520% 1H ob os FR * Vol.20 No.1 200642 A (CHINESE JOURNAL OF MATERIALS RESEARCH February 2006 Al, Osi} Y2O3 ARMERS Al ROMER aemm * FSR RHR LEH 1, MURDER DEERE se 150001 2. ELC Efe 200433 fe SE RWEAELMERRA 20s 1) Alo, MeebsemTetiaktt, MURMREU ZMH AlaOyp/OOOLAL MAH, HYSTA RID AMER. RESLAREE, AE Yas UACHEES, AleOs MEME O06 Ret FP- A otal aaa, ALAM Ae seHEART LINAS. CHEN, AlzOn HERAHECY 20% AVALEENN, MANA 90%, MME in 40%, SRAEMEAEMA 20%, SINT, sete AlaOs Maem YoOn 45 Al ARAKOLSRE IPGL, GRAPHITE ‘Iai: FUGA YoAL "5 Alas ft Al AGES TELE 6 6, SEU ACCT, AlsOs Whe, MORITMTR-Lacte, MIRA een, ERS, JPA KS TBIB ‘XH 1005-3003(2006)01-0014-05 Effect of surface modification of Al;O; powder with Y205 on microstructure and tensile properties of aluninium matrix composites YU Zhigiang!® WU Gaohui!™* JIANG Longtaot School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001 2 Department of Material Science , Pudan University, Shanghai 200583 * Supported by National Natural Science Foundation of China No.59771014 and No.50071019, Manuscript received June 21, 2005; in revised form August 6, 2005. **'To whom correspondence should be addressed, Tel-(0451)86413357, E-mail: wugh@hit.edu.cn ABSTRACT Liquid coated approach was used in Y203 modification on the surface of sub-micron ‘Alz0s particles, and 2 6061 Al matrix composite reinforced by the modified AlaOs particles was fabricated using squeeze-casting technique. The microstructure and tensile properties of the composites were inves- tigated. The results show that the disperse homogenization of a~Alz03 micro powders modified by Y20 is improved obviously in the 6061 aluminum liquid and tensile properties are increased obviously. In the ‘composite with 25% volume fraction of AlaOs, the tensile strength increases by 30%, the yield strength increases by 40% and the elastic modulus increases by 20%. It can be suggested that the improvement of the interface wettability is due to the interfaces reaction between Y,O3 and Al matrix and the formation of good bonding interfaces of the Y2Al phase with Al,Os particles and aluminum matrix. KEY WORDS composite, Alz0s micro powders, particles surface modification by rare-earth, alu- ‘minium metal matrix composites, microstructure, mechanical properties, |AlgOs BURNS AB AEM APE (AlOsp/Al) AAT EALATHIGR O~S), (EU, Als Re RERUNS $3 GATE) FAVRE, SSIOIIO YE, EHC HRI BE, REIRHER IRTP, BORE SHC, GROPP SLES ARE SHHE, EME, ARIPO LUSSIER, PEATE REP REE AL MI Oy Ta aE Sl HEALER 39 BEBE, PERLE TERE, FA AZt Pace Rab 59771014 HH 50071019 REA. HET AMHOTEIE LAE P~*1, C.A.Leon % ("I FE ALOs 2005 #6 #1 21 BUCPIATER; 2005 MF 8 A 0 MCRAE. URLAETHORM Ni, HET AlzOs ORLY Al HUTA RRA: REM, BOE ‘NGNEYE. R.Raj®) Ze AlzOy BORLA B Pd, HT1 FAM: AlOs Mi Yon AcHENt AL ARMA APRA REN 15 CHER RIS IEDR TE T SUE. IE Ni, Pd FSM RBH He LEM A, MA. AIC RAW ELE ©) FY Y203 MILK o-AlzOs BE ACF MLA, FACE RO FH 8, BESS RICHEY SE Gb BY St BE SU HE OB. 1 BRAK Tztal HEY 2 mol/L HYBHRRIZ (Y(NOs)s-6H20, AR) ACEH, HESLG o—Al2Os fb (#248 0.1~0.3 pm) JRE, RSW HH Y20s RAE. MH BLAH OR 2%) 0.5~2 b, {8 a-AlLOs #OI2TE SE ROCEE TBR SL ACFE HP. HII 2s 39 53 IR ‘ELUETAMRIZL TIER. 800 CHEE 1h, EEBORL FRIHTIMAZACHEANS o-AlQOy GRUBER RD EM doR N° fil aeORL (Rel aCHERII) HERMES oH, Al,Os HURLEY 25%, Y20s AYU SPISY SH 0, 9%, 4% Hl 5%. FA AXCZ SSH BACON. TE JBOL-200CX 288 886 RR 5 Sh MOTLEY, I MOB FEY 200 kV. 7E JEOL-2010CF #18 St 88 bt FTG BERLE, BAYER 200 kV. FLA HERER RHE Instron—1186 77 fb FHL LEFF, HUA 9 0.5 mm/min, 2 BRSit® JAE 1 ATLA, ABE AlLOs AEBHERRIE, Fe IGM (FE 1a); TTBCHEAY AlLOy BETHEL 8, RIA) SMR LAER (PH 1D). FE 2 2 AlOs MEBBURCHETH YoOs Betas 5 OOGLAL SE-APPEN (Ve=25%) BAIR OL RUT. HPA ROH, BLM AlOs BURL FET BUTE VoOs ASREHE Ft © 35 ASC BEM SPSB), He AlaOs BAH RY MAA 3.0 m?