Development of Liquid Cleansing Formula with AMISOFT Characteristics of SLES/CAPB base formulations The total amount of Soduim Laureth sulfate (SLES), Cocamidopropy! betaine (CAPB) and AMISOFT ECS-22SB was kept at 18.0wt% in an active base, and the pH was adjusted to 5.5, 6.0, 6.5 and 7.0 with citric acid. i ar, SLES "'(A.l,) 12.50 CAPB 7 (AL) 2.60 Total 18.0wt% (A.1.) AMISOFT ECS-22SB(A.l,) 3.00 “1 Texapon N-T0(70%), Cogs : "2 Dehyton K(30%),C Cocamide DEA® 2.00 Sakarle 96 28, Roda Preservative” 0.05 *4 Kathon CG, Rohm & Haas Citric acid q.8.—> Adjusted to pH 5.5, 6.0, 6.5, 7.0 Water balance Total 100.00 Foam: flasht, volumet pH<6:residual dry feet pH>6:siow rinsability, sticky skin feel Foam: flash! 7 Foam: volumet, structuret Rinsabilty’ Dry skin feet: silky and smooth pH: foamabilty and rinsabilty are better at pH 5.56.0 72 1s ° CAPB &, 0 3 6 Hand wash test with tap water (nardness: 6Oppm as CaCO) Figure. Sensory characteristics of SLES/CAPB/AMISOFT ECS-22SB temary system 0101-3260E-OME, 2004-11-30 12 16 18 AMISOFT ECS-22SB AJINOMOTO CO., INC.Comparison of Mild Surfactants 1 Sensory Evaluation / Tap Water Various mild surfactants were added to a SLES/CAP8-base liquid cleansing formulation and the hand-wash sensory test was conducted. Formulations with _ _ Control ___mild surfactants ‘Sodium laureth sulfate (SLES) 15.0 ns 11.3 Tt Cocamidopropyl betaine (CAPB)? 3.0 22 22 sage AMISOFT ECS-2288 : 160 (active) Mild surfactants : 4.8(active) ‘Cocamide DEA’ 20 2.0 20 Methylparaben 02 02 02 Water balance balance balance Total 100.0 100.0 1000 BeTc-20 Koda DE Kawaken Fine Chemicals APG Decyl Glucoside Plantaren 2000 Cognis SAR Sodium Lauroyl Sarcosinate Soypon SLE Kawaken Fine Chemicals SCl_ Sodium Cocoyl Isethionate _Hostapon SCI 85G_ Clariant CMT Sodium Methyl Cocoy! TaurateHostapon CT Clariant Sensory test with tap water (Hardness: 6Oppm as CaCO.) ’ Creamy foam with fine bubble structure. Better rinsabality AMISOFT ECS-22S8 parts smooth and siky feel tothe skin, APG Flash, airy and stable foam. Skin afterfee! is slightly rough and drying. aR Flash, thick and rich foam. Good rinsabilty Non-tacky light skin feel, slightly drying. scl Fine bubble structure and foam stability are excellent. Slick rinse- feel thus rinsability feels slow. Soft and waxy skin feel. cur ‘Coarse foam, poor in volume. Skin feel during rinse is squaky. AJINOMOTO CO., INC. Dry skin feel is smooth. 0101-22706-OME 2004-11-30Comparison of Mild Surfactants -7 Bubble Structure / Tap Water The addition of AMISOFT ECS-22SB to a SLES/CAPB-base formulation leads to finer bubbie structure*. Foam structures of various mild surfactants were observed microscopically. “Technical Data Sheet No.0101-3260 ‘The test formulations were diluted with tap water and the foams were produced by an electric mixer. Test formulations 4.09 + Tap water 20.09, water hardness: 60ppm as CaCO, Stirring time: 30 seconds at RT Foam structures ofthe test formulations were observed with a microscope (x60). RE BT, Tap Walt (tar Harness: 6OppM as CaCO), 0 Extra large Large Middle ‘Small Extra small Control AMISOFT = APG SAR scl CMT Ecs.22SB bid eer e nnn ee ee Figure. Bubble Size (Visual score determined from the images of microscope) AJINOMOTO CO, INC. 0101-3330E-OME 2003-11-30AJINOMOTO TECHNICAL NEWS 04F-006 Sep 2004 Facial Cleansing EKGEE-E16 ‘This clear gel type facial cleansing could be supplied