9. ‘The molecular formula of a saturated compound is, (CHBry.. This formula permits the existence of (a) Functional isomers (b) Optical isomers (©) Positional isomers (4) Cis-trans isomers ‘The production of an optically active compound from a symmetric molecule without resolution is termed (a) Walden inversion (b) Partial racemisation (©) Asymmetric synthesis (4) Partial resolution Which of the following is optically active (@) n- propanol (b) 2 Chlorobutane (©) n-butanol (a) 3 ~ hydroxy pentane Geometrical isomerism is not shown by CHy | (®) CH CH;C= C CH,CHs f CHy (b) CoH -C=C-CHyI (©) CH, (@) CH; -CH =CH-CH =CH, ‘The maximum number of stereoisomers possible for 3 - hydroxy - 2 -methyl butanoie acid is . @1 (&) 2 3 @4 ‘The optically active tartaric acid is named as D -(+)- tartaric acid because it has a positive (a) Optical rotation and is drived form D - glucose (b) pH in organic solvent (©) Optical rotation end is derived from D - (+) - slyceraldehyde (@) Optical rotation when substituted by deuterium ‘The enol form of acetone after treatment’ with D,O gives: e g (@) CH)-C=CH, () CH;-C-cD3 on op © ciy=0=cH,0 (@ cdy=C-cd; Two geometrical isomers are given by the following compound * {a) Ethylidene bromide (b) Acetylene tetrachloride (©) Acetylene tetrabromide (d) Acetylene dibromide Only to isomeric manochlro derivatives are possible for : (a) n-butane (©) 2,4- dimethylpentane (©) Benzene (@ 2-methylbutane 16. Keto-enol tautomerism is observe g g i (2) Cais ©) cytts-C-chis (©) CeHs-C-Cys(@) None 6 11. Ethoxy ethane and methoxy propane are (a) Geometrical isomers (b) Optical isomers (©) Functional group isomers (a) Metamers 12, The number of struttural and configurational isomers of a ‘bromo compound, C.H,Br, formed by the ation of HBr to 2- pentyne respectively are (a) Land2 (b) 2and4 (© 4and2 (@) 2and1 13, The structure, cn, H Soa : No 4 YS coonshows : cry (a) Geometrical isomerism (b) Optical isomerism (©) Geometrical and optical isomerism (@) Tautomerism 14, The number of possible enantiomeric pairs that can be produced during monochlorination of 2- methyl butane is : (a 2 ©) 3 4 @1 15; The correct statement about the compounds A, B and C is coock; coon " on H on HW ‘oH H ‘OH coon coock, “ ® 00H n—4 ‘on ou— 4 coock, © (@) A and B are identical (b) A and B are diastereomers (©) Aand C are enantiomers (@ A and B are enantiomers