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yo G = 6,67x10"" N mKg*. R = 6400 Km. m, = 2,0x10° Kg .M, = 5,97x10™ Kg eget pill pat pontall -| tmin) o | 5s | w | is | 2 |] 30 |] 45 | oo | V'qmL) 9 4.0 67 8.7 | 10.4 | 13.1 | 15.3 | 16.7 J, (mmol/L) | 0 3.0 5.0 6.5 78 98 | WS | 12.5 1) =f Ste ery — ca dt Atl] Yeo 20min) = Ar 143 Sle =2,4x 104 mol.min.L!agillall gat posal » Loli! Dalal 1 u(t) + u(t) =E SLs yl aoe Ops Gee RIO +Y OSE +R A+ y HE RSE + y= E dug E FROM TRC sibel! aS u(Q=E(L-e*) of ols}. du, ah i 7 pe See rad uD) ile Gls WB eae He BY sg ttle oll 9 So yal Reo RGEC -e Mapa lala Maul 3 oy EE RC RC «call JI fas Load! Sola! lel Saad foloctly RC jah ste 3 (U1 (QW), we) WRC} = PI (Cin Sy Se AS) RB) (2 RC fall bay aay cpasll aw pile IRC] LH LSS Mgstonts pe 68% Hey LAS poe Le Ape BAM ga ctl pall gle = seal rad ra Syd Ole 4 6 12 18 24 3.80 5.18 3.70 5.89 Pu = ft) shell paall 5 144pyhsll 5425 R51 5 Lal 6 wn dq __, du, Oe ae iW =Eer ice) -Ee a) std 5 i=per =e t= 0 Med LES 5b BLN 254,451 GUT EW =4C 1U(OF B= PCKE ery u,()=E stone tue E..= 0,5 x 1,2x 10%x 36 = 21,6 x 10°J sind gud poll og Beck gles! Bytios SL Sass Be bd IS pee ye ate nae 11 gp dhtey Z SU oll at le oF Ui GS pase tis pa A SI ota! Py > APH + He: Syyil) felisll Ula .2 A=206 2445 2105A44 sob Jl ote blewl og pk Z=82 ieey B4HZ42 atti blo’ aby na S222 sg 104s! AGL 13 ty 138x24x 3600 145Deer read =1,72x 10" noy !Ny Glas —o » TAWA SY ake ay slid JUL pep Olas — N, N(t)=N,e**=—" 4 t=44= Se =24x 107s rary etat wftgt 276 9 C33 pag gall pl ged peat gr gage BOS eggs aM Se hee Gl plall go 294g Nall Hay py BG Tle K fy My Bl ogy nll aS er spl gaye lis LS EN 0 ptatl 2 Tr 4x (h+Ry GM,” wn (1) 5 ty Teepe Ub41 aball 3 E -2G+) = VT 42 (R +h? ......2) _ 4K +h) GM, =4r(R +h 32) 3 arthy 11) Sell gy fi OM aay gh OR ®+h GM, giles phe Lea SL LSU gus gall elena alll yx jit gem pall nad 4 CE PIM FS 599 Soles eny> ces Og Bee AB gb ype Sem eel webgeeYl bd eyes gb oshte shy CHE LS oy go ch pl YI OL h=4,22 x 107- 0,64 x 107 = 35,84 x 10° m :azsy 146 Tt 40 (R+hy GM, T=24hice h+R h+R=4,22x10'm1 Ul 3 yaya GM, __[6,67x10"x5,97x 10" I ajo ea ee 2 1 3kms! ‘=> TerFaleg 3070 m.s' =3 kms . Bt se as pa GM 6,67 x 19 2XIP ASF KIO itn 5 (R+h? 2 F=447,2N gt AE EIS eee yt geleall path OY tr geleall pall byte pate 4535 MN Bo lal 3 pill 9 yyy oy ged oll ot geal + deeY ciple yas JSecll 2.9) 5 (Jelid! Hates | pais | CH,COOH+ | C,H,OH = | CH,COOC,H, | +H,0 Mle dE!