Aiits 1, Pt4 Paper Set A

FIITJEE - JEE (Advance)
PHYSICS, CHEMISTRY & MATHEMATICS

SET A
APT - 4
CODE: 080053.1
Time Allotted: 3 Hours
AIiTS - 1
Maximum Marks: 180
Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
You are not allowed to leave the Examination Hall before the end of the test.
INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer
OMR sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
1.
2.
3.
4.
5.
Attempt ALL the questions. Answers have to be marked on the OMR sheets.
This question paper contains Three Sections.
Section-1 is Physics, Section-2 is Chemistry and Section-3 is Mathematics.
Each section has one part: Part-A
Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.
B. Filling of OMR Sheet

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on
OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with HB pencil for each character of your Enrolment
No. and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
C. Marking Scheme For All Sections.

(i)
Part-A (01 08) contains 8 multiple choice questions which have only one correct answer. Each
question carries +3 marks for correct answer and 1 mark for wrong answer.
Part-A (09 16) contains 4 paragraphs with 2 questions based on each paragraph. Each question
has only one correct answer and each question carries +3 marks for correct answer and 1 mark for
wrong answer.
Part-A (17 20) contains 4 multiple choice questions which have one or more than one correct
answer. Each question carries +3 marks for correct answer. There is no negative marking.
Name of the Candidate :____________________________________________

Batch :____________________ Date of Examination :___________________
Enrolment Number :_______________________________________________
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AIiTS-PT-I-(Paper-1)-SET-A-CMP-IITJEE/13
SECTION 1 (Physics)
PART A
(Single Correct Choice Type)
This section contains 8 multiple choice questions. Each question has four choices (A), (B),
(C) and (D) out of which ONLY ONE is correct.
1.
Three small spheres A, B and C of masses 1kg, 2kg and

3kg are rotating with a circular disc with angular velocity 3
radian/sec and are connected with strings to O as shown in
figure. Coefficient of friction between spheres A, B, C and
disc is 0.4, 0.3 and 0.2 respectively.
=3 rad/sec
A
B
O
50cm
50cm
(A)
(B)
(C)
(D)
2.
Two blocks connected with the spring of force constant

100 N/m are given velocities 4i m/s and 3i m/s when
the spring is in natural length as shown in figure
(A)
(B)
(C)
(D)
3.
Friction force acting on sphere B is 6 N.

Tension in the string connecting sphere A and B is 9 N
Tension in the string connecting sphere C and O is 8 N
Data insufficient
C
100cm
4 m/s
3 m/s
5kg
2kg
The velocity of 2kg block is maximum when 5 kg block is at instantaneous rest.

The maximum and minimum velocities of 2kg block is 7i m/s and 3i m/s respectively.
The maximum and minimum velocities of 5kg block is 4 m/s and zero respectively.
All of the above
Two objects were projected simultaneously from the top of hills. One from (0, 0, 0)m, with velocity
15i 4j 3k m/s and the other from (15, 0, 0) m with speed 13 m/s. If the two object collides in
mid air. Then which of the following is incorrect (consider acceleration due to gravity in negative
z-direction)
(A) The velocity of other object is 12i 4j 3k m/s.
(B) The time after which collision occur is 5 seconds.
(C) The coordinates of point of collision is (75, 20, 110) m
(D) None of the above
Space for Rough work
4.
A block of mass 2kg starts moving at t = 0

with speed 2m/s on a smooth horizontal
surface. A horizontal force F is applied in
the direction of velocity which varies with
time shown in figure (b) the speed of
2
particle at t = 3 seconds (g = 10 m/s )
(A) 2.5 m/s
(C) 4.5 m/s
5.
6.
2kg
2m/s
qp
(a)
(B) 3.5 m/s
(D) none of these
In the figure, two point charges +q and q are placed on the xaxis at (+a, 0) and (-a, 0) respectively. A tiny dipole of dipole
moment (p) is kept at the origin along the y-axis. The torque on
the dipole equals
qp
(A) zero (B)
20 a2
40 a2
2N
O
A conducting sphere of radius r is carrying a charge Q on its outer

