()

6 ( )
/

Burrless , .
, 2 ,
. (burr)

, .
,
, , ()
,
. .

< >

1.
,
.
. .

.
(Bale)
.

58

6
.

.

,
.

.


.

.

.
.

.

.

.
, , .
.

.
2
(Topping) .
(Liner) .

2003. 4

59

 ()

.
1
.

.
,
.

. ( )
1
.

1)
.
.
(Press vulcanization), (Open vulcaniza
tion), (Continuous vulcanization), (Cold vulcanization)

)
.
, , .
.

.
.
.
10 .
.
.

.
.

60

6
,

.

)
.
.
.

.
. .

)
.
, , , .
. ,
. , , , , , .
LCM(Liquid Curing Method) ,
.
200~300 , , ,
. 53% , 40% , 7%
.
,
.
.
.

, .
(UHF)
.
.
.
, .
.
.

2003. 4

61

 ()

)
, (Sulphur mono-chloride, S2Cl2)
.
.

) (Post-cure)
2 , 1
2 . 1
24 .
.

)
()
.

.
. (Seal)
, , ,
.

2.
.
, ,
.
, .
.

.
( )
2040MPa SBR 1.54MPa
.
335MPa SBR
.

62

6
1001200 ,
600. 1001000
50800, CR 1000 .
7090
BR 95 .
SBR
. , , SBR, BR, CR
, . IIR, NBR, , ,
.
IIR, EPDM, , , .
LLR, , , , EPDM .
, . CR, IIR, EPDM,
, .
NBR, , , ,
IIR, , , , EPDM .
, , , IIR, EPDM .

.

,
. .
Polymer (, )
()

(, , )
(, , )

(, , )

.
.
,

2003. 4

63

 ()

. .

1)
() ,
.
,
.

< 6-1>

Zno

IR

SBR

BR

IIR

EPDM

33

S/A

0.5

MBT(M)

0.5

0.5

0.5

MBTS

0.6

(DM)

BBS

0.7

(NS)

11

CR

0.7

0.9
1.75

TMTD

(TT)

EU(Na22)
S

0.35
3.5

2.25

2.25

2.25

HAF

HAF

HAF

35

50

35

1.75

1.5

1.5

HAF

HAF

HAF

HAF

SRF

SRF

50

60

50

80

30

30

1.75

JIS

K6383

K6383

(1)(6)

(A2)(B2)

SRIS

3602

3603

D3189

D3188

ASTM

64

D318

D318

(1A)

(2A)

D3192

D3403

D3185
(1A)(6B)

D3268

D3190
(2A)(4A)

6
, ,
, ,
, . ,
< 6-1> .

)

(Bloom) .
.
(Thiuram disulfide), (Morpholine disulfide) ()
. (Dicumyl peroxide)
, .
(ZnO), (MgO),
(PbO) . (MgO) ,
.

)
,

< 6-2>

Aldehyde
Ammonia

Hexamethylene Tetramine [H]

Aldehyde Amine

Guanidine

DPG, DOTG

Thiazole

MBT, MBTS, 4-Morpholinyl

-2-Benzothiazole Disulfide

Sulfenamide

CBS, OBS, BBS

Dithiocarbamate

TMTM, TMTD

Thiuran

ZnMDC, ZnEPDC

Thiourea

Ethylene Thiourea

[EU]

2003. 4

65

 ()

. < 6-2> .

)
, ,

< 6-3>

3-4

3-5

OPEA

PAN

TMDQ,ETMDQ

ADPAL,ADPAR

p-

R,R
=

DPPD

R,R=2-

DNPD

R=2

IPPD

R=

*1

R,R=2

*2

4-1

4-1

4-3

6-5

MONO

POLY

BIS

THIO BIS

ANNP

DTBMP, SP
DBHQ
MBMTBT

5-4

4-3

DBMTBP

5-3

4-3

TBMTBP

5-3

4-3

5-3

4-3

IMIDAZOLE

*3

TNPP

(/ )

*1 N(1,3 -DIMETHYLBUTYL) N-PHENYL-P-PHENYLENE DIAMINE

*2 N, N'-(1,4-DIMETHYLPENTYL)-P-PHENYLENE DIAMINE
*3 2-MERCAPTOBENZIMIDDAZOLE
: 1. [ ] SRIS
2. BLOW,RUBBER TECHNOLOGY AND MANUFFACTURE"(1970), 6:, 5: ,
4: , 3: , 2:, 1:

66

6
. .

)
.

2)
. , , , ,
, , ,
, .

.

3)

.
,
(Carbon black), , , , ,
, .

. ,
. , ,
.

)

. ,
. .
, .
. DBP
. , ,
. ASTM < 6-4>
.

)
, .

2003. 4

67

 ()

< 6-4> (ASTM D 1785-85a)

ASTM
NO

12

DBP

TINT NO

()

(12/kg)

(/100g)

(IRB3=100)

kg/

N110

SAF

11-19

145

113

98

124

335

N220

ISAF-HS

20-25

121

114

100

115

345

N330

HAF

26-30

82

102

88

103

375

N550

FEF

40-48

43

121

88

360

N660

GPE

49-60

36

91

75

425

N765

SRF-HS

61-100

31

111

86

375

N88

FT

100-200

N990

MT

201-500

40

, , ,
.
(SiO2), , ,
(Soft) .
.

< 6-5>

2.7

2.6

2.6

2.2

2.6

(nm)

40-60

pH
8.8
9.2

10-10.5

4.5-5.5

6-8

(HARD CLAY)

68

(CLAY)

2.4-2.5
2.8

2-2.2

20-150

9-11

2-2.2

20-100

9-11

1.9-2.1

15-50

4.5-11

2-2.2

5-40

3.5-7

AI

2.4

4.3

6.5-7

4)
, , ,
. , .

, 14phr
15phr .

5)
, , .
, ,
.
, .

, , ,
.

.
8 R-Sx-R
. R X .
(Monosulfide) (Polysulfide)
.
. , (Free sulphur)
.
(Conventional sulfur vulcanizing system) 1
3phr . (Low sulfur
vulcanizing system) 0.20.5phr , .
(Nonelemental sulfur system) .

(EV, Efficient vulcanizing system) .

. .
.
,

2003. 4

69

 ()

.
.
.
.
(Co-agents) (Promotors) .
(Free radicals : R) .
(PH) PH (P)
. - (P-P)
. .
R

PH

RH

P-P

.
.
.
, , (Bisphenols),
.

3.

. , .
SBR
.
, , , ,
.
, , , , , ,
.
.

.

70

6
.
.

. .
.
,
.

4.
.
, , , , ,
. , , , , ,
.

.
.

.
14.

.
2000.

.
?
. 2%
.

.

2003. 4

71