| 0 0 0,2 0 0 AMV | x x 02-x x x Aste | 3, 0,2-x, 0.2 - x, x, = 2Bpbell Joly oles — = CH,COOH + (Na* + OH) =(CH,COO + Na‘) + H,O (oan) ele Yh bale SoS daghne (n.) dll jantl Sale dpeS OySG filSII tis — 1 2 = CV py = Vig 24el CQ) x=0.2-Vi,, ey MH O21 aw ptaall Iyte ge 147(1) db Jezel ryt JES] uh) Oia lords VigmL) | 200 | 168 8 12 16 | 20 | 32 | 40 | 48 | 60 148 | 132 | 118 | 104 | 74 66 66 66 a(mole) Oo | 0.032 | 0.052 | 9.068 | 0.082 | 0.096 | 0.126 | 0.134 | 0.134 | 0.134 zygiled ah 3 fled pads i GL — 3 0,134 = 0,67 =A ne felis le oles 1 Ya Sil ple 3 felis aS als — [C,H,O,], [H,O], 4 Qs ee ee i ‘a [CH,COOH], [C,H a Q, ins 9, = use = Ma 02-0134" Q,=K=4 rad 148SsSLajuill poled dale fp plill quagall 1500) Gut prt ~ 2 Glleall m, = 1,0087 u m, = 1,0073 u lu=931 MeViC? C= 3x108 m/s m, = 0,00055 u Pel ast jeu ye Shel Sate SLIT wel | a | a | tHe | Wo] WW | Bsr | Me | out |? v 2 «|? 28 se oe al plas T, ; as 2,0136 | 3,0155 | 4,0015 | 14,0065 | 14,0031 | 93,8945 | 130.8020 | 234,935 u E(MeV) fey aitey | 2.23 | 857 | 28,41 | 9954 | 10144 | 81050 | 116475 Gy B/A(MeV) Be) 4tt (Sat (phe 53 a ai 425 8,62 -(U) US biey — + Biysll ey) Ue — Fr LH Ohl opeedll My My Ay Z sly CM) oy 1S UV are alga algal bey, MUL 5 hye CaS.2 CO) PA depalitcny Zy Ay + (MEV) Ball 235 gyal, gl algal Jey) GLb Lat 3 + GL Ugh! OLS Last fle SUN el 2ST (Gell Spt i ayy coy ys) alga a LS 5 Gileell Jy pr poliall aed dey yl OV yo! OL! OT ON INC dent ergy teell Sali ow Oya) He gay — ere US ae Me + Cby Fy Sty Xe lan Oye 2009 by sgdbSlel! Sab late! 149= By sys ALIS Sy Doles oy Jy! IS Ge ped wheel 2 SSG yf Reled| cL Mees: SEL yall OV all Ge 2 / (MeV) bam sll GLY) fobs ory Mats) fold oe By mall SUI i 3 gall got pect Feb NAB Slee Be — 2 end bile one 2 +) AW LAH dept (g) sgl pe teed oly (Jail Lia Bey ode (Kash doess BL WSN peas 3 Lk eying uot 4 Osts 7s top Shell gi ah Vy Mall dep Opi LS Je 5 satlll gu pealdepo oF t(s) 20 60. 100 Prcoy (Pa) 2280 5560 7170 Teo, (mol) xmol) 5 Gl BLS JG Lal felis oe all 51S) Eola CaCO,(5) + 2H" (agqy = CO.(g) + Ca?(aq) + H,0q) + Gill felis paad Wyte ce otef 1 $ Jodi pret x y gllasbh fA Sale GeS Meg, ope MIL Le 2 2009 by sgAblenlt ba liacs ghaniaal 152Glad Sql foST (RV = mR.T) [Sey dane sly AM jul Gite seclans 3 R=831S] «© 1L=10%m': ba 2x =f) dol, ba 4 15) Ady} oe eet papi Uy Joli anny 6b CH) cpm ggegl ont pS ed a lll Jbl Ball ts) 20 60 100 [H*] (mol.L") 0.080 0.056 0.040 Ty (mol) . x(mol) LAL IS Bing lag oylpth Bole Ane’ Nyt) Geet GH) pas yg) gland ol La onll Lee yt c fois pdt Jydre Ligatine 2 whee ll caer gta oylptd (MQ) Asha Vi soll LS aL IS 3 @) pe 3 feeble r= Old tts + bel felickl sum 5 + feiss) Head gaj ty eel 6 . t=50s Mao 3 Jel Rye Ae peel Cee 7 M(Q) = 16 g/mol « M(C)=12 g/mol. M(Ca)=40 g/mol 2009 bay olbstedt Babies glacsel 153pee ee) 294) ga socal AUS SS tol Ue 3 all Lai Cat NUL ge: aly dep BL 1 2 Sb yd CL LU BUS fol = 166x107 Kg shee wold op Sey — E,=[Zm, + (A-Z)m, - mQX)] CP: alg Ly, Tb abe 2 2 QU als5 Jays a8 GL» 3 E, = [(92 x 1.0073) + (143 x 1.0087) - 234.9935] x 931.5 eri 1 ee Mia E, = 1789.5 MeV = 1,8x 10° MeV rdpab tals Jus] 4 E/A(MeV) : _ | Ll | 2.88 | 7. (pel yi JS