surface. Its inner surface is connected to the ground by means of
a wire of resistance R and a switch K as shown in the figure.
When the switch k is closed the quantity of charge flowing to the
ground equals
(A) Q (B) -Q
(C) zero
(D) -Q/2
(C)
7.
(D)
3 t (sec)
(b)
Q
r
k
R
P
O
-q (-a, 0)
+q (a, 0) x
qp
0 a2
In the figure, a square loop of side a and resistance R is moving in a

uniform and constant magnetic field B with constant velocity V. The
induced emf in the loop is equal to
(A) zero
(B) Bav
1
(C) Bav
(D) none of the above.
2
x
x
x
x
x x
B
x x
x
x
C
D x
8.
In the figure shown current in the long straight wire varies as
t t
I = I0 0
where Io is the initial current. The charge flown through
t0
resistance R in time t0 is
I b
bI0
(A) 0
(B) 0 0 ln
2 R a
2 R
I a b
aI b
(C) 0 0 ln
(D) 0 0 ln
2 R a
2 R
a
R
(Paragraph Type)
This section contains 4 paragraphs. Based upon each paragraph 2 multiple choice questions
have to be answered. Each of these questions has 4 choices (A), (B), (C) and (D) out of which
ONLY ONE is correct.
Paragraph for Questions 9 and 10
A driver moving on road ABC applies brakes so as to ensure constant
retardation throughout its motion. His speed is 27 m/s at the bottom (at
A) and 13 m/s at the top (at C). The distance of C from A along ABC is
2
80 m. The passenger experiences a total acceleration of 4.5 m/s at A
and radius of curvature at C is 130 m. DBE is a straight line
( 8 2.83, 13.94 3.7 )
9.
10.
The radius of curvature at A is

(A) 257.6 m
(C) 208.3 m
(B) 247.6 m
(D) 200.3 m
Magnitude of total acceleration at B is

2
(A) 3.5 m/s
2
(C) 4.5 m/s
(B) 3 m/s
2
(D) 3.7 m/s
C
E
B
A

If the forces are conservative and potential energy is U then we can find force (F) from potential energy U
dU
as
F . If potential energy of a body is minimum at equilibrium then this type of equilibrium is known
dr
as stable equilibrium. When potential energy of the body is constant then equilibrium is called as neutral
and when potential energy becomes maximum at equilibrium it is called as unstable equilibrium.
Equilibrium happens when force on the body becomes zero.
11.
If potential energy for a conservative system is given by U ax2 bx , where a and b are positive
b
constants. Then at x
a
(A) equilibrium is stable
(B) equilibrium is unstable
(C) equilibrium is neutral
(D) equilibrium is not possible
12.
If force on a body is F = 2x 1, the possible equilibrium is at

(A) x = 1 and stable
(B) x = and unstable
(C) x = and stable
(D) x = 1 and unstable
Four metallic plates are placed as shown in the figure. Plate 2 is given
a charge Q whereas all other plates are uncharged. Plates 1 and 4 are
earthed. The area of each plate is same.
13.
14.
The charge appearing on the right side of plate 3 is

(A) zero
(B) +Q/4
(C) 3Q/4
(D) Q/2
2d
The charge appearing on right side of plate 4 is

(A) zero
(B) Q/4
(C) 3Q/4
(D) Q/2

A long cylindrical conductor of radius R having a cylindrical cavity of
radius R/2 through out its length is lying with its axis parallel to x-axis.
The distance between the axes of the cylinder and the cavity is R/2. A
constant current I is passed through the cylinder along its length in the
positive x direction. The cross-sectional view of the cylinder is shown in
the figure.
15.
The magnetic induction at point on the cavity is

