Trial

[S2O8] M [I] M
Blue Time (s) Rate
ln(Rate) ln[S2O8]
1
0.02
0.02
287 1.74216E-006 -13.26038
-3.91
2
0.04
0.02
141 3.54610E-006 -12.54966
-3.22
3
0.07
0.02
81.6 6.12745E-006 -12.00273
-2.66
4
0.07
0.04
45.3 1.10375E-005 -11.41421
-2.66
5
0.07
0.07
28.3 1.76678E-005 -10.94376
-2.66
6
0.07
0.02
204 0.000002451 -12.91902
-2.66
7
0.07
0.02
16.8 2.97619E-005 -10.42228
-2.66
Chart Title
8
0.07
0.02
10.3 4.85437E-005 -9.933046
-2.66
0
0.0029

0.003

0.0031

0.0032

0.0033

0.0034

-1
-2
-3
-4
-5
-6
-7

f(x) = - 1785.2916401549x + 1.0664450454

R = 0.1016962953

0.0035

0.0036

0.0035

ln[I]

k
-3.91
-3.91
-3.91
-3.22
-2.66
-3.91
-3.91
-3.91

ln(k)
T (degrees C) 1/T
0.00435 -5.437579
294.6 0.003394
0.00444 -5.417101
294.7 0.003393
0.00438 -5.430707
294.3 0.003398
0.00393 -5.539116
294.3 0.003398
0.00361 -5.624048
294 0.003401
0.00175 -6.348139
283.6 0.003526
0.02129 -3.849518
321.56 0.00311
0.03464 -3.362746
334.1 0.002993

0.0036

Ln Rate (s)

Trials 1-3 Ln Rate vs. Ln [S2O8]

-4

-3.8

-3.6

-3.4

-3.2

-3

-2.8

-11
-2.4

-2.6

-11.5
-12
-12.0027317215

f(x) = 1.0070341589x - 9.3179714436

R = 0.9997726669
-12.5496623499

Ln Rate (s)

-12.5
-13

-13.2603846753
-13.5

Ln [S2O8] (M)

Trials 3-5 Ln Rate vs. Ln [I-]

-4

-3.8

-3.6

-3.4

-3.2

-3

-2.8

-2.6

-10.4
-2.4
-10.6

-10.9437642642
-10.8

Ln Rate(s)

f(x) = 0.8473934987x - 8.6882410419

R = 0.9999813845
-11.414209492

-11
-11.2
-11.4
-11.6
-11.8

-12.0027317215

-12
-12.2

Ln [I-] (M)