S GD&T HAI DNG

TRNG THPT OAN THNG

KIM TRA KIN THC LN I

NM HC 2015-2016
Mn: Ha hc Khi 12 (thi gian lm bi 90 phut)

Cu 1 (2,0 im) Vit cac phng trinh phan ng trong cac trng hp sau:
1/ C2H5OH + Na.
5/ Thuy phn hoan toan tinh b t (H+, to).
2/ CH3CHO + AgNO3 (NH3, to).
6/ Glucoz + H2 (Ni, to).
3/ Dung dich CH3COOH + NaHCO3.
7/ C3H5(OOCC17H33)3 + H2 d (Ni, to).
4/ CH3COOC2H5 + ddKOH (to).
8/ Thuy phn HCOOCH3 trong mi trng axit.
Cu 2 (2,0 im)
1/ Bng phng phap ha hc hy trinh bay cach nhn bit 3 dung dich sau: glucoz, saccaroz
fructoz.
2/ Cho m t axit cacboxylic n chc X tac dung va u vi 100 ml ddNaOH 1M. Sau phan ng thu
c 8,2 gam mui. Xac inh CTCT cua X va gi tn X.
Cu 3 (2,0 im)
1/ Vit cac phng trinh phan ng iu ch:
a/ Axit axetic t anehit axetic.
b/ Etyl axetat t ancol etylic.
c/ Ancol etylic t glucoz.
Cac cht v c va cac iu ki n cn thit khac c u.
2/ t chay hoan toan 0,1 mol m t este X, cn 0,5 mol khi O2, thu c s mol CO2 bng s mol
H2O. Xac inh CTPT cua X, vit cac CTCT cua X va gi tn.
Cu 4 (2,0 im)
1/ Cho hn hp Y gm 0,1 mol glucoz, 0,05 mol anehit fomic, 0,02 mol etyl fomat tac dung vi
lng d AgNO3 (NH3, to). Sau cac phan ng hoan toan, thu c m gam kt tua va m 1 gam hn hp
mui hu c. Vit cac phng trinh phan ng, tinh m va m1.
2/ Tinh s mg KOH dng chuyn ht 1 gam cht bo cha 2,84% axit stearic; 93,45% tristearin,
cn li la tp cht tr thanh xa phng.
Cu 5 (2,0 im)
1/ un nng m gam mt este X n chc, mch h vi 200ml dung dich NaOH aM, phan ng xong
trung ha lng NaOH d cn 25 gam dung dich HCl 14,6%. Chng ct dung dich sau trung ha
c 15,25 gam mui khan va hi ancol Y. Oxi ha ht Y bng CuO d nung nng c anehit Z.
Cho Z tac dung vi lng d dung dich AgNO 3/NH3 thu c 43,2 gam Ag. Xac inh cng thc cua
X va tinh a.
2/ Cho hai cht hu c X va Y u ch cha C, H, O trong C chim 40%; O chim 53,33% theo
khi lng. Khi t chay hoan toan 0,02 mol hn hp X va Y cn 0,05 mol oxi. Khi lng phn t
cua Y gp 1,5 ln khi lng phn t X. Khi cho s mol bng nhau cua X va Y tac dung vi dung
dich NaOH thi Y to ra khi lng mui gp 1,647 ln khi lng mui to ra t X. Xac inh cng
thc n gian, cng thc phn t, cng thc cu to cua X va Y, bit rng khi un nng Y vi CuO
to ra san phm c kha nng tham gia phan ng trang bc.
Cho: H=1, C=12, N=14, O=16, Na=23, Cl=35,5, K=39, Cu=64, Ag=108..

AP AN VA BIU IM
Cu

1
1
2
2

1
3
2

1
4
2

5
2

ap an
2,0 im
Vit ung 01 phng trinh
1,0 im
Nh n bit glu, vit pt
Nh n bit fruc, vit pt
Sac cn li
1,0 im
Gi CT, vit pt
Xac inh CT CH3COOH, gi tn
1,0 im
iu ch CH3COOH t CH3CHO
iu ch CH3COOC2H5 t C2H5OH
iu ch C2H5OH t C6H12O6
1,0 im
Xac inh este no, n chc, h
Gi CT, vit pt
Xac inh CTPT C4H8O2, vit cac CTCT va gi tn
1,25 im
Vit 3 pt
Tinh m = 47,52 gam
Tinh m1 = 23,44 gam
0,75 im
CH3COOH = 71/150000 mol; tristearin = 0,00105 mol
Vit pt
Tinh lng KOH = 202,9 mg
1,0 im
Tinh NaOH d = HCl = 0,1 mol, NaCl = 0,1 mol
Xt TH ancol CH3OH, xac inh c este CH2 = CH -COO-CH3
Tinh a = 1M
Xt TH ancol khac CH3OH, khng TM
1,0 im
Xac inh c cng thc n gian cua X va Y u la CH 2O
Xac inh c CTPT cua X la (CH2O)2 hay C2H4O2
CTPT cua Y la (CH2O)3 hay C3H6O3
- Vi ca X va Y u phan ng vi NaOH to mui X va Y ch c th la axit
hoc este.
- Vi X c th c hai cng thc cu to HCOOCH 3 hoc CH3COOH hay
RCOOR (R = CH3 ; H); phn t Y ch cha ba nguyn t oxi nn Y cng ch
c th cha mt nhm este. t Y la R1COOR2.
RCOOR + NaOH RCOONa + ROH
R1COOR2 + NaOH R1COONa + R2OH
Theo bai c: (R1 + 67) = 1,647 (R + 67) R1 = 1,647R + 43,45
- Khi X la CH3COOH R = 15 ; R1 = 68 MY = 102 + R2 >

Biu im
0,25
0,5
0,5
0,5
0,5
0,25
0,25/1
0,25
0,25
0,25
0,5
0,75
0,25
0,25
0,25
0,25
0,25
0,25
0,25
0,25
0,25
0,25
0,25

0,25

(loi)

- Khi X la HCOOCH3 thi R = 1 ; R1 = 45 MY = 45 + 44 + R2 = 90

R2 la H ; R1 phai cha mt nguyn t oxi va Y bi oxi ha bi CuO to ra
anehit Y c nhm chc ancol b c 1
V y CTCT cua Y la: HO CH2 CH2 COOH; X la : HCOOCH3

0,25