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  • Effect of Hydrogen Bonding On Physical Properties of Substance

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    Hydrogen bonding has significant effects on the physical properties of substances. Substances like NH3, HF, and H2O have higher boiling points than expected based on their molar mass due to hydrogen bonding between molecules. Covalent compounds like alcohols, carboxylic acids, and amides are soluble in water because they can form hydrogen bonds with water molecules. Ice is less dense than liquid water because in the solid state, water molecules are held farther apart in an open lattice structure by hydrogen bonds, whereas in the liquid state hydrogen bonds break during melting and molecules can get closer.

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    Hydrogen bonding has significant effects on the physical properties of substances. Substances like NH3, HF, and H2O have higher boiling points than expected based on their molar mass due to hydrogen bonding between molecules. Covalent compounds like alcohols, carboxylic acids, and amides are soluble in water because they can form hydrogen bonds with water molecules. Ice is less dense than liquid water because in the solid state, water molecules are held farther apart in an open lattice structure by hydrogen bonds, whereas in the liquid state hydrogen bonds break during melting and molecules can get closer.

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    6 views2 pages

    Effect of Hydrogen Bonding On Physical Properties of Substance

    Uploaded by

    AhJee
    Hydrogen bonding has significant effects on the physical properties of substances. Substances like NH3, HF, and H2O have higher boiling points than expected based on their molar mass due to hydrogen bonding between molecules. Covalent compounds like alcohols, carboxylic acids, and amides are soluble in water because they can form hydrogen bonds with water molecules. Ice is less dense than liquid water because in the solid state, water molecules are held farther apart in an open lattice structure by hydrogen bonds, whereas in the liquid state hydrogen bonds break during melting and molecules can get closer.

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    EFFECT OF HYDROGEN BONDING ON PHYSICAL PROPERTIES OF

    SUBSTANCE

    BOILING POINT

    SOLUBILITY OF
    COVALENT COMPOUND
    IN WATER

    NH3,HF, H20

    MOLAR MASS OF
    CARBOXYLIC ACID IN
    VAPOUR PHASE

    Alcohol (ROH), carboxylic acid (RCOOH)

    DENSITY OF ICE
    (SOLID WATER )

    Molar mass of ethanoic acid

    1)

    ICE LESS DENSE THAN WATER ?


    BOILING POINT INCREASE

    and Amide (RCONH2)

    In

    ice, the H2O molecules are


    WHY ?

    SOLUBLE IN H20
    an open lattice

    CH3 C

    OH

    held apart in

    WHY ?

    N-H bond is the least polar bond.

    WHY ?

    structure by H-bonds.
    (EN : N < O < F)

    Because they (ROH, RCOOH, RCONH2),

    # Hydrogen bond between NH3

    can form H-bond with H20 molecules.

    Ethanoic acid forms hydrogen bonded dilmer.

    molecules is the weakest.


    NOTE :

    1) Alcohol (ROH)

    BOILING POINT OF H2O > HF


    ALTHOUGH (EN O < F) BECAUSE
    HYDROGEN BOND

    when melting occurs, the


    H-BONDING THAN HF

    H-bonds break.

    2) Carboxylic acid (RCOOH)

    H20 CAN FORM MORE

    HYDROGEN BONDING

    OH

    3) Amide (RCONH2)

    MOLECULES.
    the ice lattice to break

    HYDROGEN BONDING

    PROCESS : DIMERISATION

    - causing

    down and

    molecules come

    closer together.

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