4MEH 2 is-1,2-Dichloroethene; cis-1,2-Dichloroethylene Heat Capacity 288 K, 27.2 calmol'K* 1138 Jmol “K* (One temperature ‘Molecular Weight 96.9438 ‘Wiewesser Line Notation GIUIG -C Evaluation C cHa, aig S4MEH 2 ‘rans-1,2-Dichloroethene;trans-1,2-Dichloroethylene Heat Capacity 288K, C, = 27.0.calmol"K" 1130 Jamo 'K* (One temperature Molecular Weight 96.9438 Wiewesser Line Notation GIUIG -T Evaluation CHEAT CAPACITIES AND ENTROPIES OF ORGANIC COMPOUNDS 29 ‘Table of Heat Capacities, Entropies, and Phase Transition Properties — Continued CHa, ia 1.1-Dichloroethene; Vinylidene chloride Heat Capacity 298.15K, C, = 26.60 calmol'\K* 111.29 Jmol\K" soHIL/MCD ‘Temperature range 13-290 K Entropy: ‘298.15K, S = 48.17 calmol.K- 201.54 Jmol HK Phase Changes fig, 150.59K, AH = 1557 cal-mol* 6514 Jmol AS = 1034 cabmotK 43.26 Jmol" lig’ Q9RISK, AH = 6328 calmol! 26476 bot AS = 21.22 cakmol-K* 38.80 Fmot“X: P= s003KPa “Molecular Weight 96.9838 Wieweseer Line Notation GYGU! Erauation A CHL, © siGLA/TIM Dichloroethanoic acid Dichloroacetic acid Heat Capacity 28031K, C, = 43.57 cabmol\K* 182,30 mot “K" “Temperature range -180 107°C. Value is unsmoothed experimental datum Phase Changes cfiq 2865K, AH = 2950 cal-mot" 12340 mot” AS = 103 catmot \K* 43.1 Jamol-K Molecular Welght 128.9426 ‘Wiewesser Line Notation QVYGG Evaluation B CHA, ao aLou Dichloroethanoc acid; Dichloroacete acid Heat Capacity 380K, CG, Temperature range 22 0 196 ‘Molecular Weight 128.9426 ‘Wiswesser Line Notation QVYGG Evaluation — D GHC, Gia) 1,1,22-Tetrachloroethane Hat Capacity 298K, ‘Temperature range 15 o 145°C, mean Cy fou temperatures. Molecular Weight 167.8498 Wiswesser Line Notation GYGYGG Evaluation =D CHO, © 2PAR/KEL Ethanedioi acid; Onalic acid Entropy 298.1K, S$ = 28.7 calmolK* 120.1 Jmol. Extrapolation below 90K, 9.2 calmol"K". Revision of previous data Molecular Welght 90.0354 Wiewesser Line Notation QVVQ Evaluation = C CHO, © Ethanedioic acid; Oxalic acid Heat Capacity 323K, 1180 3.mor'K* ‘Temperature range 0 to 100 °C. Mean value given. ‘Molecular Weight 90.0354 ‘Wiswesser Line Notation QVVQ Evaluation C CHO, © Ethanedioic acid; Oxalic acid Heat Capacity MOK, CG ‘Temperature range 298-373 K. Mean value. Temperature range uncertain, Molecular Weight 90.0354 ‘Wiewesser Line Notation QVVQ Evaluation _D. CHO, © ‘S2LUF/REE, Ethanedioic acid; Oxaic acid Heat Capacity 298.15 K, 2531 calmol\K" 105.9 Jmol" ‘Temperature range 5-320 K Entropy 20RISK, $= 2762 calmol'K 115.6 Jsmol-K ‘Molecular Weight 90.0354 Wiswesser Line Notation QVVQ Evaluation A HDB, Cia) 49WUY/JUN 1,2-Dibromoethane-d, Heat Capacity 310K, 3305 calmol 138.28 Jmol K (One temperature Molecular Welght 188.8678 ‘Weweaser Line Notation E2E &2/H-2 Evaluation C CHBr ci) Bromoethene; Vinyl bromide Heat Capacity 288K, (One temperature Molecular Weight 106.9497 ‘Wiewesser Line Notation E1U1 Evaluation C GHB ig) MEH Bromoethene; Viny! bromide Heat Capacity 288K, C, = 258 calmot"K* 1079 FmotK* ‘One measurement Molecular Wetght 1069487 Wiswesser Line Notation E1UI Evaluation —C CHO, Gs) TICHA Polyvinyl chloride Heat Capacity 298.15K, C= 14.11 calmer .X! 59103 Jmol "K" ‘Temperature range 6-380 K. Valve per monomer unit. Entropy 29813K, $= 17.lTealmorK" 71.90 For“ er monomer unit. Value is $-S,, 4. Phys. Chem. Ret, Data, Vol. 13, Supr30 DOMALSKI, EVANS, AND HEARING ‘Table of Heat Capacities, Entropies, and Phase Transition Properties — Continued ‘Molecular Weight 62.4987 Wiswesser Line Notation /*YG1*/ Emluation A. ‘One sample of suspension-polymerized PVC, two samples ‘of bulk-polymerized PVC. Data represent annealed bulk material, GHAR, (li) 37PER 1,1-Difluoro-I-chloroethane Heat Copacity 291.6, 1.2 calor" 1303 FmotK" ‘Temperature range -180 to 18 °C. Value is unsmoothed experimental datum. Phase cig 424K, AH = 642-calmor 2686 Jmol ‘Molecular Weight 100.4955 Wiswesser Line Notation GXFF1 Evaluation = -B aie) S7PER2 Difluoro-I-chloroethane Heat Capacity 2916K, C, = 31.2 calmot".K" 1205 Jmol -K* ‘Temperature range -180 to 18 °C. Value is unsmoothed ‘experimental datum for saturated liquid Phase Changes fig 124K, AH = 682 calmol 2686 Jmol AS = 451 calmol.K* 18.86 Jmol" ‘Molecular Weight 100.4955, Wiswester Line Notation GXFFI Evaluation B ‘Sample probably contains other isomers in small amounts. HOR, dia ‘RIE 1,1-Difluoro-I-chloroethane Heat Capacity 2949K, C, = 31.2 calmol".K" 1303 SmorK" ‘Temperature range -61 to 21 °C. Value is unsmoothed experimental datum for saturated liquid. ‘Molecular Weight 100.4955 ‘Wiswesser Line Notation GXFFI Evaluation A. GHOR, ig) sIRIE2 1,1-Difluoro-I-chloroethane Heat Capacity 2948K, CG, = 31.2 calmolK" 1305 Jmol K* ‘Temperature range -61 to 22°C. Value is unsmoothed experimental datum. Molecular Weight 100.4955 Wiewesser Line Notation GXFF1 Evaluation A. HAO Cig) ‘SIRE ‘Acetyl chloride ‘Heat Capacity 298 K, 280 calmol-K- 1172 Jmol? ‘Temperature range 289-343 K ‘Molecular Weight 78.4981 ‘Wiswesser Line Notation GV1 Evaluation =D J. Phys. Chem. Ret. Data, Vol. 13, Suppl. 1, 1984 caH.a0, Gig) SOURA/SID CChloroacetic acid Heat Cepacity 321.05K, C= 43.0 cabmot.K* 179.9 Jmol sK* ‘Temperature range 47 to 65°C. Value is unsmoothed experimental datum. Maxima st $0.7, 569, and 61.2°C. Molecular Weight 94.4975 Wiewesser Line Notation QVIG Evalsation —B 44RUB/LEV 38.49 calmol “K* 144.31 Jmol 4K" 299.59 K, ‘Temperature range 12-300 K. Value is unsmoothed ‘experimental datum. BRISK, Entropy 54.37 calmol"K! 227.48 Jmol“ K* Phase Changes ell/e 1786 calmol 1473 Snot! AS = 797 cabmol.K" 33,33 mol-K" 4450 cal mol 1880 Jmol" 1.9 calor." 