in @ tube. cold process is possible (wn ‘A AGRYLATES/CI0 30 ALKYL ACRYLATE CROSSPOLYMER™T 13 WATER balance B AMISOFT ECS-22SB (30%) 20 COCAMIDOPROPYL BETAINE (30%) 10.6 SODIUM LAURETH SULFATE (70%) 80 GLYCERIN 150 © SODIUM HYDROXIDE oa WATER os D_ METHYLCHLOROISOTHIAZOLINONE 005 ‘AND METHYLISOTHIAZOLINONE"2 FRAGRANCE as 700.0 1. Charge batch vessel with water and begin mixing, 2 Slowly add Carbopol 3 Add pant B ingredients with stirring 4. Neutralize with part C anc! keep sting 6 Add part D, “1 CerbopolETO-2020 © NOVEON. +2 Kathen co. ROHM & HAAS: pH, 83 Viscosity, €,000-12,000mPa's (B type, rotor No4. 30rpm, SOsec., 25°C) Stability 45°C for three montne |Nete: ne information ie provided based! per cw technical cata ard present krewlecpe However we make nia warrentes, expressed ov mplied arc estume na abilties in corecion lwah any use ef tie inortration with respect to spectic propery, safety ara sutabilty for speciic appicel a7 (is alec noi qusteriees thal se ef ie infereten does "ox fall wale the Bf ay nlesectual property vhs,AJINOMOTO TECHNICAL NEWS 04F-007 ‘Sep.2004 Shower Gel SKPEE-A90 This oe type formulation is also suitable as @ base-formulation of face cleansing gel. AMISOFT imparts pieesant siky fee! to skin . (at ‘A ACRYLATES COPOLYMER" 8.0 WATER 450 B AMISOFT ECS-2288 (30%) 150 COCAMIDOPROPYL BETAINE (30%) 18.0 ‘SODIUM LAURETH SULFATE (70%) 129 COCAMIDE DEA 20 © CITRIC ACID 00-03 WATER balance D- METHYLCHLOROISOTHIAZOLINONE 00s ‘AND METHYLISOTHIAZOLINONE"2 FRAGRANCE qs. 7000 4. Mix Csrbopol with water. 2 Add part B an mix. 3 Add pert B ingredients with stirring 4 Addpat Ct tin iea!vacosiy ‘Add part D. +1 Carbopol AQUA SF-1 Polymer NOVEON +2. Kethon CG ROHM & HAAS pH; 6.25.9 (Depends on the amount of Citric acid) Viscosity; 4,300-7,500mPa's (B type, rotor No.4, 30pm, 30sec., 25°C) Stability, 45, 25, 0°C for three months [Note:The iromaton provided based vpn ut echical dala and present noweaoe—_—| Nowever we maka no werantes, expensed Freie, an ase ails In conracon |with any use of the information with respect to specific property, safety and suitability for @ specific seoicabon. his 380 nt guoareed iat use ofthe formato does nll wan he scope ot any neecuel property hsAJINOMOTO TECHNICAL NEWS 04F-008 Oct.2004 Shower Gel SKPEE-A117 (wf%) ‘A SODIUM LAURETH SULFATE (70%) 12.8 COCAMIDOPROPYL BETAINE (30%) 15.0 AMISOFT ECS-228B (30%) 15.0 PPG-2 HYDROXYETHYL COCO/ISOSTEARAMIDE*1 2.0 AJIPEW NL-50 (50%) 20 PEG-7 GLYCERYL COCOATE*2 20 PEG-120 METHYLGLUCOSE DIOLEATE"3 06 ‘SODIUM CHLORIDE 0s PRESERVATIVE as. WATER balance B_ FRAGRANCE as. C_CITRIC ACID gs. 700.0 1 Mix part A ingredients and heat to 80°C. 2. Mix until uniform. 3. Cool to 50°C and add part B. 4 Cool to room temperature with string 5 Adjust pH with part C. Stir until homogeneous. 71 Promidium2 UNIQEMA, +2. Glycerox HE CRODA "3. Glucamate DOE-120 CHEMRON pH; 5558 Viscosity, 3,500mPa's (B type, rotor No 3, S01pm, 30sec., 25°C) Stability; 45, 25, 0°C for three months 'Note: The information is provided based upon our technicel dete ene present knowledge. However, we make no werreries, expressed or implied, and assume no Kbiltis in connection |with any use of the information with respect to specific property, sefety and sultbilty fore specific lapplication. tis also not guaranteed thal use ofthe information does net fell within the scope of lany intellectuel property rights.