Adva PI Sol

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CRT II
(Paper-1)
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Q.
No.
1.
PHYSICS
CHEMISTRY
MATHEMATICS
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
B, D
A, B, D
12.
A, B, C
A, B, C, D
A, B, C, D
13.
A, B, C
A, B
14.
B, D
A, B, C, D
A, B, C
15.
A, B, D
B, C, D
A, D
1.
2.
3.
4.
5.
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
Physics
PART I
dm
Av 2
dt
(Av 2 )H
3.
F ve
7.
NH qE cos
mv 2
R
(i)
NH 0
( NH horizontal component of normal force)
qER(1cos ) =
8.
9.
1
mv 2
2
qE
F 0.02

A
n 10 10 3 kg / ms 10 2 poise
2
dv

1
dx

Velocity of bike Vb = 30 m/ s
Let velocity of car be Vc
Vso Vb
Vso Vc
330 30
120 Hz = 100 Hz
330 Vc
f obs = factual
VC = 30 m/s
Distance between initial and final pulse of horn
= Vso t - VC t
{t is duration of emission of sound}
= (330 30) 6 = 1800 m
This wave train travels with 330 m/s and cross bike rider moving with velocity of 30 m/s towards
it.
length of wave train
1800
180
time taken =
=
5 sec
330 30 36
Vso Vb
11.
Kinetic friction acts opposite to relative velocity w.r.t. contact surface.
12.
XL = 2XC
XC = 4XC
XL = 2XL
XL XC = 2XL 4XC = 2[XL 2XC] = 0
14.
Since vertical Impulse is acting on A

Hence momentum of A & B will constant in horizontal direction only.
and M.E. of A & B will remain constant
SECTION C
1.
Angular momentum Conservation

MR 2
1
MR 2 0
mR2 '
2
2
M
M 2m 0 '
M
U = 'R
0R
M 2m
2.
M.E. Conservation
k
1
mg(4) x 2 mv 2
2
2
kx = 55
mg + kx = ma
5520 = 2a
a = 17.5 m/sec2
3.
qBR
=
t = 0.4
mg
5.
t=
dE B2 2C M
1000 sec = 1
Bmg
Chemistry
PART II
SECTION A
1.
In (C), the tautomeric form will be

O
H 5C 6
C6 H5
OH
H 5C 6
C 6H 5
H5 C6
C 6H 5
H 5C 6
C6 H5
The tautomeric form, contains sp-hybridised carbon in ring, making it unstable.
tautomerism is not shown by (C).
2.
2AgBr 2OH HO
Hydroquinol
3.
O 2Br aq
OH 2Ag s 2H2O O
Hydroquinone
PV = constant
105V
P1
Cons tan t
100
P 105
1
1
P 100
7
4.
5.
P 100 5
or 1
P 105
( for N2 or O2 = 7/5)
P1 = 0.93P,
7% decrease in pressure.
O2 is replaced by X-8/3, so formula of spinel is MgAl2X3 and deficiency by one anion.
W RT
M V
RT
Slope
M
0.082 293
M
3
3
4.65 10 10
6
5.16 10 g
6.
Cl
PBr5 s PBr4 Br

PCl s PCl PCl sp d
Cl O s ClO ClO sp
N2 O5 s NO2 NO3 sp2
Cl
P
3 2
Cl
Cl
Cl
Cl
7.
(I)
(II)
(III)
(IV)
H
H
(Conjugate base)
(Aromatic)
(anti-aromatic)
(Non-aromatic) (anti-aromatic)
(III) and (IV) both are anti-aromatic, but (IV) has more resonating structures than (III).
So, stability of conjugate bases: (I) > (II) > (IV) > (III)
And pka order is: (I) < (II) < (IV) < (III)
8.
pH = 9.71, H 1.95 10 10
Pr NH2 HCl
Pr NH3 Cl
Ka
Pr NH2 H
Pr NH3
Pr NH2
Ka
H Pr NH3

Pr NH2
0.1
Pr NH3
CH2
9.
CH2OH
Cl
COOH
CH2
dil
aq. NaOH
acidic
COOH
O
Na Cr O
2
O
COOH
O Pr oduct(C8H4O3 )
COOH
O
10.
Me
Me
CH
CH CH2
H / Ni B
2
2
p 2 catalyst
Me
Me
CH CH3
Ring exp ansion
Me
CH3
Me
11.
CH3
CH3
CH3
CH3
Trans - 1, 2 - dimethyl cyclohexane
Trans - 1, 3 - dimethyl cyclohexane
No plane of symmetry in both the above isomers, hence optically active.