sa) ei 4 wags JSS dey, Sl ST GAME LS SSr se Lael 25 lll 5 2 sgsi Jg# IS Wale 1 NOs NG Se 2 WN IMC Jpea—t 2 TH+ Het in sce gyteell el ope Oy 555 He pan — TAL 725) a0 8.32 | 7.62 DU + yn > BSr4lGXe + in condgcty Sty Xe che Oy cu QU i 2 Raggi OV oct aes 2 «tla if Synsll eq lade Spl = gets: Syl 2 Sy pecll Mlb OL 1 E,, = |Am| xe tgheta felis E,, = [[m({Xe) + mCjSx) + 2mCn)] - [mCU) + m(ny]| x 931.5 E,, = 17.40 MeV E,, = [[m( He) + m(n)] - [mGH) + mGH)]| x9315 yclw Yl ets 2 E,, = 17.60 MeV 154es Perle rere ey) aggaliall gat posted! i 4) 2 Eafe g SUI 5 JU) Lalas aay I K (4 {SAN Bat Ll yy tye Jes 2 1g) We cae BDA! 3 Me Fly Aaa He Fy =O reals yall emer Oslo 1 ALelaal! Uoladl 4 Halt) + uot) = 0 Syl eae Old os Ril) +u(t)=0 = RG suds 0 rc! Set, =0 tbs ae SES n 5 dae") 1 dt RC 1 + ae = abe! ac" =0 64+) = Becks ae’ btRe O>b RC b=-666.7 s! a%=E => asE= a=6V HD = 6.0 aoa u(t) BER ry gigell engl all ALS 6 2 Obl eb 7 u(0)=6V 208 @=0) Ul y+ 155.a «beet Tt =LSXIO'S Lai ype le LLL 1 =H : Pa Tex9" 7 8667s tauty ot t stil LT ged ppl Nllbey lhe) ULAR le 5 goo ltl OsSLB geen: IS pl Lo Ui Bala EF,=ma, Bifema, d : F mg-kv= mo 122) yA de by We yee tady It m Weave JS ert gots Bag jA=-K sat totaly 1 JS tala len TAN oe oY ppt ye Ble Ohl 9 Boe JSS as 2 =av+B a 5-10-08 tall fale toe B= 10 telat jpoee ae pgdceall bis dads B B=g= 10 ms? :4ylaly Be ed: ae = 7 Av+B=0 = y5-5 iy nn? TAAL Be pall & gly hase v= 12.5 mst KB segue sy & juats Z aes ae 1, Ky i HHITP Lppp She qe [z |-& a = TL PHT} sy kOe 4 Koos = k=80Nsm' m 156IVEY pid Jatt 5 Qi ll gt pest! 2 glen els dole — 1.1 CH,COOH,,, + H,0,, = CH,COO,,,, +H,0%,, padsll Jyue 2 usta | pass | CH,COOH,, | +H0,,= | CH,COO:,, | +10", ere ees] 0 cv inp 0 0 Just a x CV-x 3p x. * yur | 4 Cv-% iy 4 x [H,O*] =7.C rainy ¢ tezts x ~ [CHCOO 14,041, 1 [H,O*] 8 be oleu) 3 x, _ 1H,O* V _ 1H] CC Klas dl CU abe 4 . [CH,COOH], cv -x, Hw [CH,COOH],= y eee oe capa » Sab Jus} 1.5 A= 1/C (L.mol") 5,62 4 56,18 92.6 B=t'/1-+(10+) 1,0 2,0 10 16,7 157K,= 1.84 105 say 1K Rey ul cll (1) ASGLB rashabes 1b ye 58 pete BS 6 3,LE led! oul 6 =5,43 x 108 tee gl) ole Oe eC 1. v K\= x gaily K, Toe OC Ka“ G-9 =a 2d (2)y (1) SALLY thw Aas LI) geet gael Ga geal 1 felis! As Jyte 1 jeusiase | CaCO,,+ | 2H, =CO,,,] +Ca™,,| +H,0,, apuesnian | 2X 107 10? 0 0 ie asa | 2% 107- x 107 - 2x x x ide wyatt |2x107-x,. | 107-2x | x, ee ie 2 Oy Moo) ca Aa. PV = were n= pot Dea =* rebel Uy te idgatt! JLSI.3 Tco,{mmol) 0,92 2.24 2,89 x(mmol) 0,92 2,24 2,89 1582K f(D Obl pay Tiplall iy pall ].V=0,1V raat JS 3 Gach) Ht aS GLa 1 Mayr = Mp7 2k: pdasll Jyter oye 2 Os Ba i TE dan Sioa 2 aa n(H*) (mol) 8.0 5,6 4,0 x(mol) 1,0 2,2 30 pas juts DSR AbL si dx i He 2x 10° Kog = OP Xyy=2K107 mol sp diall gk ge Al folic wad 5 10 - 2v,,, =0 = x,,, = 0,5 x 10? mol with fetid ys (HY) an, “5 ; Nyy La Ze 25 mmol: felis ies op; 6 \) ty=70s 144 bnYL B/E X3K105 :t=50s Le felis ded ie ile 7 v=3x10* moLs'.Lt 159Aptall Lely Ce pall Ai epee) Lad sgl (of + pene) Ula) Us lina Ler ocdats 3 1 Cee pall Be eer dhe role SG BAS Cet AU ogg Ai alae ee NeW) LS abe te ff 5 S=98NKg oA Sa aby ce See bi fo 6 When ne ele eee eee setyma hill od peated jgAT + © Hl ope Ge YON Sb 2 BP pltyl N=Ne* Z = 1 Ny 5 ORK ASW ¢ pel ll Lf one N, Aga sell peli yl L pf ote N(K) N, =N(K) + N(Ar) N(K) + N(AP) o* N(K) N(K) 1+ alt NAD) a G2 ee 3 ty = 4,62.10" ans a N(K) = = 1,14.10" noy noy te 4.10? ans (2) Nee peal pithy a re fl send BC jas avai oj OV 4 Geo MS Coa yp tenally pp tel seb dell a Op IS) Jala (i [OH] = = 0,4 mol/m* on + ANH, eee 4.10% GH Dor C, = 10? mol/L. (ti _ (C.H,07,1NH,"], [C,H,0,],[NH,], me 25.10° K= a 1,25.1 K= a A N “(2.104 = x,) 10" = x,) x,= 10% mol 3 n(C,H,O}) = 104 mol n(NH,*) = 104 mol n,= (C,H,O,) = 104 mol (NH, =0 9,2 Pe n(C,H,O}) = n(C,H,0,) =a =pKa=4,1 say n,(NH,*) > n,(NH,) Chpedtmo Alli) Una pH <9,25 166Vela Vg = 2g(20) iasry Ve = 6,82 mis Rok A Fat pl ogi gabe f= ma, c —> = oe is P+R=ma, F — R 1binYy ve ‘ P+Rem—< r ape R=m—<-P v, (t) = 6,82 m/s v,@=-98t o_ x(t) = 6,82 t (iw =49r 6,32 m#7,5 m i cee be poll bi Y 167 ek cama a tp 222), O35 1363 335 5286 } zk © SU —» Rn +4 ‘He © _ aN G2N Vv ty .V = 1,25 Bim @ eke ad Y taal pil got pont 7 MsbendI 1 Wea.d+b a=10 b=50 ve = 10d +50 redged SEN Oya Ges 2 xf,=ma ext F-f=ma :Aw bE F-f og m 2a=10 => a=5 m/s? : Ailes F-f=am=25 F=25+f raiag Heat + pee) Heel 3 Epp, + Ec, = Epp, + Ec, 1 = 1 2 my,” = mgh, + 5 my,”Vigemenll ds pl Lat 3 ved dno) Vv dt _4{CO,] rT at d[MnO," fiMn0] tell aa nj A AAR nas Jeli 6 gl @GDU cpastl ya x, ee §,, =SB= 5.107 (MnO, 1, = 0,03 - 2x, [MnO,1],, = 0,02 mol/L, 1 bLANL ty =50s ‘tga hall gal posit he S eo gure l n,(H,C,0,) 3 n,(MnO,) 3 2 2{CO,] 10 [MnO,,] = 0,03 - [CO,] = 0,15 - 5[MnO-,] plait 3 Fe® = Fe* + le MnO, + 8H* + Se = Mn™ + 4H,0 MnO, + 5Fe* + 8H* = 5Fe* + 4H,O Melia LS Oy GIS se 4 Ay pBe pS phe ents Fe) (Mn) cy, =[Mn0;].V, V, _5IMn0,1.¥ y ¢c pte 5 oyu Sve 8 [Mn0:] WV. 5V, 168De Bs as ol : iy! Dhl | paid | 5H,C,0, + 2MnO," + 6H* = 2Mn™ + 10CO, + 8H.0 slaw) 0 0.05 0.03 |53n) 0 | 0 | say was] x | 005-sx | 003-2r | f 2x | tox |» HI | Mgr [005 -5tpge [008-2 pan)” | Pear [10% "| + 2ULSyi t(s) 0 30 60 90 120 150 210 vim) | 6 | 48 | 38 | 3 | 24 [ 2 | 12 MnO, [ - ] 3 2.4 19 15 12 1 0.6 10? mol/L. : 3a 169@aslyjsall pqlell dale a gulpll equagall 1 JOH) got postll eae pats 10 eel 3. VESTS mL ys (cee W je + olyglly) let, MBL ISB fred cop SW i GAS oye beets tee SY sll Jele (chat ball olds OF Ba SU Be ey (FL eS GLE + elgg JP, Leet Po =f) Lal, Jee « P= 1640 x 10? Pa Lal nt LaSlo ped HOy) HO © Ogg) f HOygy 2x2 EU carnival! cabalall OAS 1 BW 2S eh /f 