68,
70,
nd
2.
. oH et otis“
i le
CH -CH ~ CHCH, (iv) CH ~CH ~CH CH,CI
Optically active Optically inactive
‘Thus structures (i) and (iii) are optically active, each has
one chiral carbon; so each structure will give one
‘enantiomeric pair; thus total enantiomeric pairs will be
two.
The structure CHs CHBrCH BrCOOH has two different
chiral carbon atoms, hence number of enantiomers
(optically active forms) is 2"= 22 = 4
Gls Ces CH;
rl |
CH; ~ CH- CH-CH,CH3 CH, -C-CH,CH,CH,
2,3~dimethylpentane ity
{has chiral C) 2, 2~dimethylpentane
(No chiral carbon)
ots
(CH - CH -CHCH,CHCH,
2-Methylhexane
(No chiral carbon)
Only structure CH) =CHCHOHCH, has a chiral
carbon
Due to cis-addition of H, to the triple bond, the reduced
product has a plane of symmetry and hence is optically
inactive.
Geometrical isomerism due tothe presence of a double bond
whose each carbon has two different substituents, Optical
isomerism due to presence of a chiral carbon,
‘Ar-CHOHCOOH
he
1,
75,
nN.
7B,
81.
84,
85,
cay 6: cH- GA-cHrct,
a) Gy
2-Chloro-4-methylhex-2-ene
Geometrical isomerism due to C = C, each C has two
(it) > (i) >(i.
As the size ofthe ring increases, the internal angle increases
accordingly. As a result the deviation from the tetrahedral
angle and hence the angle strain increases as the size of
the ring increases. Thus, planar cyclodecane is expected to
have the maximum angle strain.