12.
NO BF4
F
F
No. of bonds in BF4 4
= B. O. of NO 3.0 , i.e. one sigma bond and two bonds.

It has 5 sigma and two , bonds.
NO+ is diamagnetic and BF4 is also diamagnetic
BF bond energy is lower in BF4 than in BF3, due to presence of back bonding in BF3.
13.
o
E 2H / H E2H
/H
2
14.
15.
1.
p H2
0.059
log10
2
2
H

Ho Hof products Hof reac tan ts
= 166 (51) = 115 KJ mol1

So = 266 243 = 23J = 0.023 KJmol-1K-1
Ho = ve
So = +ve
Go = Ho - TSo
Go will be ve at all temperature and the reaction is favour at temperature.
Formula of complex is : [Co(SCN)2(NH3)4]3[Co(ox)3]
Linkage isomerism is due to presence of SCN
Optical isomerism is exhibited due to presence of [Co(ox)3]3 which has asymmetric structure.
Geometrical isomerism is exhibited by [Co(SCN)2(NH3)4]+ part
SECTION C
AgNO3 H2S 2O3 Ag2S
Black ppt
2.
F
Sb
F
F
Sb
F
F
F
Sb-hybridisation is sp3d2 = total 6 hybrid orbitals per sb-atom.
3.
O
O
RCO H
Pr oduct X
2
The number of sp carbon is X are 10, the sum 1 + 0 = 1

4.
nM s nX Mn Xn ne
For, Mn Xn ne nM nX
5.
L.H.S
R.H.S
0.059
0.01
log10
n
0.1
n=2
1
1
A 2 B2 AB
2
2
1
1
H eA A eB B e A B
2
2
x 0.5x
100 =
x
2
2
x = 400 KJmol1
x = 4 102 KJmol1
Mathematics
1.
PART III
u xi 3xj , |u| = 2x, x > 0

2
Now u u 2i u i
2
2
2 x x 2 3x2 x 1 3x 2
4 x x 2 x 1 4x 2 2x 1
Squaring, 16x2(x2 x + 1) = 16x4 + 4x2 + 1 16x3 4x + 8x2
2
2
16x = 12x 4x + 1
4 32 1 2
x
8
2
x = 2 1
u 2 1 2 1
a = 2, b = 1
2.
2000x6 + 100x5 + 10x3 + x 2 = 0

2000x 6
10x 1
x 1000x 1
6
2 0
x 10x2 1
10x2 1
2 1000x6 1
1000x6 1= 0 or
x
10x 2 1
x = (10x2 1)
1
x2
which is not possible
10
20x2 + x 2 = 0
1 161
x
, m = 1, n = 161, r = 40
40
(m + n + r) = 200
3.
Let P(a cos , b sin )

b
Slope of cp tan
a
2
C (0, 0)
y
a b
sin2
2ab
2ab
sin2 2
tan
a b2
tan
Using sin 2 1 and e2 1
P()
b2
a2
b
2
a tan 1 2 1 e tan 1
e2
b2
1 2
a
4
2
2
3
e + 4e tan 4 tan 0
2
e2 2 tan sec tan
4.
2sin
1 sin
k 1 k k 1 k 2
1
Tk cos1
k k 1
k k 1
1
1
Let x , y
k
k 1
1 y2 1
k 1
k 12 1
k 1
k k 2
k 1
1
1 1
Tk cos1
, substituting n = 2, 3, 4
cos
k 1
k

1
1 1
S lim cos 1

cos
n
n 1
2 2 3 6
120
Sn
6
k
k = 720
5.
6.
EAC =
EAB = +
It is given that tan( ), tan and tan( + ) form a G.P.
tan2 tan2
Thus tan2 tan tan
1 tan2 tan2
tan = 1, = 45, thus
1
AD = DE = 5 2 , so that area (ABC) = BC AD CD AD 50 tan
2
Now, cot , cot( ), cot form an A.P.
2 cot(45 ) = 1 + cot cot = 3
50
ABC
3
ABCD is a trapezium and its area =
1
a bh
2
ab
EF (mid parallel)
2
Area = 2r(EF)
Now equation of EF is y = x + c
From equation (1) passes through (r, r)
c = 2r
x + y = 2r, hence E = (2r, 0) and F(0, 2r)
Where
.. (1)
EF 4r 2 4r 2 2 2r
Area ABCD = 2r 2 2r 4 2r 2
2
4 2 r 2 900 2 , r = 225 r = 15
7.
A2 2A + 2I = 0
Divide B by A2 2A + 21
B = (A2 2A + 21)(f(A)) + A I
10
0 1
B A I
1 0
8.
FG = p
DE = q
HI = r
A
F
E
H
P
AG
AF
In AFG
sin A sinB sinC

bp
cp
B
I
D
AG
, AF
a
a
Now, incircle of ABC is the excircle opposite to A for AFG the semi perimeter of AFG is
1
bp cp Sp
S AFG p
2
a
a a
A Sp
A
r S AFG tan
tan
2
a
2
A
Since r = (s a) tan
2
sp
p
a
sa
1
a
a
s
q
b
r
c
Similarly 1 1
b
s
c
s
9.
Since the coefficient of k in both A and B are the same, the only way that A and B can be
parallel is that f(t) = f(t), f(t) = g(t)
The first differential equation, f(t) = f(t)
p
f(t) = p cos t + q sin t. (p, q R) = p2 q2 sin t , tan
q
fmax t M p2 q2
A f 2 t g2 t 1 p2 q2 1
A is constant
10.
A upon simplification (a + b + c) (a b) (b c) (c a)
The only way this can be 0 is (a + b + c) = 0
fixed point is (1, 1)
x
11.
t f x t dt f t dt sin x cos x x 1
0
x
x t f t dt =
f t dt sin x cos x x 1
0
f t dt t f t dt f t dt sin x cos x x 1
Again differentiating
x f(x) + f(x) + f(x) xf(x) f(x) > f(x) sin x cos x
f(x) = f(x) sin x cos x
Solving this linear differential equation
We get, f(x) ex = ex cos x + c
If x = 0, f(0) = 0 f(x) = ex cos x
11
12.
Let w be the event that the ball drawn is white

x
Then P(w) =
y
When, ball is lost P(w) =
x x 1 y x x
x
y y 1
y y 1 y
x
When 2 balls is lost P(w) =

