Adsorption

# (Adsorption) :

) (adsorbate
) (adsorbent
) (Vander waals

# :
-1 :
.
)(
.
-2 :
.
.
-3 :
.
1000oC-350 .

 # :

.
:
-1 :
)
(
.

) (40KJ /mol

 -2 :


) (Specific

) . (KJ / mol 80




.



..

 # :
:
.

.

..
I
) (



.
..

# :
) (Heat +

Fe

G
S
.

.
.

Rh

G = H TS:



.
.
:
ns
integral heat of adsorption
Eg . Es
:
)Qint = ns(Eg-Es

 . dns
)qdiff = (dqint/dns
qdiff Differential

.
dv P dns .
Pdv = dnsRT
RT

qiso = qdiff + RT
qiso

 qiso -:

\ .

# :
-1 :
) (x
.
X / m = K P1/n
P K,n

log x/m = 1/n logP + log K:

 n/1 logK
Log x/m

Log p

 -2 :
1916
:
-1

.
-2 :
.
.
- 3
.

 (1- ) P
) K1 P (1- K1
=

= K2
:
K1 P (1- ) = K2
K1 P K1P = K2
K1 P = (K1 P + K2)
= K1P / (K1P + K2)
K2
= (K1/K2)P / ((K1/K2)P + 1)
bP/(bP+10)=
b = K1/K2

 -4
.
= , A
=a
P
= a/A =
= -1


.
)(

 ) ( m Y

x/m = Y = K = KbP/(bP+1)
)Y = a P / (bP + 1
Y = bP + 1/aP/1
p/Y = bP + 1/a
P + 1/a) b/a= (
P/Y, P
= b/a
a/1

 -3 BET :

.


site
....

) (...