78 Jano! ‘AH estimated because of errrs in C, above 225 K. Not used in calculation of entropy. ol/iq 2402, lig’ 28683 K, AH = 7962 calmol" 33313 Jmol AS = 27.19 cabot" 116.26 Jmol-K" P= 1026 kPa Molecular Weight 133.4047 ‘Wiswesser Line Notation GXGG1 Evaluation A CHA, Gia socRo/sMY |,1-Trichloroethane; Methyl chloroform Heat Capacity 252K, C, = 33.2 calmol-K* 1389 JmolK" Temperature range 117-260 K. Value is unsmoothed experimental datum. Phase Changes eller 205K, = 50.calmot 210 mot = 02cabmorK 10Smol-K" 1780 calmol* 71430 mot! = 80 calmolK" 333 Jmol “K* = 430 calimot 1880 Jmol" elle 236K, elfig 240.1 K, BEBEREEE Molecular Weight 133.4047 Wiswesser Line Notation GKGGI Evaluation CHEAT CAPACITIES AND ENTROPIES OF ORGANIC COMPOUNDS 31 ‘Table of Heat Capacities, Entropies, and Phase Transition Properties — Continued CHA, dia) 7BAND/COU 1,l,1-Trichloroethane; Methyl chloroform Heat Capacity 298.15K, C, = 34:51 calmol'\K* 144.4. morK" ‘Temperature range 10-310 K Entropy 298.15K, S = 5418 calmotK* 226.7 Sol"! Phase Changes ole 22480K, AH = 1790 calmot" 77490 Jmol AS = 796 calmot'K* 33.32 Jmol\K" oMliq 24313, AH = $62 calmol* 2350 mot AS = 231 calmolK* 9.67 Jmol K" ‘Molecular Weight 133.4047 ‘Wiswesser Line Notation GXGG1 Evaluation A. GHA, © S0CRO/SMY 1,1,2-Trichloroethane Heat Capacity 257K, CG, = 342.calmotK" 143.1 JamolsK"* ‘Temperature range 117-252 K. Valve is unsmoothed experimental datum. Phase Changes hig 237.1K, AH = 2720calmot" 11380 mot AS = 115 calmol-K! 480 5mol"-K" Molecular Weight 133.4047 Wiswesser Line Notation GYGIG Evaluation = C CHR Gig) 44RUS/GOL 11,1-Triflworoethane; Freon 143, Heat Capacity 220K, C, = 2621 calmol.K' 109.66 Jmol -K* ‘Temperature range 15-226 K Batropy 2S85K, $= 43.56 cabmol-K" 224,10 FmotK? Phase Changes We 18638K, AH = 71 cabmot 291 Jmol" AS = 045 calmot-K* 1.90 Jmol-K"! elfiq 16182K, AH = 1480 cal-mo! 6192 mot AS = 9.15 calmol 38.26 Jmol" lig/e 22440K, AH = 4583 calmot" 19175 Jmol" AS = 2042 calmor"K" P= 9454kPa Molecular Weight 84.0409 Wiswester Line Notation FXFF1 Evaluation =A CHKO, © ‘1SFER/SAN Potassium acetate Phase Changes oll/ed 423K, AH = 100calmot" 420 Jmol" AS = 024 calmot"'K* 1.0 Smo! etfiq STRTK, AH = 3640 calmor! 15230 Jmol" AS = 63 calmolK* 263 Smo! Molecular Weight 98.1428 Wisweaser Line Notation OVI.KA Evaluation = C GLO, © {1SFER/SAN Lithium acetate Phase Changes| cfg 557K, AH = 2840 calmol* as 21.3 JmolK* ‘Molecalar Weight 65.9855 ‘Wiswesser Line Notation OV! LI Evaluation C GHN (ig) o7WAL ‘Acetonitrile; Methyl cyanide Heat Capacity 291 K, 21 cabmol\K"! 88 Jmol" (One temperature ‘Molecular Weight 41.0524 Wiswesser Line Notation NCI Evaluation =D CHN (ig) (6SPUT/MCE ‘Acetonitrile; Methyl cyanide Heat Capacity 298.15K, C, ‘Temperature range 20-300 K Entropy BRISK, $= 35.76 calmolK" 149,62 Jmol: Phase Changes elVel 2169K, AH = 2146 calmot 397.9 Jmol" AS = 099 cabmol.K"! 4.14 Jmor'K elig 22932K, AH = 1982 calmol" 8167 Jmol AS = 851 cabmol!K? 35.61 JmolK" lig’ 2981SK, AH = 7941 calor" 33225 Jmol! AS = 2663 calmol XK" 11144 SmorK" P= 1183kPa ‘Molecnlar Welght 41.0524 Wiewesser Lie Notation NCI Evaluation =A CHN Gia) TIHAL/BAL, ‘Acetonitrile; Methyl cyanide Heat Capacity 297K, C, = 19.7 calmolK" 82.5 SmolK’ One temperature ‘Molecular Weight 41,0524 ‘Wiewesser Line Notation NCI Eraleation = C J. Phys. Chem. Ret. Data, Vol. 13, Suppl. 1,32 DOMALSKI, EVANS, AND HEARING ‘Table of Heat Capacities, Entropies, and Phase Transition Properties — Continued CBN Cig) 1BV1S/SOM ‘Acetonitrile; Methyl cyanide Heat Capacity 298.15K, C, = 219 calmorK" 91.7 Jmol-K" (One temperature Molecnlar Weight 41.0524 Wiaweaser Line Notation NCI Evahation —B GHNO, © SIFIN/KUM ‘Polyglycine 1 C= 2451 calmolK* 102.5 Jot ‘Temperature range 150-375 K, Polyglycine I (-sheet). Data given graphically. C, calculated from equation. ‘Molecular Weight 75.0670 ‘Wiswesser Line Notation /*MV1*/ Evaluation —B Heat Capacity 298.15K, CGHNO, © S1FIN/KUM Polyglycine It Heat Capacity 298.1K, C, = 22.34calmol\K* 93.46 Jmol-K ‘Temperature range 150-375 K, Polyglycine II (3,helin. ‘Data given graphically. C, calculated from equation. Molecular Welght 75.0670 Wiswesser Line Notation /*MV1*/ Evaluation B HNO, © Sodium acetate Heat Capacity 291.18K, C, = 21.05 calmot.K 88.07 Jamol"“K" ‘Temperature range 13-292 K. Value is unsmoothed experimental datum, SSSTR atropy 2981SK, $= 2942 calmor/K" ‘Molecular Weight 82.0343, ‘Wiswesser Line Notation OVI NA. Evaluation =A HMO, (IV) 7SFER/SAN Sodium acetate Heat Capacity 40K, C, = 26:7 calmot"\K" 17 Emo K* ‘Temperature range 340-610 K Phase Changes elV/elll 414K, AH = 70calmot! 290 Jmol" AS = O17 cabmot-K* 07 Yemot-K* elle 465K, AW = 100calmol* 4205mor! AS = O2calmor-K* (08 Jamot'K* oll/ed 527K, AH = 40calmol! 170 Femol* as liq 13K, An = AS = T1cabmol-K* 29,9 Jmol ‘Molecular Welght 82.0343 ‘Wlawesser Line Notation OVI NA Evaluation B 4. Phys. Chem. Ref. Data, Vol. 13, Suppl. 1, 1984 CHM0/3H,0 © ‘Sodium acetate trihydrate Heat Capacity 325K, G, ‘Temperatures above and below melting point. Phase Changes hig S3L7K, AH = 4840 calmot* 20250 Jmol AS = 15 calmorK* 61 mots" Molecular Weight 136.0799 Wieweaser Line Notation OVI NA &QH 3 Evaluation CHDO, dia) ORAB/NIK 112-Dihydroxyethane-dy 1,2-Edhanediol-d; Eithyene glyeol-d, Heat Capacity 298K, C= 37.27 ealmol"“K- 15594 Jmol"K* ‘Temperature range 10 to 55°C “Molecular Weight 64.0806 Wismesser Line Notation Q2Q &1/3/H-22 Evalution—B CHDO, cid STNIK/RAB 2 1.2-Dinydroxyethane-dy;1,2-Ethaneiol-dy Ethylene glycol-d, Heat Capacity 28815K, C, = 37.80 calmot".K" 158.16 Smol-K" “Temperature range 80-300 K Phase Changes fig 2888.K, AH = 2330-calmot" 9749 Jmol" AS = 9.00 calmot.K* 31.6 mot" Molecular Wetght 64.0806 Wiswesser Line Notation Q2Q &1/3/H-22 Evaluation B GHBrcl Gig) 39RAI |-Bromo-2-chloroethane Heat Capacity 300K, CG, = 31.1 calmolK* 130.1 Jot" ‘Temperature range 90-320 K. Data graphically only. Value read from graph. Phase Changes ell/ed 182K, AH = 740.calmot" 3100 Jot" AS = 4.1 calmol*K* 17.0 Famol“K* ‘Lambda-type transition. Temperature is maximum in specific heat curve. olfiq 2564K, AH = 2300 calmol 9625 Jamo! AS = 9.0calmol'.K* 373 Janol “Ke ‘Molecular Weight 143.4106 ‘Wiswesser Line Notation G2E Evaluation CHEAT CAPACITIES AND ENTROPIES OF ORGANIC COMPOUNDS 33 ‘Table of Heat Capacities, Entropies, and Phase Transition Properties — Continued CHB, Gia) S9RAT 1.2-Dibromoethane; Ethylene dibromide Heat Capacty 300K, C, = 31.8 calmot 129.5 Jemol-K* ‘Temperature range 90-320 K. Data graphically only. Value read from graph. Phase Changes eller 2806K, AH = 450 calmot’ 1880 Jmol AS = Li calmer! 15 5mm0t"K" liq 283.1K, AH = 2590cal-mor" 10835 Jmol" AS = 9. cabot .K*! 