log DHOX' vs pH

2
log DHOX'
0
0

-2

-4

-6
pH

10

11

12

13

14

Coeficiente de reparto de la Ditizona en funcin del pH

pKa1

4.5 Ka1

Vf. Orgnica [mL]

3.1623E-005

Vf.acuosa [mL]
log

5.7 DHOX

HDZ

[H3O+]

pH
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1
1.1
1.2
1.3
1.4
1.5
1.6
1.7
1.8
1.9
2
2.1
2.2
2.3
2.4
2.5
2.6
2.7
2.8
2.9
3
3.1
3.2
3.3
3.4

1
0.79432823
0.63095734
0.50118723
0.39810717
0.31622777
0.25118864
0.19952623
0.15848932
0.12589254
0.1
0.07943282
0.06309573
0.05011872
0.03981072
0.03162278
0.02511886
0.01995262
0.01584893
0.01258925
0.01
0.00794328
0.00630957
0.00501187
0.00398107
0.00316228
0.00251189
0.00199526
0.00158489
0.00125893
0.001
0.00079433
0.00063096
0.00050119
0.00039811

DHDZ'
501171.385
501167.282
501162.116
501155.613
501147.426
501137.12
501124.146
501107.813
501087.254
501061.373
501028.794
500987.787
500936.171
500871.205
500789.442
500686.547
500557.07
500394.162
500189.225
499931.463
499607.337
499199.883
498687.874
498044.783
497237.535
496224.984
494956.105
493367.88
491382.857
488906.459
485824.126
481998.527
477267.21
471441.299
464306.09

501187.234

log DHDZ'
5.69998627
5.69998271
5.69997823
5.6999726
5.6999655
5.69995657
5.69994533
5.69993117
5.69991336
5.69989092
5.69986269
5.69982714
5.69978239
5.69972607
5.69965516
5.69956592
5.6994536
5.69931223
5.69913433
5.69891047
5.69862881
5.69827447
5.69782881
5.6972684
5.69656391
5.69567863
5.69456669
5.69317087
5.69142
5.68922577
5.68647908
5.68304571
5.6787616
5.67342762
5.66680438

%RL

pDz'
99.9996009 10.2980191
99.9996009 10.2980156
99.9996009 10.2980111
99.9996009 10.2980054
99.9996009 10.2979983
99.9996009 10.2979894
99.9996009 10.2979782
99.9996009 10.297964
99.9996009 10.2979462
99.9996008 10.2979238
99.9996008 10.2978955
99.9996008
10.29786
99.9996007 10.2978152
99.9996007 10.2977589
99.9996006 10.297688
99.9996006 10.2975988
99.9996004 10.2974864
99.9996003 10.2973451
99.9996002 10.2971672
99.9995999 10.2969433
99.9995997 10.2966617
99.9995994 10.2963073
99.9995989 10.2958617
99.9995984 10.2953013
99.9995978 10.2945968
99.999597 10.2937115
99.9995959 10.2925996
99.9995946 10.2912037
99.999593 10.2894529
99.9995909 10.2872587
99.9995883 10.284512
99.9995851 10.2810786
99.9995809 10.2767945
99.9995758 10.2714606
99.9995693 10.2648374

3.5
3.6
3.7
3.8
3.9
4
4.1
4.2
4.3
4.4
4.5
4.6
4.7
4.8
4.9
5
5.1
5.2
5.3
5.4
5.5
5.6
5.7
5.8
5.9
6
6.1
6.2
6.3
6.4
6.5
6.6
6.7
6.8
6.9
7
7.1
7.2
7.3
7.4
7.5
7.6
7.7
7.8
7.9

0.00031623
0.00025119
0.00019953
0.00015849
0.00012589
0.0001
7.9433E-005
6.3096E-005
5.0119E-005
3.9811E-005
3.1623E-005
2.5119E-005
1.9953E-005
1.5849E-005
1.2589E-005
0.00001
7.9433E-006
6.3096E-006
5.0119E-006
3.9811E-006
3.1623E-006
2.5119E-006
1.9953E-006
1.5849E-006
1.2589E-006
0.000001
7.9433E-007
6.3096E-007
5.0119E-007
3.9811E-007
3.1623E-007
2.5119E-007
1.9953E-007
1.5849E-007
1.2589E-007
0.0000001
7.9433E-008
6.3096E-008
5.0119E-008
3.9811E-008
3.1623E-008
2.5119E-008
0.00000002
1.5849E-008
1.2589E-008