/e!. 2 RU PR FEAT ARLHS OK, BER AY CR LA BE DR. FEARS ARI A ED A I BB SE, CELE A a EH PARSER. PTLAAPHH, PH 2b, c, o +B FEAbES SOAS HE 20 PAN. BLA, Y2Os Bete JESEROK AlzOs URLGY PUREE BEE, SB TH ‘31. (IE, BHA YoOs thos Mn, AlzOs ORLA HIE FEPBEA. YaOs BUMRINHI 3% BBCHE AlLOs BK ZEST RRA, SPH) (PH 2b). FE 3 GTR 2 MNT RUBE ON 6 TEM AU}. FDU, Iai He Ri BURLY: SUA ERB. FMAM, BURLZ Tay sc Fr 2h eu ce ee (a) Rh .. BE 1 o-ALO, Hep ACHEHNS ERATE ORTH Fig. TEM micrographs of the a~AlsOs micro pow- der before (a) and after (b) surface modifica tion EAT EEC. Het 205 itty 3% BY BCE AR EM ME Sha EA PHS). AEH LL APA, BC HEIBDRL 5 EPA Ta] A FR ALPE TAH (IE 3b, c, d, EDR). ASTRA PAW VAI", $e SUMLRALAT AlzO, BURL Y20, 2 tke se TT. Y20s @ Hts 3% HCE BRL Fe mH 5) ta ee — YoAl Al, BOMRLZ [RIO SHBG: TT Y20s tI 4% UCHR IE OCS th I, I YoAl HE FPM ASHER, MORI YoOs de atis Bl 5% Bt, MORLEY YoAl MARE BIE AR, BB Bt AloOs MURSHLLE YoAl AEE i, 250 A BORE RAR TBA. RCE BAF RRS RK iB eEFRAR, Y20s Bete AlLOs HOBORLIEE EM SR MSS IHR. Y20s 548 EPID Se ET SC, (SEIS MT aL Oa O91. BERLE VAL Ait AlaOs RAS IAE, (OBE YoAl ff AlOs SUR 5 Al REPRE AA HERP MOI EBLE HE He AMEE SE MR Sp AE HS), ATTA giuAn sis y, reo1m ERIE RACK TRAM, EME aE, HEAD, Fete T RTE RK Sh. at, Bl MEYoAL AUR TRSREREK, BCHORLTE AE Ha St HEE. 4 WRF RAR TE Al ete #8 (111), YoAI AY [481] A ALLOs BORLAY (1231) 09 FF RY. A HREM (49 8 2k, SF + AP OM, Oy REA A. Al2Os BERL AN (1014) Hh S Y2AI BY (013) PAT, ME 4.8%; AloOs SULA (1T01) tS Yo 8 (TLL) TE FFF, — A SBE 5.1%, EE Rh MUCK; YoAL HAS Al RAF EL RS) MA, LOG AR A a a FE HH eA ME BEB. AL ME 9 (202) a 9 (0.2025 nm, 45 Yo B68 (T11) si THT 3 A 9 10.4°, 1 2d gy5yqi8in79.6°=0.3088 nm, #5 (T11}y,an A 4) TO) ee, hh ak FEM: AlsOs HEH YoOo ACHENt AL ARICA PER HEE Ww VOW. CBW APA YoAL 4748.2 PRAT AlaOn JURE BLS A PE. JET Y2A1 #95 BURLEY He 28 HE AlOs BURL 5 ME OIF TM HE 2A AS A PO FM, EYAL -S A A, TARR SRME, WRT MSR A Heft. RRA, SSMS ATE. RR BEA SH He BERS BSE. RAAT Y2Os fae oy in SRE TRE, PERERA. SURE, RA Y20s RR, ATR EIR, Be Y2Al BoM MS, RPK. “SHAR, SZ mR Y2AL AT RHE S, SPE SOF PEAY FB, EES eR Ro ‘CENT, RE RRAIR. (ELA, Bc MC A om th A SOARES RESET, AF MS MZ DE GYRE, RTS AE ARS. 4 ¥20» ati AlaOay/ Fig.4 HREM image of the interface in AlsOsp/ 6061Al composites modified by Y203 (606 1AL EBM A HEH ASP BHR 1 RUMAH ALLO /6061 AI Me RAIL ‘Table 1 Mechanical properties of as-received and modified-AlsOsp /6061Al composites at room temper- ature (content of ¥aOs is 3%, 49% and 5%) Composite vm E/GPa u2/MPa 2y/MPa ‘Ala03p/8061A1 2 108226 DAIS ‘55.1146 39%-AlzOsp /6061AL 2 1251.2 soar 402.9488 4% -AlaOsp 60611 2% 1901.1 2ors79 404.8475 39%-AlaOap /O061AL 25 1381.8 2sse84 886.138.218, oO HF OK F KR 34 RIB Y20, BOER, YoOs 45 Al ARPR AEA ET BRM, Pee CNY, UTR 5 EP a HE ABC, SITTER AlzOs URES EME fet ASUS TE BACH. FA Y2Al 5 Al2Os JRA AL FPR (EIS FA EO SAA. 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