Similarly for n = 3, P(w) =
13.
C2 x 2 x C1 y x C1 x 1 y x C2 x
x
y
y
y2
C2 y 2
C2
C2 y 2 y
x
y
v uz
uz
uz 1
uz 1
Let, |w| 1
|u z| uz 1
(u z) u z uz 1 uz 1
(|u|2 1)(|z|2 1) 1
|z|2 1 0
w
14.
f(0) = 0, f(0+) = 1, f(0) = 1

discontinuous at x = 0
f(1) = 1, f(1) = 1, f(1+) = 0
discontinuous at x = 1
15.
Squaring and adding

sin (x + y) = 1
x + y = 4n 1 , n I
2
x+ y= , y x
2
2
5 sin x = 3
4
cos x =
5
3
4
Also, cos y =
and sin y =
5
5
Hence, y > x
SECTION C
1.
f x
1
2
1
2
.....
1
2
n
n 2
n 2n 1
Terms of the sequence are decreasing and number of terms are (2n + 2)
2n 2
2n 2
f x
2
n 2n 1
n2
1
2n 1
2 n 1
Now lim
= lim
2
n
n
2 1
n 2n 1
n 1 2
n n
Similarly lim
2 n 1
2 n 1
2
n
n
= lim
/ 2
2.
I1
12
/2
sin x r cos x 3 dx =
sin
x r 3 cos3 x 3r sin2 x cos x 3r 2 sin x cos2 x dx
2 2r 3
=
r2 r
3
3
/2
I2
x cos xdx x sin x cos x
/ 2
0
4r
I2 2
2
3
2
2r + 3r 3r + 2 = 6
3
2r + 3r2 3r 4 = 0
3
3
r1 ,
r1r2 ,
2
2
2
2
I I1
3.
2
1
21
4
A event that die A was used in first two throws

B event that die B was used in first two throws
C event that next throws gives red face
E event that first two throws give red faces
1 4

2 6
4
A
P
E 1 4 2 1 2 2 5

2 6
2 6
B 1
C 3
P
P
E 5
E 5
a = 3, b = 5
4.
x2
f x 2f f 6 x 2
2
x2
f ' x 2f ' x 2xf ' 6 x 2
2
x2
f ' x 2x f ' f ' 6 x 2

2
x2
x2
2
6 x2 )
f ' f ' 6 x (if
2
2
f(x) is increasing
x2
6 x2 x2 > 4
2
x2
f ' f ' 6 x 2 0 when x < 2 or x > 2
2
f(x) > 0, when x (2, 0) (2, )
a+b+c=0
13
5.
R = 1 + sin ,
c 1c 2 = R + r
Rr
sin
Rr
R sin + r sin = R r
R(1 sin ) = r(1 + sin ) (Put R = 1 + sin )
(1 + sin )(1 sin ) = r(1 + sin )
r = 1 sin
Rr = 1 sin2 = cos2
1
1
2 2
cos 2 = 1 cos 1 cos
2
2
4
4
a = 2, b = 4

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FIITJEE

ALL INDIA TEST SERIES

Kinetic friction acts opposite to relative velocity w.r.t. contact surface.

Since vertical Impulse is acting on A

Angular momentum Conservation

In (C), the tautomeric form will be

Ring exp ansion

Trans - 1, 3 - dimethyl cyclohexane

No plane of symmetry in both the above isomers, hence optically active.

No. of bonds in BF4 4

= B. O. of NO 3.0 , i.e. one sigma bond and two bonds.

Ho Hof products Hof reac tan ts

= 166 (51) = 115 KJ mol1

Sb-hybridisation is sp3d2 = total 6 hybrid orbitals per sb-atom.

The number of sp carbon is X are 10, the sum 1 + 0 = 1

u xi 3xj , |u| = 2x, x > 0

2000x6 + 100x5 + 10x3 + x 2 = 0

Let P(a cos , b sin )

Using sin 2 1 and e2 1

e2 2 tan sec tan

sin A sinB sinC

Let w be the event that the ball drawn is white

When 2 balls is lost P(w) =

f(0) = 0, f(0+) = 1, f(0) = 1

Squaring and adding

x r 3 cos3 x 3r sin2 x cos x 3r 2 sin x cos2 x dx

x cos xdx x sin x cos x

A event that die A was used in first two throws

f ' x 2x f ' f ' 6 x 2

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