383 mot." Molecular Welght 187.8616 Wieyesser Line Notation E2E Evaluation C CHB, Gia) sorrr 2 1,2-Dibromoethane; Ethylene dibromide Heat Capacity 298.15K, C, = 32.5 calmol"-K" 1360 Fmot" ‘Temperature range 15-300 K Entropy 2RISK, $= $337 cabmotK" 223.20 Jeol -K! Phase Changes elle 24954, AH as oMrig 280K, AH = 26158 calmor 109445 Jmol AS = 9.24 calmol-K" 38.67 JmolK Molecular Weight 187.8616 ‘Wiswesser Line Notation E2E Evaluation A. CHB, Gia 48KUR 1.2-Dibromocthane; Ethylene dibromige Heat Capacity 298K, C, = 322calmol"K" 1347 mot K" ‘Temperature range 16 to 127°C, mean G,, four temperatures. ‘Molecular Weight 187.8616 ‘Wiswesser Line Notation E2E Evaluation — D CHB, Gia) 49WUY/UN 2-Dibromoethane; Ethylene dibromide Heat Capacity 310K, C, = 32.30 cahmol\K- 135.14 Jmol" (One temperature Molecular Weight 187.8616 Wiswesser Line Notation E2E Evaluation = C GHB, Gia) SowIL/SCH 1,2-Dibromoethane; Ethylene dibromide Heat Capacity 298.15K, C, = 323 calmol 1350 Jmol" ‘Temperature range 20, 30, 40C Molecular Weight 187.8616 Wiewesser Line Notation E2E Evaluation B CHO, Gig) SIREI 1,2-Dichloroethane; Ethylene dichloride Heat Capacity 298K, C, = 292 calmof-K* 1222 5motK* ‘Temperature range 290-364 K Molecular Welght 98.9596 Wieweaser Line Notation G2G Evaluation =D cHa, 4 S9RAI 1,2-Dichloroethane; Ethylene dichloride Heat Capacity 300K, 162 Jmol “K* ‘Lamds-type transition. Temperature is maximum in specific heat curve. olfiq 2371.6K, AH = 2080 calmer" 8143 Jmol" AS = 880 calmol.K? 36.8 Jmol K" ‘Molecular Weight 98.9596 Wiswesser Line Notation G2G- Evaluation = C CHa, ia opr 2 1,2-Dichloroethane; Ethylene dichloride Heat Capacity 296.15K, C= 308calmot .K" 1289 FmorK* ‘Temperature range 15-308 K Entropy DBISK, S = 49.84 calmolK" 208.53 Jmol -K"! Phase Changes ‘Anomalous region at 175-180 K, probably a lambda-type transition. No transition heat or temperature given. hig 2312K, AH = 21120calmot 8836.6 Jmol" AS = 890calmolK* 37.25 JmolK" Molecular Weight 98.9596 Wiewesser Line Notation G2G lustion =A ia) 48KUR Dichloroethane; Ethylene dichloride Heat Capacity 298K, C, = 29.4 calmofK"" 1230 FmotK* ‘Temperature range -25 to 86°C, mean C, four temperatures. Molecular Weight 98.9596 Wiswesser Line Notation G2G- Evaluation =D CHO, Gi SISIE/CRU 1,2-Dichloroethane; Ethylene dichloride Heat Capacty 293K," Cy = 29.7ealmot"K" 1243 SmolK" One temperature Molecalar Weight 98.9596 Wiameaser Line Notation G2G Eralation —B J. Phys. Chem. Ret, Data, Vol. 13, Suppl 1, 198434 DOMALSKI, EVANS, AND HEARING ‘Table of Heat Capacities, Entropies, and Phase Transition Properties — Continued CHO, ci SSSTA/TUP 1,2-Dichloroethane; Ethylene dichloride Heat Capacity 298K, C, = 31.00 calmol\K* 129.70 Jmol"! ‘Temperature range 284-348 K, ‘Molecular Weight 98.9596 ‘Wiswesser Line Notation G2G Evaluation B CHa, dia SSRUL 12-Dichloroethane; Ethylene dichloride Heat Capacity 298:15K,C, = 3096 calmorK" 129.54 Jmol -K"! ‘Temperature range 7-50" Molecular Weight 98.9596 Wiswesser Line Notation G2G Evaluation B CHa, tia 6TRAS/GAN 1,2-Dichloroethane; Ethylene dichloride Heat Capacity 293K, C, = 309 calmol\K 129.2 Jmol “K* ‘Temperature range 293-353 K Molecular Weight 98.9596 Wieweaser Line Notation G2G Evaluation C CHa, — dia 6owIL/scH 1.2-Dichloroethane; Ethylene dichloride Heat Capacity 298.15K, C, = 30.7 cahmol")K 128.6 SmorK* ‘Temperature range 20, 30, 40°C Molecular Weight 98.9596 Wieweaser Line Notation G2G Evaluation B CHa, dia TDWIL/FAR, 1,2-Dichloroethane; Ethylene dichloride Heat Capacity 298.15K, C, = 30.83 cabmol \K- 128.99 Jmol (One temperature, Molecular Weight 98.9596 Wiswesser Line Notation G2G Evaluation B CHa, dia 79WIL/GRO 1,2-Dichloroethane; Ethylene dichloride Heat Capacity 298.15K, C, = 308 calmol'K* 129.0 Jmot-K" (One temperature Molecular Welght 98.9596 Wieweaser Line Notation G2G Evaluation = B CHa, Cid SIRET 1,1-Dichloroethane; Ethylidene chloride Heat Capacity 298K, C, = 28.9 calmol"-K" 1209 J.morK" ‘Temperature range 287-344 K ‘Molecular Weight 98.9596 Wiswesser Line Notation GYG1 Evaluation D. J. Phys, Chem. Ref. Data, Vol. 13, Suppl. 1,1 CHO, Gia) 48KUR 1,1-Dichloroethane; Ethylidene chloride Hieat Capacity 298K, C, = 304 calmof“K* 127.2 Jmol -K* Temperature range -S1 to $5°C, mean C, four temperatures ‘Molecular Weight 98.9596 ‘Wiswesser Line Notation GYG1 Evaluation =D CHO, Cid SoLU/PIT 1.1-Dichloroethane; Ethylidene chloride Heat Capacity 298.15K, C, = 30:18 calmol\K 126.27 Jmol -K" ‘Temperature range 14-298 K Entropy 29B1SK, $= $061 calmotK! 2UL7S Jmol Phase Changes evlig 17618K, AH = 1881 calmer! aH 17870 Jmol AS = 1068 calmot 4467 Jmol -K AH = 1409 cabot" as lia/e 293K, 31000 Jmol 25.29 calmol-K" 105.81 Jmot P= 3032 kPa “Molecular Weight 98.9596 Wiswesser Line Notation GYG) Evaluation A. CHNO, © 6SEGA/WAK Oxamide Heat Capacity 29815K, C, = 2722 calmol“.K! 113.89 Jmol" ‘Temperature range 10-310 K Entropy QKISK, S$ = 2823 cabmol.K* 118.11 JmotK" Molecular Weight 88.0658 Wieweaser Line Notation ZVVZ Evaluation A. “Trclinie form COHN, © S2STE/BER Dicyandiamide 28.14 calmot “1 117.74 Smot®K* ‘Temperature range 15-300 K. Value is unsmoothed experimental datum. Entropy 2B1SK, S Heat Capacity 29463 K, 30.90 calmot KC" 129.29 Jmol'K" Molecalar Weight 84,0804 ‘Wiswesser Line Notation NCMYZUM Evaluation A. COHN, © waDAv Dicyandiamide Heat Capacity 340K, C, = 34calmol" 142 J-molK’ “Temperature range 298-373 K. Mean value. Temperature ange uncertain. Molecular Weight 84,0804 ‘Wewesser Line Notation NCMYZUM Evaluation —-DHEAT CAPACITIES AND ENTROPIES OF ORGANIC COMPOUNDS 35 ‘Table of Heat Capacities, Entropies, and Phase Transition Properties — Continued CHO Gy Oxirane; Ethylene oxide Heat Capacity 285K, CG, S9GIA/GOR 20,77 calmotK: £86.90 J-mor-K"! ‘Temperature range 15-283 K Entropy 28L60K, S$ = 3872calmol.K* 149.45 Jemol-K"! Phase Changes cig 160.65 K, AH = 12364 calmor" 5173.1 Fol? AS = 7.30 cabmorK" 32.20 Jmol \K" lig’ 283.66K, AH = 6101 calmot 25527 Jmol AS = 21581 calmot'K* 39.99 J.mol.K P= 101.325 kPa ‘Molecular Weight 44.0530 Wiswesser Line Notation T30TI luation =A CHO Cia) 47CON/ELV Ethanal; Acctaldehyde Heat Capacity 273K, CG, = 2300calmol.K"! (One temperature Molecular Weight 44.0530 Wiewesser Line Notation VI Evaluation B CHO, a) suet Ethanoic acid Acetic acid Heat Capacity 298K, C, = 295 calmolK! 1235 mor kK? “Temperature ange 92-358 K ‘Molecular Weight 60.0524 Wiswesser Line Notation QV1 Evaluation CHO, cia) 25PAR/KEL thanoic acid Acetic acid Heat Capacity 2947K, C= 285 calmol-K* 123.4 mot" “Temperature range 87-295 K, Value unsmoothed experimental datum Entropy -298:1K, $= 463 calmol XK" 1937 mot! Extrapolation below 90 K. 18.36 alot Phase Changes fig 2898K, AH = 2803 calor 11728 Sol AS = 9.67 cabmot'K* 4047 Jmol“ Molecular Weight 60.0524 Wiswesser Line Notation QVI Evaluation B(C;).CIS) CHO; i) 29PAR/KEL Ethanoic sci; Acetic acid Entropy DSBIK, $= 382 calmol“K* 15948 Jmol -K* Extrapolation below 90 K, 102 calamal"K" Revision of previous data Molecular Weight 60.0524 Wiswesser Line Notation QVI Evaluation = C CHO, Cig) 32NEU Ethanoic aid; Acetic acid Heat Capacity 297.1K, C, = 29.0calmof"-K" 1213 Famol ‘Temperature range 23.9-80.5 °C. Value is unsmoothed experimental datum. Molecular Weight 60.0524 ‘Wiswesser Line Notation QV! Evaluation ¢ CHO, Cid 34RADAUL, Ethanoic acid; Acetic acid Heat Capacity 298K, GC, = 28.8 cahmor"-K* 1203 JmorK" One temperature Molecular Weight 60.0524 Wiswesser Line Notation QV1 Evaluation C CHO, Cig) ssswi/ZIE Ethanoic ac Acetic acid Heat Capacity 332K, C, = 33.4 calmot “K* 139.7 Jmol “K* Mean value 22 t0 96 °C ‘Molecular Weight 60.0524 ‘Wiswesser Line Notation QV1 Evaluation = C CHO, Cig) S2MAR/AND. Ethanoic acid; Acetic acid Heat Capacity 298.18K, C, = 29.42 calmot"K"! 