455624.758
445146.597
432621.368
417820.987
400568.88
380775.46
358475.548
333860.575
307296.347
279317.476
250593.617
221869.758
193890.887
167326.658
142711.686
120411.773
100618.353
83366.2469
68565.866
56040.6363
45562.4758
36881.1437
29745.935
23920.0233
19188.707
15363.1078
12280.775
9804.37696
7819.35394
6231.12819
4962.24984
3949.69814
3142.45014
2499.35996
1987.35053
1579.89712
1255.77106
998.008711
793.071301
630.164015
500.686547
397.791194
316.028366
251.062814
199.44683

5.65860731
5.64850306
5.63610797
5.62099025
5.60267721
5.58066895
5.55445954
5.52356514
5.4875574
5.44609811
5.39897
5.34609811
5.2875574
5.22356514
5.15445954
5.08066895
5.00267721
4.92099025
4.83610797
4.74850306
4.65860731
4.56680438
4.47342762
4.3787616
4.28304571
4.18647908
4.08922577
3.99142
3.89317087
3.79456669
3.69567863
3.59656391
3.4972684
3.39782881
3.29827447
3.19862881
3.09891047
2.99913433
2.89931223
2.7994536
2.69956592
2.59965516
2.49972607
2.39978239
2.29982714

99.999561
99.9995507
99.9995377
99.9995213
99.9995007
99.9994748
99.9994421
99.999401
99.9993492
99.999284
99.9992019
99.9990986
99.9989685
99.9988047
99.9985986
99.9983391
99.9980123
99.997601
99.9970832
99.9964313
99.9956106
99.9945775
99.9932768
99.9916395
99.9895783
99.9869835
99.983717
99.9796051
99.974429
99.9679134
99.9597119
99.9493888
99.9363959
99.9200435
99.8994647
99.8735695
99.8409885
99.8000017
99.7484502
99.6836264
99.6021378
99.4997389
99.3711253
99.2096824
99.0071822

10.2566403
10.2465361
10.2341411
10.2190234
10.2007105
10.1787023
10.1524931
10.1215989
10.0855913
10.0441323
9.99700458
9.94413314
9.88559299
9.82160144
9.75249674
9.67870728
9.60071695
9.51903178
9.43415175
9.34654967
9.25665749
9.16485904
9.07148794
8.97682902
8.88112209
8.78456672
8.68732761
8.5895397
8.49131305
8.39273717
8.29388474
8.19481487
8.09557583
7.99620731
7.89674243
7.79720935
7.69763271
7.5980349
7.49843719
7.39886088
7.29932838
7.19986434
7.10049697
7.00125944
6.90219155

8
8.1
8.2
8.3
8.4
8.5
8.6
8.7
8.8
8.9
9
9.1
9.2
9.3
9.4
9.5
9.6
9.7
9.8
9.9
10
10.1
10.2
10.3
10.4
10.5
10.6
10.7
10.8
10.9
11
11.1
11.2
11.3
11.4
11.5
11.6
11.7
11.8
11.9
12
12.1
12.2
12.3
12.4

0.00000001
7.9433E-009
6.3096E-009
5.0119E-009
3.9811E-009
3.1623E-009
2.5119E-009
1.9953E-009
1.5849E-009
1.2589E-009
1.0000E-009
7.9433E-010
6.3096E-010
5.0119E-010
3.9811E-010
3.1623E-010
2.5119E-010
1.9953E-010
1.5849E-010
1.2589E-010
1E-010
7.9433E-011
6.3096E-011
5.0119E-011
3.9811E-011
3.1623E-011
2.5119E-011
1.9953E-011
1.5849E-011
1.2589E-011
1E-011
7.9433E-012
6.3096E-012
5.0119E-012
3.9811E-012
3.1623E-012
2.5119E-012
1.9953E-012
1.5849E-012
1.2589E-012
1E-012
7.9433E-013
6.3096E-013
5.0119E-013
3.9811E-013

158.439216
125.860926
99.9800514
79.4202362
63.0877922
50.113712
39.807555
31.6207815
25.1176055
19.9518289
15.8484308
12.5889379
9.99980048
7.94315646
6.30949401
5.01182222
3.98104008
3.16225771
2.51187384
1.99525437
1.58488818
1.25892225
0.999998
0.79432698
0.63095655
0.50118673
0.39810685
0.31622757
0.25118852
0.19952615
0.15848927
0.12589251
0.09999998
0.07943281
0.06309573
0.05011872
0.03981071
0.03162277
0.02511886
0.01995262
0.01584893
0.01258925
0.01
0.00794328
0.00630957

