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Reservoir-fluid properties play a key role in designing and optimizing well completions
and surface production facilities to manage reservoirs efficiently. Therefore, accurate
fluid characterization is a vital part of any oil or gas production project. Advanced
fluid-analysis techniques provide the high-quality data required to develop appropriate
production strategies.
Soraya Betancourt
Cambridge, Massachusetts, USA
Tara Davies
Ray Kennedy
Edmonton, Alberta, Canada
Chengli Dong
Sugar Land, Texas, USA
Hani Elshahawi
Shell International Exploration and Production
Houston, Texas
Oliver C. Mullins
John Nighswander
Houston, Texas
Michael OKeefe
Hobart, Tasmania, Australia
Discovery of an oil or gas accumulation immediately prompts questions about its economic
viability. Operators want to learn about the
extent of the reservoir, the types of fluids that
would be produced, expected production rates
and how long production might be sustained.
Fluid analysis is a critical part of the process by
which engineers perform reservoir characterization, determine the reservoir architecture and
decide whether an oil or gas accumulation is
worth developing. High-quality samples are
essential, because erroneous data could lead
engineers to misinterpret production parameters
such as drainage volume, flow rates, reserves and
facilities design and completion. Clearly, poor or
misleading fluid data can have a severe negative
financial impact.
If the reservoir analysis is positive, engineers
begin designing a production system that will
16,000
14,000
Wax
12,000
Pressure, psi
10,000
Reservoir
8,000
Hydrate
6,000
Asphaltene
4,000
Bubblepoint
2,000
0
Flowline
0
50
100
150
Temperature, F
200
250
300
> Typical deepwater Gulf of Mexico oil-phase diagram. During the journey from
the reservoir to the flowline, the oil temperature and pressure decline, and may
cross phase boundaries at which asphaltenes (purple), waxes (blue) and
hydrates (green) will tend to separate and form solid deposits. Gas begins to
separate from the oil as it passes through the bubblepoint boundary (red).
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Oilfield Review
45
40
35
30
25
20
15
10
5
0
45
40
35
30
25
20
15
10
5
0
Median-weight oil
Water
Hydrocarbons
90
80
Condensate
70
2
60
50
Autumn 2007
40
57
Gas Field
with Retrograde
Condensation
Critical
point
Oil
Cricondenbar
us
loc
int
o
lep
bb
50%
Bu
40%
locus
20%
10%
5%
De
wp
oint
Pressure
Cricondentherm
Oil Field
with Dissolved Gas
Gas
0%
Temperature
Reservoir-Fluid Sampling
Scientists and engineers of various disciplines rely
on fluid-sample data when making decisions about
reservoir development. For example, reservoir
engineers use the data to determine reservoir
architecture, estimate reserves, perform materialbalance calculations and analyze fluid flow in
porous media. Geologists need accurate information to perform reservoir correlations and
geochemical studies. Refining and marketing
personnel make decisions about product yield and
value. If erroneous data are used, unanticipated
and expensive consequences could result
during production.3
A wide range of fluid behaviors can influence
a sampling and analysis program. A reservoirfluid system can be roughly categorized by its
vapor-liquid phase behavior; the classifications
range from dry gas, wet gas and retrograde gas to
volatile oil, black oil or heavy oil (left).4 Another
consideration is hydrocarbon solid-phase
behavior. Wax and hydrate formation is
predominantly induced by a temperature
decline, and pressure reductions or fluid
commingling generally cause asphaltenes to fall
out of solution (next page, top).5
Engineers collect formation-water samples to
determine whether calcite, barite or halite
scales will form within flowlines. Corrosive and
toxic substances such as carbon dioxide [CO2]
and hydrogen sulfide [H2S] must be detected and
measured because they influence tubular-alloy
selection and the design of safety and
environmental systems from the wellhead to the
surface production facility. Water pH is also an
important parameter governing scale and
corrosion, and may be measured downhole to
avoid uncertainties.6
Increasing depth
> Crude-oil samples from a single column of oil in a reservoir. The continuous color change is a vivid illustration of compositional grading. (Photograph is
courtesy of Shell.)