I
I
(A) 0 ( k)
(B) 0 (k)
3R
3R
0I
I
(C)
(B) 0 ( j)
( j)
6R
6R
16.
A charged particle having specific charge (charge to mass ratio) is
z
y
18
106 SI unit is projected
0I
6
from a point on the axis of the cavity along x-axis with the speed of 10 m/s. Radius of curvature
of the path of the particle is equal to
(A) R/18
(B) R/9
(C) R/6
(D) R/3
(Multi Correct Choice Type)

(C) and (D) out of which ONE OR MORE may be correct.
17.
A conducting wire of length and mass m can slide without friction

on two parallel rails and is connected to capacitance C. Whole
system lies in a magnetic field B and a constant force F is applied to
the rod. Then
(A) the rod moves with constant velocity
F
m B2 2 c
(C) there is constant charge on the capacitor.
(B) the rod moves with an acceleration of
(D) charge on the capacitor increases with time
B
C
18.
An electric kettle heater has two coils when one coil is switched on, the water in the kettle begins
to boil after 15 minutes, when the other coil is switched on the water boils in 30 minutes.
(A)
(B)
(C)
(D)
19.
The waver will boil in 45 minutes if the coils are connected in series.
The water will boil in 10 minutes if the coils are connected in parallel.
Water boils in 22.5 minutes if coils are connected in series.
Water boils in 20 minutes if coils are connected in parallel.
2kg
Coefficient of friction between the two blocks is 0.3

2
whereas the surface AB is smooth. (g =10 ms )
(A) Acceleration of the system of masses is 5.86 ms
(B) Tension T1 in the string is 17.7 N
(C) Tension T2 in the string is about 41.4 N
2
(D) Acceleration of 10 kg mass is 7.55 ms
T1
3kg
T2
10kg
20.
Two projectiles are thrown at the same time from two different points. The projectile thrown from
the origin has initial velocity 3i 3j with respect to earth. The projectile has initial velocity ai bj
with respect to earth thrown from the point (10, 5). ( i is a unit vector along horizontal, j along
vertical). If the projectiles collide after two second, then the
(A) value of a is -2
(C) value of b is
1
2
(B) value of a is
1
2
(D) value of b is 2
SECTION 2 (Chemistry)
PART A
1.
Give the correct increasing order of acid strength.

OH
OH
OH
OH
(I)
OMe
(II)
NO2
(III)
Cl
(IV)
(A) III > IV > I > II

(C) IV > I > II > III
2.
(B) IV > III > I > II

(D) I > II > III > IV
Which of the following will easily decarboxylate on heating?

O
O
(A)
OH
(B)
H3C
OH
CH3
H3C
(C)
OH
O
OH
OH
(D)
HO
H3C
O
3.
P4 O10
CH3MgBr
Yellow ppt. with
NH2
W
X
Y
Z
Ca OH , I2
H O
Final product Z will be

O
(A)
(B)
CH3
COOH
(C)
(D)
CH3
4.
CH3OH
(A) H3C
A (major product) . The product (A) is
O
CH CH2OH
(B) H3C
H3 C
5.
6.
(D)
CH2 CH2
OCH3
CH2
OCH3
OH
OCH3
(C) H2C
CH
CH
CH2
OH
OH
OH
Which of the following is Tshaped?

(A) XeOF2
(B) XeO3
(C) XeOF4
(D) XeF6
Equal masses of SO2 , CH4 and O2 are mixed in empty container at 298K, when total pressure
is 2.1 atm. The partial pressure of CH4 in the mixture is
(A) 0.5 atm
(B) 0.75 atm
(C) 1.2 atm
(D) 0.6 atm
7.
8.
10
rd
If the radius of first Bohr orbit is x, then de Broglie wavelength of electron in 3 orbit is nearly.
(A) 2x
(B) 6x
x
(C) 9x
(D)
3
N
If 10 ml of H2O2 solution of volume strength x, required 10 ml of
MnO4 solution is acidic
0.56
medium then x is
(A) 0.56
(B) 5.6
(C) 0.1
(D) 10
(Paragraph Type)
Hybridization in the mixing of atomic orbitals belonging to the same atom but having slightly different
energies so that a redistribution of energy takes place between them resulting in the formation of new
orbitals of equal energies and identical shapes.
Hybridization is used for explaining the geometry molecules. There are several type of hybridization like
2
3
3
3 2
3 3
sp, sp , sp , sp d, sp d , sp d etc.
9.
Among the compounds BF3, NCl3, H2S, SF4 & BeCl2 identify the ones in which the central atom
has the same type of hybridization
(A) BF3, NCl3
(B) H2S and BeCl2
(C) SF4 and BeCl2
(D) NCl3 and H2S
10.
Pair of species having identical shapes for molecule is