2 ste SW LU USM cpa Jyte Slane! ape be pti! aot Aj og6 Jt 3 aa daS Gone cate _Selisll UG (i aU tfelissl lg cae GE boy lal) baal gy dud has +P =P-Pi P : ¥* Sauree TEL den: Jelisll U8 of oy 4 a fet st oj bole AS 1702 t=O Ae folic) dart! de poll el 6 SASL poli jektten fo peal Ul oe bee ea SM cL di 95-7 Ales aca) ASL aS U yc folill Geet nj ene Fell $5 yA 3 rgd pt poaellJog {80001 ogheall eal iRCOOR} Sl SH ib LSIs Qaot — » A Ladd! wee = ATS gaphl PH OS ole Jl os IO mL Gas Lice 3 Sab El oie JAF lobe ( [SES bl) gta dh plone Soll 55 sl et i vol S31 ob (CHO) 5 pend! eared Coe dtpaall Le gi - signe bibl et petal eg SiS logy M, = 11 Kg a2 S, loge thes += 30° Lyly GI ge ee Ble sys le ALS) Jags blac ete decks put Mie Lay Ley geee Sam yyy MS ag BS poe le Feel Stl SG yLelh dey Se! oy, 9) a ee M, ces gle Jue 8, le py Sy pth get ey chatted de Oye LL Aas IScaII) m dees A SLy) ALS BeBe aol) 55 hey glans Ape > Lob! fol sis mise Sl ot ULL ne tll JS2IL pas WL 8, po 173tober gl Oledll Ube obaze IL imps IS 8 Spat 1S > deg [td 2 Sy pb Uae (gol) LIS BLL! a i rae yh Fg SEN Opti! gabe 2 IE PS, pat gules GAH Bylot /f dey og 5 10 m/s? tgs sm TiLe Pl ALS S, pet oe IS dL 174Pv fA ol P,(t) s Po a = £2) gle (I) dandy Fag BO fy Po Ze BoP, 635 Po = ea oaieres (SY > FS Hnax “635 (x10°Pa) hPa = )-4i+ Po ae sty felis teat oj abe) 5 z, veto tH hy Lue BO gsay P: etme gy Pon 2 == 635 1 Po = 635, 2 635 Me 2 P,,=317,5hPa nad kai gee gle Gaga bes ty =2,4mn : le 2 t=O te daedl ic OL 6 Idx id Pes =e aa Vey yal ae) veh. Fa, Por V 635 dt aP,, .t=0 ee pla ow 8 108! co pontll Pokal obo 1 (H,OfH,0): H,O, + 2H" + 2c" = 2H,0 (O,fH,0,): O, + 2H* + 2e = H,O, TAS oll QS Gla /1 12 Dy, = Soa = 19% 10*x20=3x 10? mol ipddall Jy Jo 1] PHP a= 20+ O49 alllaas| * (mol) EI i} 003 |,, | 0 ET | x [003-2r], EF |x 003-26] 3, Xnay = 1,5 x 10? mol PA =P Pam 3 10, J asta gall! Las Fo Vos RT Po Vo, = n RT == (P,- Pad Yo, 1.2 be RT oy, = {i640 - 1005) x 10? 575 x 108 oy 8,31 x 293 ogg = 115% 10% mol Doon = * ax 5 HA GUANO py pak Iya ga 4 Po¥ 175tle es (26 (I) cy MLE E=12V, t=0,05s t t=RCO=> C= 0,05 C= =50 pF ie PLES iss Hale feet OG E.= dee =x 5x 10x (127 B.=3,6x 1043 [iS det Q,=CE=5x10%x 12 Q,=6x105C rll pA BAU! a hel 3 =1,.e*= Rem i(t) = 1,2 x 10" x 107A roll i i(A) [12x 107] 0 19) | 0 [5 1.2.x 10% hngelall gb (pilates oy Ja pare SE jab Dr ee [ul.......(2) wie pes (2) Holl ~ 15x 107x635 ~ 635 x 0,02 «3,5 v =0,2 mol/L.min 1 gglelich Jas gl! oll dL] tie .7 desaylh go OY ott Aypee! ie pall - wala jl delist wha felilh eas ay = wks dul (a5 O, J islgul soll AS eyes! O, 5 jesabell pretl OY slay etall — sqgileall gat yest ptsO abla ale ts 1 U,=0 tt: U,=E U,=E =the: U,=0 cee: isl], see Ug = 121-2 5)(V) 2 AS ef TS jee dee Lb) Ll (2) wee Up = 12(1-€")(V) (1)... 