3. Nagarajan NR, Honarpour MM and Sampath K:
Reservoir-Fluid Sampling and CharacterizationKey to
Efficient Reservoir Management, Journal of Petroleum
Technology 59, no. 8 (August 2007): 8091.
4. McCain WD Jr: The Five Reservoir Fluids, in The
Properties of Reservoir Fluids (2nd Edition). Tulsa:
PennWell Books (1990): 147164.
5. Akbarzadeh K, Hammami, A, Kharrat A, Zhang D,
Allenson S, Creek J, Kabir S, Jamaluddin A, Marshall AG,
Rodgers RP, Mullins OC and Solbakken T: Asphaltenes
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Oilfield Review
Autumn 2007
Asphaltene
Wax
Inorganic scale
Hydrate
Pressure
Reservoir pressure
Original
reservoir
fluid
Free gas
Bubblepoint
Wellbore flowing pressure
Pressure
Original
reservoir
fluid
One-phase
representative
sample fluid
59
Reservoir section
Power cartridge
100
0
Sample-bottle
module
1,000
10,000 100,000
A
500
Se
al
1,000
Se
Sample
flow
1,500
al
Pump module
(sample)
2,000
2,500
Hydraulic module
3,000
D
E
F G
H J
I
3,500
Focused sampling
probe
Guard
flow
Oil
Water
Dry gas
Rich gas and condensate
Depth, ft
> Reservoir section (left) and real-time DFA GOR measurements (right) of
reservoir fluids in a deepwater exploration well. There is good agreement
between the GOR values and the reservoir structure. The FCA analysis
suggested locations for fluid sampling (blue dots, right). The reservoir fluids
vary significantly from dry gas (Fluids A and B) and condensate gases (Fluid C)
at the top, to black oils with different GORs (Fluids D through J) at the bottom.
At the bottom of the oil column (Fluids H, I and J), GOR variations indicate a
gentle fluid-composition gradient. On the other hand, a GOR inversion is
evident between Fluids E and F; Fluid F is deeper than Fluid E, but has a higher
GOR. A similar inversion occurs between Fluids G and J, suggesting a complex
reservoir structure with a potential flow barrier at sampling station J.
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Oilfield Review
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5,500
GOR, ft3/bbl 1,500
900
Pressure, psi
Gamma Ray, API
6,000
150
2,750
F
G
2,800
F
G
Top sand
Higher concentration of
C1 corresponds to lower
density of Fluid J
2,850
2,900
Depth, ft
2,950
3,000
3,050
J
H
H
Bottom sand
I
Increasing
contribution
of thermogenic
charge
3,100
3,150
55 13C methane, parts per thousand 50
0.10
1.0
0.09
0.9
0.08
0.8
0.7
0.07
0.6
0.06
0.5
0.4
P = 0.80
P = 0.90
0.3
0.2
0.1
0
> Expanded log presentation and FCA analysis of an oil column at the bottom of a deepwater
reservoir. Correlation of the GOR log (top left) with the gamma ray log (green, top center) reveals that
Fluids F and G come from one sand zone, and Fluids J, H and I reside in another. In the upper sand,
Fluids F and G have the same GOR, while in the lower sand, Fluids J, H and I display a GOR decrease
with depth. The fluid densities derived from pressure gradients (blue) reveal two principal featuresa
fluid-density inversion between Fluids G and J, and a gradual density increase from Fluid J to Fluid I
suggesting no vertical communication between the top and bottom sands. The mud-gas log (top right)
offers further supporting evidence. At the depth of Fluid J, the 13C value (red) falls abruptly and
increases gradually with depth. The relative methane concentration (blue) also fluctuates sharply at
Fluid J, then decreases gradually with deptha feature consistent with the fluid-density increase.
