JEE Main 2013

[1]

Part - B
61.

Which of the following represents the correct order of

increasing first ionization enthalpy Ca , Ba, S, Se and
Ar ?

66.

Compound (A), C8 H 9 Br gives a white precipitate

when warmed with alcoholic AgNO 3 . Oxidation of
(A) gives an acid (B), C8 H 6O 4 . (B) easily forms anhydride on heating. Identify the compound (A)

(1) Ba Ca Se S Ar
(2) Ca Ba S Se Ar

CH2Br

(3) Ca Se Ba Se Ar

(1)

(2)

(4) S Se Ca Ba Ar

CH3
CH3

Ans: [1]
62.

A gaseous hydrocarbon gives upon combustion 0.72

CH2Br

(3)

g. of water and 3.08 g of CO 2 . The empirical formula

of the Hydrocarbon is
(1) C6 H 5

(2) C 7 H 8

(3) C 2 H 4

(4) C 3 H 4

Br
Ans: [2]
A compound with molecular mass 180 is acylated with

(1) 58.5 kJ mol 1

(2) 60.5 kJ mol 1

CH 3COCl to get a compound with molecular mass

390. The number of amino groups present per molecule of the former compound is
(1) 4
(2) 6
(3) 2
(4) 5
Ans: [4]

(3) 53.6 kJ mol 1

(4) 48.6 kJ mol 1

68.

The rate of a reaction doubles when its temperature

changes form 300 K to 310 K. Activation energy of
such a rection will be:
(R = 8.314 JK1 mol1 and log 2 = 0.301)

Ans: [3]
64.

The gas leaked from a strong tank of the Union

Carbide plant in Bhopal gas tragedy was:
(1) Ammonia
(2) Phosgene
(3) Methylsocyanate
(4) Methylamine
Ans: [3]
65.

C2H5
(4)

CH3

67.

Ans: [2]
63.

CH2Br

(1) CH 3 CH COOH (2) CH 3CH 2 COOH

|
CH 3
(3) CH 3COOH
Ans: [2]

(4) CH 3CH 2 CH 2 COOH

(1) O 2

(2) S2

(3) C 2

(4) N 2

Ans: [3, 4]
69.

An organic compound A upon reacting with NH 3 gives

B. On heating, B gives C. C in presence of KOH reacts
with Br2 to give CH 3CH 2 NH 2 . A is

Which one of the following molecules is expected to

exhibit diamagnetic behaviour?

In which of the following pairs of molecules/ions, both

the species are not likely to exist?
(1) H 22 , He 2

(2) H 2 , He22

(3) H 2 , He22

(4) H 2 , He22

Ans: [1]
70.

Which of the following complex species is not expected

to exhibit optical isomerism?

b g

(1) Co NH 3 3 Cl 3
(3) Co(en) 3
Ans: [1]

b g

(2) Co(en) NH 3 2 Cl 2
(4) Co(en) 2 Cl 2

JEE Main 2013

71.

[2]

The coagulating power of electrolytes having ions

Na , Al and Ba
creases in the order :

(1) Ba 2 Na Al 3

78.

for arsenic sulphide sol in(2) Al 3 Na Ba 2

(1) q 208 J , w 208 J

(3) Al 3 Ba 2 Na (4) Na Ba 2 Al 3

(2) q 208 J , w 208 J

Ans: [4]
72.

(3) q 208 J , w 208 J

Consider the following reaction :

x MnO 4 y C 2 O 42 z H

x Mn 2 2 y CO 2 2z H 2O
The values of x, y and z in the reaction are, respectively:
(1) 2, 5 and 16
(2) 5, 2 and 8
(3) 5, 2 and 16
(4) 2, 5 and 8
Ans: [1]
73.

Which of the following exists as covalent crystals in

the solid state?
(1) Sulphur
(2) Phosphorus
(3) Iodine
(4) Silicon
Ans: [4]
74.

(4) q 208 J , w 208 J

Ans: [3]
79.

M 3 would be :
(1) 6.05 %
(3) 7.01 %
Ans: [4]
80.

(1) secondary alcohol by S N 2

For gaseous state, if most probable speed is dentoed

(1) C* : C : C 1 : 1128
. : 1225
.
(2) C* : C : C 1 : 1228
.
: 1128
.