176E, =3,04x 107 x 9x 10" E, (Rn) = 2,736 x 10" J IMeV + 1,6x 10°) 2 — 2,736 x10 E, (Rn) = 1,71 x 10° MeV 1D gelS gai JSS dae GLb E,_1,71x 10° ‘A 222 21) Malad) yo dyqcch! aL 4 E,, = [m(Rn) + m(He) - m(Ra)] x 9315 E,, = [221,97 + 4,001 - 225,977] x 931,5 E,, =-6x 10° x 9315 =-5,589 MeV sige dan ld lbans HLL: By, < 0 = 7,703 MeV/nucléon plato! doles 1 (IL MU + ine Per eee + 3) t Msi! ope by peal! diUle!l .2 dey Sl Bib Grind Opel gree LP Op lS 55 [SS E, E, E, By =A. g 2 +A 1 (Te) +A, 2) E,, =99%8,7 + 134 x 8,4 - 235x7,.6 E,, = 861,3 + 1125,6 - 1786 i E,, = 200,9 MeV raul sll gazes! ral 3 JeuY Dole RCOGH,,, +H,0,,=RCOO,,, +H,0°,, aU, RCxE+U,=0 1 AS op ee U,(t) = Be®e rl U, = Act it=0 Le U,=A=E dU, aw “aa Aee SAL 3 Ga pl RC. Aae™ + Ae™=0 Ae™(RCa+ 1 =0 -1 RCa=-1 = ct See U,= Eee : ge dsb [> sal batt gal gel 10 8 glasyl be 1 (I 2 kSUl ja CL 2 eR —+ERn +3He 26 : pgRa ald eS) aasll Am =Zm, +(A-Z)m,-m,, Am = 88x1,007 + 138x1,009 - 225,977 Am = 88,616 + 139,242 - 225,977 Am = 1,881 u e55Uh Giles 2 2B, dea,M Gb ay at tS gO) ela al bea Sa5I er E, = Amc? 177C,=0,01 mol/L DG pill aad Gat Gall — M(C,H,,O,) = 14 + 32 ..eea(L) eee =0,01 Md C= 2/8 0,6 _ Me Qor= a 60 g/mol ......... (2) 2 3g ee OD “4 n=2= C,H,0, —+ CH,COOH He pe a n= synod col peated Vays IS GS, etl > dank 11 :O aL Av = Imvs? asot 1 t “" 6-0 0 ly Rebus dds OF LI :@ ie Li =-1 mis? = AV _ 0-6 eat 12-2 splash deblae dee aS LI 2S, Gaba, oh IS BLL OG V=f) JRA oe CL S= h.b=4.6.12=365.™ +t 2 8 d=36m dee ASL! SY SIS Clie 2 1Okall jp A Waal TA abel ue pH = 3,4 => [H,0*] = 10** = [RCOO7] OH] =o = 19 e10*= 10% HO [OH] =2,5 x 10" mol/L [RCOO} [RCOOH] iRcooH] ~ ">? [REOO} = 105 [RCOOH] = 10'*5 x [RCOO] [RCOOH] = 10'* x 10° = 10795 mol/L, [RCOOH] = 8,9 x 10° mol [RCOO} _ =0 = IRCOOH] =pH=4,75 3 [RCOO] = [RCOOH] = ROO _ 1 [RCOOH] pH= pKa = pH =4,75 PUG Ga aL Jef 1 USS) ue pent = Vig = 20 mL 1 ogimedl Upload oll 55 al oles <7 2 BIS sae CV =CY, bY be CMe _ 0,01 x 20 V, 20 C= 178:S, pl tpt ABLE YI ASI M,.g-T',=M,.a,.......(2) STAT yy hU 2) Ul) ge (M, - M,sina)g Sree (A) * M,+M, rm «My Gls wcle fears (4) () 3 peep (5) ~ il+m+M, ~ 11 om, 10 1,1 +M, well) => 1,1 -M,= 10M, - 5,5: (6) Uatall + UM, =-1,145,5=44 M,=43 04 Ke M, =04Kg £5) asLall 3 ae gncly 0.4+m-b!y10 ““Tiem+04 L5¢m=4+10m- it 9m =1,5-4+5,5=7-4 = m= 3 =033 Kg m=0,33 Kg IS, pecbl gles AA 5 Lyall 2 Mie b 3+ 7, LT Re se sy Pi E_,=ma, P+R+T,=Ma, TSAI yyne gle bln, -P sino. +T, =M, «a -sene(1) 28, ptt = - a SF, =(M, + m)a, T, P,-T,=(M, + m)a, = P. (M, + m)g - T, = (M, + m)a, T= Tey eth 2) CL) op (M, + m)g - M,gsina = (M, + m+M,)a, (M,+ m - Msine)g m+M,+M, (3) ?@ib Mi 3. 2S, pet! -Mgsina +T', = M, - a, ----..