2.19986269
2.09989092
1.99991336
1.89993117
1.79994533
1.69995657
1.5999655
1.4999726
1.39997823
1.29998271
1.19998627
1.09998909
0.99999133
0.89999312
0.79999453
0.69999566
0.59999655
0.49999726
0.39999782
0.29999827
0.19999863
0.09999891
-8.665E-007
-0.10000069
-0.20000055
-0.30000043
-0.40000034
-0.50000027
-0.60000022
-0.70000017
-0.80000014
-0.90000011
-1.00000009
-1.10000007
-1.20000005
-1.30000004
-1.40000003
-1.50000003
-1.60000002
-1.70000002
-1.80000001
-1.90000001
-2
-2.10000001
-2.20000001

98.753422
98.4358005
98.0388321
97.5436082
96.9272272
96.1622385
95.2161756
94.0512983
92.6247175
90.8891418
88.7945331
86.2909828
83.3330562
79.885663
75.9311458
71.476744
66.5609999
61.2572616
55.6725194
49.9406092
44.2102543
38.6300179
33.333289
28.4264148
23.9820209
20.0379574
16.6008805
13.6526985
11.1580401
9.07132438
7.34260167
5.92186618
4.76190386
3.81992678
3.05830339
2.44467395
1.95168667
1.55652787
1.24036488
0.98777675
0.78621623
0.62552524
0.49751243
0.39559296
0.31448653

6.80334164
6.70476896
6.60654634
6.50876347
6.41153065
6.31498312
6.21928588
6.12463892
6.03128245
5.93950182
5.84963115
5.76205479
5.67720514
5.59555539
5.51760569
5.44386201
5.37480783
5.31087079
5.25238806
5.19957555
5.15250673
5.11110511
5.07515208
5.04430834
5.01814479
4.99617723
4.97789964
4.96281234
4.95044298
4.94036024
4.93218101
4.92557241
4.9202504
4.915976
4.91255049
4.90981012
4.90762098
4.90587418
4.90448163
4.9033723
4.9024891
4.90178626
4.90122717
4.90078255
4.90042906

12.5
12.6
12.7
12.8
12.9
13
13.1
13.2
13.3
13.4
13.5
13.6
13.7
13.8
13.9
14

3.1623E-013
2.5119E-013
1.9953E-013
1.5849E-013
1.2589E-013
1E-013
7.9433E-014
6.3096E-014
5.0119E-014
3.9811E-014
3.1623E-014
2.5119E-014
1.9953E-014
1.5849E-014
1.2589E-014
1E-014

0.00501187
0.00398107
0.00316228
0.00251189
0.00199526
0.00158489
0.00125893
0.001
0.00079433
0.00063096
0.00050119
0.00039811
0.00031623
0.00025119
0.00019953
0.00015849

-2.3
-2.4
-2.5
-2.6
-2.7
-2.8
-2.9
-3
-3.1
-3.2
-3.3
-3.4
-3.5
-3.6
-3.7
-3.8

0.24996721
0.19865815
0.15786428
0.12543678
0.09966369
0.07918191
0.06290667
0.04997501
0.03970064
0.03153792
0.02505308
0.0199014
0.01580889
0.01255785
0.00997532
0.00792384

4.90014806
4.89992473
4.89974725
4.89960621
4.89949416
4.89940513
4.89933439
4.8992782
4.89923356
4.8991981
4.89916993
4.89914755
4.89912977
4.89911565
4.89910443
4.89909552

Co Dz'

2.52E-05

n*DZ'

10

0.00012617

0.5

log DHOX' vs pH
8

2
log DHOX'
0
0

-2

-4

-6
pH

%RL vs pH r=0.5
100
90
80
70
60
%RL

50
40
30

10

11

80
70
60
%RL

50
40
30
20
10
0
0

10

11

12

pH

pDz' vs pH
11
10
9
8
pDz'

7
6
5
4
0

8
pH

10

12

13

s pH

10

11

12

13

14

10

10

11

12

12

13

14

14

pH

abs fase orgaabs acuosa %R

1.31
1.19
0.002 105.309735
2.89
0.752
0.009 66.5486726
4.23
0.72
0.01 63.7168142
5.67
0.702
0.012 62.1238938
6.07
0.668
0.014 59.1150442
6.97
0.654
0.015 57.8761062
12.48
0.009
0.027 0.79646018

120
100
80
60
40
20
0
0

A
1.2

0.8

0.6

0.4

0.2

0
0

0
0

120
100
80
60
40
20
0
0

%R vs pH
120
100
80
60
40
20
0
0

10

12

14

A vs pHexperimental
1.2

0.8

0.6

0.4

0.2

0
0

10

pH
A f. orgnica

A. f. acuosa

12

14

0
0

10

12

14

pH
A f. orgnica

A. f. acuosa

%R vs pH

20

00

80

60

40

20
0
0

6
Experimental

10
Terico

12

14