123.1 Fmor-K" ‘Temperature range 13-450 K, Data also given by equation Entropy 2RISK, $= 37-76 calmot'K" 158.0 Jmor-K" Phase Changes oq 298.69K, AH = 2801.1 calmot 11720 mot" AS = 9.67 calmot"K* 4055 Jmol-K" ‘Molecular Weight 60.0524 ‘Wiswesser Line Notation QV! Evaluation A. GHO, Cia) S4MEH 2 Methyl methanoate; Methyl formate Heat Capacity 288K, C, 1213 Fol K* One temperature Molecular Weight 60.524 Wiswester Line Notation VHOI Evaluation C CHO, Gia TIHAL/BAL Methyl methanoate; Methyl formate Heat Capacity 297K, CG, = 22.8 cabmolK" 95.5 Jmol *K- (One temperature ‘Molecnlar Weight 60.0524 ‘Wiswesser Line Notation VHOL Evaluation C J. Phys. Chem. Ret. Data, Vol. 13, Suppl. 1, 190436 DOMALSKI, EVANS, AND HEARING ‘Table of Heat Capacities, Entropies, and Phase Transition Properties — Continued CHO, Gia) 19FUC Methyl methanoste; Methyl formate Heat Capacity 298.15K, CG, = 286 calmol“K* 119.7 mot K" (One temperature Molecular Weight 60.0524 ‘Wiawesser Line Notation VHO1 Evaluation —-B HO Gig) @RAB/NIK Ethanol-dj; Ethyl alcohol-d, Heat Capacity 298 K, = 27.78 cabmol\K" 11623 FmorK" ‘Temperature range 15 10 55°C Molecular Weight 47.0750 Wiswesser Line Notation Q2 &1/H-2 Evaluation = -B HO aig) GTNIK/RAB ‘Ethanol-di; Ethyl alcohot-<, Heat Capacity 280K, | C, = 2840 calmol XK" 102.09 5motsK" ‘Temperature range 80-250 K Phase Changes lle 133K, AH = 800 calmot 3347 Jmol as liq 1569K, AM = 1030 calmot" 4310 Jmol! AS = 6:56 calmolK* 2747 Smol-K ‘Molecular Weight $7.0750 Wiswesser Line Notation Q2 &1/H-2 Evaluation =A cater io 48KUR Bromoethane; Ethyl bromide Heat Capacity 298K, G, = 24.1 calmol“K" 1008 Jmor “Temperature range 30 t0 37°C, mean Cy five temperatures, Molecular Weight 18.9685 ‘Wiawesser Line Notation E2 Evasion D CHa Gia 40RIE ‘Chloroethane; Ethyl chloride Heat Capacity 298.1K, C, = 260calmol"K* 108.8 Jmor'K* ‘Temperature range -48 t0 46°C Molecular Weight 64.5145 Wieweaser Line Notation G2 Erauation A. GHA Gig s1RIE ‘Chloroethane; Ethyl chloride Heat Capacity 298K, GC, = 260calmol\K* 108.8 FmotK* ‘Temperature range -#8 to 45°C ‘Molecular Weight 64.5145 ‘Wiswesser Line Notation G2 Evaluation =A J. Phys. Chem. Ref. Data, Vol. 13, Suppl. 1, 1964 CHA Gia ‘Chiloroethane; Ethyl chloride Heat Capacity 290K, CG, = ‘Temperature range 13-287 K Entropy 2SA2K, $= 442 calmolK* 186.27 SmorsK" Phase Changes fig 182K, AW = as lig/e 28542K, AW as 8637 Smol-K"! P= 101325 kPa Molecular Weight 64.5145 Wawesser Line Notation G2 Evaluation A. CHA Gig) 48KUR ‘Chloroethane; Ethyl chloride Heat Capacity 288K, C, = 26.1 calmot 109.6 Fmot“K* ‘Temperature range -67 t0 15°C, mean C, three temperatures. Molecular Weight 64.5145 Wiewesser Line Notation G2 Evaluation =D. CHA Gig) 48KUR Todoethane; Ethyl iodide Heat Capacity 298K, C, = 275 calmot K" 115.1 mol." Temperature range -37 10 70°C, mean C, three temperatures ‘Molecular Weight 155.9660 Wiswesser Line Notation 2 Evaluation =D GHNO ig) 74V18/SOM 'N-Methyimethanamide; N-Methylformamide Heat Capacity 298.15K, C, = 30.16 calmol".K" 126.1 Jmol" One temperature Molecular Weight 59.0576 Wiewester Line Notation VHM! Eraluation A. ig) 19V1S/SOM 'N-Methylmethanamide; N-Methylformamide Heat Capacity 298.15K, C= 299 calmot.K" 1252 Samol-K" (One temperature ‘Molecular Weight 59.0676 ‘Wiawesser Line Notation VHMI Evaluation B GHNO © ‘Ethanamide; Acetamide Heat Capacity 293K, G, (One temperature ‘Molecular Weight 59.0676 Wiswesser Line Notation ZV1 Braluation = CHEAT CAPACITIES AND ENTROPIES OF ORGANIC COMPOUNDS ‘Table of Heat Capac HNO, (ia) G6LIU/Z1E Nitroethane Heat Capacity 298.15K, C, = 3208 calmol'\K* 134.22 EmotK" ‘Temperature range 80-300 K Phase Changes| cfg 183.69 K, AM = 2355 calmol 9853 Jmol! AS = 1282 calmol“K" 53.64 Jmol -K* ‘Molecular Weight 75.0670 Wiswesser Line Notation WN2 Evaluation A. HNO, © 33PAR/HUF “Aminoethanoic acid Glycine Heat Capacity 298.5K,C, = 2402 calmot" 1000 Jmol"-K"! ‘Temperature range 93-300 K. Value is unsmoothed experimental datum, Entropy (298:1K, $= 264 calmot"“K" 1082 Jmol .K" Extrapolation below 90 K, 7.58 calmolK" Molecular Welght 75.0670, Wiawesser Line Notation Z1VQ Evaluation — B(C;). CIS) HNO, © (HUT/COL ‘Aminoethanoie acid; Glycine Heat Capacity 298.15K, C, = 23.71 calmol'K* 99.20 Smot"-K"" ‘Temperature range 11-305 K Entropy 2B1SK, 5 = 2474 calmotK" 103.51 JmolK* Molecular Weight 75.0670 Wisweser Line Notation Z1VQ Evaluation A CHO, © ‘75SPL/WAD. ‘Aminoethanoie acid; Glycine Heat Capacity 298.15K, C, = 23.7 calmot"'K* 99.3 Jmol K* (One temperature ‘Molecular Weight 75.0670, Wiswesser Line Notation Z1VQ Evaluation B GHANO, Cia) S4GRA/SMI Ethyl nitrate Heat Capacity 298K, CG, ‘Temperature range 21-283 K Entropy 298K, S$ = 59.08 calmor sk" 2472 Jmol K" Phase Changes cfg 186K, AH = 2038 cal-mot” 8527 mot" AS = 11.41 calor" 40.74 mol ‘Molecular Weight 91.0664 ‘Wiswesser Line Notation WNO2 Evaluation B Entropies, and Phase Transition Properties — Continued HNO, ©) 39SAT/SOG ‘Ammonium acid oxalate Heat Capacity 323K, CG, = 365 calmol.K" 152.7 Jot" ‘Temperature range 0 to 100°C. Mean value. Molecular Weight 107.0658 ‘Wiawesser Line Notation QVVQ &ZH Evaluation C HNO, © @2LUF/REE, Biuret Heat Capecty 29815K, C= 31.39 calmor.K"! 1313 Jmol" ‘Temperature range 5-320 K Entropy 298.15K, S = 3491 calmotK" 146.1 mot K" “Molecnlar Weight 103.0894 ‘Wiawesser Line Notation ZVMVZ. Evaluation A. GH. aia) 20WIE/HUB Ethane 17.80 cat-mot" 7448 JmolK" ‘Tenperature rage 67-3052 K, Heat capacity of aturated Heat Capacity 200K, Changes el/lig 8950K, AH = 6675 cabmol" 2793 Jmol AS = 7.46calmol.K* 31.2 Jmol. lig/s 188.46K, ‘Molecular Weight 30.0694 Wiswesser Line Notation 2H Evaluation =A CH. Gia) S7WIT/KEM. Ethane Heat Capacity 180K, CG, = 17.26.calmol*.K** 7222 5 mor'K" ‘Temperature range 15-185 K Entropy 181K, S- = 30.29calmot" 126.7 Jmol -K* Entropy from 0-15 K calculated using a Debye function, Phase Changes eliq ea7K, AH as = 318 Smo K* lig’ 141K, SH = 3514 calmol" 14703 Sot AS = 19.09 calmot"K" 79.87 Jmol!" ‘Molecular Weight 30.0694 ‘Wiswesser Line Notation 2H Evaluation = A. GH. Gia) Ethane Heat Capacity 10032K, C, “Temperature range 93-301 K (saturation line), 91-330 K, pressures from 0 to 33MPa Molecular Weight 30.0694 ‘Wlawesser Line Notation 2H Evaluation A. J. Phys. Chem. Ret. Data, Vol. 19, Suppl. 