() 179cecilajall olett abe f yuolall squagall 19d ga zealne A-BY, [FY [=K.Vz, 2 BU, glen Ye ISM 3 Yoge oLSt SS eas Shek I GLt opal Qe Aplll Be aid AS Sa pilhode SLES Atte Li) Cale | Sede Bhs ye bs Se CULE SUI be tll 6 31a + JEN 5 sill cole. 2 f epi gltt tS 0 ball Los 5S lbs Sep Ls Se iL licl Doll Jel 3 Har TA os pill sto] JLeal (Se at ecaly gill 55 OPE t= 0 Le Ost 4 gem Lala cSt 3S le az _LalI ASU RL ed dey Loli) Ualall Jl 5 HAL see 2,5) fol tee See Wag ils 16 2h JS AI cel WY Vg Lai Jet Sl hall aoe of ‘Vo iniah 180G pte ie eg olen LS gal tO ee geo nll fee .7 § actales (gale ct co be come lil ill ot 8 Wile lta poeiteall alls Gai Uo cand aS. 9 g=9,8 m/s? 25 Asli ods dg ae yi rgb! Gat postal! stool lee SI) Syl) fotisll plas Jy be petily t= 120 min abel ae lyst) eae ab a5 felis Of noah a f felis Mia oyope Cnet Se BT Syl pis A rl ball GS pol Ad yo ASU pepo LSS detgdl ete -3- ol yt! | M = 130g / mol p=0,872 /mL sll M=18g/ mol p=10g/mL sega bl gat poatall OF on Olid UML. 3 Ab AS BRIN (Gane / oll) A5UH pKa 8 oll seal oe el = (C,H,COOH / C,H,COO) 22 pA! Lett OF op ASE op2 pall eS gyeled gee Bagel foam Lele dale GSS Qi olan Lay pls 185wt gpl goed C, 58 pall qcitenl 5 ISSN te. 6 Lay cley (i tee MALS edgy Lend Gall Hag eam Jylone taal 7 ws gS Jas SU ade JS Of Lake eal! UL 100 mL) ant -O= 16g/ mol ¢ H=1g/mol «C= 12g¢/ mol : dans om ASN 3 Ce 25° 4 ysl ea Ke= 10" . pKa(H,0°/H,O)=0 « pKa(H,O/OH)=14 Vo ems 186ASO) JS UT Ege tent yf Ladle O31 —£50: Vo= Vim iis © dt 2 Vein = V * 108) A-BV Gin =O 28 = Von =22 m/s 2,10? Vin = Rabie Lagi tN: Vo = Vein U6 se Pile WET sey BAF [Fil-0.56n Sete tO te pol plan gs fel 7 read a, (20) git=0 a6 : dt HEI|=9,8 SI 18) ye Vo = Von tet GUE dab Wales 8 Cp ignite bli A AL sae 9 eTylt SAS od peal pyetaO dr plans plu Vi Te Vim Mow = |fg] 24 =~" Me 1,=2,28 rJodl ga petl! wast! Lepr Oy; bin ESO. PIER YE ov, Vy=0 :t20 ue » [[Fl[=0 see 03 oe HFETD 03) uh Vg be est slaagh Ulys rope a’ . ; [iPll=m jg 350 Je P I@l=p,-VILEN: pias lbibT edb yd) cLoT desl) onl pill onal 32 103, Vga o t=O. .3 av, att ot a =a, (t=O) :of Lat pbs a,(t= 0) =A=9,8 m/s? : 5} i ol eae ee t=0.ue.4 a, ¢<0) =mllell- I a) @ m => a=0)=|/ei|-|L! i [138 [[=0 203) ¢ a, t= 0) =|] BI] oS 187Bente tg =t.in2 203 rLaity (yall ya) B=5V.6 13] t= 0,20 ms Lu, =E=25v | ees ty =0,2 ms tyat. tn lw Ca 103) t,, =RCIn2 =o} C=2,9 UF =e Uo su 7 (AZ Sop 5) oO a E i()=— es ade it) Rr ‘3 E seh vanR Alu) T= 0 see sal sae fee ti, eS x107A 035 =F gmt sei =ie" cP MM hl) 5a GES coed eld. 8 oy sig) SU ates RC Ch sls POV LU ty Rit US cll as b dare pf 05 HLA. Ri+U, =E aggiléal! gal yontll Of asts -2- ao b Doll aby 1 wld 42,16 O Se (ols i op) RIFU,, = Bw. 2 du, dt au, +U,, =E:ci Cy + (SAH ep Habe Ul RC dU, THRO pret a TUE Ji Sst ee 3 Vs! + dU, It Vi gaigyaliladt ox Uae Banyo] It Bey 0955 aghey (Gi yoll Og ae) GSES) s 2 oe Ayu! ILA ot CR lan call club og ylang oe 03) at scl Nt ces gd Lig Ung) _ 3 L-et .4 Ung) Se 20,63 203] pot eS pe Bll 