iin 7S TNT
Field application of compressor
coatings saves big dollars
Over time, turbine compressors and other driven compressors suffer from cor-
rosion, oxidation, and, in many cases, severe fouling, which in turn can
cause in-service breakdown and premature overhaul. Today’s innovative
protective coatings can be applied on-site to rotors and individual compo-
nents to replicate the surface finish, corrosion resistance, and antifouling
properties of new components.
By Mark F. Mosser and Paul Brooks, Sermatech International Inc.
Coating conundrums
The goal of any coating
ata low surface rougl eliminate cor-
rosion and fouling. But choosing a coating is
a complex decision, because turbines operate
in environments that often combine high hu
rmidity, high salinity, severely acidic or alka-
line pollution (in chemical plants), and sand
erosion. On the other hand, many turbi
‘operate in low-humidity conditions without
any extreme environmental influences.
Because of these many variables, the
OEM may apply protective coatings suitable
for “average” or “typical” conditions, Such
coatings may perform well in some environ
‘ments and fail prematurely in others, but the
OEM cannot economically provide for coat
ing protection in every different application,
In fact, driven centrifugal compressors (any
that aren’t integral to a gas turbine) are often
not coated at all and are therefore more sub-
ject to corrosion and fouling,
In addition, the time between overhauls
of all gas turbine compressors has increased,
Which means that compressors must function
efficiently for significantly longer periods of
time. That makes the quality of compressor
‘even more important.
coatin
Coating failure can quickly lead to blade
failure due to stress corrosion, pitting, and
catastfophic failure (Figure 1). Fatigue fail-
ures invariably originate with corrosion pits
forming a stress riser from which a crack
propagates—ultimately resulting in blade
failure (Figure 2)
Though fatigue failure is a serious issue,
there are other consequences of coating fail-
ture. Any inerease in surface roughness results
in a decrease in compressor eff
increased fuel consumption,
crating costs. In addition, aerodynami
in the compressor may increase exhaust gas
{temperatures and increase wear and hot cor-
1. Gone but not forgotten. stress
corrosion at the blade base caused this blade
failure. Courtesy: Sermatech International
2. Trickle-down theory. Many dow
stream blades are damaged by a single liber.
ated aol. Courtesy: Sermatech International
rosion, further increasing costs and decreas-
ing time between overhauls.
Fouling is a drag
Al compressors need a surface coating that
cen eliminate of mitigate fouling because the
aerodynamic drag in a compressor increases
with the roughness of the airfoil surfaces.
Fouling consists of any deposit on a surface
that contacts @ moving fluid (such as air
the ease ofa gas turbine), disturbs the laminar
flow ofthat fluid, and consequently decreas-
ethe erossectional area ofthe gas path. De
posits on airfoils will disturb fluid flow and
increase drag even when the accumulation is
not suf
area of the flow path in an axial compressor
Fouling can occur in a turbine engine
Lough a variety of mechanisms, For exam.
ple, materials dissolved in moisture, which
is present in the intake air, ean condense and
dry on blade surfaces. Additionally, fine par
ticles in the air can be attracted and held on
surfaces by electrostatic forces
The most prevalent source of fouling on
nt to decrease the crosssectional
foils is corrosion, Corrosion
results from the reaction of the metal surface
with its operating environment. Corrosion is
natural. All engineering metals—ineluding
iron, nickel, and aluminum—are found as
compounds of oxy
ture, These compounds must be refined to
produce eng
natural process by which these refined metals
return to their natural state as compounds of
either oxygen or sulfur.
In extreme cases, corrosion consumes
load-bearing metal and weakens engi
neering structures. Corrosion pits localize
‘mechanical stresses and can lead to cata
trophic mechanical failure. Even before
pitting or loss of metal present significant
‘mechanical problems in a turbine, rough
sn-and/or sulfur in na
{neering metals. Corrosion is the
corrosion deposits on airfoil surfaces will3. Rough air. Piting and corosion prod-
Uucts deposited on blade surfaces disrupt the
smooth airflow required for efficient opere-
tion. Source: Sermatech international In.
Turbulent fow
and structural damage
Laminar flow
Corrosion products Pts
disturb laminar flow and diminish perfor-
mance. Figure 3 presents the two types of
flow with the clearly visible result of sur-
face deposition: turbulent flow and ineffi
ciency. Deposits lead to prolonged surface
wetness; prolonged surface wetness leads to
corrosion and specifically to pitting, which
will preferentially occur under the deposit.
Causes of corrosion
Aqueous corrosion of metals is caused by
‘moisture that is contaminated with ions, es-
pecially chloride and sulfate ions. The rate of
corrosion is determined by:
‘= The length of time that the surface remains
wet
1 The acidity or alkalinity of the solution on
the surface.
‘= The exact ions present in the solution,
‘= The concentration of the ions in the solu-
tion (such as conductivity ofthe solution).
Extremes of pH—highly acidic or highly
alkaline—may be more corrosive than neu:
tral (pH = 7) solutions. For example, the low
pH of rain in northern Europe, which can be
3.0 t0 4.5, accelerates corrosion in industrial
turbines there, Chloride and sulfate ions also
tend to aggravate corrosion, For example,
steel will not corrode at high pH unless chlo-
ride is present.
‘A gas turbine vacuums contaminants
from its surroundings and concentrates them.
within the compressor’s intake air. These
‘contaminants precipitate and deposit on air-
foils as intake air is compressed and heated.
AC shutdown, these deposits absorb moisture
from the air. When the deposits first begin
to dissolve in water condensing on a fouled
airfoil, the concentration of ions in the drop-
lets is very high and the solution is extremely
corrosive. As this cycle is repeated, gas tur-
bines suffer aggressive corrosion and gas
path surfaces roughen,
Limit fouling
by treating the surface
One way of changing the response ofan i
foiltoits operating environments to teat the
surface with a coating. Coatings have been
ug 2018 POWER
Table 1. Proper
Inc.
Note: Ra = surface roughness.
used for many years to manage and limit the
corrosion of airfoils and entre compressor.
Coatings are often the only practical alterna-
tive t contol corrosion and fouling of tur
bine hardware
‘Aluminum-flled overlay coatings are
usually used in turbine applications. These
‘coatings begin as water-based slurries of alu-
minum powder (