1, 196438 DOMALSKI, EVANS, AND HEARING ‘Table of Hest Capacities, Entropies, and Phase Transition Properties — Continued cH dia) ‘6ROD 2 Ethane Heat Capacity 94K, = 164 calmot K* 685 Jmot-K" From data 903-96 K. Average value over range. Phase Changes oll/ed $9.17K, AH = $82.6 calmot 2437.5 Jmol" AS = 6.49 calmo 27.15 SmolK" ‘Molecular Weight 30.0694 ‘Wiewesser Line Notation 2H Evaluation = B CHCA Gia Sout Dimethyl cadmium; Cadmium dimethyl Heat Capacity 298.15K, C= 31.35 calmol KC! 13201 5mot-K" ‘Temperature range 15-300 K Entropy D9R1SK, S = 4825 calmol 201.88 Jmol“ Phase Changes elvel 25435K, AH as ofiq 27048K, AH 17837 Jmol" AS = 692 cabmot.K* 2897 Jmol -K* lg/e 295K, AH = 9153 calmot 38296 Jmol! AS = Ma calmol.K* 1314.4mor P= 3033 kPa Molecular Weight 142.4794 ‘Wiawesser Line Notation 1-CD-1 Evaluation A. CHNO, © TBKRI/LIC Ethylenedinitramine Heat Capacity 298K, CG, = 41.9 calmol"K" 1753. 5amotK" ‘Temperature range 200-448 K. Equation only Molecular Weight 150.0938 ‘Wiswesser Line Notation WNM2MNW Evaluation = C CHO tia 4IKEN/SAG 2-Oxapropane; Dimethyl ether; Methoxymethane Heat Capacity 240K, C, = 2445 calmol\K" 102.30 Jmol = ‘Temperature range 14-240 K Estropy 20K, $= 35.03 calmolK" 146,57 Fmot Phase Changes eflig LBL66K, AH = 11798 calmol* 4936.3 Jmol" AS = 896 calmol.K" 37.49 Jmol -K lig’ 24834K, AH = AS = 2070.calmor" 36.61 JmotK™ P= 101.325 kPa ‘Molecular Weight 46.0688 Wiswesser Line Notation 101 Evaluation A 4 Phys. Chem. Ret. Data, Vol. 13, Suppl CHO Gi sret Ethanol, Ethyl alcohol Heat Capacity 298K, CG, = 268 calmot XK" 12.1 5m00K" ‘Temperature range 288-346 K ‘Molecular Weight 46.0688 ‘Wiswesser Line Notation Q2 Evaluation =D CHO Cia) Ethanol; Ethyl alcohol Heat Capacity 293K, G, One temperate Molecular Weight 46.0688 Wiawesser Line Notation Q2 Eralation CHO cia) 24WIL/DAN Ethanol; Ethyl alcohol Heat Capacity 303K, C, = 275 calmot \K" 1151 Jmol ‘Temperature range 303-338 K, Equation only. Molecular Wetght 46.0688 ‘Wiawesser Line Notation Q2 Evaluation —C CHO Gia) 25PAR Ethanol; Ethy alcohol Heat Capacity" 2980K, C= 27.1 calmot \K* 1134 Jmol ‘Temperature range 87-298 K. Value is unsmoothed experimental datum. Entropy DRIK, $= 423 cabmol-K 177.0 Smor"K"* Extrapolation below 90 K, 13.19calmol"K" Phase Changes efiq 1S87K, AH = 1186 calmor" 4962 Jor AS = 147 calmol*K* 21.22 Smol-K" ‘Molecular Weight 46.0688 Wiswesser Line Notation Q2 Evaluation — B(C).C(S) CHO Ga) 2KEL2 Ethanol; Ethyl alcohol Heat Capacity 29431K, Cy at 26.26 cal mol 109.87 Jmol ‘Temperature range 16-298 K. Value is unsmoothed experimental datum, Entropy 2RISK, $= 38.4cabmor'K* 160.7 Smol Phase Changes onli 158K, AH = 1200calmot 3021 Fo!" aS = 157 eabmol!K* 31.68 Jmol K" ‘Molecular Weight 46.0688 ‘Wiswesser Line Notation Q2 Evaluation = -BHEAT CAPACITIES AND ENTROPIES OF ORGANIC COMPOUNDS 39 Table of Heat Capacities, Entropies, and Phase Transition Properties — Continued CHO ig) Ethanol; Ethyl alcohol Heat Capacity 270K, CG, = 254 calmolK" 29MIT/HAR 106.3 Jot ‘Temperature range 190-270 K ‘Molecular Weight 46.0688. ‘Winwesser Line Notation Q2 Evaluation B CHO Ca) 29PAR/KEL Ethanol; Ethyl alcohol Entropy DRIK, $= 384.cabmol\K* 160.7 Fmot "3 Extrapolation below 90 K, 9.3 calmol KC", Revision of previous data, ‘Molecular Weight 46.0688 ‘Wiswesser Line Notation Q2 Evaluation C CHO Gig) suFI0/oIN Ethanol; Ethyl aleabol Heat Capacity 313.15K, CG, = 2837 calmol'K* 118.72 SamotK" “Temperature range 40 10 110°C Molecalar Weight 46.0688 ‘Wiawesser Line Notation Q2 Evaluation A S6ERN/WAT CHO Gig) Ethanol; Ethyl alcohol Heat Capacity 298K, One temperature ‘Molecular Weight 46.0688 Wiswesser Line Notation Q2 Evaluation = C CHO Cia) 39BYK, Ethanol; Ethyl alcohol Heat Capacity 298K, 26,7 cal motK* 17 Folk" ‘One temperature Molecular Weight 46.0688 Wiswesser Line Notation Q2 Evaluation A. CHO Gia) oswi/ziE, Ethanol; Ethyl alcohol Heat Capacity 316K, 284 calmot"K* 1188 Jamor'* Mean value 21 t0 66°C ‘Molecular Weight 46.0688 ‘Winwesser Line Notation Q2 Evaluation C CHO Gi) 61GRE Ethanol: Ethyl alcohol Heat Capacity "29815, G, = 2676 calmot"K" 111.96 Jmol -K" ‘Temperature range 16-350 K Entropy DeISK, So = Molecnlar Weight 46.0688 ‘Wiawesser Line Notation Q2 Evaluation A. Reevaluation of 29KEL2 and 31FIO/GIN ORAB/NIK CHO Gig Ethanol; Ethyl alcohol Heat Capacity 298K, G, ‘Temperature range 15 t0 $5 °C ‘Molecular Weight 46.0688 ‘Wiswesser Line Notation Q2 Evaluation B CHO ig) 6TNIK/RAB Ethanol; Ethyl alcoho! Heat Capacity 250K, CG, = 2331 calmotK"" 97.33 Jmol-K ‘Temperature range 80-250 K Phase Changes ell/ed M14K, AH = 750calmot" 3138 Jmol! AS = 6.73 calmol.K* 28.17 Jmol -K" liq 188K, AH = 1110 calmot 4644 Jmol! as “Molecular Weight 46.0688 Wiswesser Line Notation Q2 Evaluation A CHO ia) TOPAZ/PAZ Ethanol; Ethyl alcohol Heat Capacity 312K, CG, = 283 calmolK- 118.4 EmotK* (One temperature ‘Molecular Weight 46.0688 Wiswesser Line Notation Q2 Evaluation B CHO (ig) ‘6FOR/BEN Ethanol; Ethyl alcohol Heat Capacity 298.15K, CG, = 26285 calmotK* 112.33 Jemot-K" One temperature ‘Molecular Weight 46.0688 ‘Wiswesser Line Notation Q2 Evaluation B CHO Cig) THAYSUG Ethanol Ethyl alcohol Heat Capacity 298.15K, C, = 269 calmot \K* 1123 mot “Temperature range 14-300 K, Also gs, supercooled liquid, metastable crystal Entropy 29818K, $= 38.21 calmol\K* 159.86 Fol" K* Phase Changes lig = 188 calmot" Rsk, A 659 Jmol AS = 1.24 calmol 5:19 Jmol" AH = 1179 calmot* 4931 Jmol" AS = 742 calmot.K"! 31.01 Jmol." elfiq 159.00, Molecular Weight 46.0688 ‘Wiewesser Line Notation Q2 Evaluation A J. Phys. Chem, Ret. Data, Vol. 13, Suppl. 