5] ye pall CUE wavalae Y Lpee ed oy 63% 4 ES oe eal tata 5 Usa E tat ae 2 My En -e T) iMyley 188E,, = 0,006 * 931,5 = 5,589 MeV IMeV = 1,0 x10" J E,, = 89,7 * 10° op Ike US 36 by rull GUI) — O rRa yal dl kg (389 ye-gll iy 54) 242 Cas 1000 g — N 226g — N 6,02 * 10° x 10° No 2.7 «1041p 226 N=2,7* 10" aly B= E,*N By, = 89,7 «1092.7 10%= 24x 10% FU ge UpsijLic Wb Rene Tile a + bday ays LSS Spgs y Vl juts) OT 1 yell ellaae —f dah AB Ud dely pad yt le 1S) ouall 3 abso, ey Seti spy Jel ys heal — Sstidd IS ULE alll g aS Og Gad ee 7 glass Yl Bole — ust ®, 134, 1 QU +o —» gZr + Te + 3,0 Nill coal Sepol sl oss (I poole! als shor ys Gill ple eg pills 4 gad LS aN oY (5 He) 22g yatsy oul Ra —e at Rn Jyulsle.2 pyoldlal ASU! b Oba OL 3 aay UN des Bae ye “uRa Am, =Zm, + (A-Z)m, - m,. Am,, = 88m, + (226 - 88)m, - m,,. Am, = 88 * 1,007 + 138 x 1,009 - 225.977. Am,, = 1,881u TLS — Mlb BIS We 4 AB = Am.c? fo AIL oe By spy day SI GLb. 5 YS Sel OS Ue 3 dp b55 4s gS) Lah ss E,=Am* 9315 E, = 1,881 « 931,5 = 1752,15 MeV si [SS be NN ails . 6 E, go EL 275215 as sey actos = Tos E,, = M,, ~ (m, +m.) ¥ 931,5 189ny = My 20,5 gS ace 2-7-2 CV pug = By ANH ysl n= 10 CV ney pent 10 3 oe «103 n, | 0 |19)34|45}54)61]68|78) 84 io 20 90 40 80 60 70 ttmin Ti shigY! sal Aas — > 5x0,87 130 sjUatsyh felis dani felis] DG ge 8 Ub cll oyfebuct plies pb Shh Ig? ge gel Leal (TOT AY MP sackets! Mobs dee ay 9, 9. o at! —» 4 Nb + BCE) aga gl gel powell s it GA Mg) Rb gl de peel fT o Ae ga All p :BaLll -— 9 cH, 9 fp tr & cH, -¢/0-CH, CH, -CH- cit, +,0=cH,€-0-11 cH4--ci,-ci o1 on, eS SN gat go Egle Oo hp gear CHC ‘0-H 0 : ACL 9-H eB ySl depend! sca cH cH, cH, on 2d SS! — CH, - OH : iyi gil de yao! Js 1b fate -3 1901 pISSl aaa Osseo! 2 pes jill OLLU deb Sleds had oll! 143. E pl dbs de 13d lel g E eae pH, =8,2 OySy BUS de ses at Lee . 3 Una yaar Byler 03! 63 PH>7 Sh oll Ose $SGH) aes Ah ee 4 v,= i= 4,7 mb le pS Old! le LHI ods LULL rhases OS: pH JI ye pH = pKa =4,2 pKa=-Log Ka: 4x5 Ka= 10" => Ka=6,3 x 10° 1 elisll ales 5 C, H, COOH + OH =C, H, COO + H,0- yas Ka = CHCOOMMHLO', ay [C,H,COOH}, rsa! Jelisl Sy iC,H,COO 6 SO, o_O [C,H,COOH], x[OH, «Ka [C,H,COO'}, [H,0*], Ke “st pakdall Sy te C,H,0,4 H,0 = CH, COOH+CH, OH (mol) |, =0.10 [Faw a | 0 he . uge | we [oe | x | t ne 2 Ty Algol push GLa 5 t= 120 min daa is ode aly Jeli! x,= 0,084 mol : Ole gp 1.8 gg = 0510 mol ; ud eLiclh J gto oy (atl felickly r=1,* 100 = 84% SpeS bah feel aye 7 et Se — Zip soi pp yf oVstI 9 foul apetedde gen Leb gel pata Bp cape SS Sarl d 191Ee Teel Q, a> 10 soi bas aollhy - pb Joust Of Lael Ke aney pla! B Slane Se LM Gnd OSS BISA ae . 6 c, = 2294 _ 1.88 x 107 mol. 500 LSU LS OL 7 n=C. Vy n= 1,88 107 x 0,1 = 1,88 x 10% mol ey (0 n=Qp=m=nxM tkydly m= 1,88 x 104 x 122 anes m=2,29x 10? g 1922010 - 2011