First Law of Thermodynamics

dE=Q+ W

2.A.1

dE=dU + d E K +d E P

2.D.9

dU
=Q+ W
dt

2.D.14

~
C
= ~P
CV
~
dU =n CV dT
~
U =W =n C V ( T 2T 1)

(
)
+W
+ m
^ + 1 v +g z
(H
=Q
)
2

2
j

S
U

( )

dU +

S
xj

( )

d xj

U , xi j

Qj
d S = S^ i d mi+
+ d S gen
Tj

Q
dS
= m
i S^ i+ j + S gen
dt
Tj

T2
V
= 2
T1
V1

T2
P
= 2
T1
P1

( )( )
( )( )
( )( )

j 2.G.29

Second Law of Thermodynamics

dS=

2.I.35

Closed System Adiabatic Processes

^ j+ 1 v 2j + g z j d2.G.29
d E = Q + W + H
mj
2
dU
dt

2.I.35

P2
V
= 2
P1
V1

3.A.4

2.I.37

2.I.35
1

2.I.36

2.I.36

3.B.14

3.B.15

Legendre Transforms

y(0) =U ( x 1 , x 2 , , x m )

Newtons Law of Cooling

Q=hA
(T T j )

2.I.39

4.C.10

d y(0)=i d xi

4.C.11

Types of Work

W = F j d x j

2.B.2

Pressure-Volume

PdV

2.B.2

Surface

s dA

2.B.3

Polarization

d( V D)

2.B.3

y ( 0)
d xi

( )

i=

x j i

y = y i x i
(k )

(0 )

4.C.10

i=1

d y(k) = x i d i +
i=1

i=k +1

i d xi

4.C.11

Magnetization

d ( V B )
H

2.B.5

Stress-Strain

V xd x

2.B.6

dU =TdSPdV

Chemical Work

i d n i

2.B.7

H=U + PV

4.C.14

dH=TdS+VdP

4.C.14

A=U TS

4.C.15

dA=SdT PdV

4.C.15

G=U TS+ PV

4.C.16

dG=SdT +VdP

4.C.16

Heat Capacities

Q
~
C i=
dT

( )

2.D.10

Ideal Gas Properties

PV =nRT

dU
~
CV =
dT

( )
dH
~
C =(
dT )
P

2.I.35

2.D.10

2.D.13

Thermodynamic State Functions

Fundamental Property & Maxwell Relations

U
T
P
=T
=P (
=(
( U
)
(
)
)
S
V
V
S )
V

( HS ) =T ( HP ) =V ( TP ) =( VS )
( TA ) =S ( VA ) =P ( V S ) =( TP )
G
S
V
=S (
=V
(
=(
( G
)
)
)
T
P
P
T )
P

Partial Derivative Properties

( xy ) ( yz ) ( xz ) =1
w

( xy ) ( yz ) ( xz ) =1
z

For x=f(w,y), y=f(w,z)

( wx ) =( wx ) +( xy ) ( wy )
z