(A) CF4, SF4
(B) BF3, PH3
(C) XeF2, CO2
(D) PF5, IF5
11

The salts of alkali metals are ionic and soluble in water. The solubility of an ionic compound depends on
two factors: (i) Lattice energy and (ii) Hydration energy. These two factors oppose each other. If hydration
energy is high, the ions will have greater tendency to be hydrated and therefore the solubility will be high.
The smaller the cation, the greater is the degree of its hydration. Hydration of ions is an exothermic
process. Higher is the energy released if greater is the degree of hydration. Reducing power of alkali
metals in solutions is also dependent on the hydration energy besides other factors.
11.
The radius of which ion (hydrated) is lowest?

+
(B) [Na(aq.)]
(D) [Cs(aq.)]
(A) [Li(aq.)]
(C) [K(aq.)]
12.
Strongest reducing agent amongst alkali metals in aqueous solutions is

(A) Li
(B) Na
(C) K
(D) Cs
12

Aldehydes undergo disproportionation reaction in presence of aqueous NaOH. Simultaneous oxidation
and reduction of a compound is scientifically called as disproportionation.
Aldehydes having no -hydrogen show this reaction called Cannizzaros reaction. Few exception are also
there to this generalization.
The reaction may be represented as:
NaOH
C6H5 CHO C6H5CHO
C6H5COONa C6H5CH2OH
Answer the following questions:
13.
The product formed in the following reaction will be

CHO
NaOH
Product
CHO
(A) CH2OH
(B) CH2OH
COONa
(D) All of these
CH2OH
(C) COONa
COONa
14.
Which of the following compounds gives intramolecular Cannizzaro reaction?

O
O
(A) H C
5 6
CH2 C
CHO
(C)
CHO
(B) H C
C
5 6
CHO
(D) H C
2
CHO
CHO
13

A reaction characteristic of vicinal diols is their oxidative cleavage on treatment with periodic acid (HIO 4).
The carbon-carbon bond of the vicinal diol unit is broken and two carbonyl groups result. Periodic acid is
reduced to iodic acid (HIO3).
R'
R'
R
O+
R' + HIO4
O + HIO3 + H2O
R'
OH OH
Cyclic diols react to give dicarbonyl compounds. The reaction are faster when the hydroxyl groups are cis
than when they are trans but both stereoisomers are oxidized by periodic acid. Periodic acid cleavage of
vicinal diols is often used for analytic purposes as an aid in structure determination. By identifying the
carbonyl compounds produced, the constitution of the diol may be deduced.
15.
Which of the following compound(s) is/are obtained when the following compound is oxidized by
HIO4?
CH3
CH
CH3
OH OH
O
(A)
(B) H3C
16.
O
(C)
CH3
(D) H3C
Which of the following products is/are obtained when glycerol is treated with HIO 4?
(A) HCHO
(B) HCOOH
(C) HIO3
(D) All of these
14

17.
Which of the following molecules is/are tetrahedral?

(B) NH4
(D) CH4
(A) XeF4
(C) CCl4
18.
Which of the following ethers are cleaved by hot conc. HI?

O
(A)
(B)
CH3
(C)
19.
(D)
Which of the following amines can be resolved into two enantiomers?
(A)
(B)
H
H
(A)
(B)
NH2
N
(C)
(D)
H
20.
Mixture of C6H5CHO and HCHO is treated with NaOH then Cannizzaro reaction involves
(A) oxidation of HCHO
(C) oxidation of C6H5CHO
(B) reduction of HCHO

(D) reduction of C6H5CHO
15
SECTION 3 (Mathematics)
PART A
1.
An equilateral triangle is inscribed in a circle of radius r. P is any point inside triangle.