(2) free radical

(4) carbene

An unknown alcohol is treated with eh "Lucas reagent"

to determine whether the alcohol is primary, secondary or tertiary. Which alcohol reacts fastest and by what
mechanism:

(2) 5.08 %
(4) 4.08 %

by C*, average speed by C and mean s2quare speed

by C, then for a large number of molecules the rations
of these speeds are:

amount SbCl5 due to the formation of

75.

Experimentally it was found that a metal oxide has formula M 0.98O. Metal M, is present as M 2 and M 3 in
its oxide. Fraction of the metal which exists as

A solution of () 1 chloro-1-phenylethane in
toluene racemises slowly in the presence of a small

(1) carbocation
(3) carbanion
Ans: [1]

A piston filled with 0.04 mol of an ideal gas expands

reversibly from 50.0 mL of 375 mL at a constant temperature of 37.0C . As it does so, it absorbs 208 J of
heat. The values of q and w for the process will be:
(R = 8.314 J / mol K)(ln 7.5 = 2.01)

(3) C* : C : C 1225
.
: 1128
. :1
(4) C* : C : C 1128
. : 1225
.
:1
Ans: [1]
81.

Arragne the following compound in order of decreasing acidity:

(2) tertiary alcohol by S N 2

(3) secondary alcohol by S N 1
(4) tertiary alcohol by S N 1
Ans: [4]
76.

How may litres of water must be added to 1 litre of an

aqueous solution HCl with a pH of 1 to create an aqueous solution with pH of 2?
(1) 2.0 L
(2) 9.0 L
(3) 0.1 L
(4) 0.9 L
Ans: [2]
77.

The molarity of a solution obtained by mixing 750 mL

of 0.5 (M) HCl with 250 mL of 2 (M) HCl will be
(1) 1.75 M
(2) 0.975 M
(3) 0.875 M
(4) 1.00 M
Ans: [3]

(1) III I II IV

(2) IV III I II

(3) II IV I III

(4) I II III IV

Ans: [1]

JEE Main 2013

82.

[3]

The order of stability of the following carbocations:

87.

Synthesis of each molecule of glucose in photosynthesis involves:

(1) 8 molecules of ATP
(2) 6 molecules of ATP
(3) 18 molecules of ATP
(4) 10 molecules of ATP
Ans: [3]
88.

(1) I II III

(2) III I II

Which of the following is the wrong statement?

(1) Ozone is violet - black in solid state
(2) Ozone is diamagnetic gas

(3) III II I

(4) II III I

(3) ONCl and ONO are not isoelectronic

is

Ans: [2]
83.

(4) O 3 molecule is bent

The first ionisation potential of Na is 5.1 eV. The value

Ans: [ All given statements are correct]

of electron gain enthalpy of Na will be

(1) 10.2 eV

(2) 2.55 eV

(3) 2.55 eV

. eV
(4) 51

89.

(1) Co 3 Fe3 Cr 3 Sc3 : stability in aqueous

solution

Ans: [4]
84.

one of them is expected to have the highest

b g
(3) Cr b Z 24g

(2) Co Z 27

Ans: [2]

Li2

Li2

(2)

(3) Li2 Li2 Li 2

Li2

Li2

Li2

(4) Li 2 Li 2 Li 2

Ans: [4]
86.

Energy of an electron is given by

E 2.178 1018 J

FZ I
GH n JK . Wavelength of light
2

required to excite an electron in an hydrogen atom form

level n = 1 to n = 2 will be:
( h 6.62 1034 Js and c 3.0 108 ms1 )
(1) 6.500 107 m

(2) 8.500 107 m

(3) 1214
.
107 m

(4) 2.816 107 m

Ans: [3]

(4) Ni 2 Co 2 Fe2 Mn 2 : ionic size

Ans: [3]
90.

Give
0
. V
E 0Cr 3 / Cr 0.74 V ; E MnO / Mn2 151
4

Stability of the species Li2 , Li 2 and Li 2 increases in

the order of
(1) Li2

(3) V2 Cr 2 Mn2 Fe2 paramagnetic behaviour

E 0M 3 / M 2

b g
(4) Mn b Z 24g

(1) Fe Z 26

85.

(2) Se Ti Cr Mn : number of oxidation states

For successive members of the first row transition elements are listed below with atomic numbers. Which

value ?

Which of the following arrangements does not represent the correct order of the property stated against is

E 0Cr O2 /Cr 3 133

. V ; E 0Cl / Cl 136
. V
2 7
Based on the data given above, strongest oxidising
agent will be :
(1) Mn 2

(2) MnO 4

(3) Cl

(4) Cr 3

Ans: [2]