Final confirmation resulted from applying the FCA technique (bottom). The FCA algorithm generates a
number representing the probability that two fluids are statistically different. As measurement
uncertainties () decrease, confidence in data quality increases. Therefore, low values indicate a
high probability that perceived fluid-property differences are real. The contour plot indicates that
Fluid G has a 99% probability of being different from Fluid J, and a 95% probability of being different
from Fluid H. Discovery of reservoir compartmentalization led Shell to reevaluate the field and make
significant strategic adjustments in reservoir development.
61
1.0
0.9
0.8
Optical density
0.7
0.6
0.5
0.4
0.3
0.2
0.1
Laboratory sample
LFA tool
0.0
-0.1
1,000 1,100 1,200 1,300 1,400 1,500 1,600 1,700 1,800 1,900 2,000
Wavelength, nm
1.5
1.0
1,070
1,725
0.5
1,290
1,671
1,920
1,445
1,600
0
X=Y
Data regression
0.5
1.0
1.5
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Oilfield Review
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1.6
1.4
Laboratory sample
LFA tool
Optical density
1.2
1.0
0.8
0.6
0.4
0.2
0
1,000
1,200
1,400
1,600
1,800
2,000
Wavelength, nm
1.5
1,070
LFA optical density
1.0
1,725
0.5
1,280
1,671
1,600
1,445
1,820
X=Y
Data regression
0.5
1.0
1.5
63
100.00
Weight percent
10.00
1.00
0.01
CO2
H2S
N2
C1
C2
C3
I-C4
N-C4
I-C5
N-C5
C6
MCYC-C5
Benzene
CYCL-C6
C7
MCYCL-C6
Toluene
C8
C2-Benzene
M&P-Xylene
O-Xylene
C9
C10
C11
C12
C13
C14
C15
C16
C17
C18
C19
C20
C21
C22
C23
C24
C25
C26
C27
C28
C29
C30+
0.10
Components
> Typical crude-oil compositional analysis, determined by gas chromatography. The plot shows the
hydrocarbon contribution from C1 to C30+, as well as the CO2 concentration.
Side view
Cathetometer
Solvent
Oil
Highpressure
pumps
Magnetic mixer
16,030
14,030
Tres = 176F
T = 120F
T = 75F
Pressure, psi
12,030
10,030
8,030
6,030
4,030
2,030
30
25
30
35
40
45
50
55
Volume, cm3
60
65
70
75
> Pressure-volume-temperature (PVT) cell and bubblepoint determination. The fully visual PVT cell
allows direct confirmation of bubblepoints at various temperatures and pressures (top). A magnetic
mixer provides vigorous agitation to maintain phase equilibrium. A video-based cathetometer
measures fluid levels in the cell for phase-volume calculations. The oven heats the PVT cell to the
test temperature, and technicians monitor and plot phase volumes as a function of pressure. The
inflection point in the curves as pressure decreases defines the bubblepoint. In the case depicted
here, the bubblepoint is approximately 5,000 psi [34.5 MPa] (bottom).
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Oilfield Review
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Charged
coupled
device
Hot stage
top view
Analyzer
10
Temperature 48.6
20
50
Hot stage
Polarizer
IR filter
0C
WAT = 42C
360
rotatable
stage
Cooling
gas
44C
65
Backpressure
regulator
Heated lines
Convection oven
Fluid
sample
cylinder
Temperaturecontrolled
bath
> Model pipeline test (MPT) apparatus. Stock-tank oil circulates through a
coil of tubing immersed in a temperature-controlled bath. Flow through the
coil stops when the bath reaches the test temperature, allowing the fluid to
age and form a gel structure. After the aging period, laboratory workers
measure the nitrogen pressure necessary to initiate flow in the coil and
calculate the gel strength from a simple force-balance equation.
Pressure transducer
Cooling water
Thermocouples
Cooling bath
Thermocouples
Thermocouples
Deposition section
Reservoir
Pump
Flowmeter
Remelting bath
Tempering bath
> Wax deposition flow loop (WDFL). The WDFL is a miniature flow loop that exposes stock-tank oils
(STO) to a range of heat fluxes and shear rates that would be expected in the flowline during actual
production. The deposition section of the flow loop is a 39-in. [1-m], 0.375-in. OD stainless steel tube.