Perpendiculars are dropped from P to the sides. The sum of the lengths of the perpendiculars
is
3
(A) 3r
(B) r
2
(C) 9r
(D) none of these
2.
The set of solution |x + x| = x + x is given by
(B) [0, )
(D) (-, -1] [0, )
(A) (-, -1)

(C) [-1, 0]
3.
The chords of contact of the pair of tangents drawn from each point on the line 2x + y = 4 to x +
2
y = 1 pass through the point
1 1
(A) (1, 2)
(B) ,
2 4
(C) (2, 4)
(D) none of these
4.
Let y = f(x) be a continuous and differentiable curve. The normals at (1, f(1)), (2, f(2)) and (3, f(3))

make angles , and

with positive x-axis respectively. Then value of
3 4
6
2
f x xf x dx f x f x dx is equal to
(B) 2f(2) f(1) + 1
(D) none of these
(A) f(2) + f(1) + 1

(C) f(3) f(2) + 1
5.
lim
tan sec 2 x
x 0
(A)
(C) 0
x sin1 x
is equal to
(B)
(D) none of these
16
sin1 / 4
6.
If
4 sin sin 2 ln (1 + tan (sin )) d is k, then

0
(A) 11
(C) 12
960k
is equal to
3 ln 2
(B) 10
(D) none of these
7.
If A cos x = cos (x + ) + B is an identity in x, then the number of values of ordered triplet (A,
cos, B) is
(A) 0
(B) 1
(C) 2
(D) 3
8.
Let f(x) = | x | {x} (where {.} denotes the fractional part of x) and X, Y and its domain and range
respectively, then
1
1
(A) f : X Y y = f (x) is one-one function

(B) ) x , 0, and Y ,
2
(C) X , 0, and Y [0, )

2
(D) none of these
(Paragraph Type)
A triangle ABC is given where vertex A is (1, 1) and the orthocenter is (2, 4). Also sides AB and BC are
members of the family of lines ax + by + c = 0 where a, b, c are in A.P.
9.
The vertex B is
(B) (1, 2)
(D) none of these
(A) (2, 1)
(C) (1, 2)
10.
The coordinate of the circumcentre is

(A) (6, 1)
17 1
(B) ,
2 4
17 1
(C) ,
2 2
(D) none of these
17

A circle C whose radius is 1 unit, touches the xaxis at point A. The centre Q of C lies in first quadrant.
The tangent from origin O to the circle touches it at T and a point P lies on it such that OAP is a right
angled triangle at A and its perimeter is 8 units.
11.
12.
The length of QP is
1
(A)
2
5
(C)
3
(B)
4
3
(D) none of these.
Equation of circle C is
(A) {x (2 3)}2 (y 1)2 1
(B) {x ( 3 2)}2 (y 1)2 1
(C) (x 3)2 (y 2)2 1
(D) none of these.
Let n be a positive integer such that In = xn a2 x 2 dx , then answer the following questions:
13.
The value of I1 is
1/ 2
2
(A) a2 x 2
3
3/2
2
(C) a2 x 2
3
3/2
1 2
a x2
3
3/2
1
(D) a2 x 2
3
(B)
xn1 a2 x2
n2
n 1
(A)
n2
n 1 2
(C)
a
n 2
3/2
14.
If In =
kIn2 , then the value of k is

n2
n 1
n 2 2
(D)
a
n 1
(B)
18
If f(x) is a differentiable function wherever it is continuous and f(c1) = f(c2) = 0, f(c1) . f(c2) < 0,
f(c1) = 5,
f(c2) = 0 and (c1 < c2).
15.
If f(x) is continuous in [c1, c2] and f(c1) f(c2) > 0, then minimum number of roots of f(x)
= 0 in [c1 1, c2 + 1] is
(A) 2
(C) 4
16.
(B) 3
(D) 5
If f(x) is continuous in [c1, c2] and f(c1) f(c2) < 0, then minimum number of roots of f(x)
= 0 in [c1 1, c2 + 1] is
(A) 1
(C) 3
(B) 2
(D) 4
19

