27. The structure shown below has the configuration CICH)5 cHctt), @r ws © Both (© None 28. The structure of allen is city =C=CH, (0) Slaggere (b) Planar (© Both (8) None 28. The compound showing geometrical isomerism te cattycu = (a) Colts NOH (b) Br “COD @ all Hon on 20, on HOH @ (ii) (@) chia enantiomers () achiradentea rior images (©) geometrical isomers (@) (b) and (6) both 31, Which of the following will show tautomerism ? ° 1 , *OO 0 9 “COO q 32, 33, 34, 35, 36, 37, 38, 39. Idnetify the Keto form of the following enol yw on (@) 1-penten-3-one (©) (&)3-penten-2-one (c) 2-pentanone (a) (E}3-pentanal Whats the relationship between Kelo and enol tautomers? (e) Resonance forms (b) Constitutional isomers (c) Stereoisomers. (@) different conformations of the same compound Which ofthe following has the highest percentage of enol ina Keto-enol equilibrium ? (@) Hexanal (©) 2hexanone © 2 4hexanedione _(@) 2, Schexanedione Which of the following optically active compounds recemizes in dil. KOH/CH3OH solution ? 9 @ . CH” “Cols ° HCH (b) HygC., Sols} O Se ® ne ScHy, ‘What are the configurations of carbon atoms 2 and 3 respectively in D-threose shown below ? cHo HOE H upon cH;0n (@) RR ) RS (©) SR (@) SS How many stereoisomeriealdohexoses are there 2 (@) four (©) eight (c) sixteen (d) eighteen ‘What is the relationship between open chain forms of D- ‘glucose and D-altrose ? (2) enantiomers (b) constitutional isomers (©) diastereomers (@) different conformations of the same compound ‘Which of the following compounds will not have diastereo isomers ? (@) COOH(CHOH), COOH (b) CH; CHOH.COOH (©) CH) OH (CHOH), CHO (@) CH; OH(CHOH), CH; OH