A 0.53-galUS [2.0-L] oil reservoir maintains the oil above the WAT throughout the test. The oil exits the
reservoir and flows at a controllable rate through 50 ft [15 m] of coiled copper tubing in a tempering
bath for temperature adjustment. The deposition loop is immersed in a cooling bath to simulate heat
loss in the pipeline. As the oil flows through the deposition loop, a data-acquisition system monitors
the wall temperature, oil and water temperatures, the pressure drop between the inlet and outlet of the
coil and the flow rate. Wax deposits constrict flow inside the deposition loop, increasing the pressure
required to maintain flow. The increase in pressure allows calculation of the amount of deposited wax.
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Oilfield Review
1.0E+11
160
WAT
Pour point
130
Temperature, F
100
70
40
200
700 psi
1.0E+11
1.0E+07
1.0E+08
Viscosity, mPa-s
Viscosity, mPa-s
300 psi
1.0E+09
Viscosity at 55 F
Viscosity at 65 F
Viscosity at 80 F
1.0E+08
1.0E+06
1.0E+05
1.0E+04
1.0E+07
1.0E+06
1.0E+05
1.0E+04
1.0E+03
1.0E+03
1.0E+02
1.0E+02
1.0E+01
1.0E+01
Shear stress, Pa
100
1.0E+00
10
Shear stress, Pa
100
100 psi
1.0E+10
1.0E+09
1.0E+08
Viscosity, mPa-s
800
1.0E+10
1.0E+09
1.0E+11
600
1.0E+10
1.0E+00
10
400
Pressure, psi
1.0E+07
1.0E+06
1.0E+05
1.0E+04
1.0E+03
1.0E+02
1.0E+01
1.0E+00
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Autumn 2007
Shear stress, Pa
100
67
40
170 s-1
511 s-1
35
30
25
20
15
10
70
80
90
100
Temperature, F
110
120
130
2,000
1,750
1,500
1,250
1,000
750
Maximum restart pressure
500
250
0
0
100
200
300
400
500
600
700
800
> OLGA calculation of flowline-restart pressures in 6-in. pipe. If the oil gels in
the flowline during a shutdown, pressure must be applied to overcome the gel
strength and initiate flow. The maximum pressure that can safely be applied is
500 psi. The simulation shows that maintaining an internal-flowline pressure
greater than 100 psi would allow engineers to safely restart the flowline.
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Arrival temperature, F
150
140
STO WAT
130
120
Live-oil WAT
PIP insulation
Wet insulation
110
100
2,500
5,000
7,500
10,000
12,500
15,000
17,500 20,000
140
Temperature, F
160
120
100
STO pour point
80
Live-oil pour point
60
40
10
15
20
25
Time, h
1.2
Recommended wax-removal thickness
1.0
Deposit thickness, mm
0.8
Standard n-paraffin
diffusion coefficient
0.6
WDFL n-paraffin
diffusion coefficient
0.4
0.2
0
Wellhead
0
Collection
facility
0.5
1.0
1.5
2.0
Flowline distance, mi
69
High-pressure
flow-control
valves
Shear cell
Mechanical
mounting
stand
Variable-speed
DC motor
30
Multipoint
thermocouples
25
Inner
rotating
cylinder
Coolant
out
Deposit
Electrical
heating
cartridge
Outer
stationary
cylinder
Oil
Coolant
in
Coolant
Discharge
70
RealView cell
23.7
20
15.5
15
9.2
10
5
0
Charge
WDFL
24.5
3.3
STO,
laminar
STO,
laminar
STO,
turbulent
Live oil,
laminar
Live oil,
turbulent
> Wax-deposition behavior of waxy crude oil in the WDFL and RealView
apparatus. Engineers performed tests with dead and live oils. In laminar flow,
dead-oil wax-deposition rates were essentially the same in the WDFL and
the RealView cell. Turbulent flow in the RealView cell reduced the dead-oil
deposition rate substantially. Live-oil deposition rates in the RealView
apparatus were even lower for both flow regimes.
Oilfield Review