17.
Two circles C1 and C2 intersect at two distinct points P, Q in a plane. Let a line passing through P
meets the circles C1 and C2 in A and B respectively. Let Y be the mid point of AB and QY meet
the circles C1 and C2 in X and Z respectively, then
XY 2
(A) Y is the mid point of XZ
(B)
YZ 1
(C) YX = YZ
(D) XY + YZ = 3YZ
18.
If x1 and x2 are positive numbers between 0 and 1, then which of the following is/are true?
x x 2 sin x1 sin x 2
x x 2 tan x1 tan x 2
(A) sin 1
(B) tan 1
2
2
2
2
x x2
(C) log 1
2
log x1 log x 2
x2 x22
x x2
(D) 1
1
2
2
10
19.
If R [0, ] for 1 k 10, then the maximum value of
(1 sin
R )(1 cos2 R ) is
R 1
10
9
(B)
4
20
9
(D)
4
3
(A)
2
3
(C)
2
20.
10
If y is a function of x given by 2log(y 1) log x log(y 2) = 0, then

(A) domain is [4, )
(C) range is (2, )
(B) domain is (0, )

(D) range is (0, )

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FIITJEE - JEE (Advance)

PHYSICS, CHEMISTRY & MATHEMATICS

Time Allotted: 3 Hours

B. Filling of OMR Sheet

C. Marking Scheme For All Sections.

Name of the Candidate :____________________________________________

Three small spheres A, B and C of masses 1kg, 2kg and

Two blocks connected with the spring of force constant

Friction force acting on sphere B is 6 N.

The velocity of 2kg block is maximum when 5 kg block is at instantaneous rest.

A block of mass 2kg starts moving at t = 0

A conducting sphere of radius r is carrying a charge Q on its outer

In the figure, a square loop of side a and resistance R is moving in a

Space for Rough work

In the figure shown current in the long straight wire varies as

The radius of curvature at A is

Magnitude of total acceleration at B is

Space for Rough work

Paragraph for Questions 11 and 12

If force on a body is F = 2x 1, the possible equilibrium is at

The charge appearing on the right side of plate 3 is

The charge appearing on right side of plate 4 is

Space for Rough work

Paragraph for Questions 15 and 16

The magnetic induction at point on the cavity is

A charged particle having specific charge (charge to mass ratio) is

(Multi Correct Choice Type)

A conducting wire of length and mass m can slide without friction

(B) the rod moves with an acceleration of

(D) charge on the capacitor increases with time

Space for Rough work

Coefficient of friction between the two blocks is 0.3

Space for Rough work

Give the correct increasing order of acid strength.

(A) III > IV > I > II

(B) IV > III > I > II

Which of the following will easily decarboxylate on heating?

Space for Rough work

Final product Z will be

A (major product) . The product (A) is

Which of the following is Tshaped?

Space for Rough work

Pair of species having identical shapes for molecule is

Space for Rough work

Paragraph for Questions 11 and 12

The radius of which ion (hydrated) is lowest?

Strongest reducing agent amongst alkali metals in aqueous solutions is

Space for Rough work

Paragraph for Questions 13 and 14

Answer the following questions:

The product formed in the following reaction will be

Which of the following compounds gives intramolecular Cannizzaro reaction?

Space for Rough work

Paragraph for Questions 15 and 16

(Multi Correct Choice Type)

Which of the following molecules is/are tetrahedral?

Which of the following ethers are cleaved by hot conc. HI?

Which of the following amines can be resolved into two enantiomers?

(B) reduction of HCHO

An equilateral triangle is inscribed in a circle of radius r. P is any point inside triangle.

The set of solution |x + x| = x + x is given by

(A) (-, -1)

make angles , and

(A) f(2) + f(1) + 1