1, 198440 DOMALSKI, EVANS, AND HEARING ‘Table of Heat Capacities, Entropies, and Phase Transition Properties — Continued CHO Gia 79BRO/ZIE ‘Ethanol; Ethyl alcohol Heat Capacity 29815K, C, = 2680 calmot K* 112.15 Jmol -K ‘Temperature range 159-306 K. Results as equation only “Molecular Weight 46,0688 ‘Wisweaser Line Notation Q2 Evaluation —B HOS Cig) eOKEN/LIN Dimethyl sulfoxide Heat Capacity 298.15K, C, = 356 calmot'K" 14900 Jamo “K* ‘Temperature range 298, 43.K ‘Molecular Weight 78.1288 Wiswesser Line Notation OS1&1 Evaluation — B HOS Gi TOCLE/WES Dimethyl sulfoxide Heat Capacity 29815K, C, = 3661 calmot-K" 153.18 Jmol kK “Temperature range 5-350 K Entropy 28ISK, $= 43.12 cabmot'K" 188.78 Jmol-K" Phase Changes efig BL6TK, AH = 3434.ca-mot* 14368 Somat 1.77 calmol 49.26 Jmol"! Molecnlar Weight 78.1288 Wieweaser Line Notation OS1&1 Evaluation A. HOS Gig) 19V1S/SOM Dimethy/ sulfoxide Heat Capacity 29815K, , (One temperature Molecular Weight 78.1288 Wiswester Line Notation OS1&1 Evaluation = B CHO, Gig 25PAR/KEL. 1,2-Dihydrosyethane; 1,2-Ethanediol; Ethylene glycol Heat Capacity 2930K, C, = 35.7 calmolK* 149.4 Jmol" Temperature range 88-283 K. Value is unsmoothed experimental datum. Entropy -9RIK, |S = 429.cabmol XK" 1798 Sol" Extrapolation below 90 K, 11.46 cal mot K- Phase Changes hig 208K, AH = 2778 cal mot" 11623 mot AS = 10:5 calmol-K* 44.57 Jmol “Molecular Welght 62.0682 Wisesser Line Notation Q2Q Bralution — BKC ).CS) 4. Phys. Chem. Ret. Data, Vol. 13, Suppl. 1, 1984 CHO, Gig) 29PAR/KEL 1.2-Dihydroxyethane; 1,2-Ethanediol; Ethylene glycol Entropy DRIK, $= 39.9 calmer K* 166.9 Jamol-K Extrapolation below 90 K, 8.5 calmol.K". Revision of previous data Molecular Weight 62.0682 Wiswesser Line Notation Q2Q Evaluation C CHO, Cig) 32NEV/KUR 1.2-Dihydrosyethane;1,2-Ethanediol; Ethylene glycol Heat Capacity 2934K, C, = 348 calmol K" 145.6 J.molK" ‘Temperature range 20.2 to 784°C. Value is unsmoothed experimental datum, Molecular Weight 62.0682 Wiswesser Line Notation Q2Q Evaluation C 148.87 Jmol -K" ‘Temperature range 10 10 55°C Molecular Weight 62.0682 ‘Wiswesser Line Notation Q2Q Evaluation —B CHO, Gin esTUN/MIS 1,2-Dihydroxyethane;1,2-Ethanediol; Ethylene glycol Heat Capacity 298K, C, = 352 calmol'K* 1473 Fmo-K* ‘One temperature ‘Molecular Weight 62.0682 ‘Wiswesser Line Notation Q2Q Evaluation B CHO, Ci GTNIK/RAB 2 1i2-Dihydroxyethane; 1,2-Ethanediol; Ethylene glyco! Heat Capacity 298.15K, C, = 35.93 calmol'K* 15033 JmotK" ‘Temperature range 80-300 K Phase Changes eflig 2606K, AH = 2380 calmol* 9938 Jmol AS = 9.13 calmol!-K* 38.21 JmotK" “Molecular Weight 62.0682 Wieweaser Line Notation Q2Q Evaluation B CHO, cia) TOPAZ/PAZ 1,2-Dihydroxyethane;1,2-Ethanediol; Ethylene glycol Heat Capacity 3012K, CG, ‘Temperature range 28, 40°C ‘Molecular Weight 62.0682 ‘Wiewesser Line Notation Q2Q Evaluation = BHEAT CAPACITIES AND ENTROPIES OF ORGANIC COMPOUNDS: a able of Heat Capacities, Entropies, and Phase Transition Properties — Continued CHO, Gig TKAW/OTA 1,2-Dihydroxyethane; 1,2-Ethanediol; Ethylene glycol Heat Capacity 303K, G, = 34.7 calmol-K" 1482 Jmol" One temperature ‘Molecular Weight 62.0682 ‘Wismesser Line Notation Q2Q Evaluation —B GHO, Cig) I9STE/TAM 1,2-Dihydroxyethane;1,2-Ethanediol; Ethylene glycol Heat Capacity 298K, C, = 35.7 calmol"K" 149.3 Jmol ‘Temperature range 273-493 K Molecular Weight 62.0682 Wiswesser Line Notation Q2Q Evauation —B cHOS © TOCLE/WES Dimethyl sulfone Heat Capacity 298.15K, C, Temperature range 5-410 K Entropy 2R1SK, S Phase Changes fig 38201K, AM = 4374 calmer 18301 Jmol AS = 1143 calms 4791 Smmol'K* ‘Molecular Weight 94.1282 ‘Winwesser Line Notation WSI&L Evaluation A an) 4208B/DOE Dimethylsulfide; 2~Thiapropane Heat Capacity 298.15K, CG, ‘Temperature range 11-287 K Entropy 29R1SK, So = Phase Changes cig 17485 K, AH = 19084 cal-mol 7986.7 Jmol AS = 1091 calmot"s 45.67 Jmol 'K" lig’. 291.06K, AH = 6688 cal-mol" 2983 Jmol AS = 2298 calmot 96.16 Jmol 'K"* P= 3540kPa Molecular Weight 62.1294 Wiewesser Line Notation 1S1 Enlution A cas aig samcc/sco Ethanethiol; Ethyl mercaptan Heat Capacity 29905K, C, = 2820calmot 117.9 Jno “Temperature range 14-315 K. Unsmoothed experimental datum Entropy -29815K, S$ = 4948 calmol “XK 207.02 Jmol Phase Changes evi 19526K, AH = 1189 calmor! as Molecular Weight 62.1294 ‘Wiewesser Line Notation SH2 Evaluation A. S0SCO/FIN CHS, Gig 23-Dithiabutane; Dimethyl disulfide Heat Capacity 298.15K, C, = 3492 calmol\K"* 146.1 Samot 'K" ‘Temperature range 13-352 K Entropy 298ISK, $= S626 calmot\K" 235.39 Jmol" Phase Changes eviq 18844K, AH = 21971 cab mor" 9192.7 Snot" AS = 11.66 calmot" 48.78 Jmol -K" Molecular Weight 94.1894 Wieweaser Line Notation 1SS1 Evaluation A CHN Cig) 39AST/EID Dimethylamine Heat Capacity 28044K, C, = 32.69 calmot" 1367 JamolK: Temperature range 14-280 K. Value for saturated liquid. Entropy 26003K, $= 41.35 calmotK" 17385 Fmol ik Saturated liquid at boiling point. Phase Changes cfg 19097K, AH = 1420 calmor $941 Jmol" AS = 7.85 calmot"-K* 32.83 Jmor/K" lig/e 280.03 K, (6330 cal mol" 26485 Jmol" AS = 22.40 calmot" 9458 Smol-K"! P= 101325 kPa Molecular Weight 45.0840 Wiswesser Line Notation IMI Evaluation A. CHNOS © 40HUF/FOX 2-Aminoethanesulfonic acid; Taurine Heat Capacity 303K, CG, = 339 calmol"K* 140.56 Jamot-K" ‘Temperature range 90-298 K. Value is unsmoothed experimental datum. Entropy 208.1SK, S = 368 calor 1840 Jmol .K" Extrapolation below 90K, 10.86 calmot -K Molecular Wetaht 125.1622 Winweaser Line Notation Z25WQ Evaluation B(C).CS) J. Phys. Chem. Ret. Data, Vol. 13, Suppl. 1, 198442 DOMALSKI, EVANS, AND HEARING ‘Teble of Heat Capacities, Entropies, and Phase Trans CHNO, © sOHUF/ELL Guanidine carbonate Heat Capacity 298.1K, C, = 61.87 calmol\K* 258.86 Jamol"-K* ‘Temperature range 86-298 K. Value is unsmoothed Entropy 298K, $= 7059 calmolK! 29535 Fo -K" Extrapolation below 90 K, 2:31 cal mol "K"! Molecular Weight 121.0856 Wiswesser Line Notation ZYZUM 2 8QVQ Evaluation A(C).C(S) CHM, Gig) SOHOU/MAS 12-Diaminoethane; Ethylenediamine Heat Capacity 313K, C, = 42.7 calmol'K* 178. Smo Temperature range 313-333 K Molecular Weight 60.0986 Wiawesser Line Notation 222, Evaluation B CH, ia) 75MES/FIN 1,2-Diaminocthane; Ethylenediamine Heat Capacity 298.15K, C, = 41.25 calor \K" 17259 Jamol \K" “Temperature range 11-335 K Entropy 298:15K, $= 48.38 cal-mol™K" 202.42 Jmol -K" Phase Changes clive 1890, 165 calmer 4978 Fol" AS = 0162 calmot"-K* 2.58 Jmol -K" oti 28429K, AH = 53973 calmot” 22585.1 Jmol 1899 cakmol -K* 7948 Semol"K" Molecular Weight 60.0986 Winwesser Line Notation 222 Evaluation A CHAN, cig) ssast/woo N.N-Dimethylhydrazine Heat BBISK, C, Temperature range 13-300 K Entropy (29RISK, S Phase Changes efiq 21S98K, AH = as 4664 Jmol-K" lis 285K, OH as P “Molecular Weight 60.0586 ‘Winwesser Line Notation ZNI&1 Evaluation A Phys. Chem. Ret. Data, Vol. 13, Suppl. 