/

quantum dots
Quantum size effect
Kondo effectsmagnetic
order

Kondo effects1
1960

0.001-0.03 at. %

CrMnFe

Kittel 2

Kondo theory or Kondo ion

Exchange integral J

model

Singlet state

Single ion

Single ion model a

(a)

Dilute magnetic alloy

(b)

Kondo theory

(a)

2006 10
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(b)

Sommerfeld coefficient Fermion

Heavy Fermion Compound

paramagnetism
~C/T

Kondo effect Kondo

temperature TK

Kondo temperature TK

TK>kBT

TK=R/6 R =8.31 J/K

(1)

T << TK (T)~ constant

Kondo lattice

TK

Kondo effect Kondo

Sommerfeld coefficient

cloud

FeCoNi

C(J/K mole)

RKKY

H=6.5T

Ruderman-Kieeel- Kasuya-Yosida(2)
RKKY Kondo effect

H=2.6T
1

KBT RKKY

H=0T

RKKY Kondo effect

T(K)

Kondo lattice Kondo effect Kondo

lattice

CeAl2 (, d~ 8 nm)
Kondo
theory TK=0.65 TK

Ce

Kondo lattice

Kondo

effect. Kondo effect

Ce, Pr,

Kondo lattice

Sm..

CeAl2, CePt2

CeAl2,

Quantum dot
CeAl2

CePt2

Kondo lattice Ce Ce3+

CeAl2 2.54B

Kondo effect

0.7BCeAl2 Kondo effect

Kondo lattice

RKKY interactions Kondo temperature TK

~5-6 K RKKY interactions

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828

 Kondo effect
TN=3.8 K
RKKY interactions Sommerfeld
-2

C/T(J/mol K )

coefficient 1790 mJ/mol

2

-1

Ce K ~ 150 mJ/mol Ce K

2.0

C/T(J/K mole)

80A & Bulk CeAl2

1.5

1.0

80 A

6
4

TN

2
Bulk
0

0.1

10

T(K)

Ce Al2

0.5

0.0

10

20

30

40

50

T(K)

Kondo effect RKKY interactions

CeAl2
TN ~ 3.8K

Ce3+
Kondo effect Kondo
temperature TK 5-6 K 0.5 K
CeAl2
~ 9000 mJ/mol Ce K2

CePt2
CePt2
2.8K 150 mJ/mol Ce K2

26223.1 nm

10 nm

TN Kondo effect
Kondo temperature TK

CeAl2 (TEM)
8 nm

extended x-ray
absorption fine structure (EXAFS) CeAl2

CeAl2

CePt2 ()

8 nm x-ray

disorder

CeAl2

CeAl2

CeAl2

~ 9000 mJ/mol Ce K2

2006 10
829

3. Y.Y. Chen, Y.D. Yao, C. R. Wang, W.H. Li, C.L. Chang,

T.K. Lee, T.M. Hong, J.C. Ho and S.F. Pan ,Phys. Rev.
Lett. 84, 4990(2000)
4. S.-W. Han, C.H. Booth*, E.D. Bauer, P.H. Huang, Y.Y.
Chen and J.M. Lawrence Lattice Disorder and
Size-Induced Kondo Behavior in CeAl2 and CePt2+x,
Phys. Rev. Lett. 97, 097204(2006)

extended x-ray absorption fine structure

(EXAFS) Ce Pt disorder
4

E-mail: cheny2@phys.sinica.edu.tw

1. Jun Kondo, progress of theoretical physics, 32, 37

(1964).

2. Introduction to solid state physics, C. Kittel (6

th

E-mail: oumn@phys.sinica.edu.tw

edition) p598.

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