1, 1984 jon Properties — Continued CHNO, © 39SAT/SOG ‘Ammonium oxalate Heat Capacity 323K, C,_= 506 calmot'K* 211.7 }molK" ‘Temperature range 010 100°C. Mean value. ‘Molecular Weight 124.0962 ‘Wiswesser Line Notation QVVQ &ZH 2 Evaluation = C CHAN, © BIRAH/CLA “Tetrchlorobis-(methylammonium) cadmium T Heat Capacity 298.15K, C= 626calmol"K" 2619 Sam0tK* ‘Temperature range 2.3-301 K Entropy 285K, S Phase Changes clV/ell 162K, AH = 418 calmot" 1749 Jmol" AS = 258 calmol.K" 10.8 Jmol “K* ele 282K, AW = 159 calmor 66.5 Jmol" AS = 006 cabot K"* (025 JmolK" ell/et 484K, AH = no data given ‘Molecular Weight 304.3455, ‘Wiewester Line Notation CD Z182 G4 Evaluation = B CHLCLMAN, (© 2WHI/GRA “Tetrachiorobis-(methylammonium) manganese I Heat Capacity 298.15K, C= 630 calmot -K" 263.6 mot -K" “Temperature range 10-300K Entropy 298.ISK, S = 963 cabmot\K" 4029 Senor" Phase Changes eill/ell9837K, AH = 174 cabot" 728 Yet" AS = 185 calmot\K* 176 Samol 'K" elvet 25102K, AH = 28 almol 117 mot" AS = 01108 calmot".K" 0452 JamolK: Molecular Weight 260.8802 Wiewesser Line Notation MN Z182 G4 Evaluation A CPB, Cig) 49WUY/UN 2-Dibromoethane-d, Heat Capacity 310K, C, = 35.64 calmol"'K"! 149,12 mot" One temperature ‘Molecular Weight 191.8864 Wisweser Line Notation E2E &2/H-2 4 Evaluation CHEAT CAPACITIES AND ENTROPIES OF ORGANIC COMPOUNDS 43 ‘Table of Heat Capacities, Entropies, and Phase Transition Properties — Continued cM dig) S9RUE/GIA Cyanogen Heat Capacity 285K, C, = 25.27 calmolK! 105.73 JmolsK" ‘Temperature range 15-252 K Entropy 282.0K, $= 33.18 calmotK" 138.83 JmolK" Phase Changes eng 245.32K, AH = 1938 calmot 8109 Jamo! AS = 790 calmot-K* 33.05 Jmol.K"! lig’ 2520K, 1576 cal mot" 23330 Jmol" AS = 22.13 calmot kK" 92.58 Jamol-K* P= 101325 kPa ‘Molecular Weight 52.0354 ‘Wiswesser Line Notation NCCN Evaluation A. ENO, @D TOKRI/LIC Hexanitrocthane Heat Capacity 291K, C, = 78 calmol"LK* 327 Jmol -K" ‘Temperature range 190-350 K Phase Changes ole 291K, AH = 2964 cal-mot 12400 Jmol AS = 102 calmot-K* 42.6 Jmol"K" ‘Temperature range 289-292 K; 291 K assumed, Molecular Weight 300.0350 Wiswesser Line Notation WNXNWNWXNWNWNW Evaluation —C NAO, ©) 31CHE/CHE ‘Sodium oxalate Heat Capacity 281K, CG, = 31 cabmol.K"* 130 Jmol'K* ‘Temperature range 273-373 K. Mean values, three temperatures Molecular Weight 133.9992 Wiswesser Line Notation OVVO .NA 2 Evaluation C com © OKAP/STR ‘Lead() oxalate Heat Cepacity 29937K, G, yy = 2434 cal-motK" 102.7 Jamot-K* ‘Temperature range 66-300 K, Valve is unsmoothed ‘experimental datum. Entropy 2KIGK, $= 349.calmol\K* 146.0 anol -K"* Extrapolation below 66 K, 6.7 calmol-K". Molecular Weight 295.2196 Wiewesser Line Notation OVVO .PB Evaluation B GHNO © TIGAN/PAR ‘Urea-I-dodecene adduct; 1-Dodecene-rea adduct Heat Capacity 298.15K, C, = 303 calmol'K* 1286 Fmot'K" ‘Temperature range 12-300 K. Values for one mole of urea in adduct. Entropy BRISK, S = 33.8 calmolK? 141.3 molK" Does not include possible zero-point entropy. Phase Changes ‘Anomalous region 225-235 K, AH = 2 Jmol"(urea), AS 0.010 Jmol" ole 820K, AH = 102cabmol" 426 Jmol AS = 12cabmor.K? 32. 4mor'K* Molecular Weight 77.8975 Wieweaser Line Notation 11UL &ZVZ Evaluation B HNO 6900P/PAR ‘Urea-n-undecane adduct; n-Undecane-ures adduct Heat Capacity 298.15K, C, = 309 calmolK"! 129.2 Jmol-K" ‘Temperature range 12-300 K. Values for one mole ures in adduct. Entropy 2BISK, $= 33.0 cabmor'\K* 138.0 Jmor-K" Does not include possible zero-point entropy. Phase Changes ‘Anomolous region 225-235 K, with AH = 14 J-mol (urea) and AS = 0.061 J-mol“K" ell/el 124K, AH = 346 camel! 1446 Jmol" AS = 028 calmol-K"* 18 Jmol K" Molecular Weight 77.2496 Wiswesser Line Notation ZVZ &11H Evaluation B CHINO © @®COP/PAR ‘Urea-I-hexadecene adduct; I-Hexadecene-urea adduct Heat Capacity 298.15K, C, = 31.0calmol XK" 129.6 4motK" ‘Temperature range 12-300 K. Values for one mole urea in addvct. Entropy 281SK, $= 33.7 calmer’ K* 141.2 Jmol" Does not include possible zero-point entropy. Phase Changes "Anomolous region 225-235 K, with AM = 23 Jmot(urea) and AS = 0.101 Jmol ele W4L7K, AW = 33.5 calmot" 1402 Fmot" AS = 0.24 calmor!K* (099 Jmol !K* Molecular Weight 79.3563 Wiewesser Line Notation 1SUl &2VZ Evaluation B J. Phys. Chem. Ref, Data, Vol. 13, Suppl. 1, 1984DOMALSKI, EVANS, AND HEARING ‘Table of Heat Capacities, Entropies, and Phase Transition Properties — Continued GHNO © ‘68COP/PAR Urea-1-decene adduct; I-Decene-urea adduct Heat Capacity 298.15K, C, = 320calmot\K* 133.7 bmol-K" ‘Temperature range 12-300 K. Values for one mole urea in adduct Entropy 29BISK, S$ = 348 calmorK" 148.4 Smo" ‘Does not include possible zero point entropy. Phase Changes ‘Anomolous region 225-235 K, with AH = 10 J:mot'\(urea) ‘and AS = 0.085 Jmol \K" ‘Molecular Weight 79.2721 ‘Wiswesser Line Notation ZVZ &9UI Evaluation B CHNO © TRGAN/PAR “TOctadecene-urea adduct; Urea-I-octadecene adduct Heat Capacity 298.15K, C, = 306 calmot'K" 128.1 JmorK" “Temperature range 12-300 K. Value for one mole of urea in adduct. Entropy 2981SK, $= 339 cabmol™K" 1420 Imo K* oes not include possible zero-point entropy. Phase Changes ‘Anomalous region 225-235 K, AM AS = 0.089 Jmol "K” 12 Smot (urea) and elle 1559K, AH = 460calmol* 1926 Jmol* AS = 30calmol\K* 124 Jmol -K Molecular Weight 79.8893 Wiswesser Line Notation 17U1 &ZVZ. Evaluation B CttyNO ©) 6#COP/PAR ‘Grea-t-cicosene adduct; I-Hicosene-urea adduct Heat Capacity 298.15K, CG, = 309 calmol'K* 1292 Jmol “Temperature range 12-300 K. Values for one mole ures in adduct Entropy RISK, = 33.4calmolK! 139.6 mol*K" ‘Does not include possible zero-point entropy. Phase Changes ‘Anomolous region 228-235 K, with A = 1 Jmol “(urea) fand AS = 0.002 J.mol-K° ell/ed 139K, AH = 239 calmot* 100.0 mot" as mot K* (065 Smol'K* ‘Molecular Weight 79.6929 ‘Wiswesser Line Notation 19U1 &2VZ. Evaluation —-B 4. Phys. Chem. Ret. Data, Vol. 13, Suppl. 1, 1984 CFO ig) GTPLA/PAC. “Hexafluoropropanone; Hexafluoroacetone Heat Capacity 245K, 43.33 calmol\K"! 181.29 mol" ‘Temperature range 12-244 K Entropy 24587K, $= 68.50cal-molK" 286,60 J-mol-K"! Phase Changes: fig M4770K, AH = 2003.5 calmol* 8382.6 J-mo AS = 13.58 calmot“K* 56.75 Smol"K" lig/e 24387, AH = $166 cabmot™ 21615 Jmol" as P= 101325 kPa ‘Molecular Weight 1660228 Wiswesser Line Notation FXFFVXFFF Evaluation A Oh ia) Perfluoropropane; Octafluoropropane Heat Capacity 235K, C, = 43.38 cahmol"\K? GTPAC/PLA, 181.38 Jmol" ‘Temperature range 14-236 K Entropy 23642K, $= 68.65 calmol"-K" 287.23 Jmol“K" Phase Changes ele 939K, AM = $49.8 calmol 3555.6 Jmol! AS = 855 calmol'K* 35.77 motK" eliq 12345K, AH = 114.1 calmor 4774 Semol" AS = 091 cabmol.K 381 Jmol“K" lig’ 23642K, AH = 47230calmol" 19761 mot" AS = 19.98 calmot"K" 83.58 J.mol*K P= 101325 kPa ‘Molecular Weight 188.0202 ‘Wiswesser Line Notation FXFFXFFXFFF Evaluation A. GHAR, Gia) 3-Chloro-I, Heat Capa 74VOR/KOL “Temperature range 12-300 K. Data in paper deposited at \VINITI, No. 6783-73, 25 Sept. 1973 Entropy 2KISK, |S = 74.48 calmolK* 403.67 Jmol -K"* Phase Changes fig 16542K, AH = 2503 calmot 10473 Imo! AS = 15.13 calmor'K* 6331 Smor'K" Molecular Weight 168.4938 ‘Wiswesser Line Notation GXFFIXFFF Evaluation AHEAT CAPACITIES AND ENTROPIES OF ORGANIC COMPOUNDS CHOY, Gi Trichloro-3,33-triftuoropropane Heat Capacity 298.15K, C, = 47.78 calmol\K? 199.91 Jmol K" ‘Temperature range 12-300 K. Data given in paper deposited at VINITI, No. 1760-70, 21 May 1970. ‘TIKOL/VOR Entropy RISK, $= 7443 calmolK" 311.42 Jmol." Phase Changes fig 232.69K, AH = 3362 calmot" 14067 Jmol" AS = 1445 calmotK" 60.43 JmolK" ‘Molecular Weight 201.4030 ‘Wleweaser Line Notation GXGGIXFFF Evaluation A. CHS, eswes/WUL, Malononitrle; Dicyanomethane Heat Capacity 298.15K, C, = 26:36 calmol\K"* 110.29 SmorK" “Temperature range $-320 K, Entropy 298.15K, $= 31.30calmothK" 130.96 Samol-K" Entropy as calculated from data on undercooled, el from 5K and from data on ell, 11/1 transition, and eis the Phase Changes “Transition between stable eI and metastable 6] between, 255-270 K; maximum in C, at 260.3 with AH! = 302 ccalmol and AS = 1.15 cal-mot"'K". Metastable c,1 can be ‘undercooled to $ K, ellig 30499K, AM = 2580 calmol* 10795 Imo! AS = 8.46 calmol-K* 35.39 Jmol -K" Molecular Weight 66.0622 ‘Wiswesser Line Notation NCICN Evaluation A. CHF, Cig) ‘TKOL/VOR 1,1,1-Trifluoro-3,3-dichloropropane Heat Capacity 298.15K, C, = 48.72calmol\K* 191.29 Fmot-K"* ‘Temperature range 12-300 K Entropy 2RISK, $= 7082calmolK" 295.06 Jmol." Phase Changes cle 164K, AH = -2152 cabot" 300 J-mol* “Metastable crystal transition. Non-equlibrium, ele 16.7 K, AH = 480 cabmot" 2008 Sot" AS = 029 calmot .K" 1.20 Jmol" elig 182.16K, AN = 2422 calmer 10134 Samet! AS = 13,30 cabmot".K* 3563 Jmol Molecular Welght 166.9579 Wieweaser Line Notation GYGIXFFF Evaluation A. 45 ble of Heat Capacities, Entropies, and Phase Transition Properties — Continved GHN aig) ASDAV/WIE ‘Acrylonitrile; Cyanoethene; Vinyl eyanide Heat Cepacity 298K, | C, = 27 cabmot“K* 113 mor K"* (One temperature Molecular Weight 53.0634 Wiswesser Line Notation NCIUt Evaluation D HN Gig) 7IHAL/BAL ‘Acrylonitrile; Cyanoethene; Vinyl eyanide Heat Capacity 297K, | C, = 255 calmot“-K* 106.7 mot sk" ‘One temperature “Molecular Weight 53.0634 Wiswesser Line Notation NCIUL Evaluation C HN Gig) 7 AFIN/MES: ‘Acrylonitrile; Cyanoethene; Vinyl cyanide BRISK, C, = 2600 calmot 108.78 Jamol.K"! Heat Capacity ‘Temperature range 12-350 K Entropy 285K, 5 Phase Changes elle 1625K, AH = 2840 calmot 11883 Jmot" AS = 175 cabmolK* 731 Jmol." eAiq 189.63 K, AM = 1489.0 calmot" 62300 Jmol AS = 785 calmol\K* 32.85 Jamot\K" Molecular Weight 53.0634 Wiswesser Line Notation NCIUL Evaluation A GHNS Cig) 68GOU/WES 2 Thiazole Heat Capacity 298.15K, CG, Entry 298ISK, Phase Changes efi 294BK, AH = 2292 calmer" 9390 Fmot* AS = 937 calmot.K* 4008 Jamot-K" Molecular Weight 85.1234 ‘Wiswesser Line Notation TSN CSI Evaluation A HANS Cig) @sou/cou2 Thiazole Heat Capacity 298.15K, C= 2892 calmot-K" 121.00 Jmol-K" “Temperature ange 4-350 K Entropy 29813K, $= 40.62 calmot".K" 169.98 Snot -K" Phase Changes “Anomaous region 15-175 K efi 23883K, AH = 22920calmot" 9539.7 Jmol" as ‘Molecular Weight 85.1234 ‘Wiawesser Line Notation TSN CSI Evalsation A. J. Phys. Chem. Ret. Data, Vol. 13, Suppl. 1, 198446 DOMALSKI, EVANS, AND HEARING ‘Table of Heat Capacities, Entropies, and Phase Transition Properties — Continued CAN © 79BRI/MIL, CHA, ai) 74KOL/VOR seTriazine 1,11,3-Tetrachloropropane Heat Capacity 298.15K, C, = 22.8 calmol".K* Heat Capacity 298.15K, CG, = 46.4 calmol \K 95.6 Fol -K" 196.40 Jmol\K" ‘Temperature range 160-382 K ‘Temperature range 12-300 K Phase Changes Entropy B8.15K, So 6798 calmol'K* “Transition between 130 & 177 K with AH = 75 Jmol 284,30 Fol -K"* eg 3539K, AH = 3486 calmol! Phase Changes 14884 Jmot" ele 2199K, AH = 527 calmer! AS = 985 calmot"-K* 2205 Jmol! 41.21 Jmol" AS. = 240 calmolK" “Molecular Weight 81.0768, 1003 Jot 'K" Winwesser Line Notation TSN CN ENT elfiqg 274K, AH = 2807 calmot Evaluation B 10489 Jmot" AS = 1055 calmolsK" CHAR, Gia 7KOL/VOR 44.12 mot K* 1,1,1-Triftuoro-3-chloropropane Molecular Weight 181.8766 Heat Capacity 29815K, C, = 40:89 calmol“K"" ‘Wiswesser Line Notation GXGG2G 171.08 JsmolsK" Evaluation A ‘Temperature range 12-300 K Entrory DIRISK, S = 6493 calmol"-K"" 271.67 Snot Phase Changes elle 160K, AH = -605.4.calmot" CHO, ©) 7BVAS/KOR 25330 Snot" Ethylene carbonate Metastable crystal transition. Non-eguilibrium, Heat Capacity 298.15K, C, = 28.07 calmol"K"* elVel 168K, AM = 1073 calmot" 11748 Jmol 4489 Jmol" ‘Temperature range 52-310 K. Full data deposited in AS = 632 calmot"-K* VINITI, No, 326-73, 21 June 1973 26.44 Jeno!" Entrony 28815K, $= 31.68 calmol-K" elig 17940K, AH = 1270¢almot" 132.8 Jmol K* $314 Jmol! Extrapolation below 52K AS. = 708 cabmol-K" Phase Changes 29.62 Jmol“! efi 30949K, AH = 3178 calmot" Molecular Wetght 132.5128 13295 Jmol Wiswesser Line Notation G2XFFF AS = 1027 calmor Kk" Evaluation A 42.96 Jmol" “Molecular Wetght 88.0528 CHAR, cia) 74KOL/VOR ‘Wisweaser Line Notation TSOVOTS 1,1;1-Trifluoro-3-chloropropane Evaluation -B Heat Capacity 298.18K, C= 40,89 calmol\K"* 17108 Jomol-K" ‘Temperature range 12-300 K Entrony 28.1SK, S = 6493 cabmolK" 20167 dol K" CHO, cia) SePEP Phase Changes Ethylene carbonate clli/eq 116K, AH = -605 calmor" Heat Capacity 323.15K, C, = 320.cabmot"\K" “2531 Jenol! 1339 Jmol" Maximum temperature of metastable phase. AH obtained One temperature from total heat 115-137 K, calculated to 116 K. Not ‘Molecular Weight 88.0628 reversible. Wiswesser Line Notation TSOVOTS eli/est 1698K, AH = 1073 cabmot” Evaluation C 14489 Jmol! AS = 6.32 calmol'K* 2644 Jmol "K"! lig 179.32K, AW = 1207 calmot” 3030 mot! AS = 6.73 calmot'K* 28.16 Jmol\K" Molecular Weight 132.5128 Wiswesser Line Notation G2XFFF Evaluation A J. Phys. Chem. Ret. Data, Vol. 13, Suppl. 1, 1984HEAT CAPACITIES AND ENTROPIES OF ORGANIC COMPOUNDS a7 ‘Table of Heat Capacities, Entropies, and Phase Transition Properties — Continued GHDO, Cia) @RAB/NIK 1,23-Tribydrorypropane-

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